• Title/Summary/Keyword: dry mass

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Performance of Hybrid Adhesives of Blocked-pMDI/Melamine-Urea-Formaldehyde Resins for the Surface Lamination on Plywood

  • Lubis, Muhammad Adly Rahandi;Park, Byung-Dae;Lee, Sang-Min
    • Journal of the Korean Wood Science and Technology
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    • v.47 no.2
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    • pp.200-209
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    • 2019
  • To improve the water resistance of melamine-urea-formaldehyde (MUF) resins, different levels of blocked polymeric 4,4 diphenyl methane diisocyanate (B-pMDI) were blended with MUF resins to prepare B-pMDI/MUF hybrid adhesives, and their adhesion performances were evaluated for the surface lamination of fancy veneer on plywood. FT-IR spectra showed that the de-blocked -NCO groups reacted with the -OH of hydroxymethyl groups of the MUF resins to form urethane bonds at 2% B-pMDI/MUF, which was detected before and after their hydrolysis. The mass loss after the hydrolysis consistently decreased as the B-pMDI level increased, indicating an improvement in the water resistance. As the B-pMDI level increased, the activation energy of hybrid adhesives decreased, which improved the reactivity of the hybrid adhesives. Additionally, the water resistance improvement of the hybrid adhesives increased the tensile shear strength of the surface laminated plywood in semi-water proof and water-proof by 23 % and 8 %, respectively, at 2% B-pMDI level. This was likely due to the urethane linkages in the hybrid adhesives. However, the formaldehyde emission from plywood panels bonded with the hybrid adhesives increased in the dry state, indicating incomplete curing of the hybrid adhesives.

Reactivity Evaluation on Copper Etching Using Organic Chelators (유기 킬레이터들을 이용한 구리 식각에 대한 반응성 평가)

  • Kim, Chul Hee;Lim, Eun Taek;Park, Chan Ho;Park, Sung Yong;Lee, Ji Soo;Chung, Chee Won;Kim, Dong Wook
    • Korean Journal of Materials Research
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    • v.31 no.10
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    • pp.569-575
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    • 2021
  • The reactivity evaluation of copper is performed using ethylenediamine, aminoethanol, and piperidine to apply organic chelators to copper etching. It is revealed that piperidine, which is a ring-type chelator, has the lowest reactivity on copper and copper oxide and ethylenediamine, which is a chain-type chelator, has the highest reactivity via inductively coupled plasma-mass spectroscopy (ICP-MS). Furthermore, it is confirmed that the stable complex of copper-ethylenediamine can be formed during the reaction between copper and ethylenediamine using nuclear magnetic resonance (NMR) and radio-thin layer chromatography. As a final evaluation, the copper reactivity is evaluated by wet etching using each solution. Scanning electron micrographs reveal that the degree of copper reaction in ethylenediamine is stronger than that in any other chelator. This result is in good agreement with the evaluation results obtained by ICP-MS and NMR. It is concluded that ethylenediamine is a prospective etch gas for the dry etching of the copper.

Analysis of the change in appearance according to the hardening method of leather (가죽의 경화방법에 따른 외형변화 분석)

  • Youshin, Park
    • Journal of Fashion Business
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    • v.26 no.5
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    • pp.122-134
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    • 2022
  • This study is conducted on hardening leather with improved firmness and stability of shape, based on research on types and thickness of leather. The purpose of this study is to test the physical properties of the leather for molding to prepare the foundation for leather molding based on the test results using four methods by thickness of Vegetable and Split. The tests were conducted using a total of five leather types, including three types of vegetable leathers and two types of split, by thickness. Based on the testing method for leathers in KS M 6882, the tests were performed at 27℃ with relative humidity of 65±20%. The samples were prepared with cowhide, size 9cm× 2cm. The measurement parameters are length and width. thickness, volume, mass, density. Regarding the hardening treatment method, changes in appearance and major physical characteristics of leather were reviewed by soaking in hot water, dry heating, hammering, waxing, and olive oil coating. The study results are as follows. In planar works, it is judged that hardening work using a hammer is more suitable for stiffness or density in order to prevent easy breakage with adult muscle density, rather than boiling water or baking. In conclusion, there is no curling, soot, or breaking phenomenon, and the densest curing method is 50℃ for 20 sec of V2 and 75℃ for 60 sec of V2 in boiling water. The combination of paraffin treatment improve waterproof and quality.

Liquid boundary effect on free vibration of an annular plate coupled with a liquid

  • Kyeong-Hoon Jeong
    • Coupled systems mechanics
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    • v.12 no.2
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    • pp.127-149
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    • 2023
  • A theoretical method is developed to analyze the free vibration of an elastic annular plate in contact with an ideal liquid. The displacement potential functions of the contained liquid are expressed as a combination of the Bessel functions that satisfy the Laplace equation and the liquid boundary conditions. The compatibility condition along the interface between the annular plate and the contained liquid is taken into account to consider the fluid-structure coupling. The dynamic displacement of the wet annular plate is assumed to be a combination of dry eigenfunctions, allowing for prediction of the natural frequencies using the Rayleigh-Ritz method. The study investigates the effect of radial liquid boundary conditions on the natural frequencies of the wet annular plate, considering four types of liquid bounding: outer container bounded, outer and inner bounded, inner bounded, and radially unbounded. The proposed theoretical method is validated by comparing the predicted wet natural frequencies with those obtained from finite element analysis, showing excellent accuracy. The results indicate that the radial liquid bounding effect on the natural frequencies is negligible for the axisymmetric vibrational mode, but relatively significant for the mode with one nodal diameter (n =1) and no nodal circle (m' = 0). Furthermore, the study reveals that the wet natural frequencies are the largest for the plate with an inner bounded cylinder among the radial liquid boundary cases, regardless of the vibration mode.

Quasi-steady three-degrees-of-freedom aerodynamic model of inclined/yawed prisms: Formulation and instability for galloping and static divergence

  • Cristoforo Demartino;Zhen Sun;Giulia Matteoni;Christos T. Georgakis
    • Wind and Structures
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    • v.37 no.1
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    • pp.57-78
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    • 2023
  • In this study, a generalized three-degree-of-freedom (3-DoF) analytical model is formulated to predict linear aerodynamic instabilities of a prism under quasi-steady (QS) conditions. The prism is assumed to possess a generic cross-section exposed to turbulent wind flow. The 3-DoFs encompass two orthogonal horizontal directions and rotation about the prism body axis. Inertial coupling is considered to account for the non-coincidence of the mass center and the rotation center. The aerodynamic force coefficients-drag, lift, and moment-depend on the Reynolds number based on relative flow velocity, angle of attack, and the angle between the wind and the cable. Aerodynamic forces are linearized with respect to the static equilibrium configuration and mean wind velocity. Routh-Hurwitz and Liénard and Chipart criteria are used in the eigenvalue problem, yielding an analytical solution for instabilities in galloping and static divergence types. Additionally, the minimum structural damping and stiffness required to prevent these instabilities are numerically determined. The proposed 3-DoF instability model is subsequently applied to a conductor with ice accretion and a full-scale dry inclined cable. In comparison to existing models, the developed model demonstrates superior prediction accuracy for unstable regions compared with results in wind tunnel tests.

GC-MS analysis of Salicornia herbacea L. extracts with trimethylsilyl derivatization (Trimethylsilyl 유도체화 방법을 적용한 함초 추출물의 GC-MS 분석)

  • Kyoung-In Lee;Geun-Jik Lee;Young-Seung Yoon
    • Journal of Marine Bioscience and Biotechnology
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    • v.15 no.2
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    • pp.96-102
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    • 2023
  • Salicornia herbacea, a noted halophyte, has been widely researched for its diverse physiological activities. The continuous exploration of its compounds is essential. This study employed gas chromatography (GC) coupled with mass spectrometry (MS) for qualitative analysis. This involved pretreatment including trimethylsilyl (TMS) derivatization of the S. herbacea extract, facilitating its GC analysis. Five compounds, including various fatty acids and β-sitosterol, were identified by direct analysis of the methanol extract of S. herbacea without pretreatment by GC-MS. Conversely, the analysis of the TMS-derivatized extract revealed 28 distinct peaks. Quantitative analysis further indicated that the predominant compounds in the S. herbacea extract were sugars and sugar derivatives, notably glucose, fructose, and glucitol. The collective concentration of these sugars and its derivatives amounted to 116.45 mg/g, representing 11.6% of the dry weight of the raw S. herbacea. Following sugars and their derivatives, fatty acids constituted the next most abundant group of compounds. However, the presence of amino acids and organic acids was relatively low.

Color Developing of Hanji Fabrics by Heat Treatment of Persimmon Juice and Shuliang Extract and Mud Dyeing (감물과 서랑 추출물의 열처리와 진흙염색에 의한 한지직물의 색상 발현)

  • Kyunghee Son
    • Journal of the Korean Society of Clothing and Textiles
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    • v.48 no.3
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    • pp.543-562
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    • 2024
  • This study used persimmon juice, shuliang, and mud to develop the color of hanji fabrics. Persimmon juice and shuliang were used to perform single and mixing dyeing with heat treatment using the pad-dry-cure (PDC) method. Next, mud dyeing was performed, and the hanji fabrics dyed with persimmon juice and shuliang were developed into Yellow Red (YR) Munsell colors with very low values and chroma. Through scanning electron microscopy, the persimmon juice and shuliang were observed to be evenly treated on the hanji fabrics using the PDC method. Furthermore, the presence of iron ions in the dyed fabrics was confirmed using inductively coupled plasma-mass spectrometry analysis. The stiffness of the fabrics dyed with persimmon juice was the greatest, while it gradually decreased for the fabrics treated with mixing and mud dyeing. With mixing dyeing, the colorfastness to washing improved to grade 4, whereas with mud dyeing, the colorfastness to alkaline sweat greatly improved to grade 4~4-5. Based on these findings, this study confirmed that it is possible to develop hanji fabrics with differentiated textures and colors while ensuring practical colorfastness through mixing and mud dyeing.

Studies on the Mechanical Properties of Weathered Granitic Soil -On the Elements of Shear Strength and Hardness- (화강암질풍화토(花崗岩質風化土)의 역학적(力學的) 성질(性質)에 관(關)한 연구(硏究) -전단강도(剪斷强度)의 영향요소(影響要素)와 견밀도(堅密度)에 대(對)하여-)

  • Cho, Hi Doo
    • Journal of Korean Society of Forest Science
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    • v.66 no.1
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    • pp.16-36
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    • 1984
  • It is very important in forestry to study the shear strength of weathered granitic soil, because the soil covers 66% of our country, and because the majority of land slides have been occured in the soil. In general, the causes of land slide can be classified both the external and internal factors. The external factors are known as vegetations, geography and climate, but internal factors are known as engineering properties originated from parent rocks and weathering. Soil engineering properties are controlled by the skeleton structure, texture, consistency, cohesion, permeability, water content, mineral components, porosity and density etc. of soils. And the effects of these internal factors on sliding down summarize as resistance, shear strength, against silding of soil mass. Shear strength basically depends upon effective stress, kinds of soils, density (void ratio), water content, the structure and arrangement of soil particles, among the properties. But these elements of shear strength work not all alone, but together. The purpose of this thesis is to clarify the characteristics of shear strength and the related elements, such as water content ($w_o$), void ratio($e_o$), dry density (${\gamma}_d$) and specific gravity ($G_s$), and the interrelationship among related elements in order to decide the dominant element chiefly influencing on shear strength in natural/undisturbed state of weathered granitic soil, in addition to the characteristics of soil hardness of weathered granitic soil and root distribution of Pinus rigida Mill and Pinus rigida ${\times}$ taeda planted in erosion-controlled lands. For the characteristics of shear strength of weathered granitic soil and the related elements of shear strength, three sites were selected from Kwangju district. The outlines of sampling sites in the district were: average specific gravity, 2.63 ~ 2.79; average natural water content, 24.3 ~ 28.3%; average dry density, $1.31{\sim}1.43g/cm^3$, average void ratio, 0.93 ~ 1.001 ; cohesion, $ 0.2{\sim}0.75kg/cm^2$ ; angle of internal friction, $29^{\circ}{\sim}45^{\circ}$ ; soil texture, SL. The shear strength of the soil in different sites was measured by a direct shear apparatus (type B; shear box size, $62.5{\times}20mm$; ${\sigma}$, $1.434kg/cm^2$; speed, 1/100mm/min.). For the related element analyses, water content was moderated through a series of drainage experiments with 4 levels of drainage period, specific gravity was measured by KS F 308, analysis of particle size distribution, by KS F 2302 and soil samples were dried at $110{\pm}5^{\circ}C$ for more than 12 hours in dry oven. Soil hardness represents physical properties, such as particle size distribution, porosity, bulk density and water content of soil, and test of the hardness by soil hardness tester is the simplest approach and totally indicative method to grasp the mechanical properties of soil. It is important to understand the mechanical properties of soil as well as the chemical in order to realize the fundamental phenomena in the growth and the distribution of tree roots. The writer intended to study the correlation between the soil hardness and the distribution of tree roots of Pinus rigida Mill. planted in 1966 and Pinus rigida ${\times}$ taeda in 199 to 1960 in the denuded forest lands with and after several erosion control works. The soil texture of the sites investigated was SL originated from weathered granitic soil. The former is situated at Py$\ddot{o}$ngchangri, Ky$\ddot{o}$m-my$\ddot{o}$n, Kogs$\ddot{o}$ng-gun, Ch$\ddot{o}$llanam-do (3.63 ha; slope, $17^{\circ}{\sim}41^{\circ}$ soil depth, thin or medium; humidity, dry or optimum; height, 5.66/3.73 ~ 7.63 m; D.B.H., 9.7/8.00 ~ 12.00 cm) and the Latter at changun-long Kwangju-shi (3.50 ha; slope, $12^{\circ}{\sim}23^{\circ}$; soil depth, thin; humidity, dry; height, 10.47/7.3 ~ 12.79 m; D.B.H., 16.94/14.3 ~ 19.4 cm).The sampling areas were 24quadrats ($10m{\times}10m$) in the former area and 12 in the latter expanding from summit to foot. Each sampling trees for hardness test and investigation of root distribution were selected by purposive selection and soil profiles of these trees were made at the downward distance of 50 cm from the trees, at each quadrat. Soil layers of the profile were separated by the distance of 10 cm from the surface (layer I, II, ... ...). Soil hardness was measured with Yamanaka soil hardness tester and indicated as indicated soil hardness at the different soil layers. The distribution of tree root number per unit area in different soil depth was investigated, and the relationship between the soil hardness and the number of tree roots was discussed. The results obtained from the experiments are summarized as follows. 1. Analyses of simple relationship between shear strength and elements of shear strength, water content ($w_o$), void ratio ($e_o$), dry density (${\gamma}_d$) and specific gravity ($G_s$). 1) Negative correlation coefficients were recognized between shear strength and water content. and shear strength and void ratio. 2) Positive correlation coefficients were recognized between shear strength and dry density. 3) The correlation coefficients between shear strength and specific gravity were not significant. 2. Analyses of partial and multiple correlation coefficients between shear strength and the related elements: 1) From the analyses of the partial correlation coefficients among water content ($x_1$), void ratio ($x_2$), and dry density ($x_3$), the direct effect of the water content on shear strength was the highest, and effect on shear strength was in order of void ratio and dry density. Similar trend was recognized from the results of multiple correlation coefficient analyses. 2) Multiple linear regression equations derived from two independent variables, water content ($x_1$ and dry density ($x_2$) were found to be ineffective in estimating shear strength ($\hat{Y}$). However, the simple linear regression equations with an independent variable, water content (x) were highly efficient to estimate shear strength ($\hat{Y}$) with relatively high fitness. 3. A relationship between soil hardness and the distribution of root number: 1) The soil hardness increased proportionally to the soil depth. Negative correlation coefficients were recognized between indicated soil hardness and the number of tree roots in both plantations. 2) The majority of tree roots of Pinus rigida Mill and Pinus rigida ${\times}$ taeda planted in erosion-controlled lands distributed at 20 cm deep from the surface. 3) Simple linear regression equations were derived from indicated hardness (x) and the number of tree roots (Y) to estimate root numbers in both plantations.

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Evaluation of CM (Cell Mass from Lysine Fermentation) as an Alternative Protein Source in Broiler Diets

  • Piao, X.S.;Han, Y.K.;Bae, S.H.;Lee, H.;Han, In K.
    • Asian-Australasian Journal of Animal Sciences
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    • v.11 no.5
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    • pp.550-558
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    • 1998
  • The experiment was conducted to evaluate CM (Cell Mass from Lysine Fermentation), which is used to produce synthetic lysine in industry, as an alternative protein source in broiler diets. Three different production conditions were employed to produce CMs (CM I, II, III). Treatments were control, CM I -1 (1 % of CM in the diet), CM I -3 (3% of CM in the diet), CM I -5 (5% of CM in the diet), CM II (3% of CM in the diet), and CM III (3% of CM in the diet). It was found that CM products were all high in crude protein content and especially high in lysine and methionine contents, while very low in minerals. For the starter period, all CM groups showed better weight gain, chicks fed CM I -1 diets were especially high in weight gain (p < 0.05). CM groups consumed 14.4 to 18.0% more feed than chicks fed control diets (p < 0.05). The best FCR was found in CM I -1 groups (p < 0.05), but as CM level was increased, FCR was also increased. For the finisher period, weight gain was similar through all treatments. Through whole experimental period, weight gain and feed intake were higher in all CM groups than control group (p < 0.05), however, as CM level was increased, FCR was also increased. Generally chicks fed CM diets showed higher utilizabilities of gross energy, dry matter, crude protein and crude fat. The best nutrients utilizability was obtained in CM I -1 group, and the worst was found in the control group. During the finisher period, the utilizabilities of crude protein, crude ash and phosphorus were not affected by the dietary treatments. Amino acids utilizability was not significantly affected by the treatments except CM I -5 group. In all amino acids tested, chicks did not show the big difference in utilizabilities. Only in the CM I -5 group, amino acids utilizability was significantly lower than control group. However, among CM I groups, the mean value of the amino acids utilizability was decreased as the level of CM inclusion in the diet was increased. During the finisher period, similar trend was found in amino acids utilizability.

Simultaneous Characterization of Sofalcone and Its Metabolite in Human Plasma by Liquid Chromatography -Tandem Mass Spectrometry

  • Han, Sang-Beom;Jang, Moon-Sun;Lee, Hee-Joo;Lee, Ye-Rie;Yu, Chong-Woo;Lee, Kyung-Ryul;Kim, Ho-Hyun
    • Bulletin of the Korean Chemical Society
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    • v.26 no.5
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    • pp.729-734
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    • 2005
  • A sensitive and selective method for quantitation of sofalcone and its active metabolite in human plasma has been established using liquid chromatography-electrospray ionization tandem mass spectrometry (LC-ESI/MS/MS). Plasma samples were transferred into 96-well plate using an automated sample handling system and spiked with 10 $\mu$L of 2 $\mu$g/mL $d_3$-sofalcone and $d_3$-sofalcone metabolite solutions (internal standard), respectively. After adding 0.5 mL of acetonitrile to the 96-well plate, the plasma samples were then vortexed for 30 sec. After centrifugation, the supernatant was transferred into another 96-well plate and completely evaporated at 40 ${^{\circ}C}$ under a stream of nitrogen. Dry residues were reconstituted with mobile phase and were injected into a $C_{18}$ reversed-phase column. The limit of quantitation of sofalcone and its metabolite was 2 ng/mL, using a sample volume of 0.2 mL for analysis. The reproducibility of the method was evaluated by analyzing 10 replicates over the concentration range of 2 ng/mL to 1000 ng/mL. The validation experiments of the method have shown that the assay has good precision and accuracy. Sofalcone and its metabolite produced a protonated precursor ion ([M+H]$^+$) of m/z 451 and 453, and a corresponding product ion of m/z 315 and 317, respectively. Internal standard ($d_3$-sofalcone and $d_3$-sofalcone metabolite) produced a protonated precursor ion ([M+H]$^+$) of m/z 454 and 456 and a corresponding product ion of m/z 315 and 317, respectively. The method has been successfully applied to a pharmacokinetic study of sofalcone and its active metabolite in human plasma.