• 제목/요약/키워드: dissolution properties

검색결과 385건 처리시간 0.023초

Effects of dissolution temperature on the rheological properties of polyvinyl alchol solutions in dimethyl sulfoxide

  • Cho, Yong-Han;Dan, Kyung-Sik;Kim, Byoung-Chul
    • Korea-Australia Rheology Journal
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    • 제20권2호
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    • pp.73-77
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    • 2008
  • The rheological properties of polar solutions are very sensitive to preparative methods as well as measuring conditions. The effects of dissolution temperature on the rheological properties of the solutions of polyvinyl alcohol (PVA) in dimethyl sulfoxide were investigated over the range of dissolution temperatures $70-130^{\circ}C$. Viscosity was increased as dissolution temperature was increased. PVA solutions prepared at 120 and $130^{\circ}C$ showed Bingham behavior, which became less noticeable with decreasing dissolution temperature. The modified Cole-Cole plot of the solutions gave slope less than 2, suggesting the solutions were a heterogeneous system irrespective of optical transparency. Further, the slope was decreased with increasing dissolution temperature, indicating that the solid character got more prominent as dissolution temperature was increased. However, the relaxation time of the solutions was little dependent on dissolution temperature.

나노 $BaTiO_3$ 수계슬러리에서 미세구조 및 전기적 특성에 미치는 $Ba^{2+}$이온 용출의 영향 (The Effect of $Ba^{2+}$ion Dissolution on Microstructural Changes and Electrical Properties in $BaTiO_3$ Aqueous Slurry System)

  • 김상우;신용욱;이해원;윤기현
    • 한국세라믹학회지
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    • 제37권5호
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    • pp.511-515
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    • 2000
  • The effect of Ba2+ ion dissolution with different pH and amount of PAA on microstructural changes of green and sintered bodies and its electrical properties was studied in aqueous nano-size BaTiO3 slurry system. The dissolution of Ba2+ was least at strong base, pH 10.8 and by addition of amount of 0.15 wt% PAA. The green body with the lowest of dissolution of Ba2+ at pH 10.8 and 0.15 wt% PAA had minimum values of average pore size, 40nm and shown high increase of sintered density. The compact sintered at 125$0^{\circ}C$ for 2 hr with highest Ba2+ dissolution had low density and dielectric constant due to abnormal grian growth. However, the sintered body with the lowest Ba2+ dissolution had high sintered density and then shown high dielectric constant.

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Evaluation of Patterns and Binding Forces of Tablets in Dissolution Processes

  • Kim, Jung-Woo
    • Journal of Pharmaceutical Investigation
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    • 제15권2호
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    • pp.45-52
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    • 1985
  • For the model tablets using mannitol and Avicel PH 101 as excipients, the patterns of disintegration and dissolution from the differences of physical properties were investigated. It was found that the patterns in the dissolution and binding forces in the interaction of materials by estimates of solid-solid or liquid surface free energy due to cohesive or adhesive properties of materials, and solid surface free energy in binding forces of tablet should be considered as an important factor in dissolution processes.

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Effect of Partial Flow Reductions on DNAPL Source Dissolution Rate

  • Park, Eung-Yu;ParKer, Jeck C.
    • 대한자원환경지질학회:학술대회논문집
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    • 대한자원환경지질학회 2005년도 춘계 학술발표회 논문집
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    • pp.148-151
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    • 2005
  • Field-scale DNAPL dissolution is controlled by the topology of DNAPL distributions with respect to the velocity field. A high resolution percolation model was developed and employed to simulate the distribution of DNAPL within source zones. Statistically anisotropic permeability values and capillary parameters were generated for 10${\times}$10${\times}$10 m domains at a resolution of 0.05 to 0.1 m for various statistical properties. TCE leakage was simulated at various rates and the distribution of residual DNAPL in 'fingers' and 'lenses' was computed. Variations in finger and lens geometries, frequencies, average DNAPL saturations, and overall source topology were predicted to be strongly influenced by statistical properties of the medium as well as by injection rate and fluid properties. Model results were found to be consistent with observations from controlled DNAPL release experiments reported in the literature. The computed distributions of aquifer properties and DNAPL were utilized to perform high-resolution numerical simulations of groundwater flow and dissolved transport. Simulations were performed to assess the effect of grout or foam injection in bore holes within the source zone and of shallow point-releases of fluids with various properties on dissolution in DNAPL dissolution rate, even for widely spaced injection points. The results indicate that measures that induced partial flow reductions through DNAPL source zones can significantly decrease dissolution rates from residual DNAPL. The benefit from induced partial flow reductions is two-fold: 1) local flow reduction in DNAPL contaminated zones reduces mass transfer rates, and 2) contaminant flux reductions occur due to the decrease in groundwater velocity

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토양 중 무기 오염물질의 용출 특성 (Dissolution Properties for the Inorganic Pollutants in Soils)

  • 정강섭;최병인;김상연;송덕영;김건한;성학제
    • 분석과학
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    • 제12권1호
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    • pp.53-60
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    • 1999
  • 토양 중에 존재하는 무기 오염물질의 용출 특성을 조사하였다. 현재 토양환경보전법에서 오염물질로 규정하고 있는 중금속들을 중심으로 As, Cd, Cu, Pb, Zn, Cr 등 6성분에 대하여 그 오염도를 측정하는 과정에서 수반되는 용출 시험의 기초자료 확보와 오염토양 분석법 개선을 위해 모래, 점토 및 양토 시료에 대해 다양한 용출 조건 변화에 따른 각 오염성분들의 용출 특성을 조사하였다. 용출 특성에 가장 큰 영향을 주는 요소는 용출시험시 사용되는 산 농도와 토양시료 자체의 흡착능력을 좌우하게 되는 구성 광물의 조성인 것으로 나타났다. 반면, 산의 종류나 용출 시간 및 토양을 구성하고 있는 입자의 크기는 용출 효율에 크게 영향을 주지 않았다. 실험 전반에 걸쳐 Cd 성분은 토양종류에 상관없이 매우 낮은 산 농도에서도 높은 용출 효율을 나타내었고 As 성분은 가장 낮은 용출 효율을 보였다.

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에리스로마이신 장용성 펠렛의 제제 설계 (Formulation of Erythromycin Enteric-coated Pellets)

  • 이승우;박은석;지상철
    • 약학회지
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    • 제39권6호
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    • pp.593-599
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    • 1995
  • Erythromycin was formulated as enteric-coated pellets in order to reduce degradation in stomach and gastromtestmal irritation, and to maximize the absorption in intestine followmg its oral administration. Core pellets were prepared using fluid-bed granulator with two different methods (powder layering and solvent spraying) and enteric-coated with two different coating polymers (HPMCP and Eudragit E30D). Physical characteristics md dissolution rates of core pellets and enteric-coated pellets were evaluated to optimize the formulation. Powder layering method resulted in shorter initial dissolution time than solvent spraying method, but physicochmical properties of the product were worse than solvent spraying method with respect to hardness, ftiability and density. The dissolution rate of the drug was increased with the addition of surfactants, showing concentration-dependence. The scanning electron microscopic observation of pellets revealed significant differences on the surface appearances prepared with solvent spraying method. The core pellet made with powder layering method had crystals on the surface, which resulted in poor physical properties of the pellets. The dissolution profiles of erythromycin pellets coated with HPMCP or Eudragit L30D were close to that of commercially available erythromycin enteric-coated product.

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K2O-CaO-MgO-SiO2-P2O5계 유리의 제조 및 용출특성 (Dissolution Properties of K2O-CaO-MgO-SiO2-P2O5 Glasses)

  • 이용수;윤태민;강원호
    • 한국세라믹학회지
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    • 제40권11호
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    • pp.1132-1137
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    • 2003
  • 환경친화적인 유리비료로서의 응용을 위해 인산염계 유리의 용출특성에 대한 연구를 진행하였다. 0.1K₂O-0.1SiO₂-0.6P₂O/sub 5/계 유리를 기본조성으로 하고, CaO와 MgO의 함량변화를 준 다양한 유리조성에 대한 유리 형성 조건을 확인하고자 하였다. 또한 CaO 및 MgO의 함량변화에 따른 열적특성 및 용출 특성 변화를 확인하였다. MgO 함량의 증가에 따라 유리 전이온도 및 연화온도는 증가하였으며, CaO 및 MgO의 함량변화에 따라 용출특성에 큰 영향을 미치는 것을 확인하였다.

용액(溶液)에서 백금족(白金族) 금속(金屬)의 화학적(化學的) 특성(特性) 및 용해기술(溶解技術) (Chemical Properties and Dissolution Technology of Platinum Group Metals in Solutions)

  • 이만승
    • 자원리싸이클링
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    • 제19권5호
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    • pp.3-12
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    • 2010
  • 고순도 백금족 금속은 첨단 산업의 기초 소재로 향후 국내 산업의 지속적인 발전에 꼭 필요하다. 국내에는 백금족 금속을 함유한 광물이 전무하므로 백금족 금속을 함유한 여러 폐자원으로부터 백금족 금속을 고순도로 분리 정제할 수 있는 기술의 개발이 시급하다. 백금족 금속의 화학적 성질과 침출거동에 대한 자료를 문헌에서 조사하였다. 또한 향후 백금족 금속과 같은 난용금속의 침출에 이용이 증가할 것으로 예상되는 염소가스를 취입한 염산용액의 열역학적 해석 방법을 소개하였다, 백금족 금속간의 화학적 성질과 침출거동의 미세한 차이정올 이용하면 백금족 금속을 고순도로 회수할 수 있는 기술 개발이 가능하다.

Dissolution Properties of Phosphate Glasses with Trace Elements

  • Lee, Hoi-Kwan;Kang, Won-Ho
    • 한국세라믹학회지
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    • 제42권6호
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    • pp.371-376
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    • 2005
  • Phosphate glasses were prepared by melting quenching process, and glass formation and dissolution properties were studied. The glass forming region in the $K_2O-CaO-P_2O_5$ system is quietly agreed with the report by Mazurin OV et al. with $M_2O-M'O-P_2O_5$ system (M : monovalent cation, M'divalent cation). Conditionally these glasses have solubility from absorbing the moisture or water and then release elements with trace elements, and the thermal and chemical properties were controllable by the $CaO,\;K_2O,\;P_2O_5$ contents. In the abnormal glass properties, this paper showed the possibility the present glasses can be a good candidate for one component of the slow released agriculture fertilizer.

Preparation and Dissolution Properties of the Eco-glass Fertilizer containing Trace Elements

  • Lee Hoi Kwan;Hwang Sheng Jean;Kang Won Ho
    • 한국산학기술학회:학술대회논문집
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    • 한국산학기술학회 2004년도 추계학술대회
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    • pp.96-98
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    • 2004
  • At the previous papers, we showed that K2O-CaO-P2O5 glasses had a solubility in air so that they could be used for glass fertilizer. In this work, we fabricated the Eco-glass fertilizer containing trace elements such as B, Mg, Zn, Fe, Cu, Co, and Mo by a melt-quenching process and the dissolution properties of these glasses were investigated with pH meter and ICP analyzer. In case of the glasses containing the trace elements, effect of trace elements on the dissolutions is not obvious and ignorant the stability of mother glass. Also, the dissolution amounts of each trace elements depend on the mother glass composition and the quantity of each trace element, and mother glasses determined the dissolving velocity of chemical elements.

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