• 제목/요약/키워드: dispersion agent

검색결과 210건 처리시간 0.031초

다공성 매질에서의 착화하는 방사성핵종의 이동에 대한 이론적 접근 (A Theoretical Approach on the Migration of a Chelating Radionuclide in Porous Medium)

  • 백민훈;이건재
    • Journal of Radiation Protection and Research
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    • 제17권2호
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    • pp.49-59
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    • 1992
  • 이온 또는 착화된 상태의 방사성핵종의 이동에 대한 착화제의 영향을 조사하기 위하여 새로운 모델이 제시되었다. 착화된 방사성핵종의 이동거동은 착화제와 착화된 방사성핵종의 열화를 포함하는 대류-확산 이동방정식에 의해 해석되었다. 이 수학적 모델은 해석적인 방법 에 의해 구해졌으며 지연요소를 조사함으로써 분석되었다. 계산결과들은 감소된 지연요소에 의해 착화된 방사성핵종의 이동속도가 이온형태의 방사성핵종보다 매우 빠름을 보여주었다. 따라서 원자력발전소로부터의 착화제의 발생과 환경으로의 유출을 감소시킬 수 있는 새로운 구제책이 필요하다고 하겠다.

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Preparation and Properties of Crosslinkable Waterborne Polyurethanes Containing Aminoplast(I)

  • Kwon Ji-Yun;Kim Han-Do
    • Macromolecular Research
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    • 제14권3호
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    • pp.373-382
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    • 2006
  • A series of crosslinkable, waterborne polyurethanes (I-WBPUs) were prepared by in-situ polymerization using isophorone diisocyanate (IPDI)/poly(tetramethylene oxide) glycol (PTMG, $M_n$=2,000)/dimethylol propionic acid (DMPA)/ethylene diamine (EDA)/triethylamine (TEA)/aminoplast[hexakis(methoxymethyl)melamine (HMMM)] as a crosslinking agent. Typical crosslinkable, waterborne polyurethanes (B-WBPUs) blended from WBPU dispersion and aqueous HMMM solution was also prepared to compare with the I-WBPUs. The crosslinking reaction between WBPU and HMMM was verified using FTIR and XPS analysis. The effect of the HMMM contents on the dynamic mechanical thermal, thermal, mechanical, and adhesion properties of the I-WBPU and B-WBPU films were investigated. The storage modulus(E'), glass transition temperatures of the soft segment ($T_{gs}$) and the amorphous regions of higher order ($T_{gh}$), melting temperature ($T_m$), integral procedural decomposition temperature (IPDT), residual weight, $T_{10%}$ and $T_{50%}$ (the temperature where 10 and 50% weight loss occurred), tensile strength, initial modulus, hardness, and adhesive strength of both I-WBPU and B-WBPU systems increased with increasing HMMM content. However, these properties of the I-WBPU system were higher than those of the B-WBPU system at the same HMMM content. These results confirmed the in-situ polymerization used in this study to be a more effective method to improve the properties of the WBPU materials compared to the simple blending process.

Ginseng alleviates microbial infections of the respiratory tract: a review

  • Iqbal, Hamid;Rhee, Dong-kwon
    • Journal of Ginseng Research
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    • 제44권2호
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    • pp.194-204
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    • 2020
  • The detrimental impact of air pollution as a result of frequent exposure to fine particles posed a global public health risk mainly to the pulmonary disorders in pediatric and geriatric population. Here, we reviewed the current literature regarding the role of ginseng and/or its components as antimicrobials, especially against pathogens that cause respiratory infections in animal and in vitro models. Some of the possible mechanisms for ginseng-mediated viral inhibition suggested are improvements in systemic and mucosa-specific antibody responses, serum hemagglutinin inhibition, lymphocyte proliferation, cell survival rate, and viral clearance in the lungs. In addition, ginseng reduces the expression levels of proinflammatory cytokines (IFN-γ, TNF-α, IL-2, IL-4, IL-5, IL-6, IL-8) and chemokines produced by airway epithelial cells and macrophages, thus preventing weight loss. In case of bacterial infections, ginseng acts by alleviating inflammatory cytokine production, increasing survival rates, and activating phagocytes and natural killer cells. In addition, ginseng inhibits biofilm formation and induces the dispersion and dissolution of mature biofilms. Most clinical trials revealed that ginseng, at various dosages, is a safe and effective method of seasonal prophylaxis, relieving the symptoms and reducing the risk and duration of colds and flu. Taken together, these findings support the efficacy of ginseng as a therapeutic and prophylactic agent for respiratory infections.

다층 경사기능재료의 제조를 위한 Zr(Y,Ce)$O_2$ TZP/Mullite 현탁액의 가압여과 (Pressure Filtration of Zr(Y,Ce)$O_2$ TZP/Mullite Suspensions for the Preparations of Functionally Gradient Materials with Multi-layer)

  • 이상진;박상희;박홍채;전병세
    • 한국세라믹학회지
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    • 제37권7호
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    • pp.693-699
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    • 2000
  • Casting behavior of Zr(Y,Ce)O2 TZP/Mullite suspension during pressure filtration was investigated to prepare multi-layered Functionally Gradient Materials(FGM). The dispersion stabilities of each layer suspension were investigated by examination of zeta potential and viscosity. The each suspensions with 20 vol.% solid loading and 100 첸 of viscosity was prepared after fix of the dispersing agent (Sodium hexa-meta phosphate) and the binder (Hydroxyethyl cellulose), and then the cakes were formed at the 2.5 MPa~10.0MPa pressure range. The cake thickness of all suspensions was increased with the square root of time at the constant pressure, and the relations between filtration pressure(P)a nd dehydration rate (Q=dh/dt) showed that the flows of filtrates in the consolidated layers were laminar. The permeabilities were nearly constant during filtration, and kozeny constants(Kc) of the suspensions were 4.8~6.7. These valumes were seen as close to 5, which might be homogeneous particle packing during filtration. On the basis of those data, the multi layered compaction with 9 mm thickness and 52.5% green density was prepared by continuous pressure filtration.

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원거리 화학영상탐지시스템의 시야각에 대한 연구 (A Study on the Field of View of the Remote FTIR Chemical Imaging Detection System)

  • 이종민;강영일;김주현
    • 한국군사과학기술학회지
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    • 제17권1호
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    • pp.122-128
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    • 2014
  • Remote fourier transform infrared(FTIR) chemical imaging detection system allows detection and identification of gases in the atmosphere from long distances. In this paper, the appropriate field of view(FOV) of the FTIR imaging system was examined and the main performance of the system for the interferometer was described. For the determination of the FOV, simulations of gas dispersion range were performed with the NBC reporting and modeling software(NBC-RAMS) developed by ADD. As a result, minimum 192 mrad of FOV was required for the remote FTIR imaging system to visualize chemical warfare agents dispersed in several hundred meters. At the same time, 0.75 mrad of instantaneous field of view(IFOV) for a linear interferometer proper to take a FOV for the chemical agent imaging.

Development of specific organ-targeting drug delivery system 1

  • Kim, Chong-Kook;Jeong, Eun-Ju;Yang, Ji-Sun;Kim, Seung-Hwan;Kim, Yang-Bae
    • Archives of Pharmacal Research
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    • 제8권3호
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    • pp.159-168
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    • 1985
  • In attempt to develop a drug delivery system using serum albumin microspheres, bovine serum albumin microspheres containing antitumor agent, cytarabine, were prepared. The shape, surface characteristics, size distribution, behavior of in vitro distribution, drug release behaior, and degradation of albumin microspheres in animal liver tissue homogenate and proteolytic enzyme were investigated. The shape of albumin microspheres was spherical and the surface was smooth and compact. The size distribution of the albumin microspheres was affected by dispersion forces during emulsification and albumin concentration. Distribution of albumin mirospheres after intravenous administration in rabbit was achieved immediately. In vitro, albumin microsphere matrix was so hard that it retained most of cytarabine except initial burst during the first 10 minutes, and the level of drug release during the initial burst was affected by heating temperature, drug/albumin concentration ratio and size distribution. After drug release test, the morphology of albumin micropheres was not changed. Albumin microsphere matrix was degraded by the rabbit liver tissue homogenate and proteolytic enzyme. The degree of degradation was affected by heating temperature.

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나일론 전사 DTP 원단 전처리에 따른 발색성 및 견뢰도 특성 (Color and Fastness Properties of Nylon Transfer Digital Textile Printing(DTP) using Acrylic-based Polymer as Pre-treatment Agent)

  • 김혁진;홍진표;곽동섭;서혜지;김현조
    • 한국염색가공학회지
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    • 제31권2호
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    • pp.88-97
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    • 2019
  • In this study, when printed on a nylon material, the color strength and fastness are lower than that of a polyester material, and the nylon material shrinks due to heat and pressure, resulting in poor design and poor compatibility. To overcome this problem, we investigated the possibility of transfer DTP by adding pre-treatment process to nylon transfer DTP process. For the basic study of pre-treatment preparation, we used pure nylon material which is not compounded and dispersion ink and transfer paper applied to existing PET transfer DTP. Pre-treatment preparations were classified into three types of acryl-base polymer and pre-treated with nylon and then applied to transfer DTP to confirm their color strength and fastness. The color strength of the pre-treated nylon material increased and poly-methyl-acrylate amulsion pre-treatment showed the best color at $210^{\circ}C$, 1.5m/min and 0.3MPa. The nylon material pre-treated with washing, friction, and light fastness was judged to be more excellent and stable.

EPDM/POSS(Polyhedral oligomeric silsesquioxane) 복합재료의 물성 연구 (A Study on Physical Properties of EPDM/Polyhedral Oligomeric Silsesquioxane (POSS) Composites)

  • 박현호
    • 공업화학
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    • 제32권4호
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    • pp.472-477
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    • 2021
  • 다면체 올리고머 실세스퀴옥산 (POSS) 중 케이지 형태 8개의 아크릴레이트 그룹을 포함하는 POSS가 에틸렌-프로필렌-디엔고무 (EPDM) 과산화물 가교에서의 가교 거동, 기계적 특성에 미치는 영향 및 열 안정성 등을 조사하였다. 고무 100 phr당 0~12 phr의 POSS를 함량 별로 혼합하고 과산화물 가교제를 첨가하여 EPDM/POSS 복합재료를 만들었다. 가교 특성 결과 POSS의 아크릴레이트 그룹이 과산화물에 의해 활성화 되었고, 과산화물 가교 효율을 향상시키는 것으로 나타났다. EPDM/POSS 복합재료에서 POSS의 분산안정성은 떨어졌지만, 복합재료의 파단 강도, 신장률 및 열 안정성은 향상되었다.

EFFECT OF PROCESS CONTROL AGENT ON THE MICROSTRUCTURE OF Ni-BASED ODS SUPERALLOY PRODUCED BY MECHANICAL ALLOYING AND SINTERING

  • JU-YEON HAN;HYUNJI KANG;SUNG-TAG OH
    • Archives of Metallurgy and Materials
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    • 제64권3호
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    • pp.949-952
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    • 2019
  • The effects of different types of process control agents (PCA) on the microstructure evolution of Ni-based oxide dispersion-strengthened superalloy have been investigated. Alloy synthesis was performed on elemental powders having a nominal composition of Ni-15Cr-4.5Al-4W-2.5Ti-2Mo-2Ta-0.15Zr-1.1Y2O3 in wt % using high energy ball milling for 5 h. The prepared powders are consolidated by spark plasma sintering at 1000℃. Results indicated that the powder ball-milled with ethanol as PCA showed large particle size, low carbon content and homogeneous distribution of elemental powders compared with the powder by stearic acid. The sintered alloy prepared by ethanol as PCA exhibited a homogeneous microstructure with fine precipitates at the grain boundaries. The microstructural characteristics have been discussed on the basis of function of the PCA.

Rosiglitazone 가용화를 위한 PEG-PLA(PLGA) 고분자 미셀의 제조 및 특성분석 (Preparation and Characterization of PEG-PLA(PLGA) Micelles for Solubilization of Rosiglitazone)

  • 김연환;임정혁;민현수;김준기;이용규;박고은;조광재;허강무
    • 폴리머
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    • 제34권3호
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    • pp.274-281
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    • 2010
  • 본 실험에서는 일련의 poly(ethylene glycol)-poly(D,L-lactide)(또는 -poly(D,L-lactide-co-glycolide))이중블록 공중합체들을 D,L-lactide(또는 glycolide)의 고리열림 중합에 의해 합성하고, 당뇨병 치료제 일종인 rosiglitazone의 가용화를 위한 고분자 미셀 제형으로서의 특성을 평가하였다. 고체분산법을 이용하여 높은 봉입률의 약물함유 미셀 제형을 효과적으로 제조하였고, 미셀 제형의 수용액 내 안정성을 hydrotropic agent의 일종인 2-hydroxy-N-picolylnitinamide(HPNA)의 사용으로 더욱 향상시킬 수 있었다. 생체 외 세포생존평가에서 생체적합성과 낮은 독성을 보였고, 쥐를 이용한 동물실험에서도 약물을 함유한 고분자 미셀이 약물 대조군보다 혈당을 보다 효과적으로 감소시켰다.