• 제목/요약/키워드: dissolved inorganic nitrogen

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부안 상록해수욕장의 사상 녹조류 금발대마디말(Cladophora vadorum) 대량발생과 영양염 농도 (Bloom of a Filamentous Green Alga Cladophora vadorum (Areschoug) Kützing and Nutrient Levels at Shangrok Beach, Buan, Korea)

  • 하동수;유현일;장수정;황은경
    • 한국수산과학회지
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    • 제49권2호
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    • pp.241-246
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    • 2016
  • A filamentous green alga Cladophora vadorum (Areschoug) Kützing, bloomed at Shangrok Beach, Buan, Republic of Korea, in September 2015. This alga is currently distributed worldwide. Concentrations of total nitrogen (TN), total phosphorus (TP), dissolved inorganic nitrogen (DIN), and dissolved inorganic phosphorus (DIP) were analyzed in the bloom area and compared to those of other areas in the vicinity. DIN and DIP concentrations were similar to those of other areas. However, TN and TP were as much as six and ten times higher than in other areas, respectively. As in other Cladophora species, the bloom of C. vadorum at Shangrok Beach in 2015 appears to have depended on the TP concentration in the seawater. This suggests that blooms in the area can be controlled by reducing TP.

Effect of the Freshwater Discharge on Seawater and Sediment Environment in a Coastal Area in Goheung County, South Korea

  • Nguyen, Hoang Lam;Jang, Min-Seok;Cho, Hyeon-Seo
    • 해양환경안전학회지
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    • 제20권3호
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    • pp.270-276
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    • 2014
  • Seasonal characteristics of water and sediment qualities and potential effects of the freshwater discharge from a small tide embankment interior in a coastal area in Goheung county were investigated from May to September in 2012. Chemical oxygen demand values (COD) were mostly higher than 2 mg/L in summer ebb tide, which exceed the standard value of water quality criteria II of acceptable level for aquaculture activities. Nitrogen and phosphorus were found as the limiting nutrients for algae growth in summer and fall and in spring, respectively. Nitrogen was the limiting nutrient for diatom growth in the whole studied period. The sudden high values of COD, ammonia, dissolved inorganic nitrogen (DIN), dissolved inorganic phosphorus (DIP) were found in water sample collected from station 5 which located in front of the tide embankment sluice gate during spring ebb tide. The freshwater discharge form the tide embankment interior maybe affected the survey areas during a short time interval. Mean values of eutrophication index of the surveyed coastal region in spring, summer and fall were all bigger than 1. Water quality was mostly considered at level II which acceptable for aquaculture activities. Sediment quality in this study was generally in the range of standard for fisheries environment.

1983年 7月 鎭海灣의 海洋化學指數의 水質分布에 관하여 (Vertical Distributions of Chemical Oceanographic Parameters in Jinhae Bay in July, 1983)

  • 양동범;김석현;이광우
    • 한국해양학회지
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    • 제19권1호
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    • pp.89-93
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    • 1984
  • 진해만에서 83년 7월의 장마직후에 수직적 및 수평적 해양화학적 환경을 조사 하였다. 마산만-가덕수도의 종축면상에는 염분이 낮은 내만쪽의 표층수에서 높은 농도의 용존성 질산염, 암모니아, 클로로필 a, 입자성질소, 입자성탄소가 측정 되었다. 입자성 C/N비는 내만쪽에서 낮고, 외만에서 높은 값을 보였다. 이 해역 에서 무기질소와 인의 양은 적조가 발생하기에 충분한 향으로 나타났다.

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기계학습 기반 모델을 활용한 시화호의 수질평가지수 등급 예측 (WQI Class Prediction of Sihwa Lake Using Machine Learning-Based Models)

  • 김수빈;이재성;김경태
    • 한국해양학회지:바다
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    • 제27권2호
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    • pp.71-86
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    • 2022
  • 해양환경을 정량적으로 평가하기 위해 수질평가지수(water quality index, WQI)가 사용되고 있다. 우리나라는 해양수산부고시 해양환경기준에 따라 WQI를 5개 등급으로 구분하여 수질을 평가한다. 하지만, 방대한 수질 조사 자료에 대한 WQI 계산은 복잡하고 많은 시간이 요구된다. 이 연구는 기존의 조사된 수질 자료를 활용하여 WQI 등급을 예측할 수 있는 기계학습(machine learning, ML) 기반의 모델을 제안하고자 한다. 특별관리해역인 시화호를 모델링 지역으로 선정하였다. AdaBoost와 TPOT 알고리즘을 모델 훈련을 위해 사용하였으며, 분류 모델 평가 지표(정확도, 정밀도, F1, Log loss)로 모델 성능을 평가하였다. 훈련하기 전, 각 알고리즘 모델의 최적 입력자료 조합을 탐색하기 위해 변수 중요도와 민감도 분석을 수행하였다. 그 결과 저층 용존산소(dissolved oxygen, DO)는 모델의 성능에서 가장 중요한 인자였다. 반면, 표층 용존무기질소(dissolved inorganic nitrogen, DIN)와 표층 용존무기인(dissolved inorganic phosphorus, DIP)은 상대적으로 영향이 적었다. 한편, 최적 모델의 시공간적 민감도와 WQI 등급 별 민감도를 비교한 결과 각 조사 정점 및 시기, 등급 별 모델의 예측 성능이 상이하였다. 결론적으로 TPOT 알고리즘이 모든 입력자료 조합에서 성능이 더 우수하여 충분한 자료로 훈련된 최적 모델은 새로운 수질 조사 자료의 WQI 등급을 정확하게 분류할 수 있을 거라 판단된다.

시화호 해수유통량 증대에 따른 통계학적 수질 영향 분석 (A Statistical Assessment of Increasing Tidal Mixing Effects on Water Quality in the Shiwha Coastal Reservoir)

  • 이범연;이창희
    • 한국물환경학회지
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    • 제37권6호
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    • pp.425-432
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    • 2021
  • A tidal power plant (TPP) has been in operation since the end of 2011 to improve the water quality of Shihwa Coastal Reservoir (SCR). Tidal mixing rate increased 5.6 times after the TPP operation so that in this study, its effects on water quality was assessed through statistical analysis of long-term water quality monitoring data. It was found that the increased tidal mixing contributed to solving the hypoxia problem in the bottom water by preventing the summer stratification. The analysis also showed that the increased tidal mixing had different effects depending on the relative concentration difference for each water quality substances between the SCR and the outside of SCR. The average concentrations of some substances (chemical oxygen demand, total phosphorus, chlorophyll-a) with higher concentrations than the outside of SCR decreased due to the dilution effect, but the other substances (total nitrogen, dissolved inorganic nitrogen, dissolved inorganic phosphorus) with lower concentrations compared to the outside ones increased on the contrary. Factor analysis also showed a consistent result that the first factor accounting for the water quality was changed from the organic-related substances to the nutrient-related substances after the increased tidal mixing. These results imply that the focus of future water quality management needs shifting from the organic substances to the nutrients, particularly dissolved inorganic nutrients. Considering the effect of inflow seawater on the nutrients, the management area should be extended to cover not only SCR but also a certain area outside of SCR.

일본 Kochi현 Uranouchi만의 와편모조류, Heterocapsa circularisquama (Dinophyceae) 적조발생에 대한 환경 고찰 (Environmental Feature Causing a Bloom of the Novel Dinoflagellate Heterocapsa circularisquama (Dinophyceae) in Uranouchi Bay, Kochi Prefecture, Japan)

  • 오석진;마쯔야마유키히코;오다수미오;모리야마타카미쯔;우찌다타쿠지
    • ALGAE
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    • 제18권4호
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    • pp.281-288
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    • 2003
  • To study the environmental features causing a bloom of the novel dinoflagellate Heterocapsa circularisquama (Dinophyceae), hydrographic and chemical aspects were measured in the Uranouchi Bay, Kochi Prefecture, Japan, from January to December, 1997. The cell density of H. circularisquama increased rapidly in early October, and dropped sharply in mid-October. Growth rate of H, circularisquama during bloom period appeared 1.50 division day$^{-1}$ under high water temperature (25$^{\circ}C$) and salinity (32 psu) conditions. Althought the result from hydrographic aspect indicated good condition for their growth, dissolved inorganic phosphorus (DIP) concentration in surface layer before bloom formation was less than 0.70uM, which is lower than their half saturation constant(Ks). Dissolved inorganic nitrogen(DIN): DIP ratio was > 30, indicating potential P-limitation. However, before bloom formation period of H. circularisquama, DIP concentrations were high in bottom layer (> 4.0 uM). Some studies reported that H. circularisquama had the ability to migrate vertically and to utilize dissolved organic phosphorus (DOP). Thus, DIP in bottom layer might have been utilized by H. circularisquama for their growth.DOP might have weakly affected their growth because of low reactive DOP concentrations owing to low DOP concentration (ca. 0.39 uM). Thus, if nutrient condition of bottom layer in Uranuchi Bay is not improved, the outbreaks of H. circularisquama red tides may became an annual feature.

2009년 추계와 동계 가막만 북부해역에서 alkaline phosphatase 활성과 phosphatase 가수 분해성 인의 분포 특성 (Distribution Characteristics of Alkaline Phosphatase Activity and Phosphatase Hydrolyzable Phosphorus in Northern Gamak Bay in Autumn and Winter, 2009)

  • 권형규;오석진;양한섭
    • 한국수산과학회지
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    • 제43권5호
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    • pp.540-546
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    • 2010
  • We investigated variations in alkaline phosphatase (APase) activity and alkaline phosphatase hydrolyzable phosphorus (APHP) in northern Gamak Bay from September to December 2009. Dissolved inorganic nitrogen (DIN) and dissolved inorganic phosphorus (DIP) decreased gradually, and the DIN/DIP ratio was higher than the Redfield ratio (16) based on molecular concentrations during most of the observation period. The total APase (T-APase) activity increased with decreasing DIP concentration; i.e., the Relationship between T-APase and DIP showed a high negative correlation (r=-0.80, P<0.001), with APase activity being a good indicator of DIP limiting the Redfield ratio. The T-APase was positively correlated with the concentration of chlorophyll a (r=0.73, P<0.001). This suggests that a major portion of APase activity in northen Gamak Bay seawater is attributed to phytoplankton. The proportion of APHP among dissolved organic phosphorus (DOP) was low in September and high in November. Thus, APase-producing phytoplankton may be able to grow by utilizing APHP as a phosphorus source in autumn when DIP is limiting. Thus, APase activity and the use of DOP by phytoplankton may play an important role in the growth of phytoplankton under DIP limiting conditions such as those of northern Gamak Bay.

서해 군산 연안의 2001년부터 2010년까지의 용존성무기영양염류의 변동 (The Variation of the Dissolved Inorganic Nutrients in the Costal Area of Gunsan, Yellow Sea from 2001 to 2010)

  • 허승;권정노;박종수
    • 해양환경안전학회지
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    • 제17권4호
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    • pp.357-365
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    • 2011
  • 본 연구는 국립수산과학원의 국가해양환경측정망 자료를 이용하여 2001년부터 2010년까지 년 4회 군산연안의 10개 정점에서의 용존성무기영양염류의 조사시기별 및 정점별 변동을 분석하였다. 용존성무기질소(DIN)의 연도별 평균값은 표층과 저층 모두 비슷한 농도 분포를 보였는데, 10년간 표층 평균은 0.421mg/L(0.198~0.846mg/L)였고, 저층 평균은 0.344mg/L(0.148~0.717mg/L)였다. 연도별 평균값은 표층에서 2002년 0.846mg/L로 가장 높았고 그 이후 차차 낮아지는 경향을 보여 2010년 0.198mg/L로 가장 낮은 값을 보였으며, 저층도 유사한 경향을 보였다. 군산연안의 10개 정점에서의 DIN의 10년간 평균의 암모니아질소, 아질산질소 및 질산질소의 비율은 각각 27%, 3% 및 70%정도로서 대부분 질산질소였으며, 표 저층간의 차이도 거의 없었다. 용존성무기인(DIP)의 연 평균값은 2002년 저층에서 0.085mg/L로 높은 값을 보인 것을 제외하고는 표 저층간의 농도 차이는 거의 없었으며, 표층에서 10년 평균이 0.024mg/L 였으나, 2008년 0.021mg/L, 2009년 0.007mg/L, 2010년 0.008mg/L로 농도가 급격히 낮아졌다. 2002년부터 2010년까지 DIN/DIP 농도비를 비교한 결과 표층에서 평균 6.0(3.2~10.1), 저층에서 평균 4.6(2.6~7.0)으로서 2002년을 제외하고는 연도별 및 표 저층 간에 큰 차이는 없었다. 2004년부터 조사된 용존성무기규소는 7년 평균이 표층에서 0.372mg/L, 저층에서 0.352mg/L로 표 저층간에 차이가 거의 없었으며, 표층에서 2005년 평균 0.552mg/L, 2006년 평균 0.575mg/L의 값을 보인 후, 지속적으로 감소하는 경향을 보였으며, 2009년에는 0.130mg/L로 최소값을 보였다. 전체적으로 염분과 용존성무기영양염류와의 10년간 상관관계는 표층에서 용존성무기질소는 -0.72, 용존성무기인은 -0.46, 용존성무기규소는 -0.63 이었으며, 저층은 용존성무기질소는 -0.70, 용존성무기인은 -0.44, 용존성무기규소는 -0.57로서, 군산 연안의 용존성무기영양염류은 금강으로 부터의 담수유입에 의한 영향이 크게 나타났으며, 특히 금강을 통해 용존성무기질소가 많이 유입되는 것으로 나타났다. 용존성무기영양염류는 군산시에 가까운 정점 1, 2, 3에서 높은 값을 보였는데, 이는 금강과 군산시의 영향으로 생각된다. 조사 시기에 따른 농도 변화는 크지 않았으나, 연도별 평균값을 보면 2001년부터 용존성무기영양염류의 농도가 점차 감소하는 경향을 보여, 이에 대한 지속적인 모니터링과 그 원인 연구가 필요할 것으로 판단된다.

수영만의 생태계모델링에 의한 물질분포 (The Material Distribution by the Ecosystem Modeling in Suyoung Bay)

  • 김동선;조규대
    • 한국환경과학회지
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    • 제7권6호
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    • pp.817-825
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    • 1998
  • A three-dimensional ecosystem model is applied to the Suyoung Bay, located at the southeastern part of Korea, to study of the material distribution in the time scale of several tens days. The model has included of the DIN(Dissolved Inorganic Nitrogen), DIP(Dissolved Inorganic Phosphate), phytoplankton, zooplankton and detritus, and also was coupled with the physical processes. The spatial distribution of chlorophyll-a and primary productivity in the model is determined by the physical and chemical-biological parameters. The horizontal distributions of the DIN, DIP and chlorophyll-a are decreased from the coast to the off-shore, though the nutrients show some more complicated pattern than the chlorophyll-a. The nutrient contents in the off-shore are low, and thus a relatively low productivity(chlorophyll-a) are presented. On the whole, the distribution of the results of model are smoother than the observed ones and some small scale variation in the observed data cannot be reproduced by the model due to the resolution limits of model. However, the basic pattern and the quantitavities has been reproduced by the model well.

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물질순환모델을 이용한 제주항의 수질관리(III) - 오염부하의 정량적 관리 - (Water quality management of Jeiu Harbor using material cycle model(III) - Quantitative Management of Pollutant Loadings -)

  • 조은일;강기봉
    • 한국환경과학회지
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    • 제12권3호
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    • pp.307-317
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    • 2003
  • In this study, the material cycle model was applied to suggest alternative management of water quality for Jeju Harbor. The distribution of COD, DIN (dissolved inorganic nitrogen) and DIP (dissolved inorganic phosphorus) concentrations was reasonably reproduced by simulations on the model area of the Jeju Harbor using a material cycle model. The simulations of COD, DIN and DIP concentrations were performed under the conditions of 20∼100% pollution loadings reductions from pollution sources. In case of the 100% reduction of the input loads from Sanzi river, concentrations of COD, DM and DIP were reduced to 39%, 78% and 52%, respectively at Jeju harbor. In contrast, in case of the pollutant loadings reductions from sediment, the effect of DIN and DIP reduction relatively seemed to increase around the center of study area. The 95% reduction of the pollutant loadings from river and sediment is required to meet the COD and nutrients concentration of second grade of ocean water quality criteria.