• Title/Summary/Keyword: dual membrane process

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Characteristics of residuals from the 2nd-stage microfiltration in a dual membrane process (침지식 2단 막여과 고도 정수처리 시스템의 최종배출수 특징)

  • Lee, Seung Ryul;Kweon, Ji Hyang;Hur, Hyung Woo;Yeon, Kyeong Ho;Park, Ki Young
    • Journal of Korean Society of Water and Wastewater
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    • v.23 no.1
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    • pp.31-37
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    • 2009
  • Low-pressure membrane processes have been extensively expanded their applications to drinking water production in a few decades. As a capacity of a membrane plant becomes greater in recent years, proper methods to increase water production as well as to treat residuals have drawn great attention. A possible treatment option for the better water production is to apply a dual membrane system. The second stage microfiltration was installed and operated for approximately six months. The residuals from the two stage microfiltration were investigated to learn their characteristics in settling and dewatering processes. The settlability of the membrane residuals were greatest at the SS concentration of approximately 15000mg/L. The proper dose of the polyelectrolytes for filterability were obtained in the range of 0.5~1%. In the dosage range, the water contents of the membrane residuals were greater but the SRF were lower than the residual from the conventional process.

Optimization and modification of PVDF dual-layer hollow fiber membrane for direct contact membrane distillation; application of response surface methodology and morphology study

  • Bahrami, Mehdi;Karimi-Sabet, Javad;Hatamnejad, Ali;Dastbaz, Abolfazl;Moosavian, Mohammad Ali
    • Korean Journal of Chemical Engineering
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    • v.35 no.11
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    • pp.2241-2255
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    • 2018
  • RSM methodology was applied to present mathematical models for the fabrication of polyvinylidene fluoride (PVDF) dual-layer hollow fibers in membrane distillation process. The design of experiments was used to investigate three main parameters in terms of polymer concentration in both outer and inner layers and the flow rate of dope solutions by the Box-Behnken method. According to obtained results, the optimization was done to present the proper membrane with desirable properties. The characteristics of the optimized membrane (named HF-O) suggested by the Box-Behnken (at the predicted point) showed that the proposed models are strongly valid. Then, a morphology study was done to modify the fiber by a combination of three types of a structure such as macro-void, sponge-like and sharp finger-like. It also improved the hydrophobicity of outer surface from 87 to $113^{\circ}$ and the mean pore size of the inner surface from 108.12 to 560.14 nm. The DCMD flux of modified fiber (named HF-M) enhanced 62% more than HF-O when it was fabricated by considering both of RSM and morphology study results. Finally, HF-M was conducted for long-term desalination process up to 100 hr and showed stable flux and wetting resistance during the test. These stepwise approaches are proposed to easily predict the main properties of PVDF dual-layer hollow fibers by valid models and to effectively modify its structure.

Verification for Reduction of Membrane Stress Measurement Equipment Size Using White Noise Sound Wave (화이트노이즈를 이용한 막장력 측정장치의 소형·경량화 검증)

  • Jin, Sang-Wook
    • Journal of Korean Association for Spatial Structures
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    • v.14 no.3
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    • pp.67-74
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    • 2014
  • The author has proposed and verified the accuracy through experiments on a method of measurement through the use of sound waves that not only can quantitatively measure each of the dual directions of the fiber axis with high accuracy of membrane tension created on the surface of the membrane structure, but also can be easily operated in the field of construction. This paper reports the solution for problems of variables caused in the process of downsizing of the measurement equipment in order for practical use, and verifies the correspondence possibility of various stress ratios.

Biphasic Activity of Chloroquine in Human Colorectal Cancer Cells

  • Park, Deokbae;Lee, Youngki
    • Development and Reproduction
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    • v.18 no.4
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    • pp.225-231
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    • 2014
  • Autophagy is a homeostatic degradation process that is involved in tumor development and normal development. Autophagy is induced in cancer cells in response to chemotherapeutic agents, and inhibition of autophagy results in enhanced cancer cell death or survival. Chloroquine (CQ), an anti-malarial drug, is a lysosomotropic agent and is currently used as a potential anticancer agent as well as an autophagy inhibitor. Here, we evaluate the characteristics of these dual activities of CQ using human colorectal cancer cell line HCT15. The results show that CQ inhibited cell viability in dose- and time-dependent manner in the range between 20 to 80 uM, while CQ did not show any antiproliferative activity at 5 and 10 uM. Cotreatment of CQ with antitumor agent NVP-BEZ235, a dual inhibitor of PI3K/mTOR, rescued the cell viability at low concentrations meaning that CQ acted as an autophagy inhibitor, but CQ induced the lethal effect at high concentrations. Acridine orange staining revealed that CQ at high doses induced lysosomal membrane permeabilization (LMP). High doses of CQ produced cellular reactive oxygen species (ROS) and cotreatment of antioxidants, such as NAC and trolox, with high doses of CQ rescued the cell viability. These results suggest that CQ may exert its dual activities, as autophagy inhibitor or LMP inducer, in concentration-dependent manner.

A Study on Unit Cell Design for the Performance Enhancement in PEMFC System (PEMFC 시스템의 성능향상을 위한 단위전지 설계에 관한 연구)

  • Kim Hong-Gun;Kim Yoo-Shin;Yang Sung-Mo;Nah Seok-Chan
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.14 no.4
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    • pp.104-109
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    • 2005
  • The catalyst layer design is one of the most important factors to enhance the performance of PEMFC(Proton Exchange Membrane Fuel Cell) system. The hydrophobic and ion conductive type is studied for the MEA(Membrane Electrolyte Assembly). It is found that those have some limitations for performance enhancement when they are used separately. Thus, the dual catalyst type, a mixed model, is developed for the better MEA performance. In the meantime, the design of flow field plate is subsequently carried out in order to give more enhanced output during its operation. The conductivity of flow field plate showed better performance in the case of manufactured by the more compressed process(20MPa) than by the less compressed process(10MPa). The micro-structure of the flow field plate is examined in details using SEM(Scanning Electron Microscope) to analyse the effects on the different compression processes.

Nitrogen-Oxygen Separation Characteristics by Polyimide Membrane System for Controlled Atmosphere Storage (CA저장을 위한 폴리이미드 막 시스템의 질소-산소 분리특성)

  • 이호원;현명택;고정삼
    • Food Science and Preservation
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    • v.5 no.3
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    • pp.239-246
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    • 1998
  • Polyimide membrane system was designed for manufacturing nitrogen-enriched gas, and basic technical data was suggested for appling this system to controlled atmosphere storage. The permeability characteristics of pure oxygen and nitrogen could be explained by dual-mode sorption model. There was substantial decrease in the permeation rates of oxygen, which is the more permeable gas, through the polyimide membrane due to the presence of nitrogen in comparison with pure oxygen. However, the permeation rates of nitrogen was increased by the presence of oxygen. The ideal separation factor was in the range of 5 to 6 in the range of temperature and pressure difference studied, and the separation factor of air was lower than the ideal separation factor. The increase of ideal separation factor with increasing temperature is due to the fact that the activation energy for oxygen is larger than that for nitrogen. Nitrogen concentration decreased rapidly with increasing product recovery, and it was found that this is a major operating factor to obtain nitrogen concentration required for controlled atmosphere storage. A relation equation, by which nitrogen concentration in storehouse can be predicted, was suggested under the establishment of a hypothetical model for controlled atmosphere storage process using polyimide membrane system.

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Removal Characteristics of Organic Matters in Pretreatment and Reverse Osmosis Membrane Processes for Seawater Desalination (해수담수화 전처리 및 역삼투막여과 공정의 유기물 제거특성)

  • Kim, Dong-Kwan;Choi, June-Seok;Lee, Chang-Kyu;Kim, Jinho;Choi, Jeong-Hak;Lee, Wontae
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.7
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    • pp.492-497
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    • 2014
  • This study investigated removal characteristics of organic matters in pretreatment and reverse osmosis (RO) membrane processes for seawater desalination. Also, the influence of the changes in characteristics of organic matters on the membrane fouling was assessed. The pretreatment processes included dual media filtration (DMF), pressurized membrane filtration (MF), and submerged membrane filtration (SMF). Turbidity, UV absorption at 254 nm, dissolved organic carbon, size exclusion chromatography (SEC), fluorescence excitation emission matrix (FEEM), and transparent exopolymer particles (TEP) in raw and processed waters were analyzed. Ions and minerals were not removed by any pretreatment process tested, but were removed over 99% through the RO membrane process. Hydrophobic organics, which can play major role in organic membrane fouling, were relatively readily removed compared with hydrophilic ones. Membrane based pretreatment such as MF and SMF exhibited better removals of organics than conventional DMF. As the levels of organics in pretreated water decreased, the silt density index (SDI) decreased. MF treated water exhibited the lowest SDI value; this is possibly due to the lowest TEP ($0.1-0.4{\mu}m$) concentrations.

Improvement of Fouling in Membrane Separation Process for Leachate Treatment using Ultrasound(II) : Analysis of Membrane Materials, Solutes and Multi-ultrasonic Effect (초음파를 이용한 침출수 처리를 위한 막분리 공정의 막힘현상 개선(II) : 막의 재질, 용질과 복합초음파의 효과 분석)

  • Kim, Seok-Wan;Lim, Jae-Lim;Lee, Jun-Geol
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.2
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    • pp.207-215
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    • 2006
  • This study evaluated the effect of ultrasonic irradiation on reducing membrane fouling for the treatment of chemically treated leachate and biologically treated leachate. The experiments on improvement of membrane flux according to the membrane types(MF and UF) and membrane materials were performed with changing frequency(40 kHz and 120 kHz) and intensity(200 W and 400 W) of ultrasound in ultrasonic membrane separation apparatus which ultrasound can be periodically irradiated. Additionally, the effect of dual frequency ultrasound which 40 kHz md 120 kHz are irradiated simultaneously was evaluated. The improvement of membrane flux by periodical ultrasound irradiation was higher in microfiltration(MF) membrane than in ultrafiltration(UF) membrane. It was sustained more in the MF membrane of polyvinylidene fluoride(PVDF) than in that of polysulfon(PS). Ultrasonic improvement of membrane flux was different depending on the characteristics of target wastewater. It was sustainably maintained without reclogging using dual frequency ultrasound although the improvement of membrane flux was lower.

Cost comparison of pretreatment processes in large SWRO desalination plant (대규모 해수담수화 플랜트에서의 전처리공정 비용 분석)

  • Kim, Youngmin;Kim, Jin-Ho;Lee, Sangho;Lee, Chang-Kyu;Park, Kwang Duk;Choi, June-Seok
    • Journal of Korean Society of Water and Wastewater
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    • v.27 no.5
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    • pp.555-560
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    • 2013
  • A cost analysis method for pretreament processes of a large scale seawater desalination plant was considered using a cost estimation model, WaTER (Water Treatment Estimation Routine). This model is based on cost functions of U.S. EPA to conduct economic analysis of water treatment facilities. A virtual seawater desalination plant which has pretreatment production capacity of $100,000m^3$ per day was chosen as a model plant. Dual media filtration and microfiltration systems were compared as pretreatment process, and the following reverse osmosis process was modeled. As a result, microfiltration showed a price competitiveness in condition of operating with reverse osmosis process by reducing the loads of water treatment and membrane cleaning despite it's high annual cost.

Review on Proton Exchange Membranes for Microbial Fuel Cell Application (미생물 연료 전지 적용을 위한 양성자 교환막에 대한 검토)

  • Kim, Ji Min;Patel, Rajkumar
    • Membrane Journal
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    • v.30 no.4
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    • pp.213-227
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    • 2020
  • As unrenewable energy resources have depleted over the years, the demand for renewable energy has increased promoting research for more effective methods to produce renewable energy. The field of fuel cell development, specifically microbial fuel cells (MFCs), has developed because of the dual performance potential of the technology. MFCs convert power by facilitating electrode-reducing organisms such as bacteria (microbes) as a catalyst to produce electrical energy. MFCs use domestic and industrial wastewater as fuel to initiate the process, purifying the wastewater as a result. Proton exchange membranes (PEM) play a crucial role in MFCs as a separator between the anodes and cathodes chambers allowing only protons to effectively pass through. Nafion is the commercially used PEM for MFCs, but there are many setbacks: such as cost, production time, and less effective proton conductivity properties. In this review there will be largely two parts. Firstly, several newly developed PEM are discussed as possible replacements of Nafion. Secondly, MFC based on PEM, blended PEM and composite PEM are summarized.