• 폴리머
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• 제35권1호
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• pp.66-71
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• 2011

현탁중합에 이은 프리델 크래프츠 촉매에 의한 hyper crosslinking 반응 및 hydrolysis반응으로 hydroxyl 반응 관능기를 포함하는 hyper crosslinked polymer particle(HCPP)을 합성할 시, 1) 각 단량체의 함량 변화에 따른 HCPP의 표면 모폴로지, 기공 크기 및 분포도의 변화, 2) hyper crosslinking 반응조건 변화에 따른 HCPP의 BET 비표면적 값의 변화 및 3) $CO_2$ 초임계 건조공정을 이용한 HCPP에서의 미반응 잔류 단량체, 올리고머 및 촉매의 제거 등에 관해 연구하였다. 이번 연구를 통해 초기 HCPP의 합성 시 관찰되었던 고분자 입자 표면의 균열 및 파괴현상은 hyper crosslinking 과정 중에 진행되는 microphase separated domain간의 반응과 깊은 관계가 있음을 관찰하였고, 또한 hyper crosslinking 반응 시 반응온도 반응시간 및 사용 용매의 증가는 HCPP의 BET 비표면적 값의 증가에 기여함을 관찰하였다. 그리고 hyper crosslinking을 유발하는 단량체의 함량변화는 다른 단량체에 비해 HCPP의 BET 비표면적, 기공 크기 및 분포도에 상대적으로 큰 영향을 미침을 확인하였다. 또한 HCPP에서의 미반응 잔류 단량체, 올리고머 등의 제거에 $CO_2$ 초임계 건조공정이 매우 효과적임을 확인할 수 있었고 특히 이 과정에서의 보조용매(메탄올)의 첨가는 잔류촉매(Fe)의 제거에 있어 탁월한 효과를 나타내었다.

• 한국농공학회지
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• 제16권4호
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• pp.3600-3610
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• 1974

Experimental work of batch-type dryer was conducted to develop its optimurm operating conditions by analyzing the major factors which affect the drying performance. A laboratory batch-type dryer was constructed and tested for various levels of heated-air rates, and depths of grain deposit. Tong-il rice variety having the initial moisture content of approximaely 23 per cent in wet basis was used for the experiment. The criteria selected for establishing the optimum operating condition were the drying performance rate, the thermal efficiency, and the operational cost of the dryer. The results of the study are summarized as follows: 1. The performance rate of dryer for a specific operating condition was defined as total amount of material dried per hour when the moisture content of grains in the upperlayer reaches to 16 per cent in wet basis. The optimum operating conditions as viewed in the rate of drying performance could be justified by functional realtionship between the depth of grain deposit and air flow rate. In other words, there was a definite depth of grain deposit for a given air-rate which make the dryer performance maximum. The optimum grain depth for the batch-type dryer with 3.3㎡ loading area and with the attached axial fan was about 35cm. 2. The thermal efficiency for the dryer was evaluated by the ratio of the latent heat required to evaporate the grain moisture to the heat input required to raise the ambient air-temperature to 40 degree centigrade. The optimum operating condition as viewed in term of thermal efficiency analyzed was that grater depth and lower air flow-rate may be desirable. This condition is contracted with the optimum condition as viewed by the dryer performance rate. 3. The annual operating cost of batch-type dryer was analyzed for different annual hour of use and for different operation condition. The optimum condition as viewed in terms of operating cost was almost identical to one as viewed in terms of dryer performance rate. Therefore, the most economical use of batch-type dryer for the same annual operating hours can be obtained when the dryer operated in the condition of maximum dryer performance rate. Increasing the annual operating hour may be desirable to cut down the dryer operation cost, since the annual hour of dryer use is much sensitive to the operating cost than any peractical conditions of dryer operation. 4. The most desirable operational condition as justified by combining all the criteria, dryer performance rate, thermal efficiency and annual operating cost, could be concluded to operate the dryer in the condition of maximum performance rate. The condition in general is identical to the lowest operation cost for a given annual operating hour.

• 한국지반공학회논문집
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• 제30권3호
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• pp.47-58
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• 2014

본 연구에서는 임기광산 폐석적치장을 형성하고 있는 광미의 불포화 특성을 조사하기 위하여 자동 흙-함수특성곡선(SWCC) 측정장치를 이용하여 건조 및 습윤과정에 따른 모관흡수력과 체적함수비를 측정하였다. 측정결과를 토대로 van Genuchten 방법을 이용하여 흙-함수특성곡선(SWCC)을 산정하였다. 산정된 흙-함수특선곡선(SWCC)의 ${\alpha}$와 n을 이용하여 흙의 종류를 구분하면 폐석적치장 광미시료는 점토질 모래(clayey sand)에 해당한다. Lu and Likos 방법으로 광미시료의 흡입응력특성곡선(SSCC)을 산정한 결과 흙-함수특성곡선(SWCC)과 유사한 S자형 곡선을 나타낸다. 동일한 유효포화도에서 건조과정의 흡입응력이 습윤과정의 흡입응력보다 크게 발생되는 이력현상이 나타났다. 그리고 불포화토의 유효응력은 공기함입치 이내로 작용할 경우 포화시 유효응력과 동일하나, 공기함입치 이상의 모관흡수력이 작용할 경우 포화토의 유효응력보다 큰 값을 갖는다. 한편, van Genuchten 방법으로 산정된 광미시료의 불포화 투수계수는 모관흡수력이 증가함에 따라 감소하며, 건조과정의 투수계수가 습윤과정의 투수계수보가 크게 발생됨을 알 수 있다.

• 보존과학회지
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• 제33권6호
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• pp.553-564
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• 2017

본 연구는 토벽화 채색층 고착제로서의 도박풀 적용 가능성을 파악하기 위하여, 내후성 실험에 따른 표면변화를 평가하였다. 내후성 실험에 대한 평가는 색차계(CR-400, MINOLTA)를 사용하였으며, 열화로 인한 변화가 특징적으로 나타난 주사 3% 조건은 반사투과장치(CARY-5000, AGILENT)를 사용하여 추가적인 평가를 실시하였다. 자외선 열화 실험 후, 대부분의 도박풀 도포 시료가 아교풀 도포 시료에 비해 색변화가 적었으며, 흡습 건조 열화시험 결과에서는 도박풀이 0.5%와 3% 조건에서 아교에 비해 색변화가 낮게 나타나는 것을 확인하였다. 또한 열화 실험 후 반사 흡수도 측정결과, 아교에 비해 도박풀의 열화 후 반사 흡수도 변화정도가 낮은 것으로 나타났다. 따라서 도박풀을 토벽화 고착제로 사용할 경우 열화에 따른 변색은 비교적 안정적일 것으로 판단된다.

• 한국건축시공학회지
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• 제6권1호
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• pp.101-107
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• 2006

While a Study with regard to the measurement on Concrete Strength and the Change of Drying Shrinkage in accordace with Content Ratio of Crushed Stone Powder, it is being analyzed as the result that the strength according to Content Ratio of crushed Stone Powder is somewhat lowering. Accordingly, it is the real situation that the Concrete mixed with Crushed Stone Powder is utilized for non-structural material, not for the structural material. Therefore, this Research willing to furnish the suitable utilizing scheme for construction site as well as practical life by means of conduct the experiment on both Concrete Pressure Strength according to mixture with Crushed Stone Powder and Elastic Modulus, it also presumes the optimum Elastic Modulus Equation after analysis of comparison with common concrete strength. As the result of the experiment, in case of the Content Ratio of Crushed Stone Powder is less than 5%, it did not display a big difference in its both strength and matter-property compare with common concrete. In case of Elastic Modulus, when the Pressure Strength is 50% and 40% respectively, the Elastic Modulus Equation accords very well with the provided condition of Quadratic function, and as the result of the Presumption on Elastic Modulus according to Content of Crushed Stone Powder, in case the Pressure Strength is 50%, Elastic Modulus Equation showed that Error Ratio of Cubic function is at degree of 0.0005%, in case the Pressure Strength is 40%, Elastic Modulus Equation was accorded well with the value of the experimental data likely as the Error Ratio of Cubic function is at the degree around 0.0034%, respectively.

• 한방안이비인후피부과학회지
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• 제13권1호
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• pp.253-266
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• 2000

In order to strengthen objectivity and availability of oriental herb medicine, the standard formula for herbs has been attempted to set up by experimenting and documentary testing original herbs which were recorded in authorized document. The object herb medicine is Codonopsis Pilosulae Radix. The internal and external morphological standard in this study is expected to supply the search for several physiochemical reaction, biological reaction, determination of indicator material and identification of gene with basic sources in the future. The result of study is as follows; In the external shape, it was possible that herbs were distinguished according to artificial classification and that same genus-degree of relatedness among herbs could be distinguished by more precise and active observation. In the shape of real herbs, I compared current herbs in market with original herbs which were just collected or were on the course of drying. In addition, it was possible that the internal shape could be identified by using microscope after butanol series. In powder herbs, it was possible to purify the shape by microscope through maceration of natural and powder herbs. Though it was impossible to make distinction of herbs which are not current in my search contents, this search contents will be a standard for alpplying herbs in the future. Despite such a useful character, it was difficult to deal with power herbs because it was uncertain to make a standard for them on account of the crush of these tissue. Since powders shape of herbs in a few documents were regard not as the powder shapes of natural herbs but as the maceration state of them. It is suggested that we should inspect the original herbs which are not crushed yet with a microscope in order to identify crushed shape of powder herbs from now on. An Additional standard establishment including physiochemical reaction and gene research is required in order to supplement the fault of this search. As for the supplement about this search, considering that many kinds of same genus-degree of relatedness are being current now, it is necessary that each herb should he collected only after identifying and that the succeeding search of each herb should be proceeded for the regular establishment of internal and external standard.

• Journal of Forest and Environmental Science
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• 제38권4호
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• pp.229-238
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• 2022

Q. mongolica and Q. dentata are representative species of deciduous forest communities in Korea and are known to be relatively resistant to soil drying condition among Korean oaks. This study attempted to elucidate the degree of competition and ecological niche characteristics of the two species by comparing the ecological responses of the two species according to soil moisture. Competition between Q. mongolica and Q. dentata was shown to be more intense under the conditions where moisture content was low than under the conditions where moisture content was high. As for the ecological niche overlaps of the two species for soil moisture, the structural traits of plant such as stem diameter overlapped the most, the traits of biomass such as petiole weight overlapped the least, and photosynthetic organ-related traits such as leaf width and length overlapped intermediately. When looking at the competition for soil moisture between the two species, it can be seen that Q. mongolica won in nine traits (leaf width length, leaf lamina length, leaf lamina weight, leaf petiole weight, leaf area, leaves weight, shoot weight, root weight, and plant weight) and Q. dentata won in the remaining seven traits (leaf petiole length, leaves number, stem length, stem diameter, stem weight, shoot length, and root length). Competition between the two species for the moisture environment of the soil was shown to be intense under the conditions where moisture content was low. The degree of competition between Q. dentata and Q. mongolica for soil moisture is high under the conditions where soil moisture content is low, and it is judged that Q. mongolica is more competitive for soil moisture than Q. dentata.

• 대한토목학회논문집
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• 제29권4A호
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• pp.373-384
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• 2009

다공성 경량골재의 사전흡수수에 따른 콘크리트 수축 저감 효과의 정량적 평가와 부등수축해석모델 상수 제공을 위한 첫번째 단계로서, 수분이동모델을 설정하고 이에 따른 수분이동 특성상수인 유효수분확산계수, 수분용량, 습도공급도, 습도소모도를 물-결합재비, 골재 종류를 변수로 하여 측정하였다. 콘크리트 내, 외부 습도차에 의한 정상상태에서의 유효수분확산계수는 물-결합재비가 낮을수록 낮은 값을 나타내었으며 동일한 물-결합재비인 경우 일반골재를 사용한 배합이 경량골재를 사용한 배합보다 낮은 유효수분확산계수값을 나타내었다. 콘크리트 내 수분의 저장 능력 즉, 수분용량을 산정하기 위해 9가지 습도에서 콘크리트의 수분량을 측정하였으며 경량골재를 사용한 배합이 일반골재를 사용한 배합보다 모든 습도조건에서 수분량이 크게 나타났다. 일반 대기환경 습도 50% 이상 조건에서 적용할 수 있는 경량골재의 습도공급도를 측정하여 정량화 하였으며, 경량골재에서의 수분 방출량은 주변 습도에 반비례하고 시간에 비례하는 뚜렷한 경향을 나타내는 지수함수의 형태로 설정하였다. 시멘트 수화 자기건조에 의한 수분의 내부소모에 따른 콘크리트 내 습도소모도를 측정하였으며, 측정결과 물-결합재비 0.3의 경우 7~10일 이내의 초기재령에서 약 10% 내외의 급격한 습도감소를 나타내었으며 물-결합재비 0.4, 0.5의 경우 완만한 형태로 약 5%, 1% 내외의 습도 감소를 나타내었다.

• 동아시아식생활학회지
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• 제25권3호
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• pp.484-491
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• 2015

This study investigated the quality variation characteristics of Ssamjang containing Cheongkukjang, in order to improve the degree of preference of Cheongkukjang. The amount of Cheongkukjang was set at 1% based on sensory evaluation. Ssamjang containing Cheongkukjang was stored at $37^{\circ}C$ for 13 weeks, after which quality variation characteristics were weekly. During storage for 13 weeks, physicochemical quality characteristics, moisture content, and pH of Ssamjang containing Cheongkukjang slightly decreased, whereas salt content did not change. Amino nitrogen content slightly increased by 1 week but decreased by 3 weeks and then increased by 5 weeks. For microbiology quality characteristics, viable cell counts and total cell counts of B. cereus were unchanged. For sensory quality characteristics, shape quality was poor after 13 weeks while mold, drying phenomenon, and swelling phenomenon were not observed. Therefore, physicochemical quality and microbiology quality of Ssamjang containing Cheongkukjang were unchanged during storage for 13 weeks, and the storage limit was determined to be 12 weeks according to sensory quality evaluation.

• 공업화학
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• 제7권2호
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• pp.393-400
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• 1996

Seed 유화 중합법과 용매 추출법을 이용하여 전도성 고분자 복합체를 위한 다공성 입자를 제조하였다. 건조된 다공성 입자를 모체 고분자로 사용하여 dopant로 사용하는 $FeCl_3$를 methanol에 녹여 흡수시킨 뒤에 건조시키고, 이를 다시 pyrrole를 녹인 ethyl ether 용액으로 중합하여 용액을 증발시킴으로서 전도성 고분자 복합체를 합성하였다. 이때, 모체 고분자로 사용된 비다공성 입자와 다공성 입자의 전도도를 비교하였다. 실험결과, 전도성 복합체의 전도도는 비다공성 입자보다는 다공성 입자를 사용하여 제조한 복합체가 전도성 중합체가 입자의 표면뿐만 아니라 pore안에서도 용이하게 형성되어 더 우수한 전도도를 나타내었다.