• Title/Summary/Keyword: dissolution properties

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Effect of WO3 or Ga2O3 Addition on the Phase Evolution and Properties of Y2O3-Doped AlN Ceramics (Y2O3-AlN 세라믹스의 생성상 및 물성에 미치는 WO3 및 Ga2O3의 첨가효과)

  • Shin, Hyunho;Yoon, Sang-Ok;Kim, Shin;Hwang, Injoon
    • Journal of the Korean Ceramic Society
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    • v.50 no.3
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    • pp.206-211
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    • 2013
  • The effect of a $WO_3$ or $Ga_2O_3$ addition on the densification, phase evolution, optical reflectance, and elastic and dielectric properties of $Y_2O_3$-doped AlN ceramics sintered at $1800^{\circ}C$ for 3 h is investigated. The investigated compositions of the additives are 4.5 wt% $Y_2O_3$ (YA), 3.5 wt% $Y_2O_3$-1.0 wt% $Ga_2O_3$ (YGA), and 3.5 wt% $Y_2O_3$-1.0 wt% $WO_3$ (YWA). $YAlO_3$ and $Y_4Al_2O_9$ form as the secondary phases in all of the investigated compositions, whereas $W_2B$ appears additionally in the YWA. In the YGA, Ga is detected in the AlN grains, indicating that the dissolution of $Ga_2O_3$ into the AlN lattice occurs. The addition of $WO_3$ blackens the specimen more significantly than that of $Ga_2O_3$ does. In all of the investigated specimens, the linear shrinkage and the apparent density are above 20 percent and in the range of 3.34-3.37 $g/cm^3$, respectively. The elastic modulus, Poisson's ratio, the dielectric constant, and the dielectric loss are in the ranges of 335-368 GPa, 0.146-0.237, 8.60-8.63, $2.65-3.95{\times}10^{-3}$, respectively. The sinterability and the properties of $Y_2O_3$-doped AlN ceramics are not much altered by the addition of $WO_3$ or $Ga_2O_3$.

Physicochemical Property and Release Behavior of Ibuprofen Solid Dispersion with Cellulose Acetate Prepared with Various Methods (이부프로펜과 셀룰로오스아세테이트의 고체분산체 제조방법에 따른 물리화학적 성질 및 용출 특성)

  • Lee, Eun-Yong;Oh, Myeong-Jun;Kim, Se-Ho;Seong, Kyong-Yeol;Lee, Young-Hyun;Kim, Soo-Jin;She, Han-Sol;Lee, Dong-Won;Khang, Gil-Son
    • Polymer(Korea)
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    • v.35 no.2
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    • pp.113-118
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    • 2011
  • Solid dispersion is used to improve the solubility of water-insoluble drug. Release properties depend on the characteristics of polymer and the physicochemical properties of solid dispersion. In this study the solid dispersions of ibuprofen and cellulose acetate were prepared using spray-drying and rotary evaporation. The physicochemical properties of the solid dispersions were analyzed by SEM, XRD, DSC, and FTIR. The hydrophilicity of polymer was analyzed by measuring the contact angle of water. The results of DSC and XRD analysis demonstrated that the crystallinity of ibuprofen was changed by solid dispersion preparation. The results of contact angle showed that hydrophilicity was proportional to polymer content. Release profile showed that for solid dispersion. the release rate of ibuprofen decreased as polymer content increased in intestinal juice (pH 6.8). The dissolution rate of ibuprofen was improved with increasing polymer content in gastric juice (pH 1.2).

Rheological Behavior of Lyotropilc Solutions of Cellulose in the $NH_3/NH_4SCN$ Solvent System

  • Jo, Jae-Jeong;Cuculo, J.A.;Theil, M.H.
    • Proceedings of the Korean Fiber Society Conference
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    • 1990.06b
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    • pp.36-37
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    • 1990
  • In the past, facile dissolution of cellulose has been hampered by the lack of suitable nondegrading solvents. Recently, this problem has been solved in our laboratory by the discovery of an inexpensive, convenient solvent system, that is the mixture of $NH_3\;and\;NH_4SCN$, for cellulose. Also, the $cellulose/NH_3/NH_4SCN$ solution system has been found to form the anisotropic, i.e., liquid crystalline phase. It is believed that both the cholesterio and the nematic phase occur. This finding has prompted extensive on-going researoh on the formation of the liquid crystalline phase from an inexpensive natural source such as cellulose since the nematic phase is envisioned as an excellent precursor sources for products with desirable properties, for example, high modulus and high strength. This interest naturally leads to a desire to understand the theological properties of the nematic phase so that the transformation of the nematic phase to the solid state with desirable properties can be efficiently accomplished, ;From this point of view, the theological behavior of the $cellulose/NH3_/NH_4SCN$ system has been studied as a function of shear rate and shear stress over a wide range of solvent compositions, cellulose concentration, centrifugation and urea contents, Results indicate that the viscosity decreases with increasing shear rate. A marked shear thinning behavior and a quasi-Newtonian behavior were observed in the low shear rate region and in the high shear rate region, respectively for all solvent compositions. The $cellulose/NH_3/NH_4SCN$ solution system only exhibited the viscosity increase with increasing cellulose concentration and failed to show the viscosity drop generally observed at the point of incipience of liquid crystal formation, This may be due to the gel-like nature of the solution by the association of the rodlike molecules into bundles which may serve as crosslinking points giving the cellulose solution a network structure. Also, simply hydrogen bonding may be so restrictive of molecular mobility that a viscosity drop is blocked. In addition to the above results, yield stress and thixotropy were also observed in the $cellulose/NH_3/NB_4SCN$ solution system which are characteristics of liquid crystal and gel, The results of the effect of centrifugation on viscosity show that viscosity decreases by the application of centrifugation. This may be explained by the change of the piled polydomain structure to the dispersed polydomain structure due to the pressure gradient generated during centrifugation.ation.

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Characteristics of Shear Strength and Consolidation Behavior of Soft Ground according to Stage Fill (단계성토에 따른 연약지반의 전단강도 및 압밀거동 특성)

  • Bang, Seongtaek
    • Journal of the Korean GEO-environmental Society
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    • v.21 no.7
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    • pp.17-26
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    • 2020
  • The soft ground in the southwest coastal area composed of marine clay is greatly influenced by sediment composition, particle size distribution, particle shape, adsorption ions and pore water characteristics, tide and temperature. In addition, the geotechnical properties are very complex due to stress history, change in pore water, dissolution process and gas formation. In this study, the physical and mechanical properties of the soft ground were evaluated through field tests and laboratory tests to investigate the strength increase characteristics according to consolidation on the soft ground in the southwest coast. In addition, in order to understand the consolidation behavior of soft ground such as subsidence, pore water pressure, horizontal displacement of soil by embankment load, measuring instruments such as pore water pressuremeter, settlement gauge, inclinometer and differential settlement gauge was installed, and a piezocon penetration test was carried out step by step to confirm the increase in shear strength of the ground. Through this, it was confirmed that the shear strength of the ground is increased according to the stages of filling. In addition, by evaluating the properties of consolidation behavior, strength increase and consolidation prediction by empirical methods and theories were compared to analyze the characteristics of strength increase rate and consolidation behavior in consideration of regional characteristics.

Characterization of Hydroxy-interlayered Mineral in Non-Andic Soils from Jeju Island

  • Lee, Gyoo-Ho;Yungoo Song;Ha, Dae-Ho;Moon, Hi-Soo;Moon, Ji-Won
    • Proceedings of the Mineralogical Society of Korea Conference
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    • 2001.06a
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    • pp.45-47
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    • 2001
  • Jeju island is composed mainly of volcanic rocks such as basalts, trachytic andesites, tracytes, and sedimentary rocks. About 80% of Jeju soils are classified as Andisols. The amount of annual precipitation in Jeju island is about 1872mm, which is 1.5 times the annual precipitation of south Korea. There is a significant difference In amount of precipitation with regions even within Jeju island. In study area, the annual amount of rainfall is about 1280mm, the lowest in Jeju island while south part of the island has the annual precipitation of 2056mm, though they are only tens of kilometers apart. The parent materials of soils in study area are pyroclastic rocks and tuffs. The soils of non-andic properties have developed in this area since pedogenic process of pyroclastic materials is strongly influenced by climatic factor, especially precipitation. In order to investigate the mineralogical characteristics of soils, X-ray analysis for <0.2 and 2-0.2$\mu\textrm{m}$ size fractions was performed with ethylene glycol solvation, K-, Mg-saturation, heat treatment(110, 330, 550$^{\circ}C$). Acid-oxalate and DCB(sodium hydrosulfite, sodium citrate, sodium bicarbonate) dissolution method was used to assess tile total amounts or Al, si, and hydroxy interlayer or 2:1 layer silicates. XRD was also applied for samples treated with DCB only and DCB-oxalate sequentially. XRD patterns showed that 2:1 and 1:1 layer silicates were found, which are different from soils of Andisols. Vermiculite, chlorite, hydroxy interlayered minreals, and interstratified minerals(vermiculite/chlorite) were observed in 2-0.2$\mu\textrm{m}$ size fractions. After DCB treatments, ethylene glycolated samples with Mg-saturation showed expanded d-spacing, suggesting the possibility of hydroxy interlayered minerals. The amounts of hydroxy interlayered minerals increased in surface soil. Unlike Andisols, short range ordered minerals such as allophane, imogolite and gibbsite were hardly found. Mica and kaolinte existed in small amounts. Results are summarized in Fig 1 and Fig. 2.

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Effect of Glass Composition on the Properties of Glass-Infiltrated Alumina (II) : Effect of La2O3 (유리침투 알루미나 복합체의 물성에 미치는 유리조성의 영향 (II) : La2O3의 영향)

  • Lee, Jae-Hee;Kim, Cheol-Young
    • Journal of the Korean Ceramic Society
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    • v.41 no.12 s.271
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    • pp.939-945
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    • 2004
  • Glasses of $SiO_2-B_{2}O_3-Al_{2}O_3-CaO-La_{2}O_3$ with various amounts of $La_{2}O_3$ were infiltrated into a porous alumina to make an alumina-glass composite. The infiltration characterization and bending strength of the composite were examined in terms of glass composition. $La_{2}O_3$ in the glass decreased the high temperature viscosity and this enhanced the wetting behaviour of this glass to alumina, and made glass infiltration easier. The infiltrated glass dissolved the alumina skeleton, and $Al_{2}O_3$ component in the glass melt reprecipitated on the alumina. The grain growth occurred to a specific crystal direction. The glass containing $20mole\%$ of $La_{2}O_3$ was crystallized after infiltration, and this enhanced the bending strength of the composite.

Fabrication and Evaluation of Electrospun TiO2 Nanocomposite Fibers for the Development of UV-protective Textile Materials (자외선 차단 소재 개발을 위한 전기방사 TiO2 복합나노섬유의 제조 및 특성)

  • Lee, Kyung;Lee, Seung-Sin
    • Journal of the Korean Society of Clothing and Textiles
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    • v.34 no.11
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    • pp.1767-1778
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    • 2010
  • This study investigates applying $TiO_2$ (titanium dioxide) nanoparticles to polypropylene nonwoven fabrics via electrospinning for the development of UV-protective materials. To fabricate uniform nanocomposite fibers, three types of $TiO_2$ nanoparticles were applied: powder, colloid, and $TiO_2$ coated polymer pellets. $TiO_2$/polyurethane (PU) and $TiO_2$/poly(vinyl alcohol) (PVA) nanocomposite fibers were electrospun and the morphology was examined using a field-emission scanning electron microscope and a transmission electron microscope. Layered fabric systems with electrospun $TiO_2$ nanocomposite fiber webs were developed at various concentrations of $TiO_2$ in a range of the web area density. The effects of $TiO_2$ concentration and web area density on UV-protective properties were examined. When $TiO_2$ colloid was added into a PVA polymer solution, uniform nanocomposite fiber webs in which $TiO_2$ particles were evenly dispersed were produced. Water-soluble PVA nanofiber webs were given a heat treatment to stabilize the electrospun PVA fibrous structure against dissolution in water. $TiO_2$/PVA nanoeomposite fiber webs with 2wt% $TiO_2$ and 3.0g/$m^2$ web area density exhibited an ultraviolet protection factor of greater than 50, indicating excellent UV protection.

Suggestion for Reform of Korean Medical-Juridical-Person System: through review on for-profit ownership of Korean medical institutions (영리법인병의원에 대한 고찰을 통한 국내 의료법인제도의 재구성 방안)

  • 정형선;이해종;김정덕
    • Health Policy and Management
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    • v.13 no.3
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    • pp.52-70
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    • 2003
  • The rate of conversion to Medical-juridical-persons' ownership of medical institutions has increased rapidly since its start in 1970s in Korea. The most sensitive issue to introduce for-profit medical institutions, ignited particularly by the WTO/DDA negotiations, has sparked considerable debate, stemming largely from conflicting views on the theoretical effects of ownership status on organizational behavior. This study surveyed health-related experts' opinions on allowing for for-profit-firms-owned medical institutions. Some fear that the obligation to maximize the share-holders' return on their investment will cause the medical institutions to eliminate necessary but less lucrative services. They may easily fall under more pressure to generate income, and respond more aggressively than not-for-profit medical institutions to financial pressures. Advocates of for-profit ownership of medical institutions argue that greater responsiveness to the demands of the marketplace will lead to larger investment, higher quality and lower costs to consumers. Referring to both foreign countries' experience and domestic experts' opinions, this study suggests for reform of the current Korean Medical-Juridical-Person(MJP) System. Introduction of so-called “Capital-investment” MJPs is recommended where the properties left in case of their dissolution can be distributed to original investors according to the procedures stipulated in their statutes. However, their annual profits are not allowed to be allocated to investors, but should be reinvested for their medical institutions, as is the case in current MJPs. Their legal aspects are also reviewed in this study.

Properties of Fatigue Crack Initiation and Arrest in Structural Steel Under Acid Fog (산성안개 하의 구조용강에서 피로균열의 발생 및 정류특성)

  • Kim, Min-Geon;Kim, Jin-Hak;Kim, Myeong-Seop;Ji, Jeong-Geun;Gu, Eun-Hoe
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.26 no.2
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    • pp.374-379
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    • 2002
  • Corrosion fatigue tests were carried out to clarify the influence of acid fog as environmental factor on the fatigue strength of SM55C using rotary bending fatigue tester. The fatigue strength of acid fog specimen extremely decreased about 80% compared to that of distilled water specimen. In acid fog environment, a number of cracks commenced at corrosion pit and coalesced with the adjacent cracks during they propagate, and they formed a single non-propagating circumferential crack under the endurance stress of N=5$\times$10$\^$7/ cycles. Also, the depth of the crack is smaller than that of normal fatigue crack, so the crack has a veil small aspect ratio. The reason of this peculiar crack growth characteristics is that the crack opening-closure behaviors are hindered by corrosion products on the surface crack faces, and hence it is thinkable that the strong corrosion action like anodic dissolution for crack growth in depth direction is weaker compared with surface, resulting from faint pumping action of crack during loading-shedding processes.

Material Degradation of 2Cr and 12Cr Tube Steels for High Temperature and Long-Time Exposure (2Cr 및 12Cr 크롬강튜브의 고온 장시간 사용에 따른 열화현상)

  • Choe, Byung-Hak;Lee, Gil Jae;Kim, Sang-Ho;Hong, Key-Yong;Kim, Woo Sik;Baek, Un Bong;Nahm, Seung Hoon
    • Journal of the Korean Institute of Gas
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    • v.16 no.5
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    • pp.28-34
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    • 2012
  • Material degradation of Cr steels in using for boiler tubes was studied in the relation of microstructural changes like carbide behavior and mechanical properties of hardness and creep-rupture life. The carbide dissolution was occurred in 2Cr steel of T22 during high temperature operation. And the grain refinement within martensite lath of 12Cr steel of X20 was derived by the high temperature-long time exposure. But the specific phenomena of material degradation which might be represented by hardness or creep-rupture time of the used tubes were not shown in all the tubes of T22 and X20 even in the fire-side using.