• Title/Summary/Keyword: dissolved form

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Effects of Gumi City Sewage Treatment Effluent in the Downstream Nutrient Matter: Comparison of Daily Loading (구미시 하수처리 방류수가 하류 하천 영양염류에 미치는 영향: 부하량 비교)

  • Seong, Jin-Uk;Lee, Sang-Pal;Lee, Jae-Kyun;Park, Je-Chul
    • Journal of Environmental Science International
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    • v.22 no.12
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    • pp.1643-1650
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    • 2013
  • This study investigated water quality of effluents and stream from the sewage treatment plants located at Gumi Complex 4, Gumi, and Wonpyeong in Gumi. Downstream region was found to increase the concentration of nutrients for sewage treatment plant effluent. Both phosphorus and nitrogen were accounted most as soluble form. In particular, the high ratio of dissolved effluent of sewage treatment plants were investigated. In the streams, Phosphorus concentration was high during rainy season and nitrogen concentration was high in the dry season. Sewage treatment plant effluent was relatively less microbial activity and nutrient concentrations were higher in the winter. TN/TP ratio was the highest in the upstream region and the lowest in the sewage treatment plant effluent. The effect of the nutrient matter from a discharge of a sewage treatment plant on rivers varied depending on the size of the river and the treatment plant. However, the influence of the concentration was greater than that of flowrate. Sewage treatment plant effluent loads phosphorus, nitrogen accounted for 8% and 6% respectively at the point N3 of the Nakdong river.

A Novel Approach to Cloning and Expression of Human Thymidylate Synthase

  • Lv, Ying-Tao;Du, Pei-Juan;Wang, Qiao-Yan;Tan, Yuan;Sun, Zong-Bin;Su, Zhong-Liang;Kang, Cong-Min
    • Asian Pacific Journal of Cancer Prevention
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    • v.14 no.12
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    • pp.7523-7527
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    • 2013
  • Thymidylate synthase (TS) catalyzes the transfer of a methyl group from methylenetetrahydrofolate to dUMP to form dTMP. It is a primary target in the chemotherapy of colorectal cancers and some other neoplasms. In order to obtain pure protein for analysis of structure and biological function, an expression vector TS-pET28b (+) was constructed by inserting wild-type human thymidylate synthase (hTS) cDNA into pET28b (+). Then an expression strain was selected after transformation of the recombined plasmid into Rosetta (DE3). Fusion protein with His-tag was efficiently expressed in the form of inclusion bodies after IPTG induction and the content was approximately 40.0% of total bacteria proteins after optimizing expression conditions. When inclusion bodies were washed, dissolved and purified by Ni-NTA under denatured conditions, the purity was up to 90%. On SDS-PAGE and West-blotting, the protein band was found to match well with the predicted relative molecular mass-36kDa. Bioactivity was 0.1 U/mg. The results indicated that high-level expression of wild-type hTS cDNA can be achieved in prokaryotes with our novel method, facilitating research into related chemotherapy.

Analysis of Rainwater in Clean Air Area : Characteristics of Rainwater at 1100 Site of Mt. Halla and Cheju City in 1997-1998 (청정 강우의 분석:1997-1998년 한라산 1100 고지와 제주시 강우의 특성)

  • 강창희;김원형;홍상범;이기호;홍민선;심상규
    • Journal of Korean Society for Atmospheric Environment
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    • v.15 no.5
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    • pp.555-566
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    • 1999
  • The rainwater samples were collected from the 1100 Site of Mt. Halla and Cheju city during the period of March in 1997 to August in 1998, and the major soluble ions were analyzed. The confidence of analytical data was confirmed by using the comparison methods such as ino-balance, electric conductivity and acid fraction, all of which correlation coefficients were above 0.94. The ionic strengths lower than $10^{-4}$ M, the basis for the pure rainwater, were found in 47% and 38% at 1100 Site and Cheju city, respectively. The precipitations in Cheju city were more influenced by the oceanic effect than those in 1100 Site. The acidity contribution was mainly by $SO_4^{2-}$ and $NO_3^-$ in both areas, and the organic acids have contributed to the acidity with only 5~7%. The neutralization factors by $NH_3$ were about 46% at both 1100 site and Cheju city, whereas those by $CaCO_3$ were 11% and 15% at 1100 site and Cheju city respectively, and the free acidity were both about 35% in average. From the MSA analysis, it was found that the air in Cheju island has been influenced by the pollution from the other areas. The sources of the rainwater components in 1100 Site and Cheju city were also studied with a factor analyzing way, and the most probable factors were found to be anthropotgenic, oceanic, and soil-sourced. The results of multiple regression analysis have shown that $SO_4^{2-}$ was dissolved mostly in the form of $H_2SO_4, CaSO_4 and (NH_4)_2SO_4$, and $NO_3^-$ was in the form of $HNO_3, Ca(NO_3)_2 and NH_4NO_3$.

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Formaldehyde Free Cross-linking Agents Based on Maleic Anhydride Copolymers

  • Yoon, Kee-Jong;Woo, Jong-Hyung;Seo, Young-Sam
    • Fibers and Polymers
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    • v.4 no.4
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    • pp.182-187
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    • 2003
  • Low molecular weight copolymers of maleic anhydride and vinyl acetate were prepared to develop formaldehyde free cross-linking agents. Since lower molecular weight is favorable for efficient penetration of the finishing agent into the cotton fibers in the padding process, the concentration of the initiator, chain transfer agent and the monomer ratios were varied to obtain copolymers of low molecular weights. The prepared polymers were characterized by GPC, $^1{H-NMR}$, FTIR, DSC and TGA. Copolymers of molecular weights of 2 000 to 10 000 were obtained and it was found that the most efficient method of controlling the molecular weight was by varying the monomer ratios. Poly(maleic anhydride-co-vinyl acetate) did not dissolve in water, but the maleic anhydride residue hydrolyzed within a few minutes to form poly(maleic acid-co-vinyl acetate) and dissolved in water. However, the maleic acid units undergo dehydration to form anhydride groups on heating above ${160}^{\circ}C$ to some extent even in the absence of catalysts. The possibility of using the copolymers as durable press finishing agent for cotton fabric was investigated. Lower molecular weight poly(maleic anhydride-co-vinyl acetate) copolymers were more efficient in introducing crease resistance, which appears to be due to the more efficient penetration of the cross-linking agent into cotton fabrics. The wrinkle recovery angles of cotton fabrics treated with poly(maleic anhydride-co-vinyl acetate) copolymers were slightly lower than those treated with DMDHEU and were higher when higher curing temperatures or higher concentrations of copolymer were used, and when catalyst, $NaH_2$$PO_2$, was added. The strength retention of the poly(maleic anhydride-co-vinyl acetate) treated cotton fabrics was excellent.

Studies on the Fouling Reduction through Oxyfluorination of Porous Polyethylene Membranes (함산소불소화법을 통한 다공성 폴리에틸렌막의 파울링현상 감소연구)

  • Kang, Su Yeon;Rhim, Ji Won;Cheong, Seong Ihl
    • Membrane Journal
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    • v.24 no.6
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    • pp.431-437
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    • 2014
  • To overcome the flux reduction due to the fouling by adsorption of foulants onto the porous hydrophobic polyethylene membrane surface, the oxyflorination was introduced to hydrophilize the hydrophobic membranes. After the hydrophilization through oxyfluorination, the contact angle decreased from $93^{\circ}$ to $50^{\circ}$ while the water flux increased to 60%. It was considered that for the model foulants dissolved in water, such as albumin (form bovine serum, BSA), humic acid sodium salt (HA), and alginic acid sodium salt (SA), the flux was enhanced since the adsorbed foulants decreased by the oxyfluorination. Particularly, it was obtained that the water flux was over twice more than the untreated polyethylene membrane in case of SA foulant.

The ecosystem modelling for enhancement of primary productivity in Kamak Bay (가모만에서의 기초생산력 향상방안에 관한 생태계모델링)

  • Lee, Dae-In;Jo, Eun-Il;Park, Cheong-Gil
    • Journal of Environmental Science International
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    • v.8 no.5
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    • pp.575-586
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    • 1999
  • From the environmental aspects, primary productivity of phytoplankton plays the most improtant role in enhancement of marine culture oyster production. This study may be divided into two branches; one is estimation of maximum oyster meat production per unit facility(Carrying Capacity) under the present enviromental conditions in Kamak Bay, the other is improvement of carrying from increase of primary productivity by changing the environmental conditions that cause not ot form an unfavorable environment such as the formation of oxygen deficient water mass using the eco-hydrodynamic model. By simulation of three-dimensional hydrdynamic model and ecosystem model, the comparison between observed and computed data showed good agreement. The results of sensitivity analysis showed that phytoplankton maximum growth rate was the most important parameter for phytoplankton and dissolved oxygen. The estimation of mean primary productivity of Wonpo, Kamak, Pyongsa, and Kunnae culture grounds in Kamak Bay during culturing period were 3.73gC/$m^2$/d, 2.12gC/$m^2$/d, 1.98gC/$m^2$/d, and 1.26gC/$m^2$/d, respectively. Under condition not ot form the oxygen deficient water mass, four times increasing of pollutants loading as much as the present loading from river increased mean primary productivity of whole culture grounds to 4.02gC/$m^2$/d. Sediment N, P fluxes that allowed for 35% increasing from the present conditions increased mean primary productivity of whole culture grounds to 3.65gC/$m^2$/d. Finally, ten times increasing of boundary loadings from the present conditions increased mean primary productivity of whole culture grounds to 3.95gC/$m^2$/d. The maximum oyster meat production per year and that of unit facility in actual oyster culture grounds under the present conditions were 6,929ton and 0.93ton, respectively. This 0.93ton/unit facility is considered to be the carrying capacity in study area, and if the primary productivity is increased by changing the environmental conditions, oyster production can be increased.

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The investigation on the actual conditions and the conservation on the countmeasure paper cultural properties stored in Kirimsa temple (경주 기림사 소장 지류문화재의 보존실태 및 대책)

  • Han, Sung-Hee;Lee, Kyu-Shik;Chung, Young-Jae
    • 보존과학연구
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    • s.19
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    • pp.75-107
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    • 1998
  • The cultural properties of paper made from 11 to 16th century of the Kirimsa temple were found in Birozana Buddhist Statue which was made from 15 to 16th century. These have been stored and exhibited in the exhibition showcase. To examine the environment of conservation and the state of paper, we investigated the temperature and the relative humidity in the inside and outside of the Kirimsa museum and examined the external form and the internal state (water content, acidity and whiteness) of paper. During the investigation period from 27 Aug. to 30 Aug. 1997. The average of temperature and relative humidity were $28.2^{\circ}C$, 67% in the outside and $27.1^{\circ}C$, 73% in the inside, respectively. These indicated the air conditioning was wrong. Among the cultural properties of 79 papers stored in the Kirimsa museum, 37 cases had been repaired but 42 cases not. From the result examining the external form, 20 cases needed to repair. In the internal state of the cultural properties of paper, the water contents were from 11.9% to 16.5%, the average was 15.7%, the acidities from pH 5.7 to pH 6.2 and the whiteness from 37 to 45. From these results, we could see the cultural properties of paper stored in the Kirimsa museum was damaged by the several factors (hydrolysis by fungi, repeated elongation and retraction of cellulose) caused mainly by the high temperature and relative humidity. Therefore, for the conservation of the cultural properties of paper stored in the Kirimsa museum, it need to control the temperature at $18~20^{\circ}C$ and the relative humidity at $55\pm5%$ by the appropriate air conditioning. In order to sterilize fungi occurred to the surface of paper, the cultural properties of paper needed to fumigate. The fungi occurred on the surface of paper were wiped out by using of 70%solution dissolved thymol in ethyl alcohol.

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Development of Uniform Ag Electrode and Heating Sensors Using Inkjet Printing Technology (잉크젯 프린팅 기술을 이용한 Ag 전극 균일성 및 발열 센서 연구)

  • Gun Woong Kim;Jaebum Jeong;Jin Ho Park;Woo Jin Jeong;Jun Young Kim
    • Journal of Sensor Science and Technology
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    • v.33 no.1
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    • pp.24-29
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    • 2024
  • Inkjet printing technology is used to mass-produce displays and electrochemical sensors by dropping tens of pico-liters or less of specific-purpose ink through nozzles, just as ink is sprayed and printed on paper. Unlike the deposition method for vaporizing material in a vacuum, inkjet printing technology can be used for processing even under general atmospheric pressure and has a cost advantage because the material is dissolved in a solvent and used in the form of ink. In addition, because it can only be printed on the desired part, masks are not required. However, a technical shortcoming is the difficulty for commercialization, such as uniformity for forming the thickness and coffee ring effect. As sizes of devices decrease, the need to print electrodes with precision, thinness, and uniformity increases. In this study, we improved the printing and processing conditions to form a homogeneous electrode using Ag ink (DGP-45LT-15C) and applied this for patterning to fabricate a heat sensor. Upon the application of voltage to the heat sensor, the model with an extended width exhibited superior heat performance. However, in terms of sheet resistance, the model yielded an equivalent value of 21.6 Ω/□ compared to the ITO.

Simultaneous Removal of Hydrogen Sulfide and Ammonia Using Thiobacillus sp. IW in a Three-Phase Fluidized-Bed Bioreactor

  • Kum, Sung-Hoon;Oh, Kwang-Joong;Moon, Jong-Hae;Kim, Dong-Uk
    • Journal of Microbiology and Biotechnology
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    • v.10 no.3
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    • pp.419-422
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    • 2000
  • A three-phase fluidized-bed bioreactor including Thiobacillus sp. IW was tested to remove H_2S and $NH_3$ simultaneously. The inlet $H_2S$ was oxidized to $SO_4^{2-}$ by Thiobacillus sp. IW, and the $NH_3$ reacted with the $SO_4^{2-}$ to form $(NH_4)_2SO_4$. The removal efficiency of $H_2S$ was 98.4-99.9% for an inlet concentration of 36-730 ppm and that of $NH_3$ was 60.2-99.2% for an inlet concentration of 45-412 ppm. The removal efficiency of $NH_3$ was reduced when the inlet loading rate of $NH_3$ was increased above 10 mg/l/h. When the bioreactor was operated for 25 days with a lower inlet concentration of $NH_3$ compared with the of $H_2S$, the bioreactor exhibited an excellent performance with a stable pH, dissolved oxygen content, and cell concentration.

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Preparation of Ag/PVP Nanocomposites as a Solid Precursor for Silver Nanocolloids Solution

  • Hong, Hyun-Ki;Park, Chan-Kyo;Gong, Myoung-Seon
    • Bulletin of the Korean Chemical Society
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    • v.31 no.5
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    • pp.1252-1256
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    • 2010
  • A polyvinylpyrrolidone (PVP)/Ag nanocomposites was prepared by the simultaneous thermal reduction and radical polymerization route. The in situ synthesis of the Ag/PVP nanocomposites is based on the finding that the silver n-propylcarbamate (Ag-PCB) complex can be directly dissolved in the NVP monomer, and decomposed by only heat treatment in the range of 110 to $130^{\circ}C$ to form silver metal. Silver nanoparticles with a narrow size distribution (5 - 40 nm) were obtained, which were well dispersed in the PVP matrix. A successful synthesis of Ag/PVP nanocomposites then proceeded upon heat treatment as low as $110^{\circ}C$. Moreover, important advantages of the in situ synthesis of Ag/PVP composites include that no additives (e.g. solvent, surface-active agent, or reductant of metallic ions) are used, and that the stable silver nanocolloid solution can be directly prepared in high concentration simply by dissolving the Ag/PVP nanocomposites in water or organic solvent.