• Title/Summary/Keyword: dispersed solution

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Analysis of Electrical and Physical Property of the PU/MWNT Film and Dispersion Characteristics of MWNT According to the Solvent (용매에 따른 MWNT의 분산특성과 제조된 PU/MWNT 필름의 전기적·물리적 특성 분석)

  • Kim, Jeong-Hyun;Ma, Hye-Young;Yang, Sung-Yong;Kim, Seung-Jin
    • Textile Coloration and Finishing
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    • v.24 no.1
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    • pp.69-78
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    • 2012
  • This paper surveys the physical properties of the MWNT dispersion solution dispersed with the three types of solvents and of the polyurethane composite film for improvement of mechanical properties and electrical characteristics of PU/MWNT composite film. For this purpose, the MWNT dispersed solution was mixed with three types of solvent such as IPA, MEK and Toluene and then mixed with polyurethane (100part) with variation of loading content (0, 10, 20, 30, 40, 50 part) of MWNT dispersed solution in the ultrasonic wave dispersion apparatus. And eighteen PU/MWNT composite films were prepared as specimens. The various physical properties of these PU/MWNT films were measured and discussed with the loading content of three types of MWNT dispersed solutions. The highest absorbancy among the three types of dispersed solutions was shown in the IPA/MWNT solution. But the absorbancy of PU/MWNT films was not same as the solution. The low electrical surface and volume resistivity of PU/MWNT film were shown at the condition of 20 and 10 parts loading of IPA/MWNT dispersed solution, respectively. The low triboelectricity of PU/MWNT film was shown at the condition of above 30part loading of IPA/MWNT dispersed solution. The breaking strength and strain of PU/MWNT film prepared with IPA/MWNT dispersed solution were decreased with increasing loading content of IPA/MWNT from 10 to 40 parts. The maximum breaking strength and breaking strain according to the dispersion solution were shown on the IPA/MWNT dispersed solution. The uniform dispersion of PU/MWNT film according to the loading content of MWNT solution was shown by surface image analysis on the films dispersed with IPA.

Fabrication of Carbon-dispersed $UO_3$ Microspheres by an Internal Gelation

  • Lee, Jung-Won;Lee, Young-Woo;Shigeru Yamagishi;Akinori Itoh;Toru Ogawa
    • Proceedings of the Korean Nuclear Society Conference
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    • 1995.05a
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    • pp.662-667
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    • 1995
  • An internal gelation process was adopted for the fabrication of carbon-dispersed UO$_3$ microspheres which will be fed to the fabrication for uranium nitride microsphere fuels by the carbothermic reduction. For investigating the proper process conditions, a composition range of feed solution for preparing good UO$_3$ gel spheres was firstly defined by observing the gelation behavior. Within the defined solution compositions, carbon-dispersed microspheres were prepared and carbon distribution in microspheres were observed by SEM. The results showed that production of good carbon-dispersed microspheres was possible, and the most of carbon were evenly distributed in the microspheres although large carbon-rich aggregates were sparsely existent.

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Characterization and Biocompatibility with Dispersed Solutfon of PLA-POE-PLA Block Copolymer (PLA-POE-PLA 블록공중합체 분산액에 의한 생체적합성의 평가 및 특성)

  • Lee, Chan-Woo;Kim, Hong;Song, Kyung-Hun;Moon, Sung-Il
    • Polymer(Korea)
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    • v.26 no.2
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    • pp.174-178
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    • 2002
  • PLLA-POE-PLLA block copolymers were prepared using PLLA and POE with different compositions. Copolymers were obtained in high yield and the polydispersity of the copolymers was very narrow. A dispersed solution of 0.1 g/mL of PLLA-POE-PLLA copolymer was mixed with a dispersed solution of 0.1 g/mL of PDLA-POE-PDLA copolymer. Gel formation was observed from the mixed product obtained at the human body temperature of $37^{\circ}C$. The mixed product comprising PDLA-POE-PDLA and PLLA-POE-PLLA was found to have higher cloud points than that of PLLA-POE-PLLA copolymer. The cloud points decreased with increasing the concentration of the mixed copolymer dispersed solution.

Raman and Photoluminescence Study of Single-Walled Carbon Nanotubes Dispersed in Sodium Dodecyl Sulfate Aqueous Solution Using Ultrasonication (계면활성제를 이용한 단층 탄소나노튜브 분리에 따른 라만과 Photoluminescence 연구)

  • Park, June;Seong, Maeng-Je
    • Journal of the Korean Vacuum Society
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    • v.17 no.2
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    • pp.170-174
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    • 2008
  • We have studied, using Raman and photoluminescence (PL) spectroscopy, material property changes of single-walled carbon nanotubes (SWCNTs) dispersed in sodium dodecyl sulfate(SDS) aqueous solution by ultrasonication. Radial breathing mode Raman intensities of the dispersed SWCNTs shows different behavior depending on their chiralities as the sonication time increases. As the amount of SWCNTs dispersed in 1wt% SDS solution increases, both a downshift of the G-band Raman frequency and an enhancement in the PL intensity were observed.

Image Capturing of Dispersed Phases in DCHXs by Electric Tomography

  • Chun, Won-Gee;Kim, Min-Chan;Lee, Heon-Ju;Kang, Yong-Heack;Kwon, Hyok-Bo
    • Journal of the Korean Solar Energy Society
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    • v.21 no.2
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    • pp.69-78
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    • 2001
  • This paper introduces the physical phenomena involved in Direct Contact Heat Exchangers (DCHXs) and also investigates the possibility of applying of EIT(Electrical Impedance Tomography) technique for capturing the images of dispersed phases as they stream through a stagnant body of water. A number of cases are studied where two dimensional cross-sectional static images are given for fictitious and actual masses present in a column of water(saline solution). In most direct contact liquid-liquid heat exchangers, oil or hydrocarbon with a density different(lighter or heavier) from water is normally used as dispersed working fluid. The main difficulty that arises with this arrangement lies in the elucidation of complicated flow field where the dispersed phase fluid tends to change its shape and size constantly during its journey through the other phase(water). This paper presents a number of results with different types of dispersed phases that are immiscible with water. The EIT technique has been employed in this context to test its applicability in capturing the dynamic images of dispersed phases. It shows static images of dispersed phases where dynamic images could be obtained by simply extending the algorithms and strategies employed in the present analysis.

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The Injection of PDLC Solution Mixture in a Reduced Pressure

  • Kim, Kang-Pil;Yang, Kee-Jeong;Kim, Dae-Hwan;Choi, Byeong-Dae
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08a
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    • pp.524-526
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    • 2007
  • Polymer dispersed liquid crystal (PDLC) films consist of micro-droplets of liquid crystals dispersed in a polymer matrix. To make wide area PDLC filled devices, it is necessary to develop reliable method of vacuum injection of PDLC solution instead of the capillary injection. However, well-known 2-ethylhexylacrylate (EHA), main element of a prepolymer, exhibits the volatility problems, when the PDLC solution is placed under the low pressure. In this study, we developed the vacuum injection process to fill a wide area cell. Experimental results indicate that the $V_{90}$(turn-on voltage) of the PDLC cell made by a vacuum injection method are lower than that of the PDLC cell made by a capillary injection method.

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Characterization of Associating Polymers in Solution

  • Sato, Takahiro
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.118-119
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    • 2006
  • The characterization method for associating polymer solutions was briefly reviewed. The method has not yet established in comparison with the characterization method for molecularly dispersed polymers in solution. However, two examples of associating polymer systems, living polybutadiene anions and amphiphilic statistical copolymers, were successfully characterized on the basis of suitable model and theory.

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Effects of Ammonia Swelling Treatment in Carboxymethylation of Domestic Kraft Pulp on Characteristics of Corboxymethylcellulose(CMC) and CMC Solution (국산(國産) 크라프트 펄프의 카르복시메틸화시(化時) 암모니아 팽윤처리(膨潤處理)가 카르복시메틸셀룰로오스와 카르복시메틸셀룰로오스 용액(溶液)의 특성(特性)에 미치는 효과(效果))

  • Ahn, Byoung-Kuk;Ahn, Won-Yung
    • Journal of the Korean Wood Science and Technology
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    • v.18 no.2
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    • pp.25-35
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    • 1990
  • To investigate the effects of swelling treatment by ammonia on characteristics of carboxymethy1cellulose(CMC) and CMC solution, the domestic kraft pulp pretreated with 5%, 10%, 15% and 20% $NH_4OH$ solution, was carboxymethylated by the standard method, and then the CMC prepared was tested. The physical properties of CMC and CMC solution, such as degree of substitution, transparency. viscosity, weight increase and solubility, were measured, and the comparison with commercial domestic CMC used as a food additive was done. The results obtained were as follows; 1. In CMC manufactured by standard solvent method, hardwood bleached kraft pulp(LBKP) was more substituted than safwood bleached kraft pulp(NBKP), and viscosity of NBKP was higher than that of LBKP. 2. When ammonia swelling treatment was done, degree of substitution gradually decreased with increasing concentration of $NH_4OH$, and degree of substitution of LBKP decreased with a larger range than that of NBKP. 3. When ammonia swelling treatment was done. transparency of CMC solution from LBKP was hardly effected, but in case of NBKP gradually increased with increasing concentration of $NH_4OH$. 4. When ammonia swelling treatment was done, viscosity of CMC solution was higher than that of CMC solution without ammonia swelling treatment. Especially, CMC of high viscosity could be manufactured in 5%, 10% concentration levels of $NH_4OH$. 5. In CMC manufactured from domestic NBKP, CMC at the range of 0.40 to 0.50 in DS was dispersed easily and quickly dissolved, and CMC at more than 0.50 in DS was dispersed slowly in water solution. 6. In comparison with commercial domestic CMC used as a food additive, CMC manufactured from domestic NBKP was higher in DS, and was lower in viscosity and transparency.

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Fabrication of Zirconium Phosphate Nanoparticles through Solution Technique (수용액법에 의한 인산 지르코늄 나노입자의 합성)

  • 정영근;최현규
    • Journal of Powder Materials
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    • v.9 no.5
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    • pp.336-340
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    • 2002
  • The $\alpha$-zirconium phosphate particles as fine as 20 nm were fabricated through solution technique using $ZrOCl_2{\cdot}8H_2O$ and $H_3PO_4$ as precursors. Stability of $\alpha$-Zirconium phosphate could be ensured by adding excess phosphoric acid to a stoichiometric composition Instead of using reflux route that resulted in coarsening of particles due to an inevitably long aging. The excess phosphorous incorporated in the crystal could be successfully eliminated afterwards through careful washing. Moreover, heavily agglomerated particles are observed before washing, but fairly dispersed state is found out after washing treatment. Thus, it is found that dispersed state as well as phase stability is ensured through proper washing treatment.

AN IMPROVED MONTE CARLO METHOD APPLIED TO THE HEAT CONDUCTION ANALYSIS OF A PEBBLE WITH DISPERSED FUEL PARTICLES

  • Song, Jae-Hoon;Cho, Nam-Zin
    • Nuclear Engineering and Technology
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    • v.41 no.3
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    • pp.279-286
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    • 2009
  • Improving over a previous study [1], this paper provides a Monte Carlo method for the heat conduction analysis of problems with complicated geometry (such as a pebble with dispersed fuel particles). The method is based on the theoretical results of asymptotic analysis of neutron transport equation. The improved method uses an appropriate boundary layer correction (with extrapolation thickness) and a scaling factor, rendering the problem more diffusive and thus obtaining a heat conduction solution. Monte Carlo results are obtained for the randomly distributed fuel particles of a pebble, providing realistic temperature distributions (showing the kernel and graphite-matrix temperatures distinctly). The volumetric analytic solution commonly used in the literature is shown to predict lower temperatures than those of the Monte Carlo results provided in this paper.