• Title/Summary/Keyword: distribution coefficient($K_D$)

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Changes of Distribution Coefficients of Cu, Cr, and As in Different Soil Matrix in a Laboratory Scale

  • Kang, Sung-Mo;Ra, Jong-Bum;Kim, Suk-Kuwon
    • Journal of the Korean Wood Science and Technology
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    • v.37 no.2
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    • pp.137-140
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    • 2009
  • Chromated copper arsenate (CCA), a long history of successful preservative, have raised environmental concerns. Adsorption characteristics of domestic soils for chromium, copper, and arsenic were assessed by measuring distribution coefficient ($K_d$) values of these metal components in a laboratory scale. The results revealed that $K_d$ values were higher in chromium, followed by arsenic and copper in soil matrix. Different soil matrixes resulted in varying mobilities of CCA components. The values of $K_d$ for all three metals increased with organic matter contents. The results suggest that the mobility of metal components may be very limited to the surface area adjacent to CCA-treated wood due to their fairly large distribution coefficient ($K_d$). However, the metal components would be persistent and accumulated in the soil, resulting in high chemical concentration in service area of treated wood.

Probabilistic Characteristics of Effective Diffusion Coefficient in the Porous Media

  • Khim, Jeehyeong
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 1996.11a
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    • pp.58-62
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    • 1996
  • To check the variability of the effective diffusion coefficient in the unsaturated porous soil media. a Monte Carlo simulation was done for the equation suggested by Millington and Quirk(1961). The results shows that the probability density function of D$_{c}$/D$_{o}$ is positively skewed. It means the chance of having less effective diffusion coefficient values in the soil media than mean value is high. Also, the distribution types of D$_{c}$/D$_{o}$ are about same regardless of assumed distribution types of input parameters.ers.ers.

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On Probability Distribution of Chloride Diffusion Coefficient for Recycled Aggregate Concrete

  • Ying, Jingwei;Xiao, Jianzhuang;Meng, Qiujiang
    • International Journal of Concrete Structures and Materials
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    • v.10 no.1
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    • pp.61-73
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    • 2016
  • In predicating the probability distribution of chloride diffusion coefficient of recycled aggregate concrete ($D_{RAC}$), the morphological characteristics of three phases, i.e., the old attached mortar, the natural aggregate and the new mortar, should all be taken into account. The present paper attempts to develop a probability density evolution method (PDEM) to achieve this. After verifying the derived PDEM results with experimental results, the effects of old attached mortar to the $D_{RAC}$ are examined in a quantitative manner. It is found that (1) the variation of the attached mortar content is much sensitive to $D_{RAC}$; (2) given the probability distribution of the content and chloride diffusion coefficient of old mortar, the probability distribution of DRAC can be analysed based on the PDEM; and (3) the critical chloride diffusion coefficient at a certain assurance rate can be obtained by the PDEM. The analysis results of this investigation will be valuable to the durability design for RAC.

Pedestrian Distribution in High-Rise Commercial Complexes: An Analysis of Integrating Spatial and Functional Factors

  • Xu, Leiqing;Xia, Zhengwei
    • International Journal of High-Rise Buildings
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    • v.5 no.2
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    • pp.95-103
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    • 2016
  • One of the key problems in the design of high-rise commercial complex is how to guide reasonable pedestrian distribution in commercial space. In this study, pedestrian distribution in three high-rise commercial complexes in Shanghai and Hong Kong was studied using spatial configuration analysis software Space Syntax and quantification of physical elements in commercial spaces, such as functional attractiveness, entrances, escalators, level variations and passage width. Additionally, in an attempt to integrate functions with spatial integration and spatial depth, two combination variables, the spatial coefficient of function (IF) and spatial depth coefficient of function (F/D), were proposed. The results of the correlation analysis and multiple regression analyses reflected the following: (1) Regarding the influence on pedestrian distribution, there was a synergistic and complementary relationship between function and space; (2) The comprehensive flow distribution analytic model could successfully interpret flow distribution in high-rise commercial complexes and its R Square ranged up to about 70% in the three cases; (3) The spatial coefficient of function (IF) and spatial depth coefficient (F/D) could effectively integrate functions and spatial configuration, which could help close the gap between over-emphasis on function in commercial research and the lack of consideration of function in space-syntax analysis.

A Study of Performance Estimate and Flow Analysis of the 500 kW Horizontal-Axis Wind Turbine by CFD (CFD에 의한 500kW급 수평축 풍력발전용 터빈의 성능평가 및 유동해석에 관한 연구)

  • Kim, Y.T.;Kim, B.S.;Kim, J.H.;Nam, C.D.;Lee, Y.H.
    • The KSFM Journal of Fluid Machinery
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    • v.5 no.4 s.17
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    • pp.32-39
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    • 2002
  • The purpose of this 3-D numerical simulation is to calculate and examine the complex 3-D stall phenomena on the rotor blade and wake distribution of the wind turbine. The flow characteristics of 500kW Horizontal Axis Wind Turbine (HAWT) are compared with the calculated 3-D stall phenomena and wake distribution. We used the CFX-TASCflow to predict flow and power characteristics of the wind turbine. The CFD results are somewhat consistent with the BEM (Blade Element Momentum) results. And, the rotational speed becomes faster, the 3-D stall region becomes smaller. Moreover, the pressure distribution on the pressure side that directly gets the incoming wind grows high as it goes toward the tip of the blade. The pressure distribution on the blade's suction side tells us that the pressure becomes low in the leading edge of the airfoil as it moves from the hub to the tip. However, we are not able to precisely predict on the power coefficient of the rotor blade at the position of generating complex 3-D stall region.

An Experimental Study on Droplet Size according to Discharge Coefficient of Sprinkler Head (스프링클러 헤드의 방수상수에 따른 물방울 크기에 관한 실험적 연구)

  • Hur, Min Noung;Shin, Changsub
    • Journal of the Korean Society of Safety
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    • v.32 no.4
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    • pp.16-21
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    • 2017
  • The sprinkler system is a basic fire extinguishing system that uses water as an extinguishing agent. In order to evaluate the fire extinguishing performance of the sprinkler system, information such as the discharge angle, discharge speed, discharge pressure, flow rate, and water droplet size of the installed head are required. However, there is a lack of research on droplets size compared to other requirements. In this study, to evaluate the extinguishing characteristics of sprinkler system, the droplet size distribution was measured for various types of sprinkler heads actually used. The size of the droplet was measured using laser diffraction method. The 50% cumulative volume distribution ($D_{v50}$) according to discharge coefficient(K factor) was $540{\mu}m{\sim}695{\mu}m$ for K50, $542{\mu}m{\sim}1,192{\mu}m$ for K80, $980{\mu}m{\sim}1,223{\mu}m$ for K115 and $1,188{\mu}m{\sim}1,234{\mu}m$ for K202. Based on the measured results, the vaeiance of the droplet particle distribution and the distribution ($D_{v50}$) according to discharge coefficient(K factor) was $540{\mu}m{\sim}695{\mu}m$ for K50, $542{\mu}m{\sim}1,192{\mu}m$ for K80, $980{\mu}m{\sim}1,223{\mu}m$ for K115 and $1,188{\mu}m{\sim}1,234{\mu}m$ for K202. Based on the measured results, the vaeiance of the droplet particle distribution and the Rosin-Rammler index value are presented. As a result of the fire simulation with FDS, it was confirmed that the performance difference occurs according to the water droplet size distribution even when the same amount of water is used. Therefore, the extinguishing performance of the sprinkler system should be evaluated considering the droplet size distribution according to the sprinkler head type.

Chloride diffusivity of concrete: probabilistic characteristics at meso-scale

  • Pan, Zichao;Ruan, Xin;Chen, Airong
    • Computers and Concrete
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    • v.13 no.2
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    • pp.187-207
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    • 2014
  • This paper mainly discusses the influence of the aggregate properties including grading, shape, content and distribution on the chloride diffusion coefficient, as well as the initiation time of steel corrosion from a probabilistic point of view. Towards this goal, a simulation method of random aggregate structure (RAS) based on elliptical particles and a procedure of finite element analysis (FEA) at meso-scale are firstly developed to perform the analysis. Next, the chloride diffusion coefficient ratio between concrete and cement paste $D_{app}/D_{cp}$ is chosen as the index to represent the effect of aggregates on the chloride diffusion process. Identification of the random distribution of this index demonstrates that it can be viewed as actually having a normal distribution. After that, the effect of aggregates on $D_{app}/D_{cp}$ is comprehensively studied, showing that the appropriate properties of aggregates should be decided by both of the average and the deviation of $D_{app}/D_{cp}$. Finally, a case study is conducted to demonstrate the application of this mesoscopic method in predicting the initiation time of steel corrosion in reinforced concrete (RC) structures. The mesoscopic probabilistic method developed in this paper can not only provide more reliable evidences on the proper grading and shape of aggregates, but also play an important role in the probability-based design method.

Transport of Urea in Waterlogged Soil Column: Experimental Evidence and Modeling Approach Using WAVE Model

  • Yoo, Sun-Ho;Park, Jung-Geun;Lee, Sang-Mo;Han, Gwang-Hyun;Han, Kyung-Hwa
    • Journal of Applied Biological Chemistry
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    • v.43 no.1
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    • pp.25-30
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    • 2000
  • The main form of nitrogen fertilizer applied to lowland rice is urea, but little is known about its transport in waterlogged soil. This study was conducted to investigate the transport of urea in waterlogged soil column using WAVE (simulation of the substances Water and Agrochemicals in the soil, crop and Vadose Environment) model which includes the parameters for urea adsorption and hydrolysis, The adsorption distribution coefficient and hydrolysis rate of urea were measured by batch experiments. A transport experiment was carried out with the soil column which was pre-incubated for 45 days under flooded condition. The urea hydrolysis rate (k) was $0.073h^{-1}$. Only 5% of the applied urea remained in soil column at 4 days after urea application. The distribution coefficient ($K_d$) of urea calculated from adsorption isotherm was $0.21Lkg^{-1}$, so it was assumed that urea that urea was a weak-adsorbing material. The maximum concentration of urea was appeared at the convective water front because transport of mobile and weak-adsorbing chemicals, such as urea, is dependent on water convective flow. The urea moved down to 11 cm depth only for 2 days after application, so there is a possibility that unhydrolyzed urea could move out of the root zone and not be available for crops. A simulated urea concentration distribution in waterlogged soil column using WAVE model was slightly different from the measured concentration distribution. This difference resulted from the same hydrolysis rate applied to all soil depths and overestimated hydrodynamic dispersion coefficient. In spite of these limitations, the transport of urea in waterlogged soil column could be predict with WAVE model using urea hydrolysis rate (k) and distribution coefficient ($K_d$) which could be measured easily from a batch experiment.

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Effect of Trunk Height and Approaching Air Velocity of Notchback Road Vehicles on the Pressure Distribution of the Car Surface (Notchback자동차의 트렁크 높이와 공기속도가 차체 표면의 압력변화에 미치는 영향)

  • 박종수;최병대;김성준
    • Transactions of the Korean Society of Automotive Engineers
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    • v.10 no.6
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    • pp.178-186
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    • 2002
  • 3-D numerical studies are performed to investigate the effect of the trunk height and approaching air velocities on the pressure distribution of notchback road vehicle. For this purpose, the models of test vehicle with four different trunk heights are introduced and PHOENICS, a commercial CFD code, is used to simulate the flow phenomena and to estimate the values of pressure coefficients along the surface of vehicle. The standard k-$\xi$ model is adopted for the simulation of turbulence. The numerical results say that the height variation of trunk makes almost no influence on the distribution of the value of pressure coefficient along upper surface but makes very strong effects on the rear surface. That is, the value of pressure coefficient becomes smaller as the height is increased along the rear surface and the bottom surface. Approaching air velocity make no differences on pressure coefficients. Through the analysis of pressure coefficient on the vehicle surfaces one tried to assess aerodynamic drag and lift of vehicle. The pressure distribution on the rear surface affected more on drag and lift than pressure distribution on the front surface of the vehicle does. The increase of trunk height makes positive effects on the lift decrease but negative effects on drag reduction.

An Experimental Study on Heat Transfer of Semi-cylindrical Surface by Impinging Water Jet (충돌수분류(衝突水噴流)에 의한 Semi-cylinder면(面)에서의 열전달(熱傳達)에 관(關)한 실험적(實驗的) 연구(硏究))

  • Ohm, K.C.;Choi, G.G.;Seo, J.Y.
    • The Magazine of the Society of Air-Conditioning and Refrigerating Engineers of Korea
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    • v.17 no.6
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    • pp.708-716
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    • 1988
  • Local heat transfer coefficients were measured on semi-cylinders on which a circular water jet impinged in crossflow. The ratio of the semi-cylinder's diameter and the nozzle outlet diameter were varied parametrically, as were the Reynolds number and the supplementary water heights. The measurements showed that the circumferential distribution of the heat transfer coefficient peaked at the stagnation point. For a fixed supplementary water height, the peak heat transfer coefficient was not depend on the curvature of test specimen(d/D). Optimum height of supplementary water which brought about the augmentation of heat transfer at the stagnation point was S/D=1. The Nusselt number decreased as the circumferential distance or angle increased. The circumferential distribution of dimensionless heat transfer (Nu/Nus) was independent of d/D ($d/D{\geq}8.33$), but for the d/D<8.33, it was depended on d/D. At a fixed angle of specimen, dimensionless heat transfer (Nu/Nus) decreased as the ratio d/D increased. The extent of the decrease between d/D=6.67 and 8.33 was markedly greater than that between d/D=8.33 and 10, or d/D=10 and 11.67.

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