• Title/Summary/Keyword: distribution of chemical species

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Chemical characteristics of particulate species in Mt. Sobaek atmosphere(I) : The distribution and behaviour of major ion components (소백산 대기 중 입자상 물질의 화학적 특성에 관한 연구(I) : 이온 성분의 분포와 거동을 중심으로)

  • 이선기;최재천;이민영;최만식
    • Journal of Korean Society for Atmospheric Environment
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    • v.11 no.2
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    • pp.179-184
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    • 1995
  • This study was carried out to characterize sources of suspended particulate matter(SPM) in Mt. Soback area from January to Novembver in 1993. The collection and major water soluble ion analysis of SPM were conducted by using a High Volumn Air Sampler(HVAS; W&A Inc., PM-10) and ion chromatograph(DIONEX 4000i), respectively. The variations of SPM and major ion concentrations were found to be 9. sim. 156.mu.g/ $m^{3}$, $F^{-10}$ 0.00 .sim. 0.15.mu.g/ $m^{3}$, C $l^{-10}$ 0.06 .sim. 3.79.mu.g/ $m^{3}$, N $O_{3}$$^{-10}$ 0.90 .sim. 6.85.mu.g/ $m^{3}$, S $O_{4}$$^{2-}$ 1.99 .sim. 9.36.mu.g/ $m^{3}$ N $a^{+}$0.00 .sim. 0.27.mu.g/ $m^{3}$, N $H_{4}$ $^{+}$0.72 .sim. 5.77.mu.g/ $m^{3}$, $k^{+}$0.03 .sim. 0.88.mu.g/ $m^{3}$ and $Ca^{2+}$0.12 .sim. 2.76.mu.g/ $m^{3}$. Tree sources were identified by Principal Component Amalysis(PCA) using a SPSS/P $C^{+}$. The explanation ability of forst, second and third Principal Component were 60.8%, 13.6%, 8.2%, of total variance. The sources classfied by PCA were found to be secondary aerosol/fuel combustion, soil dust related cement production/yellow sand and aerosol related waste burning.related waste burning.g.

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Chemical Composition Characteristics of Dustfall in Nakdong River Area (낙동강 하류역 강하먼지의 화학적 조성 특성)

  • Jeon, Byung-Il;Hwang, Yong-Sik
    • Journal of the Korean earth science society
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    • v.25 no.6
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    • pp.428-442
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    • 2004
  • Dustfall samples were collected by the modified American dust jar (bulk type) at 5 sampling sites in the Nakdong river area from lune 2002 to May 2003. Nineteen chemical species (Al, Ca, Cd, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, Pb, Si, V, Zn, $Cl^-$, $NO_3^-$, $SO_4^{2-}$, and $NH_4^+$) were analyzed via the combination of ICP/AES, AAS, IC and UV. The purposes of this study were to qualitatively evaluate the chemical composition of dustfalls by examining their regional and seasonal distribution patterns. Computation of the enrichment factor showed that well-defined anthropogenic sources, particularly in Pb were found in the order Gamjeondong (industrial area), Wondong, Silla University, Samrangiin and Mulgum. The seasonal mean of soil contribution showed its highest value (16.3%) during the winter with an annual mean of 11.2%. The concentration ratio of [$SO_4^{2-}/NO_3^-$] was found to be highest (5.12) during the winter, while the lowest ratio value (3.30) was seen during the all. fall, Also regional equivalent ratios of [$SO_4^{2-}/NO_3^-$] were found in the order: Silla University (6.78), Gamjeondong (4.98), Mulgum (3.95), Wondong (3.85), and Samrangjin (2.87). Seasonal distribution of water soluble components for total dustfall were found in the order: spring (71.6%), summer (61.2%), fall (49.2%) and winter (48.6%) with a mean ratio of 57.6%. Regional contribution of sea salts of water soluble ions were found in the order: Silla university (34.5%), Gamjeondong (28.3%), Wondong (17.3%), Samrangiin (17.2%) and Mulgum (13.8%), the total mean contribution rate was 22.1%. As for the chemical composition of dustftll on the lower Nakdong river, there is a decreased influence of sea salt and artificial anthropogenic sources and increased influence of soil particle inland. Also, the total amount of deposition on the lower Nakdong river has decreased, with the river's surface serving as a confounding factor in resuspending dusts.

Accumulation of Microcystins in Fish and Evaluation of Potential Human Health Risks: A Case Study on a Eutrophic Reservoir in Korea (마이크로시스틴의 어류내 축적성 및 인체 위해성 평가: 국내 저수지 사례연구)

  • Yoon, Hyojung;Seo, Jungkwan;Kim, Taksoo;Jo, Areum;Kim, Jungkon;Lee, Doohee;Kim, Pilje;Choi, Kyunghee
    • Journal of Environmental Health Sciences
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    • v.42 no.1
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    • pp.10-18
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    • 2016
  • Objectives: Microcystin (MC) produced during cyanobacterial blooms is a worldwide problem presenting a serious health threats to humans and ecosystems. During July through October of 2013, the Ilwol Reservoir experienced a high biomass of phytoplankton (maximum $211.7mg/m^3$ of Chlorophyll-a) containing the toxigenic cyanobacterium Oscillatoria sp. The aim of this study is to analyze MC concentration in the reservoir water, as well as in representative fish species (Carassius cuvieri, Carassius auratus, Channa argus). We also evaluated the human health risk of exposure to MCs accumulated in the fish. Methods: Concentrations of MCs in the water and fish samples were analyzed by liquid chromatography with a triple quadrupole tandem mass spectrometer (LC/MS/MS) and enzyme-linked immunosorbent assay (ELISA). Results: The total levels of four MC variants, including MC-LR, MC-RR, MC-YR and MC-LA were below the WHO drinking water guideline limit (1 ug MC-LR per liter) both for the dissolved and particulate fraction present in the water samples. The mean MC concentrations in the livers of all species were significantly higher than in the gills (p < 0.01) and muscles (p < 0.05). The values of estimated daily intake of MCs in muscles, the edible part of the fish, would be only $0.005-0.015{\mu}g/kg{\cdot}day$, much lower than WHO's provisional tolerable daily intake of $0.04{\mu}g/kg{\cdot}day$. Conclusion: This study suggests that, owing to the spatial distribution or temporal variation of MC, there is a need for careful monitoring of cyanotoxin in reservoir water and aquatic animals to protect public health.

STUDIES ON ENVIRONMENTAL FACTORS IN MARINE BIVALVE CULTURE (패류양식을 위한 적지환경요인에 관한 연구)

  • LEE Choonkoo;CHANG Nam Kee;CHOI Shin Sok
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.2 no.1
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    • pp.33-40
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    • 1969
  • 1. Physicochemical properties of sea water and soil of Korean tidal flats densely populated with species of Mactra veneriformis, Cyclina sinensis, Meretrix lusoria, and Tapes philippinarum, were investigated in order to find out the index of environmental factors in marine bivalve culture. 2. The turbidity varied with the change in concentrations of organic matter, silicate, and the exchangeable copper in sea water. All of these concentrations in Inchon, Kunsan, and Hansando were higher than those in Yusoo. In the 5 areas investigated the lowest were ditected at Kangnung. 3. The minerals and organic matter content in sea water dia not vary significantly among the different bivalve beds. And it was presumed that the soil texture was one of the most important environmental factors for the density of the bivalves in tidelands. 4. The soil texture index of the different bivalve beds was obtained as follow: 5. There were no significant differences of pH, the exchangeable calcium, and the exchangeable copper contents of bottom soils in the 4 different bivalve beds. As important factors in these areas, it seems that the amount of chemical properties might not affect the distribution of bivalve species. 6. Among the 4 beds the soil organic matter content was highest at the T. philippinarum bed and varied with the total nitrogen content. 7. Among the different bivalve beds, it was significant that the water holding capacity and available phosphorus content were highest at the M. veneriformis bed.

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Habitat Classification and Distribution Characteristic of Aquatic Insect Functional Feeding Groups in the Geum River, Korea (금강 수계 서식지 유형분류 및 수서곤충 섭식기능군 분포특성)

  • Park, Young-Jun;Kim, Ki-Dong;Cho, Young-Ho;Han, Yong-Gu;Kim, Yeong-Jin;Nam, Sang-Ho
    • Korean Journal of Environment and Ecology
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    • v.25 no.5
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    • pp.691-709
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    • 2011
  • This study was performed to classify habitat types depending on environmental factors and to find out distribution characteristics of functional feeding groups of aquatic insects which were collected at that habitat types. Field survey was conducted twice in a year for every spring and fall from 2007 to 2008 for 38 sites in the Geum River. During the field survey 15 environmental factors were measured at each 38 sites and analyzed by similarity analysis method to classify habitat types. The result of similarity analysis showed that the 38 sites could be grouped into 7 classes like as C1 and C3 class belong to Head water(HD), C2 and C4 and C5 class belong to Middle stream(MS), C6 and C7 class belong to Large River(LR) based on euclidean distances 4. And also, we could extract the main environmental factors affecting the classification of habitat types such as Stream Width and Elevation of physical environmental factors, Water Temperature, Conductivity and DO of chemical environmental factors, percentages of Sand, Silt and Gravel of substrate factors. Total 142 species of aquatic insects in 46 families, 9 orders were collected during the field surveys and the occurrence number of species and individuals showed high correlation with the Velocity factor and the percentage of Sand factor of each habitat types. In addition, correlation analysis between functional feeding groups and environmental factors represented that (1) Filtering-collectors(FC) affected by Velocity, Stream Width and Silt, (2) Gathering-collector(GC) affected by Velocity, (3) Predator(P) affected by Elevation, Velocity, Boulder, Conductivity and Sand, (4) Plant-piecer(PP) affected by Water Width and Silt, (5) Scraper(SC) affected by Elevation and Conductivity, (6) Shredder(SH) affected by Elevation, Boulder, DO, pH, Conductivity and Water Temperature respectively. As a result of this study, Elevation, Stream Width, Velocity, Conductivity, Water Temperature and percentage of Sand factors which were deduced by stepwise multiple regression analysis had correlations($r{\geqq}0.600$, p<0.01) with biota community inhabitation. Therefore these six environmental factors were regarded as major environmental factors that might affect highly the distribution of functional feeding groups in stream ecosystem of the Geum River.

A Study of Variation Characteristics of the Phytoplankton Community by UPLC Located in the Jinju Bay, Korea (UPLC를 이용한 남해 진주만 식물플랑크톤 군집 변동특성 연구)

  • Lee, Eugene;Son, Moonho;Kim, Jeong Bea;Lee, Won Chan;Jeon, Ga Eun;Lee, Sang Heon
    • Korean Journal of Environmental Biology
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    • v.36 no.1
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    • pp.62-72
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    • 2018
  • In order to provide important information for the efficient management of the identified farm ecosystem in Jinju Bay, we investigated the spatial and temporal distribution of the phytoplankton community using a UPLC pigment analysis and a CHEMTAX program from the timeframe of February 2013 to January 2014. In addition, we measured the available physical and chemical parameters controlling the distribution of the phytoplankton communities. As a result of this comprehensive pigment analysis, it was noted that the Diatoms were the predominant species with an average of 77.1% as noted located in Jinju Bay. It was discovered that during the summer season, the phytoplankton community composition was changed by a reduction of diatoms and noted increases of the Cryptophytes, Prasinophytes, and Dinoflagellates. Especially, it was noted that the Cryptophytes and Prasinophytes were shown with an average of 18.8% and 17.8% in June, respectively. However, it was revealed that the Cryptophytes and Prasinophytes were not shown by a microscopic observation. The phytoplankton community composition was correlated with the temperature and salinity variations as noticed in the Jinju Bay. Therefore, the water temperature and freshwater inputs in the Jinju Bay were important environmental factors for controlling the phytoplankton community composition and the varying Cryptophytes and the noted amounts of Prasinophytes as well.

Relationship Between Soil Properties and Tip Burn of Chinese Chive Cultivated in Plastic Film House (시설재배 부추 잎끝마름증 발생에 영향을 미치는 토양특성)

  • Seo, Young-Jin;Choi, Young-Seub;Park, Jun-Hong;Kweon, Tae-Young;Choi, Seong-Yong;Kim, Chan-Yong;Kim, Jong-Su;Park, So-Deuk;Park, Man;Jeon, Sang-Ho;Jang, Yong-Sun;Ha, Sang-Keun
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.3
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    • pp.380-386
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    • 2011
  • Tip burn has been reported as one of the most serious physiological disorder in Chinese chives (Allium tuberosum Rottl.) cultivated in plastic film house. In this study, a physiography and chemical properties of 132 plastic film house soils were investigated to elucidate factors affecting tip burn symptom. Also influence of soil properties on tip burn was statistically determined by path analysis and association analysis including a chi-square test or logistics analysis. Probability distribution of inorganic aqueous species, such as ammonia (g) was calculated using MINTEQ program. Soil order and chemical properties, especially pH, exchangeable calcium and inorganic nitrogen, showed a significant relationship with tip burn of Chinese chives. Tip burn symptoms occur mainly in an alkaline soil classified as Alfisols. Result of linear regression and path analysis exhibited that formation of ammonia (g) from soil solution depend upon soil pH and were associated with ammonium resulting from soil organic matter or nitrate. These results indicate that tip burn symptom of Chinese chives is directly affected by ammonia gas originated from alkaline soil condition.

Formation of Passivation Layer and Its Effect on the Defect Generation during Trench Etching (트렌티 식각시 식각 방지막의 형성과 이들이 결함 생성에 미치는 영향)

  • Lee, Ju-Wook;Kim, Sang-Gi;Kim, Jong-Dae;Koo, Jin-Gon;Lee, Jeong-Yong;Nam, Kee-Soo
    • Korean Journal of Materials Research
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    • v.8 no.7
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    • pp.634-640
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    • 1998
  • A well- shaped trench was investigated in view of the defect distribution along trench sidewall and bottom using high resolution transmission electron microscopy. The trench was formed by HBr plasma and additive gases in magnetically enhanced reactive ion etching system. Adding $0_2$ and other additive gases into HBr plasma makes it possible to eliminate sidewall undercut and lower surface roughness by forming the passivation layer of lateral etching, resulted in the well filled trench with oxide and polysilicon by subsequent deposition. The passivation layer of lateral etching was mainly composed of $SiO_xF_y$ $SiO_xBr_y$ confirmed by chemical analysis. It also affects the generation and distribution of lattice defects. Most of etch induced defects were found in the edge region of the trench bottom within the depth of 10$\AA$. They are generally decreased with the thickness of residue layer and almost disappeared below the uni¬formly thick residue layer. While the formation of crystalline defects in silicon substrate mainly depends on the incident angle and energy of etch species, the region of surface defects on the thickness of residue layer formed during trench etching.

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Environmental Factors and Growth Properties of Sasa borealis (Hack.) Makino Community and Effect its Distribution on the Development of Lower Vegetation in Jirisan National Park (지리산국립공원 조릿대의 입지환경 및 생장특성 분석과 하층식생에 미치는 영향)

  • Park, Seok-Gon;Yi, Myung-Hoon;Yoon, Jung-Won;Sin, Hyun-Tak
    • Korean Journal of Environment and Ecology
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    • v.26 no.1
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    • pp.82-90
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    • 2012
  • In this study, we investigated the environmental factors and growth characteristics of Sasa borealis community inside a temperate deciduous forest and reviewed its effect on the lower vegetation and natural regeneration. The S. borealis community in the Jungsan-ri region of Jirisan National Park was chosen as the study area, and the vegetation and the environmental factors were investigated. The dominance value, height and foliage layer thickness were investigated as the growth characteristics of S. borealis in the area. As the environmental factors, we investigated the photosynthesis photon flux density (PPFD) of the shrub and ground layers as well as the chemical characteristics of the soil. Additionally, we investigated the flora on the ground layer of the area as well as the number and height of woody plants. The result showed that the height and foliage layer thickness of the S. borealis was closely related to the light conditions but the distribution was not determined simply by the effect of the environment or vegetation of the particular area. This may be deeply related with the unique survival strategy of S. borealis, a vegetably propagated plant, that it can extensively distributed on a heterogeneous resources environment in a forest as multiple culm are interconnected with each other through the rhizomes. The dense dominance and great height of S. borealis reduced the plant species diversity in the ground layer by decreasing the PPFD on the ground surface.

Effects of Fiber Characteristics on the Greaseproofing Property of Paper

  • Perng, Yuan-Shing;Wang, Eugenei-Chen;Kuo, Lan-Sheng;Chen, Yu-Chun
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2006.06b
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    • pp.231-237
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    • 2006
  • Grease barrier food containers are commonly used for packaging of fast food, cooked food, and food in general. Greaseproofing is also used for certificate paper and label paper etc. Different pulp raw materials, due to their different fiber morphology and chemical compositions, produce papers of varying characteristics. We used optical photomicroscopy and fiber analysis data to evaluate fiber morphology and traits under various beating conditions in order to understand which pulp raw materials produced superior greaseproofing property when a fluorinated greaseproofing agent was added internally. The experiment studied 9 species of pulps, including 2 softwood (northern pine and radiata pine) bleached kraft pulps which were beaten to 550 and 350 mL CSF, respectively; 3 hardwoods (eucalypts, acacia, mixed Indonesian hardwoods) bleached kraft pulps which were beaten to 450 and 250 mL CSF, respectively; and nonwood fibers of reed, bagasse, and abaca. A fluorinated greaseproofing chemical at 0.12% dosage with respect to dry pulp was added to each pulp preparation and formed handsheets. A total of 67 sets of handsheets were prepared, and their basis weights, thickness, bulks, opacities, wet opacities, air resistance, water absorption and degrees of greaseproofing were measured for an overall evaluation of pulp and freeness on greaseproofing papers. The experimental fiber length, coarseness and distribution characteristics and the greaseproofing results suggest that softwood pulps (radiate pine > northern pine) were superior to hardwood pulps (eucalypts > acacia > mixed Indonesian hardwoods). The unbeaten pulps gave papers with high porosities and nearly devoid of greaseproofing property. Greaseproofing is proportional to air resistance. Among the nonwood fibers, bagasse had the best greaseproofing property, followed by reed and abaca was the poorest. With regards to waterproofing property, hardwood pulps (mixed Indonesian hardwoods > acacia > eucalypts) were better than softwood pulps (northern pine > radiate pine). Among the Nonwood fibers, reed had the highest waterproofing property, and it was followed by abaca, while bagasse had the poorest waterproofing characteristic. In summary, bleached kraft northern pine, eucalypts and reed pulps were best suited for making greaseproofing papers, Freeness of the pulps should be kept at $200{\sim}280mL$ CSF for optimal performance.

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