• Title/Summary/Keyword: distribution of chemical species

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Influence of Sediment on the Chemical Speciation of Copper and Cadmium in an Aquatic System (저질이 천연수중 구리와 카드뮴의 화학종 분포에 미치는 영향)

  • 이군자;박청길
    • Journal of Environmental Science International
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    • v.1 no.2
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    • pp.59-69
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    • 1992
  • In order to predict the distribution of chemical species of copper and cadmium in water, conditional stability constant and complexation capacity between copper or cadmium and natural aquatic sediment have been determined in a shallow lake in Haman, Kyungnam. Kinetic parameters were calculated by Langmuir isotherm equation. Conditional stability constant was log $K_{cuSed}=4.78 and log K_{cdSed}=4.45$. Complexation capacity was $1.70{\times}10^{-4}$moles/g for copper and $5.54{\times}10^{-5}$moles/g for cadmium. Accuracy of experimental values of conditional stability constant was checked by comparing the calculated concentration of the metals with the measured one. Relatively good agreement between these values was obtained. Relative errors were 8.9% for copper and 6.5% for cadmium. Data of the measured conditional stability constant were put into data base of MINEQL computer program, and concentration of various chemical species of copper and cadmium in a model aquatic system was calculated. Aquatic sediment was associated with copper at the concentration of $10^{-5M}(0.059g/\ell)$10-5M(0.059g/l) and with cadmium at the concentration of $10^{-6M}(0.018g/\ell)$, and it significantly influenced on the distribution of chemical species of the metals. This result showed that prediction of chemical species of the heavy metals in an aquatic system should be taken into account the influence of the sediment.

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Single Particle Analysis of Atmospheric Aerosol Particles Collected in Seoul, 2001, Using Low-Z Particle Electron Probe X-ray Microanalysis (Low-Z Particle Electron Probe X-ray Microanalysis를 이용한 2001년 서울시 대기 중 입자상 물질 분석)

  • Koo Hee Joon;Kim HyeKyeong;Ro Chul-Un
    • Journal of Korean Society for Atmospheric Environment
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    • v.20 no.6
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    • pp.823-832
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    • 2004
  • Atmospheric aerosol particles collected in Seoul on four single days, each in every seasons of 2001, were characterized and classified on the basis of their chemical species using low-Z particle electron probe X-ray microanalysis (low-Z particle EPMA). Low-Z particle EPMA technique can analyze both the size and the chemical species of individual aerosol particles of micrometer size and provide detailed information on the size distribution of each chemical species. The major chemical species observed in Seoul aerosol were aluminosilicate, silicon dioxide, calcium carbonate, organic, carbon-rich, marine originated, and ammonium sulfate particles, etc. The soil originated species, such as aluminosilicate, silicon dioxide, and calcium carbonate were the most popular in the coarse fraction, meanwhile, carbonaceous and ammonium sulfate were the dominant species found in the fine fraction. Marine originated species such as sodium nitrate was frequently encountered, up to 30% of the analyzed aerosol particles.

Two-dimensional continuum modelling of an inductively coupled plasma reactor

  • Kim, Dong-Ho;Shung, Won-Young;Kim, Do-Hyun
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.10 no.2
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    • pp.128-133
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    • 2000
  • Numerical analysis of the transport phenomena in an inductively coupled plasma reactor was conducted with two-dimensional axisymmetric model including the electromagnetic field model, electron and species density models. The spatial distribution of the charged species in the ion flux to the wafer have been calculated to examine the influence of the process conditions including antenna and reactor geometry. The antenna radius had a significant influence on the plasma state and axial ion flux distribution.

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Distribution characteristic of invasive alien plants in Jeju Island

  • Ryu, Tae-Bok;Kim, Mi-Jeoung;Lee, Chang-Woo;Kim, Deok-Ki;Choi, Dong-Hui;Lee, Hyohyemi;Jeong, Hye-Ran;Lee, Do-Hun;Kim, Nam-Young
    • Journal of Ecology and Environment
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    • v.41 no.6
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    • pp.173-181
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    • 2017
  • Background: This study was undertaken to analyze the distribution and ecological characteristics of invasive alien plant species on Jeju Island, and to provide basic data for their management and control. Results: A field research was conducted at 436 locations on Jeju Island. The field research identified nine species of invasive alien species growing on Jeju Island. Based on the distribution pattern, Hypochaeris radicata L., Rumex acetosella, and Ambrosia artemisiifolia L. were found to be distributed horizontally throughout Jeju Island, with vertical growth in two or more vegetation zones, from warm temperate to the subalpine zone. Widely distributed species penetrate various habitats, such as grasslands, ranches, roadsides, farmlands, and empty lots, and have an immensely negative impact on the ecosystem, including declining biodiversity on Jeju Island. Paspalum distichum var. indutum Shinners, Paspalum distichum L., Solanum carolinense L., and Aster pilosus Willd. were distributed in some areas as a biased distribution species, whereas Lactuca scariola L. and Solidago altissima L. were found only in certain areas as centralized distribution species. Conclusions: The centralized distribution species and biased distribution species of the invasive plants in the ecosystem of Jeju Island should be physically eliminated, keeping in mind the short- and mid-term perspectives and monitoring, and by considering expansion of additional distribution areas. Due to limitations of physical/chemical elimination, time, and cost, widely distributed species require to be eliminated and managed, mainly to restore the integrity of the ecosystem, by planting native species to reestablish the habitat.

Distributional Pattern of Tree Species in Response to Soil Variables in a Semi Natural Tropical Forest of Bangladesh

  • Ara, Saida Hossain;Limon, Mahedi Hasan;Kibria, Mohammad Golam
    • Journal of Forest and Environmental Science
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    • v.37 no.1
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    • pp.14-24
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    • 2021
  • A plant community is a group of populations that coexist in space and interact directly or indirectly with the environment. In this paper, we determined the pattern of tree species composition in response to soil variables in Khadimnagar National Park (KNP), which is one of the least studied tropical forests in Bangladesh. Soil and vegetation data were collected from 71 sample plots. Canonical Correspondence Analysis (CCA) with associated Monte Carlo permutation tests (499 permutations) was carried out to determine the most significant soil variable and to explore the relationship between tree species distribution and soil variables. Soil pH and clay content (pH with p<0.01 and Clay content with p<0.05) were the most significant variables that influence the overall tree species distribution in KNP. Soil pH is related to the distribution and abundance of Syzygium grande and Magnolia champaca, which were mostly found and dominant species in KNP. Some species were correlated with clay content such as Artocarpus chaplasha and Cassia siamea. These observations suggest that both the physico-chemical properties of soil play a major role in shaping the tree distribution in KNP. Hence, these soil properties should take into account for any tree conservation strategy in this forest.

Relationship between Plant Species Covers and Soil Chemical Properties in Poorly Controlled Waste Landfill Sites

  • Kim, Kee-Dae;Lee, Eun-Ju
    • Journal of Ecology and Environment
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    • v.30 no.1
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    • pp.39-47
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    • 2007
  • The relationships between the cover of herbaceous species and 15 soil chemical properties (organic carbon contents, total N, available P, exchangeable K, Na, Ca and Mg, HCl-extractable Cd, Cr, Cu, Fe, Mn, Ni, Pb and Zn) in nine poorly controlled waste landfill sites in Korea were examined by correlation analysis and multiple regression equations. Species showed different patterns of correlation between their cover values and soil chemical properties. The cover of Ambrosia artemisiifolia var. elatior, Aster subulatus var. sandwicensis and Erechtites hieracifolia were negatively correlated with the contents of Fe, Mn and Ni within landfill soils. Total cover of all species in quadrats was positively correlated with the contents of Cd and negatively correlated with the contents of Mn and Fe from stepwise regression analysis with 15 soil properties. Canonical correspondence analysis demonstrated that the distribution of native and exotic plants on poorly controlled landfills was significantly influenced by the contents of Na and Ca in soils, respectively.

Study on optical emission spectroscopic method for measuring OH radical distribution in rocket plume (로켓 플룸 내부 OH 라디칼 공간분포 계측을 위한 발광 분광 기법에 관한 연구)

  • Han, Kiwook;Hahn, Jae W.
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2017.05a
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    • pp.1135-1139
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    • 2017
  • Spatial distribution of chemical species in flame is a important indicator understanding the flame structure and combustion characteristics, and optical emission spectroscopy has been widely used for the measurement because of its simple and non-intrusive methodology. In this study, we suggest the feasibility of the measurement of chemical species (OH radical) distribution in rocket plume using optical emission spectrometer which was developed for the spatially resolved measurement along the line-of-sight. In order to predict the ground state concentration of species from the measured emission intensity by optical emission spectrometer, we consider thermal and chemical excitation mechanisms in flame, and assume thermodynamic equilibrium for the thermally excited species. We also present the spatial resolution and the correction of collection characteristics of the optical emission spectrometer depending on object distance.

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Simulation on the Distribution of Vanadium- and Iron-Picolinate Complexes in the Decontamination Waste Solution (제염 폐액에서 바나듐- 및 철-피콜리네이트 착화물의 평형분배 모사)

  • Shim, Joon-Bo;Oh, Won-Zin;Kim, Jong-Duk
    • Korean Chemical Engineering Research
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    • v.43 no.1
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    • pp.33-38
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    • 2005
  • The distribution of vanadium and iron ionic species in the presence of picolinate ligand has been simulated at various conditions with different pH values and compositions in the decontamination waste solution. In spite of variations of metal concentration in the decontamination solution, the shape of distribution diagrams were not changed greatly at both high (the molar ratio of picolinate to vanadium is 6) and low (the molar ratio is 3) LOMI decontamination conditions. However, in the solution of low-picolinate condition the shape of the distribution diagram of iron(II)-picolinate complexes was changed significantly. This phenomenon is attributed to the shortage of relative amount of picolinate ligand to iron existed in the solution, and originated from the difference in stability constants for complexes formed between vanadium(III) and iron(II) species with picolinate ligand. The distribution diagrams obtained in this study can be applied very usefully to the prediction or understanding the reaction phenomena occurred at various conditions in the course of the LOMI waste treatments such as an ion exchange operation.

Aqueous Chemistry of Molybdenum (몰리브덴의 용액화학)

  • Lee, Man Seung;Choi, Seung Hoon
    • Resources Recycling
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    • v.27 no.4
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    • pp.44-49
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    • 2018
  • $MoO{_4}^{2-}$ is the stable chemical species of Mo(VI) in alkaline solution. In the pH range of 2 to 6, condensation polymerization between $MoO{_4}^{2-}$ and hydrogen ion results in the formation of various polyanions of Mo(VI). Polycations of Mo(VI) begin to form when solution pH is less than 2. As the concentration of inorganic acid increases, polycations of Mo(VI) can react with the anion of the inorganic acid, resulting in the formation of heteranions of Mo(VI). The distribution of Mo(VI) species at pH < 6 depends on the concentration of Mo(V) and inorganic acid. In order to analyze the solvent extraction and ion exchange data on Mo(VI) from concentrated inorganic acid solution, it is necessary to elucidate the nature of Mo(VI) complexes.

Spatial Distribution of Excited Argon Species in and Inductively Coupled Plasma

  • 최범석
    • Bulletin of the Korean Chemical Society
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    • v.19 no.11
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    • pp.1172-1174
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    • 1998
  • Spatial(radial and height) distributions of excited argon species are measured for an inductively coupled plasma under five operating conditions: 1) no carrier gas, 2) carrier gas without aerosol, 3) carrier gas with desolvated aerosol, 4) carrier gas with aerosol, 5) carrier gas with aerosol and excess lithium. A complete RF power mapping of argon excited states is obtained. The excited states of argon for a typical analytical torch rapidly diffuse towards the center in the higher region of the plasma. The presence of excess lithium makes no significant change in the excited states of argon. The increase in the RF power increases the intensity of argon excited states uniformly across the radial coordinate.