• Title/Summary/Keyword: dry-wet spinning

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A Study on Fiber Formation and Physical Properties of Polyacrylonitrile Copolymer with Itaconic acid (이타콘산을 함유한 폴리아크릴로니트릴 공중합체의 섬유제조 및 그 물성에 관한 연구)

  • Sin, Ik Gi;Lee, Sin Hui;Park, Su Min
    • Textile Coloration and Finishing
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    • v.14 no.2
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    • pp.109-109
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    • 2002
  • A study has been made of the dry-jet-wet spinning of PAN copolymer fibers using 60% aqueous zinc chloride solution as solvent and 25∼40% aqueous zinc chloride solution as non-solvent. The technological characteristics of this method were that small streams of dope were extruded from the die and allowed to pass through a short distance of air gap(about 10mm) before entering the spinning bath for full coagulation. This work showed the importances which coagulation condition, stretch ratio and fiber tenacity up to 10.5 g/d could be obtained with elongation of 11∼16%. Individual fibers were evaluated on the basis of density and mechanical properties such as tenacity and elongation etc.

A Study on Fiber Formation and Physical Properties of Polyacrylonitrile Copolymer with Itaconic acid (이타콘산을 함유한 폴리아크릴로니트릴 공중합체의 섬유제조 및 그 물성에 관한 연구)

  • 박수민;신익기;이신희
    • Textile Coloration and Finishing
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    • v.14 no.2
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    • pp.33-39
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    • 2002
  • A study has been made of the dry-jet-wet spinning of PAN copolymer fibers using 60% aqueous zinc chloride solution as solvent and 25∼40% aqueous zinc chloride solution as non-solvent. The technological characteristics of this method were that small streams of dope were extruded from the die and allowed to pass through a short distance of air gap(about 10mm) before entering the spinning bath for full coagulation. This work showed the importances which coagulation condition, stretch ratio and fiber tenacity up to 10.5 g/d could be obtained with elongation of 11∼16%. Individual fibers were evaluated on the basis of density and mechanical properties such as tenacity and elongation etc.

Dry-jet Wet Spinning of Polyhydroxyamide Fibers

  • Park, Seung-Koo;Cho, Seo-Hyun;Farris, Richard-John
    • Fibers and Polymers
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    • v.1 no.2
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    • pp.92-96
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    • 2000
  • A high molecular weight polyhydroxyamide (PHA) solution in N, N-dimethyl acetamide (DMAc) was prepared from 3, 3'-dihydroxybenzidine and isophthalic chloride (IPC), which was used for spinning PHA fiber. Before spinning, the diffusion property of DMAc into various coagulants was examined. The fiber was well formed in coagulants such as water/ethanol with a composition of 5/5, ethanol, and ethanol/isopropanol with a composition of 7/3 and 5/5. However, the PHA fiber spun in the water/ethanol mixture contained voids. After the fiber spun in ethanol was annealed at over $350^{\circ}C$, the ultimate stress and initial modulus of the fiber increased from 75.5 MPa and 3.22 GPa to 369 MPa and 29.5 GPa, respectively. These properties of the PHA fiber spun by the dry spinning method were also enhanced, attaining 154 MPa and 5.56 Gpa, respectivel.

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Development of Membrane Humidifier for Fuel Cell Bus (200kW) (연료전지 버스용 (200kW급) 막가습기 개발)

  • Lee, Moo-Seok;Kang, Chung-Seok;Yoon, Young-Seo;Kim, Kyoung-Ju;Yun, Joon-Khee
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.471-473
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    • 2006
  • An object of the present study is to provide a hollow fiber membrane humidifier capable of improving the humidification efficiency while lowering the pressure loss, and is suitably usable for PEMFC(Polymer Electrolyte Membrane Fuel Cell). The performance of PEMFC is decisively dependent on the humidity of the electrolyte membrane(fluorinated membrane) and a humidifier plays an important role in moisturizing electrolyte membrane. Especially this humidifier is adaptable for lower price to promote the commercialization of fuel cell vehicles and is passive type to be power free and to be volumetrically optimized. In this research, we propose the substitutes for the expensive fluorinated materials and the optimum dry-jet wet spinning conditions of hollow fiber membrane to get the fuel cell humidifier. In addition to that we established the standard method of evaluating the moisturizing performance of the humidifier of various materials.

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Development of Membrane Humidifier for FCEV (연료전지 자동차용 막 가습기 개발)

  • Kim, Kyoung-Ju;Lee, Moo-Seok;Yun, Joon-Khee;Shin, Yong-Cheol
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.177-179
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    • 2007
  • An object of the present study is to provide a hollow fiber membrane humidifier capable of improving the humidification efficiency while lowering the pressure loss, and is suitably usable for PEMFC(Polymer Electrolyte Membrane Fuel Cell). The performance of PEMFC is decisively dependent on the humidity of the electrolyte membrane(fluorinated membrane) and a humidifier plays an important role in moisturizing electrolyte membrane. Especially, this humidifier is a passive type(power-free) item and is volumetrically optimized. In this research, we propose the substitutes for the expensive fluorinated humidifier materials and the optimum dry-jet wet spinning conditions of hollow fiber membrane. In addition to that, This study will present an performance of an humidifier and compare computational results with the experimental data.

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Preparations of Chemical Cellulose from Ascidian Tunic and Effect of Spinning Conditions on the Properties of New Regenerated Cellulose Fiber

  • Koo, Won-Mi;You, Sang-Hoon;Lee, Dong-Jin;Kim, Eun-Young;Kim, Han-Do
    • Proceedings of the Korean Fiber Society Conference
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    • 2000.04a
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    • pp.125-128
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    • 2000
  • Chemical cellulose from an ascidian tunic is isolated by extraction, digestion and bleaching steps. The content of $\alpha$-cellulose was above 98 wt%, and it's DPw was about 918. A new regenerated cellulose fiber from the chemical cellulose obtained in this study was made using NMMO/water(87/13 wt%) as a solvent by dry jet-wet spinning. The effects of spinning speed and cellulose content of spinning dope on the properties were investigated.

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Development and physical properties on the monofilament for gill nets and traps using biodegradable aliphatic polybutylene succinate resin (생분해성 지방족 폴리부틸렌 석시네이트 수지를 이용한 자망과 통발용 단일섬유의 방사기술 개발 및 물리적 특성)

  • Park, Seong-Wook;Bae, Jae-Hyun;Lim, Ji-Hyun;Cha, Bong-Jin;Park, Chang-Doo;Yang, Yong-Su;Ahn, Heui-Chun
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.43 no.4
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    • pp.281-290
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    • 2007
  • This study was aimed not only to develop the gill net and trap made of biodegradable monofilaments in order to prevent a ghost fishing and to protect marine ecosystem, but also to analyze their spinning process and physical properties. Results showed that the spinning speed of biodegradable polybutylene succinate(PBS) monofilament was estimated to be approximately 100m/min when spinning temperature and cooling water temperature were adjusted at $180^{\circ}C$ and $3^{\circ}C$, respectively. The breaking loads of PBS monofilaments were estimated to be $35.3kg/mm^2$ at ${\phi}0.2mm$, $46.5kg/mm^2$ at ${\phi}0.3mm$, and $49.7kg/mm^2$ at ${\phi}0.4mm$ in the dry condition, respectively. However, its breaking loads in the wet condition were reduced by 2.4-5.5%, compared to those in the dry condition. The knotted strength of PBS monofilament at ${\phi}0.2mm$ was estimated to be 98.6% of PE in the dry condition. The breaking load of PBS monofilament at ${\phi}0.3mm$ was evaluated to be 81.8% of PA, and its softness showed 3 times less than that of PA in the wet condition. The breaking load of PBS monofilament at ${\phi}0.4mm$ was 95.3% of PA, and its softness showed 1.6 times less than that of PA in the wet state. However, the load elastic elongations of two kinds of monofilaments were estimated to be 1% higher than that of PA.

Effect of Wet Cleaning on Shrinkage and Detergency of Wool and Rayon Fabrics (웨트클리닝이 양모, 레이온 직물의 치수 안정성과 세탁성능에 미치는 영향)

  • Chung, Seung-Eun;Yun, Chang-Sang;Park, Chung-Hee;Kim, Hyun-Sook
    • Journal of the Korean Society of Clothing and Textiles
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    • v.36 no.2
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    • pp.127-137
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    • 2012
  • This study focuses on the optimal washing conditions for dry cleaning recommended fabrics to minimize dimensional changes using wet cleaning. We suggest water-based alternatives to a perchloroethylene based cleaning process. Wool and rayon fabrics were laundered under various washing conditions and then air-dried for 24hrs. All specimens were extended after spinning and shrunk after drying. This is probably because the fibers were swollen and extended by wetting. The wool fabrics were shown to be acutely influenced by washing temperature and mechanical force. The optimal washing conditions for wool fabric to minimize the dimensional change implied a normal washing temperature and minimized mechanical force. For rayon specimens, dimensional change by a hand wash showed a remarkable decrease compared with a machine wash. Rayon fabric seemed to be influenced by the quantity of water contained in the fabric after spinning and washing time. Therefore, the desirable washing conditions for rayon fabric are to reduce the time required for washing and to increase the spin speed.