• Title/Summary/Keyword: dissolution properties

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Effects of dissolution temperature on the rheological properties of polyvinyl alchol solutions in dimethyl sulfoxide

  • Cho, Yong-Han;Dan, Kyung-Sik;Kim, Byoung-Chul
    • Korea-Australia Rheology Journal
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    • v.20 no.2
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    • pp.73-77
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    • 2008
  • The rheological properties of polar solutions are very sensitive to preparative methods as well as measuring conditions. The effects of dissolution temperature on the rheological properties of the solutions of polyvinyl alcohol (PVA) in dimethyl sulfoxide were investigated over the range of dissolution temperatures $70-130^{\circ}C$. Viscosity was increased as dissolution temperature was increased. PVA solutions prepared at 120 and $130^{\circ}C$ showed Bingham behavior, which became less noticeable with decreasing dissolution temperature. The modified Cole-Cole plot of the solutions gave slope less than 2, suggesting the solutions were a heterogeneous system irrespective of optical transparency. Further, the slope was decreased with increasing dissolution temperature, indicating that the solid character got more prominent as dissolution temperature was increased. However, the relaxation time of the solutions was little dependent on dissolution temperature.

The Effect of $Ba^{2+}$ion Dissolution on Microstructural Changes and Electrical Properties in $BaTiO_3$ Aqueous Slurry System (나노 $BaTiO_3$ 수계슬러리에서 미세구조 및 전기적 특성에 미치는 $Ba^{2+}$이온 용출의 영향)

  • 김상우;신용욱;이해원;윤기현
    • Journal of the Korean Ceramic Society
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    • v.37 no.5
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    • pp.511-515
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    • 2000
  • The effect of Ba2+ ion dissolution with different pH and amount of PAA on microstructural changes of green and sintered bodies and its electrical properties was studied in aqueous nano-size BaTiO3 slurry system. The dissolution of Ba2+ was least at strong base, pH 10.8 and by addition of amount of 0.15 wt% PAA. The green body with the lowest of dissolution of Ba2+ at pH 10.8 and 0.15 wt% PAA had minimum values of average pore size, 40nm and shown high increase of sintered density. The compact sintered at 125$0^{\circ}C$ for 2 hr with highest Ba2+ dissolution had low density and dielectric constant due to abnormal grian growth. However, the sintered body with the lowest Ba2+ dissolution had high sintered density and then shown high dielectric constant.

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Evaluation of Patterns and Binding Forces of Tablets in Dissolution Processes

  • Kim, Jung-Woo
    • Journal of Pharmaceutical Investigation
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    • v.15 no.2
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    • pp.45-52
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    • 1985
  • For the model tablets using mannitol and Avicel PH 101 as excipients, the patterns of disintegration and dissolution from the differences of physical properties were investigated. It was found that the patterns in the dissolution and binding forces in the interaction of materials by estimates of solid-solid or liquid surface free energy due to cohesive or adhesive properties of materials, and solid surface free energy in binding forces of tablet should be considered as an important factor in dissolution processes.

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Effect of Partial Flow Reductions on DNAPL Source Dissolution Rate

  • Park, Eung-Yu;ParKer, Jeck C.
    • Proceedings of the KSEEG Conference
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    • 2005.04a
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    • pp.148-151
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    • 2005
  • Field-scale DNAPL dissolution is controlled by the topology of DNAPL distributions with respect to the velocity field. A high resolution percolation model was developed and employed to simulate the distribution of DNAPL within source zones. Statistically anisotropic permeability values and capillary parameters were generated for 10${\times}$10${\times}$10 m domains at a resolution of 0.05 to 0.1 m for various statistical properties. TCE leakage was simulated at various rates and the distribution of residual DNAPL in 'fingers' and 'lenses' was computed. Variations in finger and lens geometries, frequencies, average DNAPL saturations, and overall source topology were predicted to be strongly influenced by statistical properties of the medium as well as by injection rate and fluid properties. Model results were found to be consistent with observations from controlled DNAPL release experiments reported in the literature. The computed distributions of aquifer properties and DNAPL were utilized to perform high-resolution numerical simulations of groundwater flow and dissolved transport. Simulations were performed to assess the effect of grout or foam injection in bore holes within the source zone and of shallow point-releases of fluids with various properties on dissolution in DNAPL dissolution rate, even for widely spaced injection points. The results indicate that measures that induced partial flow reductions through DNAPL source zones can significantly decrease dissolution rates from residual DNAPL. The benefit from induced partial flow reductions is two-fold: 1) local flow reduction in DNAPL contaminated zones reduces mass transfer rates, and 2) contaminant flux reductions occur due to the decrease in groundwater velocity

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Dissolution Properties for the Inorganic Pollutants in Soils (토양 중 무기 오염물질의 용출 특성)

  • Chung, Kang-Sup;Choi, Byung-In;Kim, Sang-Yeon;Song, Duk-Young;Kim, Kun-Han;Seong, Hak-Je
    • Analytical Science and Technology
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    • v.12 no.1
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    • pp.53-60
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    • 1999
  • Dissolution properties for the 6 inorganic pollutants (As, Cd, Cu, Pb, Zn, Cr) in soils have been studied. These 6 inorganic pollutants were spiked to 3 kinds of fresh soils which were sand, clay, and loam. The dissolution properties of the prepared samples were investigated under the various extracting conditions such as extracting time, acid concentration, particle size, etc. in order to obtain basic information about the process of extraction test and improvement of related analytical methods. As the results, dissolution properties were affected mainly by acid concentration in extracting procedure and mineral composition of soils. On the other hand, extracting time, sort of acids and particle size of soils had a little influence on the dissolution properties. Cd revealed very high dissolving efficiency and As was very low in whole extracting test.

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Formulation of Erythromycin Enteric-coated Pellets (에리스로마이신 장용성 펠렛의 제제 설계)

  • 이승우;박은석;지상철
    • YAKHAK HOEJI
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    • v.39 no.6
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    • pp.593-599
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    • 1995
  • Erythromycin was formulated as enteric-coated pellets in order to reduce degradation in stomach and gastromtestmal irritation, and to maximize the absorption in intestine followmg its oral administration. Core pellets were prepared using fluid-bed granulator with two different methods (powder layering and solvent spraying) and enteric-coated with two different coating polymers (HPMCP and Eudragit E30D). Physical characteristics md dissolution rates of core pellets and enteric-coated pellets were evaluated to optimize the formulation. Powder layering method resulted in shorter initial dissolution time than solvent spraying method, but physicochmical properties of the product were worse than solvent spraying method with respect to hardness, ftiability and density. The dissolution rate of the drug was increased with the addition of surfactants, showing concentration-dependence. The scanning electron microscopic observation of pellets revealed significant differences on the surface appearances prepared with solvent spraying method. The core pellet made with powder layering method had crystals on the surface, which resulted in poor physical properties of the pellets. The dissolution profiles of erythromycin pellets coated with HPMCP or Eudragit L30D were close to that of commercially available erythromycin enteric-coated product.

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Dissolution Properties of K2O-CaO-MgO-SiO2-P2O5 Glasses (K2O-CaO-MgO-SiO2-P2O5계 유리의 제조 및 용출특성)

  • 이용수;윤태민;강원호
    • Journal of the Korean Ceramic Society
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    • v.40 no.11
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    • pp.1132-1137
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    • 2003
  • For the application of environment conscious glass-fertilizer, dissolution characteristics of phosphate glass was investigated. In 0.1K₂O-0.1SiO₂-0.6P₂O/sub 5/ glass system, the compositions were designed according to variation of CaO & MgO contents, and glass formation region was confirmed. From the glass composition, the confirmed glasses were investigated to figure out thermal and dissolution properties. It was detected that glass transition & softening temperature of the glasses increased with increasing MgO contents. The dissolution properties of the glasses was affected by CaO and MgO content ratio.

Chemical Properties and Dissolution Technology of Platinum Group Metals in Solutions (용액(溶液)에서 백금족(白金族) 금속(金屬)의 화학적(化學的) 특성(特性) 및 용해기술(溶解技術))

  • Lee, Man-Seung
    • Resources Recycling
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    • v.19 no.5
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    • pp.3-12
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    • 2010
  • Platinum group metals with high purity are important raw materials for high technology industry. Since there are no domestic ores containing PGMs, it is of importance to develop a separation process by which ultra pure PGMs can be recovered from diverse spent resources. Data on the chemical properties and dissolution behavior of PGMs were obtained from the literature. A method for the thermodynamic analysis of the HCl solution with chlorine gas was introduced. Utilizing the difference in the chemical properties and dissolution behavior of PGMs would lead to an efficient separation process to recover ultra pure PGMs.

Dissolution Properties of Phosphate Glasses with Trace Elements

  • Lee, Hoi-Kwan;Kang, Won-Ho
    • Journal of the Korean Ceramic Society
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    • v.42 no.6 s.277
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    • pp.371-376
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    • 2005
  • Phosphate glasses were prepared by melting quenching process, and glass formation and dissolution properties were studied. The glass forming region in the $K_2O-CaO-P_2O_5$ system is quietly agreed with the report by Mazurin OV et al. with $M_2O-M'O-P_2O_5$ system (M : monovalent cation, M'divalent cation). Conditionally these glasses have solubility from absorbing the moisture or water and then release elements with trace elements, and the thermal and chemical properties were controllable by the $CaO,\;K_2O,\;P_2O_5$ contents. In the abnormal glass properties, this paper showed the possibility the present glasses can be a good candidate for one component of the slow released agriculture fertilizer.

Preparation and Dissolution Properties of the Eco-glass Fertilizer containing Trace Elements

  • Lee Hoi Kwan;Hwang Sheng Jean;Kang Won Ho
    • Proceedings of the KAIS Fall Conference
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    • 2004.11a
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    • pp.96-98
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    • 2004
  • At the previous papers, we showed that K2O-CaO-P2O5 glasses had a solubility in air so that they could be used for glass fertilizer. In this work, we fabricated the Eco-glass fertilizer containing trace elements such as B, Mg, Zn, Fe, Cu, Co, and Mo by a melt-quenching process and the dissolution properties of these glasses were investigated with pH meter and ICP analyzer. In case of the glasses containing the trace elements, effect of trace elements on the dissolutions is not obvious and ignorant the stability of mother glass. Also, the dissolution amounts of each trace elements depend on the mother glass composition and the quantity of each trace element, and mother glasses determined the dissolving velocity of chemical elements.

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