• Title/Summary/Keyword: direct water surface

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Hydrophilic/Hydrophobic Dual Surface Coatings for Membrane Distillation Desalination (막증류 담수화를 위한 친수성/소수성 이중 표면 코팅)

  • Kim, Hye-Won;Lee, Seungheon;Jeong, Seongpil;Byun, Jeehye
    • Journal of Korean Society on Water Environment
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    • v.38 no.3
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    • pp.143-149
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    • 2022
  • Membrane distillation (MD) has emerged as a sustainable desalination technology to solve the water and energy problems faced by the modern society. In particular, the surface wetting properties of the membrane have been recognized as a key parameter to determine the performance of the MD system. In this study, a novel surface modification technique was developed to induce a Janus-type hydrophilic/hydrophobic layer on the membrane surface. The hydrophilic layer was created on a porous PVDF membrane by vapor phase polymerization of the pyrrole monomer, forming a thin coating of polypyrrole on the membrane walls. A rigid polymeric coating layer was created without compromising the membrane porosity. The hydrophilic coating was then followed by the in-situ growth of siloxane nanoparticles, where the condensation of organosilane provided quick loading of hydrophobic layers on the membrane surface. The composite layers of dual coatings allowed systematic control of the surface wettability of porous membranes. By the virtue of the photothermal property of the hydrophilic polypyrrole layer, the desalination performance of the coated membrane was tested in a solar MD system. The wetting properties of the dual-layer were further evaluated in a direct-contact MD module, exploring the potential of the Janus membrane structure for effective and low-energy desalination.

Performance Comparison on the Condenser Shapes of Direct Contact Heat Pipe using CFD (전산유체역학을 이용한 직접 접촉식 히트파이프의 응축부 형상에 따른 성능비교)

  • Ko, Jo-Han;Kang, Kyung-Mun;Seo, Tae-Beom
    • 한국태양에너지학회:학술대회논문집
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    • 2008.04a
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    • pp.203-208
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    • 2008
  • The purpose of this study is to compare the different shapes of condenser of the direct contact heat transfer from the heat pipe condenser to the receiving water using CFD. The heat transfer from the working fluid of the heat pipe to receiving fluid flows through the manifolder is one of the important part in evacuated solar collector system. The retrenchment of the thermal resistance between the heat pipe and the manifolder could increase the thermal performances of the whole system. Recently, direct heat transfer from the heat pipe condenser wall to the receiving water was suggested and accompanied experiments were achieved. This experiment shows the better performances of the direct contact heat transfer analogically. Preceding calculations are carried out for the performance comparison: mesh dependence test, discretization method test and equation model test. with these preceding tests, 4 different shapes of condenser are compared and each case were set up for the same heat flux at the condenser wall. The calculation result shows that the efficiency of the extended surface condenser shape is 10% higher then the that of the others.

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Investigation of direct growth behavior of carbon nanotubes on cathode powder materials in lithium-ion batteries (리튬이차전지 양극 분말 소재 위 탄소나노튜브의 직접 성장 거동 고찰)

  • Hyun-Ho Han;Jong-Hwan Lee;Goo-Hwan Jeong
    • Journal of the Korean institute of surface engineering
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    • v.57 no.1
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    • pp.22-30
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    • 2024
  • This study reports a direct growth of carbon nanotubes (CNTs) on the surface of LiCoO2 (LCO) powders to apply as highly efficient cathode materials in lithium-ion batteries (LIB). The CNT synthesis was performed using a thermal chemical vapor deposition apparatus with temperatures from 575 to 625 ℃. Ferritin molecules as growth catalyst of CNTs were mixed in deionized (DI) water with various concentrations from 0.05 to 1.0 mg/mL. Then, the LCO powders was dissolved in the ferritin solution at a ratio of 1g/mL. To obtain catalytic iron nanoparticles on the LCO surface, the LCO-ferritin suspension was dropped in silicon dioxide substrates and calcined under air at 550℃. Subsequently, the direct growth of CNTs on LCO powders was performed using a mixture of acetylene (10 sccm) and hydrogen (100 sccm) for 10 min. The growth behavior was characterized by scanning and transmission electron microscopy, Raman scattering spectroscopy, X-ray diffraction, and thermogravimetric analysis. The optimized condition yielding high structural quality and amount of CNTs was 600 ℃ and 0.5 mg/mL. The obtained materials will be developed as cathode materials in LIB.

Band Structure Engineering of Monolayer MoS2 by Surface Ligand Functionalization

  • Lee, Sang Yoon;Ramzan, Sufyan
    • Proceeding of EDISON Challenge
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    • 2015.03a
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    • pp.367-370
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    • 2015
  • Monolayer transition metal dicalcogenide (TMDC) materials are currently attracting extensive attention due to their distinctive electronic, transport, and optical properties. For example, monolayer $MoS_2$ exhibits a direct band gap in the visible frequency range, which makes it an attractive candidate for the photocatalytic water splitting. For the photoelectrochemical water splitting, the appropriate band edge positions that overlap with the water redox potential are necessary. Similarly, appropriate band level alignments will be crucial for the light emitting diode and photovoltaic applications utlizing heterojunctions between two TMDC materials. Carrying out first-principles calculations, we here investigate how the band edges of $MoS_2$ can be adjusted by surface ligand functionalization. This study will provide useful information for the realization of ligand-based band engineering of monolayer $MoS_2$ for various electronic, energy, and bio device applications.

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Evaluation of Efficiency on Glass Precision Machining by using Abrasive Water-jet (연마재 워터젯 가공을 이용한 유리 미세 가공 성능 평가)

  • Bahk, Yeon-Kyoung;Park, Kang-Su;Kim, Hyung-Hoon;Shin, Bo-Sung;Ko, Jong-Soo;Go, Jeung-Sang
    • Journal of the Korean Society for Precision Engineering
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    • v.27 no.7
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    • pp.87-93
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    • 2010
  • This paper presents an evaluation of efficiency on glass precision machining by using abrasive water-jet machine. In this study, problems of conventional water-jet machining are examined experimentally and are analysized numerically. Especially, the reason of whitening on the machined surface of biochip glass is determined. It is found that the mass flow rate of abrasive input and transverse speed of water-jet are key parameters to control the direct machining of micro hole and channel on a glass substrate. Based on results of experimental analysis, possibility of direct fabrication of micro holes and channels on a glass substrate is successfully confirmed.

A Study on the Characteristics of Laser Deposition Surface and Cross-section for Metal Powder (금속 분말의 레이저 적층 시 표면 및 단면 특성에 관한 연구)

  • Hwang, Jun-Ho;Shin, Seong-Seon;Jung, Gu-In;Kim, Sung-Wook;Kim, Hyun-Deok
    • Journal of Welding and Joining
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    • v.34 no.4
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    • pp.17-22
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    • 2016
  • In this study, we compared the physical and chemical properties evaluation for each size in the SUS316L metal powder produced by water atomization and gas atomization. and we analyzed the experimental data in order to find the basis of a suitable metal powder (SUS316L) for DED (Direct Energy Deposition) processing. Also it evaluated the properties of each layered surface and cross section according to the number of deposition and deposition speed. In the result of optical microscopy measurements, the metal powder by water atomization was the crack generated between the deposition layer, the deposition layer was poor quality. However, metal powder by gas atomization was obtained a relatively good deposition results than metal powder by water atomization.

Inorgainc fouling and it fouling reduction in direct contact membrane distillation process (직접 접촉식 막 증발공정에서 무기 막오염 특성 분석 및 저감방법)

  • Lee, Tae-Min;Kim, Seung-Hyun
    • Journal of Korean Society of Water and Wastewater
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    • v.34 no.2
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    • pp.115-125
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    • 2020
  • This study was aimed to examine inorganic fouling and fouling reduction method in direct contact membrane distillation(DCMD) process. Synthetic seawater of NaCl solution with CaCO3 and CaSO4 was used for this purpose. It was found in this study that both CaCO3 and CaSO4 precipitates formed at the membrane surface. More fouling was observed with CaSO4(anhydrite) and CaSO4·0.5H2O(bassanite) than CaSO4·2H2O(gypsum). CaCO3 and gypsum were detected at the membrane surface when concentrates of SWRO(seawater reverse osmosis) were treated by the DCMD process, while gypsum was found with MED(multi effect distillation) concentrates. Air backwash(inside to out) was found more effective in fouling reduction than air scouring.

Numerical Solutions for the Flow past a Cylinder (원주주위를 지나는 흐름에 관한 수치해석)

  • 조용식;윤태훈
    • Water for future
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    • v.21 no.3
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    • pp.291-291
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    • 1988
  • The two dimensional time dependent flow past a circular cylinder is analyzed numerically. In the analysis, equations of conservation of mass and momentum are transformed to equations of stream function-vorticity and vorticity transport, and nondimensionalized by nondimensional parameters representing flow characteristics, The resulting stream function-vorticity equstion and vorticity transport equation are solved by successive over relaxation scheme and alternating direct implicit scheme. Numerical experments are performed for the flow in the range of Reynolds number 125 to 275. The time dependent streamlines, vorticities, pressure on cylinder surface, separation angle, and drag and lift coefficients are calculated, and the method for estimation of pressure on cylinder surface and the outer boundary limit are developed.

- Numerical Solutions for the Flow past a Cylinder- (원주주위를 지나는 흐름에 관한 수치해석)

  • 조용식;윤태훈
    • Water for future
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    • v.31 no.4
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    • pp.291-297
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    • 1998
  • The two dimensional time dependent flow past a circular cylinder is analyzed numerically. In the analysis, equations of conservation of mass and momentum are transformed to equations of stream function-vorticity and vorticity transport, and nondimensionalized by nondimensional parameters representing flow characteristics, The resulting stream function-vorticity equation and vorticity transport equation are solved by successive over relaxation scheme and alternating direct implicit scheme. Numerical experiments are performed for the flow in the range of Reynolds number 125 to 275. The time dependent streamlines, vorticities, pressure on cylinder surface, separation angle, and drag and lift coefficients are calculated, and the method for estimation of pressure on cylinder surface and the outer boundary limit are developed.

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Bloating Mechanism for Artificial Light Weight Aggregate of Surface Modification with Coal ash

  • Lee, Ki Gang
    • Journal of the Korean Ceramic Society
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    • v.52 no.2
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    • pp.159-164
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    • 2015
  • We manufacture artificial lightweight aggregates (ALWAs) using bottom-ash as the primary raw material. We coat the ALWA surfaces with low-melting point materials in order to enable them to bloat, which is essential to reduce the bulk density of the aggregate. Then, we sinter the prepared aggregates at 1000, 1100, and $1200^{\circ}C$ using either the direct or two-step firing schedules. Finally, we evaluate the properties of the fired samples through analyzing their bulk density, water absorption, and microstructure. The surface-modified samples result in a reduction of their bulk density by $0.3{\sim}0.4g/cm^3$ regardless of the firing method used. Based on these results, we conclude that this approach could provide a viable method for the mass-production of ALWAs from industrial waste such as bottom-ash.