• Title/Summary/Keyword: dissolution behavior

Search Result 276, Processing Time 0.022 seconds

Factors Affecting the Dissolution Behavior of Metals from Binary Alloys

  • Han, Kenneth N.
    • Resources Recycling
    • /
    • v.10 no.1
    • /
    • pp.49-55
    • /
    • 2001
  • The strategy of recovering metals from scrap is in general much different from primary sources. One of the main differences between the treatment of scrap and that of primary sources lies with the fact that metals are frequently associated with other met-als to form alloys in scrap, while metals occur in primary sources as oxides or sulfides. In this paper, factors affecting the dis-solution behavior of metals from various alloy systems have been reviewed and discussed. Specific examples have been drawn from Au/Ag, Au/cu and Ag/cu systems. Results of the dissolution behavior of various metals from these alloys have been reviewed and compared to the dissolution behavior of single metal systems in various lixiviants such as acids, cyanide and ammonia. It has been observed that the presence of other metals in alloys would significantly affect the dissolution rate of the metal in question. The leaching behavior of metals from homogeneous alloys relies on the chemical interaction between atoms in the lattice of the alloys, while that from heterogeneous alloys is affected by galvanic interaction established in the solution The manner in which the dissolution of a certain metal is influenced by surrounding metals has been discussed in terms of pas-sive and noble nature of the metal in relation to the neighboring metals. The role of the standard electrochemical Potential of these metals on the selective dissolution for a given lixiviant has also been discussed.

  • PDF

A Study on the Relationship Dissolution between Fashion Product Consumers and Stores (패션상품 소비자의 점포 관계단절에 관한 연구)

  • Kim, Eun-Sook;Lee, Sun-Jae
    • Journal of the Korean Society of Clothing and Textiles
    • /
    • v.33 no.3
    • /
    • pp.366-378
    • /
    • 2009
  • The purpose of this study was to understand fashion product consumers' relationship dissolution by considering the characteristics of customer behavior and examining the connection between the main variables. The survey was conducted on 623 women over 20 years old who had experienced relationship dissolution or problems with regular fashion stores in the areas of Seoul and Kyungki in September 2005. The SPSS 12.0 package and Amos program were used to analyze the data. The results of this study were as follows: First, service recovery justice of a fashion store, interactional justice, distributive justice, and procedural justice had effects on encounter satisfaction. Furthermore, encounter satisfaction influenced relationship dissolution behavior, voice, exit, loyalty, neglect via overall satisfaction. Second, there were differences in relationship dissolution behavior according to consumer loyalty and switching costs.

Homogenization Analysis of Problems related to Quartz Dissolution and Hydroxide Diffusion (석영광물의 용해 및 수산화 이온의 확산에 관한 균질화해석)

  • Choi, Jung-Hae;Ichikawa, Yasuaki
    • The Journal of Engineering Geology
    • /
    • v.20 no.3
    • /
    • pp.271-279
    • /
    • 2010
  • Time-dependent behavior similar to secondary deformation related to mineral dissolution is easily observed when performing a laboratory pressure experiment. In this research, to observe the dissolution of quartz found in bentonite used as buffer material for the geological disposal of high-level waste (HLW) under conditions of high pH, we calculated the diffusion of $OH^-$ ions and the behavior of quartz dissolution using the homogenization analysis method. The results reveal that the rate of quartz dissolution is proportional to the temperature and interlayer water thickness. In particular, in a high-pH environment, the reacted area (and therefore the dissolution rate) increases with decreasing interlayer water thickness.

Modeling of Dissolution Potential of Diesel Components (Diesel 용출에 따른 지하수 오염물질의 거동)

  • 김낙경;김현성;염익태
    • Proceedings of the Korean Geotechical Society Conference
    • /
    • 2003.03a
    • /
    • pp.577-584
    • /
    • 2003
  • This study investigated the modeling of dissolution Diesel to estimate the behavior of contaminants in the ground. The modeling based on the initial concentration change considering dissolution potential of pure Diesel and Xylene was performed using VISUAL MODFLOW, and was compared with general modeling ignored the initial concentration change condition.

  • PDF

Alkaline Weight Reduction Monitoring of Sea-island Type Polyarnide Microfiber Fabrics

  • Kwon Yoon-Jung;Koh Joon-Seok;Oh Myung-Joon;Kim Sung-Dong
    • Fibers and Polymers
    • /
    • v.7 no.1
    • /
    • pp.20-25
    • /
    • 2006
  • The alkaline dissolution behavior of sea-island type polyarnide microfibers were successfully monitored using a cationic dye staining method. Weight reduction behavior of the alkali-treated microfiber fabrics and the treated fabrics stained with cationic dye were investigated in a comparative manner. The termination of dissolution monitored by both methods was also confirmed by scanning electron microscopy.

Dissolution Behavior and Hydrate Effect on $CO_{2}$ Ocean Sequestration

  • Kim Nam Jin;Kim Chong Bo
    • Journal of Mechanical Science and Technology
    • /
    • v.19 no.5
    • /
    • pp.1216-1225
    • /
    • 2005
  • $CO_{2}$ ocean sequestration is one of the promising options to reduce $CO_{2}$ concentration in the atmosphere because the ocean has vast capacity for $CO_{2}$ absorption. Therefore, in the present investigation, calculations for solubility and dissolution behavior of liquid $CO_{2}$ droplets released at 1000 m and 1500 m deep in the ocean from a moving ship and a fixed pipeline have been carried out in order to estimate the $CO_{2}$ dissolution characteristics in the ocean. The results show liquid $CO_{2}$ becomes bubble at around 500 m in depth, and the solubility of seawater is about $5{\%}$ less than of pure water. Also, it is shown that the injection of liquid from a moving ship is a more effective method for dissolution than from a fixed pipeline, and the presence of hydrate on liquid $CO_{2}$ acts as a resistant layer in dissolving liquid $CO_{2}$.

Shear Strength Characteristics of Geo - Soluble - Materials (용해재료가 포함된 지반의 전단강도 특성)

  • Tran, M. Khoa;Park, Jung-Hee;Byun, Yong-Hoon;Shin, Ho-Sung;Lee, Jong-Sub
    • Journal of the Korean Geotechnical Society
    • /
    • v.27 no.12
    • /
    • pp.17-25
    • /
    • 2011
  • A fabric of soil media may change due to certain factors such as dissolution of soluble particles, desiccation, and cementation. The fabric changes affect the mechanical behavior of soils. The purpose of this study is to investigate the effects of geo-material dissolution on shear strength. Experiments and numerical simulations are carried out by using a conventional direct shear and the discrete element method. The dissolution specimens are prepared with different volumetric salt fraction in sand soils. The dissolution of the specimens is implemented by saturating the salt-sand mixtures at different confining stresses in the experimental study or reducing the sizes of soluble particles in the numerical simulations. Experimental results show that the angle of shearing resistance decreases with the increase in the soluble particle content and the shearing behavior changes from dilative to contractive behavior. The numerical simulations exhibit that macro-behavior matches well with the experimental results. From the microscopic point of view, the particle dissolution produces a new fabric with the increase of local void, the reduction of contact number, the increase of shear contact forces, and the anisotropy of contact force chains compared with the initial fabric. The shearing behavior of the mixture after the particle dissolution is attributed to the above micro-behavior changes. This study demonstrates that the reduction of shearing resistance of geo-material dissolution should be considered during the design and construction of the foundation and earth-structures.

Effects of dissolution temperature on the rheological properties of polyvinyl alchol solutions in dimethyl sulfoxide

  • Cho, Yong-Han;Dan, Kyung-Sik;Kim, Byoung-Chul
    • Korea-Australia Rheology Journal
    • /
    • v.20 no.2
    • /
    • pp.73-77
    • /
    • 2008
  • The rheological properties of polar solutions are very sensitive to preparative methods as well as measuring conditions. The effects of dissolution temperature on the rheological properties of the solutions of polyvinyl alcohol (PVA) in dimethyl sulfoxide were investigated over the range of dissolution temperatures $70-130^{\circ}C$. Viscosity was increased as dissolution temperature was increased. PVA solutions prepared at 120 and $130^{\circ}C$ showed Bingham behavior, which became less noticeable with decreasing dissolution temperature. The modified Cole-Cole plot of the solutions gave slope less than 2, suggesting the solutions were a heterogeneous system irrespective of optical transparency. Further, the slope was decreased with increasing dissolution temperature, indicating that the solid character got more prominent as dissolution temperature was increased. However, the relaxation time of the solutions was little dependent on dissolution temperature.

Dissolution of North Korean Magnesite by using Hydrochloric Acid

  • Baek, Ui-Hyun;Park, Hyungkyu;Lee, Jin-Young;Kang, Jungshin
    • Korean Chemical Engineering Research
    • /
    • v.55 no.5
    • /
    • pp.711-717
    • /
    • 2017
  • A fundamental study was conducted on the dissolution of North Korean magnesite using hydrochloric acid to understand the dissolution behavior of the magnesium and impurities. The influence of the acid concentration, particle size of the magnesite, reaction temperature, and pulp density on the dissolution of magnesium, iron, calcium, aluminum, and silicon dioxide was studied. The experimental results showed that 98.5% of magnesium, 86.9% of iron, 87.3% of calcium, 23.6% of aluminum, and 20.4% of silicon dioxide were dissolved when magnesite particle sizes within the range of $75{\sim}105{\mu}m$ were reacted using 3 M HCl solution under 6% pulp density at 363 K for 3 h. The residues that remained after the dissolution were silicon dioxide, talc, and clinochlore.

Dissolution Behavior of Plagioclase in HCl and KOH Solutions (염산과 수산화칼슘 수용액과의 반응에 의한 사장석의 용해 거동)

  • 현성필;김수진
    • Journal of the Mineralogical Society of Korea
    • /
    • v.9 no.2
    • /
    • pp.71-81
    • /
    • 1996
  • Dissolution experiments were conducted to understand chemical nature of weathering of anorthosite from the Hadong area. Anorthosite and plagioclase from it were reacted with HCl or KOH solutions under various conditions concerning such as grain size, initial pH of solutions, and shaking Average composition of plagioclase used in the experiment was Na0.32Ca0.71Al1.71Si2.28O8.Under acidic conditions, solution pH increases rapidly in the initial stage and then gradually to reach palteau. Shaking agitates the reaction rate in the initial stage but does not affect after the system reached steady state. Ca and si concentrations show rapid increase and then gradual increase. Al concentration increases rapidly in the early stage and then decreases. Later decrease was interpreted as the precipitation of an Al-bearing material. Different dissolution rates of different constituents of plagioclase together the with precipitation of al-bearing material might be responsible for the non-stoichiometric dissolution of plagioclase.X-ray diffraction analyses on anorthosite before and after dissolution experiment show dissolution rates differ with different lattice planes of plagioclase. It suggests the crystallographic control on dissolution reaction. X-ray photoelectron spectroscopic result shows that the average composition of plagioclase surface reacted with HCL of initial pH 1.97 for 2000 hours is Na0.20Ca0.26Al1.7Si2.3O8. It means that Na- and Ca-depleted H-feldspar is developed without Al-depleted layer on the surface of plagioclase by reaction with HCl and that dissolution reaction takes place sparsely on the surface of plagioclase. Al and Si are dissolved preferentially over Ca from anorthosite powder in KHO solution. Reaction of acid-reacted anorthosite with KOH solution shows the same Si dissolution behavior as in the fresh anorthosite. This indicates that the Al-depleted and Si-enriched layer does not build up on the acid-reacted surface.

  • PDF