• Title/Summary/Keyword: direct determination

Search Result 511, Processing Time 0.027 seconds

Analysis of Operation Cost Savings Effects of Direct Delivery Logistics Strategy Considering Carbon Emission (탄소배출을 고려한 직배송 물류전략의 운영비용 절감효과 분석)

  • Kim, Mi-Rye;Cho, In-Ho
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.18 no.6
    • /
    • pp.653-661
    • /
    • 2017
  • This study compares and analyzes the operation costs of traditional and direct delivery strategies considering carbon emissions. For the determination of minimum operation costs and order quantity, we use the Economic Order Quantity (EOQ) model, which is the proper method for calculate the operation costs by logistics strategy. Using the classical EOQ model, we expand the EOQ model considering carbon emissions and domestic logistics environment. We conduct an empirical study on two agri-food logistics strategies under limitation of the carbon emissions using the expanded EOQ model. From the results of the empirical study, we find that the operation costs of direct delivery strategy are about 50% lower than those of the traditional strategy. Economic order quantity is also smaller than that of the traditional strategy. These results indicate that agri-food products can be transported quickly and freshly under direct delivery strategy. Consequently, considering carbon emissions, direct delivery logistics strategy are analyzed to have more positive effect on economic and environmental issues than existing logistics strategy. It is judged that direct strategy will also increase the freshness of agricultural products.

Evaluation of Modeling Approach for Suspended Sediment Yield Reduction by Surface Cover Material using Rice Straw at Upland Field (모델링 기법을 이용한 밭의 볏짚 지표피복의 부유사량 저감효과 평가 방법)

  • Park, Youn Shik;Kum, Donghyuk;Lee, Dong Jun;Choi, Joongdae;Lim, Kyoung Jae;Kim, Ki-sung
    • Journal of Korean Society on Water Environment
    • /
    • v.32 no.1
    • /
    • pp.108-114
    • /
    • 2016
  • Sediment-laden water leads to water quality degradation in streams; therefore, best management practices must be implemented in the source area to control nonpoint source pollution. Field monitoring was implemented to measure precipitation, direct runoff, and sediment concentrations at a control plot and straw-applied plot to examine the effect on sediment reduction in this study. A hydrology model, which employs Curve Number (CN) to estimate direct runoff and the Universal Soil Loss Equation to estimate soil loss, was selected. Twenty-five storm events from October 2010 to July 2012 were observed at the control plot, and 14 storm events from April 2011 to July 2011 at the straw-applied plot. CN was calibrated for direct runoff, and the Nash-Sutcliffe efficiency and coefficient of determination were 0.66 and 0.68 at the control plot. Direct runoff at the straw-applied plot was calibrated using the percentage direct runoff reduction. The estimated reduction in sediment load by direct runoff reduction calibration alone was acceptable. Therefore, direct runoff-sediment load behaviors in a hydrology model should be considered to estimate sediment load and the reduction thereof.

Direct and Derivative Spectrophotometric Determination of Cobalt (II) in Microgram Quantities with 2-Hydroxy-3-methoxy Benzaldehyde Thiosemicarbazone (2-Hydroxy-3-methoxy Benzaldehyde Thiosemicarbazone를 사용하여 마이크로 그램 코발트(II)의 직접 및 유도 분광광도법에 의한 정량)

  • Kumar, A.Praveen;Reddy, P.Raveendra;Reddy, V.Krishna
    • Journal of the Korean Chemical Society
    • /
    • v.51 no.4
    • /
    • pp.331-338
    • /
    • 2007
  • A rapid, simple and sensitive spectrophotometric method was developed for the determination of cobalt(II) using 2-hydroxy-3-methoxy benzaldehyde thiosemicarbazone (HMBATSC) as a analytical reagent. The metal ion in aqueous medium forms a brown coloured complex with HMBATSC at pH 6.0. The complex has two absorption maxima at 375 nm and 390 nm. At 375 nm, the reagent shows considerable absorbance, while at 390 nm the reagent does not shows appreciable absorbance. Hence, analytical studies were carried out at 390 nm. Beer's law is obeyed in the range of 0.059-2.357 μg ml-1 of Co(II). The molar absorptivity and Sandall's sensitivity of the method are 2.74×104 l mol-1 cm-1 and 0.0024 μg cm-2 respectively. The interference of various diverse ions has been studied. The complex has 1:2 [Co(II)- HMBATSC] stoichiometry. A method for the determination of cobalt(II) by second order derivative spectrophotometry has also been proposed. The proposed methods were applied for the determination of cobalt(II) in alloy steels, vitamin B12 and in some biological samples.

Quantitative Comparison of Activity Calculation Methods for the Selection of Most Reliable Radionuclide Inventory Estimation

  • Hwang, Ki-Ha;Lee, Sang-Chul;Lee, Kun-Jai;Jeong, Chan-Woo;Ahn, Sang-Myeon;Kim, Tae-Wook;Kim, Kyoung-Doek;Herr, Y.H.
    • Proceedings of the Korean Radioactive Waste Society Conference
    • /
    • 2003.11a
    • /
    • pp.322-327
    • /
    • 2003
  • It is important to know the accurate radionuclide inventory of radioactive waste for the reliable management. However, estimation of radionuclide concentrations in drummed radioactive waste is difficult and unreliable because of difficulties of direct detection, high cost, and radiation exposure of sampling personnel. In order to overcome these difficulties, scaling factors (SFs) have been used to assess the activities of radionuclides that could not be directly analyzed. A radionuclide assay system has been operated at KORI site since 1996 and consolidated scaling factor method has played a dominant role in determination of radionuclides concentrations. However, some problems are still remained such as uncertainty of estimated scaling factor values, inaccuracy of analyzed sample values, and disparity between the actual and ideal correlation pairs and the others. Therefore, it needs to improve the accuracy of scaling factor values. The scope of this paper is focused on the improvement of accuracy and representativeness of calculated scaling factor values based on statistical techniques. For the selection of reliable activity determination method, the accuracy of estimated SF values for each activity determination method is compared. From the comparison of each activity determination methods, it is recommended that SF determination method should be changed from the arithmetic mean to the geometrical mean for more reliable estimation of radionuclide activity. Arithmetic mean method and geometric mean method are compared based on the data set in KORI system.

  • PDF

The Influence of Online Basic Clinical Training on Critical Thinking Disposition, Self Determination Motivation and Learning Satisfaction for Nursing student

  • Seo, Ji-Un;Hong, Sun-Yeun
    • Journal of the Korea Society of Computer and Information
    • /
    • v.27 no.2
    • /
    • pp.91-98
    • /
    • 2022
  • The purpose of this study is to investigate the effect of online basic clinical training on critical thinking disposition, self determination motivation and learning satisfaction for nursing student in the COVID-19 situation. This study is one group pre-test and post-test design. The subjects of this study were collected using an online questionnaire for third-year nursing students located in G city, and 41 students participated in the final. The results of this study showed that critical thinking disposition(p=.013) and self determination motivation(p=.007) increased statistically significantly after the online basic clinical training. This findings indicate that online basic clinical training is effective in improving critical thinking disposition, self determination motivation. As it is difficult to perform direct nursing in the COVID-19 medical field recently, it is expected that the limitations of online clinical practice can be overcome by using various online contents.

Synthesis of a New α-Dioxime Derivative and Its Application for Selective Homogeneous Liquid-Liquid Extraction of Cu(II) into a Microdroplet Followed by Direct GFAAS Determination

  • Ghiasvand, A. R.;Shadabi, S.;Kakanejadifard, A.;Khajehkoolaki, A.
    • Bulletin of the Korean Chemical Society
    • /
    • v.26 no.5
    • /
    • pp.781-785
    • /
    • 2005
  • A fast and reliable method for the selective separation and preconcentration of $Cu^{2+}$ ions using homogeneous liquid-liquid extraction was developed. A new $\alpha$-dioxime derivative (2H-1,4-benzothioazine-2,3(4H)dionedioxime, Dioxime I) was synthesized and investigated as a suitable selective complexing ligand for $Cu^{2+}$ ions. Zonyl FSA (FSA) was applied as a phase-separator agent under the slightly acidic pH conditions. Under the optimal experimental conditions ([FSA] = 3.2% w/v, [THF] = 19.5% v/v, [Dioxime I] = 1.9 ${\times}\;10^{-3}$ M, and pH = 4.7), 10 ${\mu}g\;of\;Cu^{2+}$ in 5.2 mL aqueous phase could be extracted quantitatively into 80 $\mu$L of the sedimented phase. The maximum concentration factor was 65-fold. The limit of detection of the proposed method was 0.005 ng $mL^{-1}$. The reproducibility of the proposed method, on the 10 replicate measurements, was 1.3%. The influence of the pH, type and volume of the water-miscible organic solvent, concentration of FSA, concentration of the complexing ligand and the effect of different diverse ions on the extraction and determination of $Cu^{2+}$ ions were investigated. The proposed method was applied to the extraction and determination of $Cu^{2+}$ ion in different synthetic and natural water samples.

Optimal Seam-line Determination for the Image Mosaicking Using the Adaptive Cost Transform (적응 정합 값 변환을 이용한 영상 모자이크 과정에서의 최적 Seam-Line 결정)

  • CHON Jaechoon;KIM Hyongsuk
    • The Transactions of the Korean Institute of Electrical Engineers D
    • /
    • v.54 no.3
    • /
    • pp.148-155
    • /
    • 2005
  • A seam-line determination algorithm is proposed to determine image border-line in mosaicing using the transformation of gray value differences and dynamic programming. Since visually good border-line is the one along which pixel differences are as small as possible, it can be determined in association with an optimal path finding algorithm. A well-known effective optimal path finding algorithm is the Dynamic Programming (DP). Direct application of the dynamic programming to the seam-line determination causes the distance effect, in which seam-line is affected by its length as well as the gray value difference. In this paper, an adaptive cost transform algorithm with which the distance effect is suppressed is proposed in order to utilize the dynamic programming on the transformed pixel difference space. Also, a figure of merit which is the summation of fixed number of the biggest pixel difference on the seam-line (SFBPD) is suggested as an evaluation measure of seamlines. The performance of the proposed algorithm has been tested in both quantitively and visually on various kinds of images.

Sulfhydryl Cotton Enrichment Separation-Determination of Silver in Geological Samples by ICP-MS

  • Li, Dan;Zhao, Zhifei;Chu, Qin;Fang, Jindong
    • Bulletin of the Korean Chemical Society
    • /
    • v.32 no.10
    • /
    • pp.3561-3565
    • /
    • 2011
  • A rapid and inexpensive method was developed for the determination of trace silver in geological samples by using sulfhydryl cotton coupled with ICP-MS. The interferences such as $^{90}Zr$, $^{92}Mo$ and $^{93}Nb$ on silver were investigated in detail. Sulfhydryl cotton was found to be an effective adsorbent for separation of interferences for Ag in the solutions. Excellent agreements with the certified values were obtained for all the certified reference materials. The memory effects of Ag by ICP-MS were examined by using different agents, including water, nitric acid, and HCl-thiourea to all standards/samples. The agents also acted as cleansing solutions. A combination of HCl with thiourea gave the minimum memory effect. For comparison of results, a proposed Chinese Geology Survey procedure DC-ARC-AES and a direct determination pretreatment method of ICP-MS (water bath- auqa regia digestion) were studied. Under optimal conditions, the detection limits of our method for $^{107}Ag$ and $^{109}Ag$ were 1.2 ng/g and 1.3 ng/g, which offered much better accuracy for some difficult analysis geological samples such as GBW07604, GBW07605.

AN IMPROVED ANALYSIS FOR DETERMINATION OF MONOVINYL AND DIVINYL PROTOPORPHYRIN IX

  • Kim, Jin-Seog;Rebeiz, Constantin A.
    • Journal of Photoscience
    • /
    • v.2 no.2
    • /
    • pp.103-106
    • /
    • 1995
  • For studying chlorophyll biosynthetic heterogeneity of plants, it is necessary to establish a technique for microassay of a putative monovinyl and divinyl protoporphyrin IX. Precise determination of the amounts of monovinyl and divinyl protoporphyrin IX is difficult with optical electronic spectroscopy even at 77$\circ$C. Such a problem could be solved by conversion of protoporphyrin IX to protoporphyrin IX dimethylester with diazomethane and subsequent Mg insertion into protoporphyrin IX dimethylester by reaction with a Grignard solution. The proportion of monovinyl and divinyl Mg-protoporphyrin IX dimethylester formed was measured instead of direct measuring that of protoporphyrin IX by low-temperature spectrofluorometry. The relative proportions of monovinyl and divinyl of protoporphyrin IX, Mg-protoporphyrin IX, and Mgprotoporphyrin IX dimethylester have not changed during the chemical conversion steps. This analysis system could be useful for the study of the monovinyl and divinyl chlorophyll biosynthetic routes in plants.

  • PDF

A New PVC-Membrane Electrode Based on a Thia-Substituted Macrocyclic Diamide for Selective Potentiometric Determination of Silver Ion

  • Shamsipur, Mojtaba;Kazemi, Sayed Yahya;Niknam, Khodabaksh;Sharghi, Hashem
    • Bulletin of the Korean Chemical Society
    • /
    • v.23 no.1
    • /
    • pp.53-58
    • /
    • 2002
  • A new PVC-membrane electrode for $Ag^+$ ion based on a thia-substituted macrocyclic diamide has been prepared. The electrode exhibited a Nernstian response for $Ag^+$ over a wide concentration range $(1.7{\times}10^{-6}-1.0{\times}10^{-1}M)$. It has a response time <15 s and can be used for at least 3 months without divergence. The proposed membrane sensor revealed good selectivities for $Ag^+$ over a variety of metal ions and can be used in a pH range 3.0-7.5. It has been used successfully for direct determination of $Ag^+$ in different real samples and, as an indicator electrode, in the titration of silver ion.