• Title/Summary/Keyword: dispersion agent

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EVALUATION 01 OIL DISPERSION AGENT BY ASSESSMENT 01 COLOR STRENGTH 01 ORGANIC PIGMENT

  • H., Young-Chan;R., Seo-Joon;L., Dong-Wook;H., Soon-Taek
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.24 no.3
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    • pp.73-80
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    • 1998
  • This Study was performed to get the suitable oil dispersion agent by assessment of color strength of organic pigment in non-aqueous systems. Organic pigment is used as a color expression material with other body pigments in the make-up products. But occasionally aggregation or agglomeration occurs for the lack of affinity with medium, This function is the cause of disturbing homogeneous dispersion, and then bring about an instability of products. Our study, research of dispersion mechanism between the pigment and oil phase, has been executed to solve this problem, and find a oil dispersion agent having optimum dispersion condition. Generally dispersion is related to between the solid-liquid mutual properties and electrical phenomena associated with solid-liquid interface. This factor is determined to input energy, milling time, optical properties, particle size, rheological properties, etc. Ideal dispersion state is told that coloring primary solid particle is homogeneously dispersed in medium. Good dispersed colorants are strongly and clearly appeared. We are already known that the particle size of organic pigment, chemical properties and viscosity of medium, refractive index. Consequently We determine the affinity of medium and organic pigment by measuring of color strength in the same mechanical condition. UV-VISIBLE RECORDING SPECTRO PHOTOMETER is used for measuring apparatus. We can decided the dispersion level of oil dispersion agent by measuring absorbance of color strength in the visible range that diluted medium for colloid colorant particles.

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Evaluation of dispersion degree of nanoparticles in TiO2/epoxy resin nanocomposites

  • Nam, Ki-Woo;Moon, Chang-Kwon
    • Journal of Ocean Engineering and Technology
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    • v.28 no.4
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    • pp.338-344
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    • 2014
  • The purpose of this study was to evaluate the dispersion degree of particles using a nanoindentation test for titanium oxide nanoparticles/epoxy resin nanocomposites. Thus, the effects of the particle size and weight fraction, dispersion agent, and position of the sample on the modulus and degree of particle dispersion in the nanocomposites were investigated. As a result, the dispersion degree of large particles was found to be better than that of smaller particles in composites. It could be found that the aggregation or agglomeration of small particles with large surface energy occurred more easily in nanocomposites because of the large specific surface area. The moduli of the upper side of the film-shaped sample obtained from a nanoindentation test were low scattering, while the values for the bottom side were high scattering. Thus, the dispersion situation of the nanoparticles on the upper side of film-shaped samples could be considered to be better than that for the bottom side. This could be concluded due to the non-uniform nanoparticle dispersion in the same sample. The modulus obtained from nanoindentation test increased slightly with the content of nanoparticles and increased with the indented depth for the same sample. The latter is presumably due to the increase in the accumulated particles facing the indenter with the indented depth. The nanoindentation test was found to be a useful method to evaluate the dispersion status of nanoparticles in nanocomposites.

A Study on the Methyl Salicylate Dispersion in the Vicinity of Obstacles by Wind Tunnel Test (아음속 풍동을 이용한 구조물 형상 변화에 따른 살리실산메틸 확산 유동 연구)

  • Hong, Chang-Ki;Uhm, Han-Sup;Choi, Seung-Ki;Kim, Youn-Jea
    • The KSFM Journal of Fluid Machinery
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    • v.17 no.6
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    • pp.69-73
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    • 2014
  • To predict flow fields and chemical agent dispersion in urban area, wind tunnel experiments was performed. The agent was adopted MS (methyl salicylate) because the real chemical agent is unsafe. The exact concentration of methyl salicylate was generated by the commercial gas generator (STI-2500) and three different obstacle shapes were applied (i.e., rectangular, cylinder and pyramid). The concentration was measured with the qualified ion mobility sensor and gas chromatography. The data necessary for virtual test method of the real chemical agent were obtained.

Ab Initio Dispersion Polymerization of Styrene in the Presence of the Poly(methacrylic acid) Macro-RAFT Agent

  • Wi, Yeon-Hwa;Lee, Kang-Seok;Lee, Byung-Hyung;Choe, Soon-Ja
    • Macromolecular Research
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    • v.17 no.10
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    • pp.750-756
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    • 2009
  • Stable, spherical, polystyrene particles were synthesized in ab initio dispersion polymerization by using the poly(methacrylic acid)[PMAA] macro-RAFT agent. The presence of the PMAA macro-RAFT agent on the polystyrene (PS) particles was confirmed by NMR and FTIR spectroscopy. The PS particle size was influenced by the concentration of the RAFT agent and monomer due to the initial nucleation. When the concentration of the PMAA macro-RAFT agent was increased from 2 to 10 wt% relative to the monomer, the average particle size decreased from 2.31 to 1.36 ${\mu}m$, the conversion decreased from 93.3 to 88.9%, the weight-average molecular weight increased from 46,300 to 150,200 g $mol^{-1}$ and the PDI decreased from 2.79 to 1.94, respectively. In particular, the incorporation of 10 wt% of PMAA macro-RAFT agent produced monodisperse PS spheres of 1.36 ${\mu}m$ with a coefficient of variation (CV) of 6.44%. Thus, the PMAA macro-RAFT agent worked as a reactive steric stabilizer providing monodisperse, micron-sized, PS particles.

Effect of Dispersing Agent for Carbon Black in Aqueous Systems (Carbon Black의 수계분산에서 계면활성제의 영향)

  • 김현성;손성민;김성빈
    • Journal of the Korean Graphic Arts Communication Society
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    • v.18 no.1
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    • pp.71-81
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    • 2000
  • The water-based ink has lately attracted considerable attention because of problems of energy and population. Carbon blacks have been widely utilized in water-based systems to provide pigmentation. One of the most important factors in the successful formulation of an aqueous system containing carbon black is the dispersion and the selection and proper utilization of the dispersing agent. This is similar to water-based ink. This paper discusses dispersion of carbon black with the factors affecting the dispersing agent requirement (DAR) and describes a laboratory method for determining it. Variables that affect the dispersion, such as structure, surface area, and oxidation level of the carbon black are examined through test data. Anionic and nonionic dispersing agents are evaluated using the DAR method. From this study, the increased surface area, the increased DAR is indicated. DAR is indicated to depend on HLB(Hydrophilic Lipophilic Balance) of dispersing agent and pH of dispersing system.

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Strength and conversion characteristics of DeNOx catalysts with the addition of dispersion agent (분산제 첨가에 따른 탈질촉매의 강도세기 및 전환특성)

  • Lee, Hyun Hee;Park, Kwang Hee;Cha, Wang Seog
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.12
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    • pp.6575-6580
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    • 2013
  • Various modified SCR catalysts were prepared and tested to improve the strength of catalysts for use under severe conditions. The SCR catalysts were modified with a binder and dispersion agent, and tested at the fixed bed reactor. FT-IR and $H_2$-TPR were used to analyze the degree of hydrogen use and ammonia adsorption by the modified catalysts. In the case of the SCR catalysts coated with 2.3g of the binder, 4.7g of ethanol, and 0.1g of dispersion agent, the strength of catalyst was increased by approximately 12%. On the other hand, despite the enhancement of strength, the activities of the SCR catalysts were decreased by 2-10%. When the mixed solution composed of binder, dispersion agent and $SiO_2$ solution was precipitated on the catalyst, the $NO_x$ conversion of the catalyst was decreased slightly. The Bronsted acid site and Lewis acid site worked as the activators for the SCR reaction, and were decreased by $SiO_2$.

The Effect of Lignin Compound on Dispersibility of Concrete (Lignin 화합물의 Concrete 분산성에 대한 연구)

  • 문정연;한기성
    • Journal of the Korean Ceramic Society
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    • v.13 no.3
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    • pp.37-42
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    • 1976
  • Although the water mixed into the concrete plays the role of hydration and acquiring the necessary workability, the more portion of water acts to obtain the substantial workability rather than to complete the hydration. However, the excess amount of water causes the poor quality of concrete, therefore it is useful to add the minimum amount of water as required as to acquire the proper workability. There have been the considerable numbers of investigations in which the dispersion phenomena of strong eletrolytic high polymer compounds such as lignosulfate and some of surface activation agents were studied to utilize as the dispersion agent of concrete. In the present study, Na-lignate, dispersion properties of which has not been studied yet, were investigated with the purpose of utilizing as a dispersion agent of concrete. The microscopic observations showed a great improvement in the dispersion of cement particles, also the fluidity and compressive strength of concrete were remarkably increased with the addition of Na-lignate: The addition of Na-lignate by 0.02% showed the increase of 1.76 times and 1.27 times of slump value and flow value respectively, and the compressive strength was increased by 1.07 times.

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Effect of $TiO_2$ Nanoparticle on the Mechanical and Thermal Properties of Epoxy Resin Composites (에폭시수지 복합재료의 기계적.열적 성질에 대한 $TiO_2$ 나노입자의 영향)

  • Moon, Y.J.;Choi, J.Y.;Kim, B.A.;Moon, C.K.
    • Journal of Power System Engineering
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    • v.14 no.4
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    • pp.68-75
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    • 2010
  • The effect of dispersion agent, the content and size of nanoparticle on the mechanical and thermal properties has been investigated in $TiO_2$ nanoparticle/epoxy resin composites(nanocomposites). The weight fraction of fabricated nanocomposites were 0, 1, 3, 5%, respectively. The glass transition temperature was lower than pure epoxy resin and decreased with the increasing of nanopaticle content. This is considered that the cross link of epoxy resin during solidification was hindered by the presence of nanoparticles. Nanocomposites of 3wt% content with dispersion agent showed the best tensile strength. The tensile strength of 20㎚ $TiO_2$ nanocomposites were higher than one of 200nm $TiO_2$ nanocomposites.

Development of Specific organ targeting drug delivery system II : Physico-pharaceutical study on the crose-linked albumin microspheres containing cytarabine

  • Kim, Chong-Kook;Lee, Jin-Kyu;Lah, Woon-Lyong
    • Archives of Pharmacal Research
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    • v.9 no.1
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    • pp.39-43
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    • 1986
  • Bovine serum albumin microspheres containing cytarabine were prepared using cross-linking agent, formaldehyde. The shape and the size distribution of them were observed. The shape of them was spherical and the susrface was compact and smooth. The size distribution of them was affected by dispersion forces during emulsfication. The release of cytarabine from albumin microspheres was dependent upon cross-linking time, amount of cross-linking agent and drug/albumin ratio. However, the difference of drug release by the dispersion forces was not great. After release test, the shape of albumin microspheres was nonspherical and the albumin matrix seemed to be a little relaxed. The degradation tests of albumin microspheres by the proteolytic enzyme showed that albumin microspheres were progressively digested according to the cross-linking degree.

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A comparative Study for dispersion model in evacuation plan by using MAS-based evacuation simulation (MAS 기반 피난시뮬레이션을 이용한 분산대피 비교 연구)

  • Jang, Jae-Soon;Rie, Dong-Ho
    • Journal of the Korean Society of Safety
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    • v.29 no.1
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    • pp.59-63
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    • 2014
  • Smoke is one of the most critical factor when escaping from the fire since it reduces visibility and interrupts finding emergency exit lights. Therefore, it is recommended that an evacuation simulation program should incorporate the smoke factor. In addition, it is suggested that the program should include not only the unilateral damage by the smoke but also the detour evacuation by risk communication. In this study, MAS (Multi Agent System)-based simulation program which incorporates the reduced walking speed by smoke and adopts the dispersion evacuation logic during escaping from the fire. To make comparison, a commercial evacuation program, Pathfinder was used. It was found that the simulation results of MAS (Multi Agent System)-based program is better than Pathfinder in terms of safe evacuation. It means that evacuation simulation need a additional evaluation categories that include not only quick evacuation time but also safe evacuee number.