• Title/Summary/Keyword: direct determination

검색결과 513건 처리시간 0.027초

부피법을 이용한 고압·극저온 수소 흡착량 측정 방식의 기본 원리 (Volumetric Hydrogen Sorbent Measurement at High Pressure and Cryogenic Condition - Basic Measurement Protocols)

  • 오현철
    • 한국수소및신에너지학회논문집
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    • 제27권4호
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    • pp.349-356
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    • 2016
  • Volumetric capacity metrics at cryogenic condition are critical for technological and commercial development. It must be calculated and reported in a uniform and consistent manner to allow comparisons among different materials. In this paper, we propose a simple and universal protocol for the determination of volumetric capacity of sorbent materials at cryogenic condition. Usually, the sample container volume containing porous sample at RT can be directly determined by a helium expansion test. At cryogenic temperatures, however, this direct helium expansion test results in inaccurate values of the sample container volume for microporous materials due to a significant helium adsorption, resulting significant errors in hydrogen uptake. For reducing this container volume error, therefore, we introduced and applied the indirect method such as 'volume correction using a non-porous material', showing a reliable cold volume correction.

MEASUREMENT OF SYNTHESIS RATE OF LONG-CHAIN ACYL-COENZYME A ESTER IN BOVINE LIVER BY HIGH-PERFORMANCE LIQUID CHROMATOGRAPHY

  • Mitsuhashi, T.;Mitsumoto, M.;Yamashita, Y.;Ozawa, S.
    • Asian-Australasian Journal of Animal Sciences
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    • 제1권2호
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    • pp.99-106
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    • 1988
  • A high performance liquid chromatographic procedure is described for the direct determination of the picomole amount of palmitoyl-Coenzyme A and stearoyl-Coenzyme A, using a stainless steel column packed with C-18 derivatized porous silica ($5{\mu}m$), an isocratic elution with a mixture of 33 mM $KH_2PO_4$/acetonitrile as a mobile phase and a UV detector. The long-chain acyl-Coenzyme A esters were determined in incubated microsomal fractions of a bovine liver to demonstrate the utility of this method for monitoring acyl-CoA synthesis in biological samples. The reaction rate of palmitate was higher than that of stearate. After a 60 minute incubation period, the generated amount of palmitoyl-Coenzyme A and stearoyl-Coenzyme A were approximately 70 and 20 n mol/mg micresomal protein, respectively. The advantage of this method are in that no decomposition of the CoA esters is involved, while the constituent molecular species is detected.

혈액투석 환자의 역할행위 이행과 관련된 사회·심리적 변인들 간의 구조분석 (A Structural Analysis for Psychosocial Variables related to Sick Role Behavioral Compliance in Hemodialysis Patients)

  • 조영문
    • 성인간호학회지
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    • 제28권4호
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    • pp.415-423
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    • 2016
  • Purpose: This study was designed to identify the structural relationships among psychosocial variables related to sick role behavioral compliance among patients undergoing hemodialysis. Methods: The subjects were 476 patients from seven major hospitals and twelve dialysis centers located in D and P cities. Data were collected using self-report questionnaires. Data analysis was done by using SPSS/WIN 18.0 and AMOS 18.0 programs for structural equation modeling, to estimate the hypothesized model. Results: This findings support that a modified path model is efficient and appropriate to explain sick role behavioral compliance among hemodialysis patients. These factors account for 80.1% of the variance of sick-role behavioral compliance among hemodialysis patients. The variables having direct effect on sick role behavioral compliance were knowledge related to hemodialysis, social support, attitude, self-efficacy and intention. Conclusion: The modified model explains the integration process of psychosocial and behavior variables for sick-role behavioral compliance among patients undergoing hemodialysis.

중국의 해양강국 추구와 새로운 미중관계 (China's Pursuit for Seapower and New U.S.-China Relationship)

  • 김흥규
    • Strategy21
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    • 통권36호
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    • pp.59-93
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    • 2015
  • A Paradigm shift is in process in China's foreign policies during Xi Jinping's era. Such changes occur with changing national identities from developing country to great power, and from continental power to continental-maritime power. China's pursuit for sea power embraces its global strategy. Accommodating the new identity of maritime power, China is developing its maritime strategy. New silk-road strategy actively utilizes China's advantage in economy, while avoiding direct military challenges against the U.S. China seeks an associated balance of power with the U.S. On the other hand, China make its determination clear to protect its core national interests, particularly Taiwan straits issue, deploying Anti-Access and Area-Denial strategy. 'Pax-Americana 3.0' and 'China's rise 2.0' have convoluted and evolved in complexity. South Korea faces much tougher challenges ahead in its foreign and security environments.

3D 프린팅으로 제작한 Ti-6Al-4V 재료의 Johnson-Cook 모델의 유동 응력 결정 (Flow Stress Determination of Johnson-Cook Model of Ti-6Al-4V Material using 3D Printing Technique)

  • 박대균;김태호;전언찬
    • 한국기계가공학회지
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    • 제17권4호
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    • pp.64-69
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    • 2018
  • This paper investigates the compressive deformation behavior of direct metal tooling (DMT), processing titanium alloy (Ti-6Al-4V) parts under high strain loading conditions. Split Hopkinson Pressure Bar (SHPB) experiments were performed to determine the flow stress and the coefficients of the Johnson-Cook model. This model is described as a function of strain, strain rate, and temperature. SHPB experiments were performed to characterize the deformation behavior of specimens made with 3D printers, using Ti-6Al-4V material under high temperature and dynamic loading.

Liquid Chromatographic Determination of Optical Purity of Liquid Crystals

  • Lee, Seng-Kue;Shin, Myung-Soo;Lee, Jong-Gun;Kang, Kyung-Tae;Kim, Yong-Bae
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2002년도 International Meeting on Information Display
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    • pp.491-493
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    • 2002
  • Liquid chromatographic direct resolution of racemic naphthyl propionate liquid crystals were successful on a commercial chiral column, (S,S)-Whelk-O1. The very simple procedure can be applied to the intermediate and final products without any structural modification.

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수위관측과 수리학적 하도추적에 의한 수위-유량 관계식작성 (Determination of Stage-discharge Relations by Hydraulic Channel Routing and Stage Measurement)

  • 이상호
    • 한국수자원학회논문집
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    • 제34권5호
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    • pp.551-560
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    • 2001
  • 낙동강의 화원-교령교-현풍 수위관측소 구간에 대하여 수리학적 하도추적을 통하여 조도계수를 추정하였다. 세 관측소의 연속 수위자료와 하천 종횡단 측량자료만이 이에 사용되었다. 하도추적에 의해 계산된 유량자료로부터 수위-유량 관계식을 작성하였으며 이는 기존의 수위-유량 관계식보다 나은 결과를 보였다. 수위측정 오차가 유량계산에 미치는 영향에 대하여 분석하였으며, 측방유입류를 억제할 수 있도록 하도길이를 제한하는 방법도 제시하였다.

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Determination of temperature and flux variations during ultra-thin InGaN quantum well growth on a 2" wafer for GaN Green LED

  • 김효정;김민호;정훈영;이현휘
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2010년도 제39회 하계학술대회 초록집
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    • pp.149-149
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    • 2010
  • The origin of the inhomogeneous distribution of photoluminescence (PL) peak wavelength on a commercial 2" GaN wafer for green light emitting diode has been investigated by wide momentum transfer (Q) range x-ray diffraction (XRD) profile of InGaN/GaN multiple quantum wells. Near the GaN (0004) Bragg peak, wide-Q range XRD (${\Delta}Q$ > $1.4{\AA}-1$) was measured along the growth direction. Wide-Q XRD gives precise and direct information of ultra-thin InGaN quantum well structure. Based on the QW structural information, the variation of PL spectra can be explained by the combined effect of temperature gradient and slightly uneven flow of atomic sources during the QW growth. In narrow variations of indium composition and thickness of QW, an effective indium composition can be a good character to match structural data to PL spectra.

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유한요소 역 해석을 이용한 축대칭 다단계 박판성형에서의 공정변수 설계에 관한 연구 (Design of Porcess Parameters in Axisymmetric Multi-step Deep Drawing by a Finite Element Inverse Method)

  • 조천수;이충호;허훈
    • 소성∙가공
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    • 제6권4호
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    • pp.300-310
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    • 1997
  • A finite element inverse method is introduced for direct prediction of blank shapes, strain distributions, and reliable intermediate shapes from desired final shapes in axisymmetric multi-step deep drawing processes. This mothod enables the determination of process disign. The approach deals with the Hencky's deformation theory. Hill's second order yield criterion, simplified boundary conditions, and minimization of plastic work with constraints. The algorithm developed is applied to motor case forming, and cylindrical cup drawing with the large limit drawing ratio so that it confirms its validity by demonstrating resonably accurate numerical results of each problem. Numerical examples reveal the reason of difficulties in motor case forming with corresponding limit diagrams.

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Nuclear Microanalysis에 의한 텅스텐 표면의 산소 흡착조사 (Oxygen Coverage Measurment on Tungsten Surface by Neclear Microanalysis)

  • 김명원;황정남
    • 한국진공학회지
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    • 제1권1호
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    • pp.96-99
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    • 1992
  • 텅스텐 표면의 (110)면에 흡착된 산소량을 18O(P,$\alpha$)15N 핵반응으로 직접 측정하여 미세분석 하였다. Van de Graaff 가속기로 양성자를 가속시켜 시료 표면 가까이에 있는 원 자와 충돌시켜 생성되는 $\alpha$ 입자를 측정함으로써 표면에 있는 미소량의 원소도 측정이 가능 했다. $\alpha$ 입자의 수율은 oxygen exposure에 비례하였는데 coverage ($ heta$)는 5 Langmuir에서 0.5가 되었고, 15 Langmuir에서 포화되었다.

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