• Title/Summary/Keyword: distant dipolar field

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Cross Correlated Effects of Radiation Damping and the Distant Dipolar Field with a Pulsed Field Gradient in Solution NMR

  • Chung Kee-Choo;Ahn Sang-Doo
    • Journal of the Korean Magnetic Resonance Society
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    • v.10 no.1
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    • pp.46-58
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    • 2006
  • With a simple pulse sequence ($\pi/2$-{gradient, duration T}-acquisition) in solution NMR, detected signal has slowly grown up to percents of the equilibrium magnetization. The source of this unusual resurrection of dephased magnetization after a crushed gradient is cross-correlated effects of radiation damping and the distant dipolar field, which has been demonstrated by a numerical simulation and theoretical analysis.

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Magnetic Resonance Imaging with Intermolecular Double Quantum Coherences

  • Ahn, Sang-Doo
    • Journal of the Korean Magnetic Resonance Society
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    • v.8 no.2
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    • pp.108-114
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    • 2004
  • Recently a new method for magnetic resonance imaging based on the detection of relatively strong signal from intermolecular multiple quantum coherences (iMQCs) is reported. Such a signal would not be observable in the conventional framework of magnetic resonance; it originates in long-range dipolar couplings that are traditionally ignored. In this paper, we present the results of experimental studies to assess the feasibility of intermolecular double quantum coherences (iDQCs) imaging in humans. We show that the iDQC images are readily observable at 4T and that they do indeed provide different contrast than appears in conventional images.

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Solvent-localized in-situ NMR Monitoring by Intermolecular Single-quantum Coherence Study

  • Cha, Jin Wook;Park, Sunghyouk
    • Journal of the Korean Magnetic Resonance Society
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    • v.24 no.4
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    • pp.96-103
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    • 2020
  • A new NMR method to monitor solvent-localized NMR signals in the two-phase liquid system is suggested. This method based on intermolecular single-quantum coherence (iSQC). Here, we exploited the feature of the local action of distant dipolar field (DDF) effect in order to filter out specific NMR signals dissolved in different solvents. This solvent specific iSQC spectroscopy was carried out on a model two-phase liquid system (D-glucose in water/palmitic acid in chloroform), and showed solvent-localized NMR signals. We believe our approaches might be useful in metabolic analysis such as two-phase liquid extraction scheme for labile chemical species.