• Title/Summary/Keyword: dispersion property

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Enhanced Compatibility of PC/PMMA Alloys by Adding Multiwall Carbon Nanotubes

  • Bae, Do-Young;Lee, Heon-Sang
    • Carbon letters
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    • v.11 no.2
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    • pp.83-89
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    • 2010
  • We prepared polycarbonate (PC)/poly(methyl methacrylate) (PMMA)/multiwall carbon nanotube (MWCNT) nanocomposites by co-rotating twin screw extruder at 533 K. Thermal analysis results indicate that the miscibility of PC and PMMA is enhanced by MWCNTs. Bead necklace-like morphology of PMMA-rich phase is observed in PC/PMMA/MWCNT nanocomposites with increasing PMMA weight fraction due to the bead necklace-like morphology. The tensile strength of PC/PMMA (75/25)/MWCNT (1 wt.%) nanocomposite is 3% higher than those of PC/PMMA (75/25) alloy. Suppression of die swell by MWCNT filler is observed in the melt flow of PC/PMMA/MWCNT nanocomposites during extrusion.

Electrical and Mechanical Properties for Micro-and-Nano Mixture Composites using Electric Field Dispersion Technique (전기장 분산기술을 이용한 에폭시 마이크로-나노 입자가 혼합된 콤포지트의 전기적 그리고 기계적특성)

  • Cho, Dae-Lyoung;Han, Jin-Hee;Kim, Jung-Joong;Kim, Jung-Hoon;Yoo, Byoung-Bok;Park, Jae-Jun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.98-98
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    • 2010
  • A epoxy/multilayered silicate nanocomposite was prepared by a new AC electric application method and micro silica particle was poured into the nanocomposite in order to prepare epoxy/micro-and-nano- mixed composites (EMNC). Electric insulation breakdown strength was measured in a sphere-sphere electrode system designed for the prevention of edge breakdown and the data were estimated by Weibull plot. As the exfoliated silicate nano-plates were homogeniously dispersed in the micro silica particles, the insulation property was higher.

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Effect of Surface Modificaion on the Rheology and Property of CNTs/Epoxy Nanocomposites (표면 개질된 탄소나노튜브/에폭시 나노복합재료의 유변학적 거동과 물성)

  • Kim Jin Ah;Seong Dong Gi;Youn Jae Ryoun
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2004.10a
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    • pp.43-46
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    • 2004
  • Multi-walled carbon nanotubes (MWNTs) produced by chemical vapor deposition were treated with acidic solution for purification and oxidization of CNTs. The surface modification of the oxidized CNTs was achieved by amine treatment and oxygen plasma treatment. The functionalized CNTs were embedded in the epoxy resin by sonication method and the resulting composite was investigated by FESEM. Rheological and mechanical properties of nanocomposites were measured by AR2000 and Instron. The rheological properties and dispersion of modified CNTs/epoxy composites were improved as CNTs were modified, because the modification of CNTs led to a improvement interaction between the CNTs and the epoxy resin. In addition to this, mechanical properties are also improved because of the effective stress transfer between the CNTs and the polymer.

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Influence of Bingham Characteristics for ER Fluid on Semi-Active Suspension System (ER유체의 역학적 특성이 반능동 현가시스템에 미치는 영향)

  • 김옥삼;김일겸;조남철;박우철
    • Journal of Advanced Marine Engineering and Technology
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    • v.28 no.3
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    • pp.434-440
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    • 2004
  • The electro-rheological fluids for semi-active suspension system are a class of colloidal dispersion which exhibit large reversible changes in their rheological behavior when they are subjected to external electrical fields. This paper presents Bingham properties of ER fluids subjected to temperature variations. In addition, an appropriate size of the ER damper for a passenger car is proposed to investigate the effects of Bingham characteristics on the damping performance. The filed-dependent damping forces are evaluated according to the temperature variation and sedimentation ratio.

A Study on Polyurethane Treatment of Fabric - Synthesis of Water Dispersing Agent, and Anti-static and Softening Finishing - (직물의 우레탄처리 가공 - 수분산성 가공제의 합성과 대전방지 및 유연가공에 대하여 -)

  • Ahn, Young-Moo
    • Fashion & Textile Research Journal
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    • v.3 no.1
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    • pp.42-47
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    • 2001
  • The hardening system of polyurethanes has usually caused by air pollution. bad working condition and fire hazard according to using orgarnic solvents. Therefore there have been researched on emulsion, water soluble and colloid-dispersion based water soluble instead of using organic solvents recently. This study synthesized polyurethane dispersing particle by means of mixing precursor and neutralized emulsion method. In the first step, polyurethane was preparated from isophorone diisocyanate and poly (ethylene-adipate) glycol, and got precursor by introducing dimethyl propionic acid as a hydrophilic group. Synthesized polyurethane was bonded to the surface of fiber and crosslinked as a anti-static agent, and then looked for the change of color and softening property.

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Characterization of Polyolefin Bumper Recycled by Chemical Removal Method using Electronic Speckle Pattern Interferometry (화학적 박리방법과 ESPI에 의한 재생된 폴리올레핀 범퍼수지의 물성평가)

  • 김현경;강기수;김경석;홍진후
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1997.10a
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    • pp.295-298
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    • 1997
  • Recycl ing of PP/EPR based bumper coated with polyester urethane paint has been per formed by chemical decoating method. Electronic Speckle Pattern Interferometry (ESP11 has been applied to characterize the deformation of polyolef in based bumper. In additon, physical properties and processability of recycled materials have been investigated by dynamic mechanical thermal analysis, impact test and melt flower index measurement. The results show that the deformation ratio of recycled material is higher than that of virgin one. The morphological change of EPR, degree of distribution and dispersion during the recycling process seem to be the most important factor for the deformation and the mechanical properties of recycled materials. The experimental results obtained show that ESPI is very powerful technique to study the thermal mechanical property of polyolefin bumper system.

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Grease from Korean Bentonites (국산 벤토나이트 그리이스 제조)

  • Tak Jin Moon;Oh Kwan Kwon
    • Journal of the Korean Chemical Society
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    • v.16 no.3
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    • pp.193-199
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    • 1972
  • Bentones from Korean bentonites were first prepared by reacting bentonites with high molecular weight imidazolines. The cation exchange capacity of bentonites was found more than 100meq/100g sample. Greases were then prepared by dispersing bentones into a lubricating oil and milling through a three-roll dispersion mill. Consistency in microscale, oxidation stability (static), water resistance, and wear property of the greases were tested by the ASTM methods, and good experimental results were obtained.

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Thermal properties of latent heat storage microcapsule-water slurry

  • Mun, Soo-Beom
    • Journal of Advanced Marine Engineering and Technology
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    • v.39 no.8
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    • pp.807-812
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    • 2015
  • A microcapsule water slurry is a latent heat-storage material having a low melting point. In this study, the thermal properties of a microcapsule water slurry are measured. The physical properties of the test microcapsule water slurry, i.e., thermal conductivity, specific heat, latent heat, and density, are measured, and the results are discussed for the temperature region of solid and liquid phases of the dispersion material (paraffin). It is clarified that Eucken's equation can be applied to the estimation of the thermal conductivity of the microcapsule water slurry. Useful correlation equations of the thermal properties of the microcapsule water slurry are proposed in terms of the temperature and concentration ratio of the microcapsule water slurry constituents.

A study on nonlinear channel equalization using RBF network (RBF 네트워크를 이용한 비선형 채널 등화에 관한 연구)

  • 전선도;위진우;강철호
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.22 no.1
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    • pp.64-71
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    • 1997
  • Digital communication channels are imparied by linear effects such as dispersion, ISI(intersymbol Interference), fading phenomenon etc. But, the practical channel equalization system is required to design for compensating the nonlinear distortion caused by harmonic distortion etc. This paper is a study on the performance of nonlinear channel equalization using RBF(Radial Basis Funclion) network, which has the equivalent structure to the optimal Basian filter. Expecially, the variance of RBF network is modifiedby nonlinear polynomial filters to compare the convergence characteristic of nonlinear channel equalization. Experimental results show that the modified RBF network achieves the faster convergence property than conventional RBF network. Moreover, the RBF network ofhigher order variance modified represents the better performance than that of lower order variance in the bandpass channels and second/third order polynomial channels.

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Structure-property relationship of melt intercalated maleated polyethylene nanocomposites

  • Reddy, M.M.;Gupta, Rahul K.;Bhattacharya, S.N.;Parthasarathy, R.
    • Korea-Australia Rheology Journal
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    • v.19 no.3
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    • pp.133-139
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    • 2007
  • Low density polyethylene nanocomposites were prepared by melt intercalating maleic anhydride grafted polyethylene and montmorillonite clay. It has been found that maleic anhydride has promoted strong interactions between polyethylene and montmorillonite, leading to the homogeneous dispersion of clay layers. Rheological experiments revealed that prepared nanocomposites exhibited shear thinning behaviour. Polyethylene nanocomposites exhibited an increase in steady shear viscosities compared to virgin polyethylene owing to strong polymer clay interactions. The tensile strength of nanocomposites was improved but elongation at break decreased considerably. Also, barrier properties improved significantly with montmorillonite content.