• 한국정보디스플레이학회:학술대회논문집
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• 2008.10a
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• pp.879-882
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• 2008

The discotic liquid crystal in compensating film used for the viewing angle improvement of the twist nematic liquid crystal display panel is analyzed. For the optical characterization of the compensating film, we measured the polarization state of the light passing through the film as the tilt angle and the azimuth angle of the film were varied, and then we compared the measured polarization state with the calculated one. Finally we suggested the best fit configuration of the discotic liquid crystal.

• Polymer(Korea)
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• v.30 no.5
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• pp.373-379
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• 2006

Polymerizable discotic liquid crystals containing diacetylene and acryloyl groups were formed through hydrogen bonding between phloroglucinol core and polymerizable pyridine derivatives, and their photopolymerization behavior was investigated. The discotic complexes exhibited discotic columnar and rectangular columnar mesophases depending on the number of aromatic rings. Photopolymerization of the discotic complexes was carried out by UV irradiation in the liquid crystalline state. IR and UV-Vis spectroscopy affirmed that diacetylene and acryloyl groups were selectively Polymerized, and that crosslinked polymers containing short conjugated diacetylene oligomers were produced by 1,4-addition. X-ray diffraction experiment showed that the columnar order in the discotic complex containing phenyl-pyridine moiety was maintained after photopolymerization, and that the rectangular columnar order in he discotic Complex with biphenyl units was changed to the lamellar order.

• Journal of Adhesion and Interface
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• v.15 no.4
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• pp.161-168
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• 2014

New self-assembled discotic liquid crystals have been prepared through single hydrogen bonding between phenol and pyridine moieties, and their liquid crystalline properties were investigated. For the construction of discotic structure, we used phloroglucinol as a core molecule and trans-4-alkoxy-4'-stilbazoles with systematically varied alkyl chain lengths as peripheral units. FTIR results showed that the intermolecular hydrogen bonds between core and peripheral molecules are successfully formed, and the stability of the hydrogen bond is strongly influenced by molecular ordering. Discotic complexes exhibited different liquid crystalline phases depending on the length of alkyl chains around the discotic mesogen. The discotic complexes with longer alkyl chains showed hexagonal columnar mesophases, while the other complexes formed nematic columnar mesophases. These results indicated that the type of mesophase structure was strongly dependent on the alkyl chain length around the aromatic core.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.21 no.12
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• pp.1101-1104
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• 2008

We have studied electro-optic characteristics to improve viewing angle of the in-plain switching (IPS) liquid crystal display using an compensation film. The IPS mode shows relatively large light leakage and color shift in diagonal directions in a dark state. To solve this problem, we have compensated the low contrast ratio in diagonal directions using one optimized discotic film and adjusting TAC films of polarizers. The compensated IPS mode shows wide viewing angle characteristics that region of CR 50:1 is over $60^{\circ}$ of polar angle in all directions. The optimized IPS cell exhibits much better performances than other methods do in terms of CR and color uniformity.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2004.11a
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• pp.518-521
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• 2004

We have investigated about compensation film to reduce the light leakage at an oblique angle in-plane switching mode. It is well known that uncompensated in-plane switching (US) and fringe field switching (FFS) liquid crystal displays (LCDs) have much better viewing angle than other modes owing to the in-plane rotation of the LC director. However, to accomplish optimal viewing angle characteristics in these devices, they must be compensated by one or more films. So, in this paper, we have studied how to reduce the light leakage with viewing angle using discotic film in dark state.

• Bulletin of the Korean Chemical Society
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• v.9 no.2
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• pp.98-101
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• 1988

A pure columnar cholesterogen based on the octasubstituted phthalocyanine $(PcH_2)$, S-(+)-2, 3, 9, 10, 16, 17, 23, 24-octakis[5-(dodecyloxy)-2-oxa-pentyl]-phthalocy anine(1a), is described. To evaluate a cholesteric character of 1a, the corresponding achiral $PcH_2$ 1b and the copper complex of chiral $PcH_2$ 1a (CuPc), S-(+)-2,3,9,10,16,17,23,24-octakis[4-(dodecyloxy)- 2-oxapentyl]-phthalocyanine(2a) were also prepared. The chiral 1a exhibited a typical cholesteric texture change in which the transition of platelet (blue phase) to fan-shape texture was observed (K－M－I), whereas the corresponding achiral 1b showed only a focal conic texture (K－ M－I). This is the first instance of a pure columnar cholesterogen observed with discotic liquid crystal systems.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2006.11a
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• pp.294-295
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• 2006

Field sequential liquid crystal display (FSLCD) has advantages such as a high transmittance due to no use of color filter and high color reproductivity because of LED backlight for a luminance source. However, to realize FSLCD response time of the LCD must be below 5ms. In this paper, we have chosen electrically controlled birefringence (ECB) mode for this application and studied film compensation to improve the operating voltage and viewing angle and to achieve a fast response time optimizing the condition of the discotic film and TAC film, operating voltage decreases to 5V, and viewing angle range is $160^{\circ}$ at horizontal and vertical direction, respectively and $120^{\circ}$ in diagonal direction. (contrast ratio > 10:1) and optimized cell exhibits a fast response time of 4ms in most grey levels.

• 한국정보디스플레이학회:학술대회논문집
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• 2002.08a
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• pp.433-436
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• 2002

Retardation liquid crystal films with a profiled titled optic axis (splay films) of both nematic and discotic types are used as compensation films for twisted nematic displays (TN-LCD). A new method is developed to characterize retardation vs. inclination (retardation profile) of splay films by three parameters: "full retardation" $d^{\ast}{\triangle}n$, "inplane retardation" $R_0$ and "retardation difference" $R_d$ . Splay films with the same retardation profile but with different tilt profile (retardation invariants) are discovered. Splay films with different structure parameters but belong to the same retardation invariant have the same compensation opportunities for TN-LCD.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2005.07a
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• pp.483-484
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• 2005

The field sequential liquid crystal display (FSLCD) does not need a color filter so that it is suitable for high resolution display. However, FSLCD has a drawback which requires a fast response time of sub-5 ms. We have studied the FSLCD with electrically controlled birefringence (ECB) mode. The ECB mode exhibits fast response time, high transmittance, low operating voltage and adequate viewing angle with a help of optical compensation films. In this paper, we present electro-optic characteristics of the ECB mode using a discotic film.

• 한국정보디스플레이학회:학술대회논문집
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• 2009.10a
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• pp.610-613
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• 2009

New rod-disc liquid crystal (LC) molecule RD12 (12 is the number of carbon atoms between the rod and disc mesogenic liquid crystals) was synthesized via the chemical attachment of six cyanobiphenly calamitic mesogens linked to the triphenyl discotic mesogen with six alkyl chain linkage. Aligning characteristics associated with homogenous alignment is investigated at first and then field-dependent molecular reorientation under a vertical electric field is studied. Interestingly, they show abnormal slow molecular transition from initiate state (no electric field condition) to certain voltage. In this condition, we observe the molecular competition during reorientation. However, once a tilting direction of disk molecules are defined, the frustration is not observed anymore. The origin of this phenomenon is explained with a suggested model for the first time.