• Elastomers and Composites
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• 제52권3호
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• pp.180-186
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• 2017

In this work, the effect of low-temperature dehydration of a poly(styrene-co-styrenesulfonic acid) (PSSA) membrane was investigated by differential scanning calorimetry, fourier transform infrared spectroscopy (FT-IR), electron magnetic resonancespectroscopy (EMR), and $^1H$- and $^{13}C$ solid-state nuclear magnetic resonance spectroscopy. These analyses were performed at room temperature for powdered PSSA specimens with and without dehydration and the following key observations were made. First, FT-IR analysis showed that low-temperature dehydration not only transformed the [${SO_3}^-{\cdots}H^+$] ionic pair in the non-hydrated PSSA to an $SO_3H$ group, but also induced the formation of -C=C- double bonds in the dehydrated PSSA. Second, the ${-SO_3}^{\bullet}$ radical was unambiguously identified by EMR spectroscopy. Third, H-abstraction was detected by $^1H$ magic-angle spinning spectroscopy. Finally, an unexpected color shift from white for the non-hydrated PSSA to a yellowish brown for the dehydrated sample was observed. In order to explain these experimental results, it was proposed that the formation of the intermediate hydrogen ($H^{\bullet}$) or hydroxyl radical ($HO^{\bullet}$) species was initiated by the dehydration process. The sespecies attacked the $SO_3H$ group and the tertiary proton at the ${\alpha}-carbon$, resulting in the formation of $-SO^{\bullet}$ radicals and -C=C- double bonds, which correlated with the color shift in the dehydrated PSSA sample. The semechanisms are useful for understanding the simultaneous loss of an aromatic ring and -SO- groups in the PSSA fuel cell membrane.

• 한국펄프종이공학회:학술대회논문집
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• 한국펄프종이공학회 2004년도 춘계학술발표논문집
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• pp.192-210
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• 2004

Application methods of chemicals were investigated tn minimize strength reduction of corrugated boards under the high humidity environment encountered in the cold chain system. Starch insolubilizers were introduced in the starch solution preparation of the Stain hall method and their insolubilization effect of starch binder were estimated. The performance of water repellent agents(WRA) and moisture proof agents(MPA) were evaluated in terms of water and moisture resistance. And effects of the combination of the chemicals and the coating method were also examined. Addition of the polyamine polyamide insolubilizer to the main part in the Stain hall process improved the binding force and water resistance of starch, which contributed to minimize the strength reduction of paper under the high humidity environment. AZC and Glyoxal type insolubilizers could not be used in the experiment due to an excessively increased viscosity of starch solution and the poor stability. Conventional WRA treatment to the base paper enhanced water and moisture resistance very slightly even though water repellency of the paper reached R10 by the treatment. MPA showed excellent performance than WRA not only in water and moisture resistance but in water repellency. Double coating on paper with MPA was more effective than the single coating at the same coating weight. A newly developed MPA showed excellent performance and runnability only by a single coating instead of a double coating.

• Journal of Chest Surgery
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• 제18권2호
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• pp.241-249
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• 1985

Twenty-one patients with Double Chambered Right Ventricle [DCRV] associated with Ventricular Septal Defect [VSD] were treated by open heart surgery under cardiopulmonary bypass with moderate hypothermia in the Department of Thoracic and Cardiovascular Surgery, Hanyang University Hospital between June 1982 and October 1984. The following results were obtained 1. The symptoms and physical signs, specific for DCRV, could not be identified. 2. The radiologic findings on simple chest X-ray, specific for DCRV, could not be identified. 3. Electrocardiographic findings, specific for DCRV, could not be identified. 4. Cardiac catheterization was found to be the most important diagnostic method, revealing pressure gradient between proximal chamber and distal chamber in the right ventricle. The average pressure gradient between two chambers showed 48.1523.29 mmHg[varying from 15mmHg to 94mmHg]. 5. Cardiac angiography was found to visualize the anomalous muscle bundles in right ventricle [in 17 cases, 81%] but the evidence of pressure gradient between two chambers within right ventricle is considered necessary for the diagnosis of DCRV. 6. Via surgical observation, anatomical and pathologic findings of the anomalous muscle bundles, associated DCRV were identified. 7. As the direct pressure was measured on the operating table before and after surgery, the average pressure gradient across the muscle bundles showed 40.5219.75mmHg [varying from 16 to 89mmHg] preoperatively and 8.909.72mmHg [varying from 0 to 32mmHg] postoperatively, indicating significant surgical correction of the obstruction present. 8. The presence of anomalous muscle bundles, dividing the right ventricle into two separated chambers, and the presence of the pressure gradient over 15mmHg are considered necessary for the diagnosis of DCRV.

• 한국정보통신학회논문지
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• 제19권12호
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• pp.2892-2898
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• 2015

양극성 이중 독립 게이트 실리콘 나노와이어 전계 효과 트랜지스터를 새롭게 제안한다. 제안한 트랜지스터는 극성 게이트와 제어 게이트를 가지고 있다. 극성게이트의 바이어스에 따라서 N형과 P형 트랜지스터의 동작을 결정할 수 있고 제어 게이트의 전압에 따라 트랜지스터의 전류 특성을 제어할 수 있다. 2차원 소자 시뮬레이터를 이용해서 양극성 전류-전압 특성이 동작하도록 두 개의 게이트들과 소스 및 드레인의 일함수를 조사했다. 극성게이트 4.75 eV, 제어게이트 4.5 eV, 소스 및 드레인 4.8 eV일 때 명확한 양극성 특성을 보였다.

• 대한치과보철학회지
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• 제38권2호
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• pp.214-225
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• 2000

The purpose of this study was to investigate the effects of investing conditions on the marginal discrepancy of conical telescope outer crown with Co-Cr-Ti alloy(Dentitan) and to compare the marginal discrepancy and the retention force of outer crowns using different pattern materials(plastic foil, casting wax, pattern resin). To evaluate the effects of investing conditions on the marginal discrepancy, patterns with plastic foil were invested under three different liquid/powder ratio conditions using phosphate bonded investment(Univest-nonprecious): standard, 10% decreased and 10% increased. At each liquid/powder ratio condition, metal ring was lined with single or double layers of ceramic ring liner. The marginal discrepancy of outer crown at different investing conditions was measured by ${\times}100$ compact measuring microscope(STM5, Olympus, Japan). For measurement of the marginal discrepancy and the retention force of outer crown using different pattern materials, the investing condition of 10% decreased liquid/powder ratio and double layers of ring liner was selected because this investing condition resulted in the best fit of outer crown. Marginal discrepancy was measured in the same way above and retention force on universal testing machine. Under the conditions of this study, the following conclusions were drawn: 1. The thickness of ring liner had more influence on the marginal discrepancy of outer crown than the liquid/powder ratio, and the acceptable marginal fitness could not be expected at the investing condition directed by investment manufacturer 2. There were no differences in the marginal discrepancy of outer crown among three different pattern materials(P>0.05). 3. Casting wax showed the greatest retention force(1640g) of outer crown, followed by pattern resin(1110g), plastic foil(820g). However, there was no significant difference between plastic foil and pattern resin(P>0.05). 4. Plastic foil showed the least variation in marginal discrepancy and retention force.

• 한국콘텐츠학회논문지
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• 제19권11호
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• pp.482-498
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• 2019

본 연구는 장·노년층의 스마트폰 중독에 관련하여 이에 영향을 미치는 주요 변인들과의 인과관계를 검증하고자 하였다. 특히, 장·노년층의 스마트폰 중독에 영향을 미치는 주요 요인으로 사회적 고립감에 초점을 맞추어 장·노년층의 사회적 고립감이 자아통제감과 사회적지지에 영향을 미치는 동시에, 자아통제감과 사회적지지를 매개하여 스마트폰 중독에 영향을 미칠 것으로 보고 연구모형을 설정하였다. 이를 위하여 본 연구는 대전광역시에서 거주하는 장·노년층을 대상으로 1:1 설문조사를 실시하여 404명의 자료를 수거하였으며, 최종 404명의 자료를 분석하였다. 구조방정식모형을 통해 분석한 결과, 장·노년층의 사회적 고립감은 스마트폰 중독에 직접적인 영향을 미쳤으며, 자아통제감과 사회적지지의 이중매개 경로를 거쳐 스마트폰 중독에 영향을 미치는 것으로 나타났다. 본 연구는 이러한 연구결과에 기초하여 장·노년층의 스마트폰 의존 특성을 이해하고 관련 연구를 제고시킴은 물론, 함의 및 관련 후속연구의 필요성을 제시하였다.

• 농업과학연구
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• 제23권1호
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• pp.13-24
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• 1996

널말뚝을 이용하여 연약지반을 굴착할 때 굴착단계에 따른 지반의 변위 변형 및 안정성을 분석하여 다음과 같은 결론을 얻었다. 1. 수평방향의 변위는 버팀대 설치전에는 굴착면 상부에서 크게 나타났으나, 버팀대 설치 후는 굴착저면의 아래쪽으로 이동되면서 집중되는 현상을 나타냈다. 2. 버팀대 설치후에 널말뚝의 변위는 설치 전보다 1/2정도로 급격히 감소함을 나타냈고, 지반의 안정한 굴착깊이의 한계는 2단 버팀대 설치후는 GL-8.0m정도로 나타났다. 3. 최대전단변형은 굴착깊이에 따라 점차로 증가하였고, 또 굴착저면에서 나타나는 전단변형에 의한 국부적인 파괴가능성은 버팀대로 보강함으로써 감소시킬 수 있었다. 4. GL-7.5m에서 널말뚝의 최대수평변위는 탄소성법에서는 굴착깊이의 0.2%, 유한요소법에서는 0.6%로 나타났으며, 굴착저면부근에서 최대변위를 나타냈다. 5. 해석모델지반에서 근입깊이에 대한 안전성을 확보하기 위해서는 버팀대 1단 설치의 경우는 D/H가 0.89이상, 2단설치의 경우는 D/H가 0.77이상이 될수 있도록 근입깊이를 확보하여야 할 것으로 판단된다. 6. 근입깊이에 대한 안전율과 D/H와의 관계에서 버팀대 1단 설치의 경우는 Fs = 0.736(D/H) + 0.54, 버팀대 2단 설치의 경우는 Fs = 0.750(D/H) + 0.62의 관계식을 나타냈다.

• Bulletin of the Korean Chemical Society
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• 제23권2호
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• pp.295-300
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• 2002

The construction of the T-shaped post-column flow cell has been changed to enhance the practicability as a UV-visible absorbance detector for capillary electrophoresis. In this new design, a rectangular cube-shaped inner structure is employed, which completely fits the outer rectangular tubing. This arrangement has greatly facilitated the fabrication of the T-cells. In addition, the volume for the auxiliary flow has been dramatically reduced down to 300 ${\mu}L$, and its volume flow rate is optimized at 4.2 ${\mu}L$/min. The short optical path length in the sheath flows (500 ${\mu}m$ on each side) minimizes background absorption, and thus enhances its performance in low-UV wavelengths. We have optimized the auxiliary flow rate at 50 ${\mu}m$/s, so that migration times are insensitive to the flow rate. This optimization has improved repeatabilities in migration times and peak heights. A double-beam detection scheme using a pair of photodiodes is employed to increase the signal-to-noise ratio.

• 펄프종이기술
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• 제34권1호
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• pp.46-53
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• 2002

This study was carried out to analyze the effects of preservation temperature and relative humidity to the physical properties of corrugated fiberboard boxes for fruit and vegetable packaging. The preservation temperature did not affect severely to physical properties of corrugated fiber-board. Relative humidity was a major cause of corrugated fiberboard box quality deterioration. The burst and compressive strengths of experimental boxes measured with Mullen high pressure tester and tong crush tester were decreased gradually as relative humidity increased from 55% to 75%. But, the strength properties slightly decreased relative humidity at 75% or higher. This tendency was the greater for single wall (SW) corrugated fiberboard box than that for double wall (DW). It is suggested that development of the water-resistant corrugated fiberboard and box be needed that can be used under the condition of low temperature and high moisture content, which are being employed in the cold chain system.

• 한국포장학회지
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• 제7권2호
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• pp.43-51
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• 2001

This study was carried out to analyze changes of the physical properties of corrugated fiberboard boxes for fruits packaging by various moisture and temperature changes. There were significant decrease in burst strength with increased relative humidity. And also compressive strength(ring crush test) of corrugated fiberboard and box were reduced with moisture content. The decreasing amounts of single wall(SW) corrugated fiberboard was bigger than that of double wall(DW). The physical properties reductions of corrugated fiberboard and box were mainly affected by relative humidity. Therefore, it is suggested that development of the water-resistant corrugated fiberboard and box be useful under the condition of low temperature and high relative humidity such as the cold chain system.