• Clean Technology
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• v.24 no.3
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• pp.198-205
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• 2018

This study investigated the influence of catalyst preparation on the activity of $Co-CeO_2$ catalyst for $N_2O$ decomposition. $Co-CeO_2$ catalysts were synthesized by co-precipitation and incipient wetness impregnation. In order to estimate the performance of the as prepared catalysts, direct catalytic $N_2O$ decomposition test was carried out under $250{\sim}375^{\circ}C$. As a result, the catalyst prepared by co-precipitation (CoCe-CP) showed an enhanced performance on $N_2O$ decomposition reaction even in the presence of $O_2$ and/or $H_2O$, whereas the impregnation catalyst (CoCe-IM) did not. In order to investigate the difference in catalytic activity, characterization such as XRD, BET, TEM, $H_2-TPR$, $O_2-TPD$, and XPS was conducted. It is confirmed that the particle size and specific surface area were changed depending on the catalyst preparation method and the synthesis process influenced the physical properties of the catalysts. In addition, the improvement in the activity of the catalyst prepared by co-precipitation is due to the enhanced reduction from $Co^{3+}$ to $Co^{2+}$ and the improved oxygen desorption rate. However, it has been confirmed that the surface electron state and binding energy, which are related to $N_2O$ decomposition, do not change depending on the preparation method.

• Transactions of the Korean hydrogen and new energy society
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• v.22 no.5
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• pp.649-655
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• 2011

Methane direct cracking can be utilized to produce $CO_x$ and $NO_x$-free hydrogen for PEM fuel cells, oil refineries, ammonia and methanol production. We present the results of a systematic study of methane direct cracking using a mixed conducting oxide, Y-doped $BaZrO_3$ ($BaZr_{0.85}Y_{0.15}O_3$), membrane. In this paper, dense $BaZr_{0.85}Y_{0.15}O_3$ membrane with disk shape was successfully sintered at $1400^{\circ}C$ with a relative density of more 93% via addition of 1 wt% ZnO. The ($BaZr_{0.85}Y_{0.15}O_3$) membrane is covered with Pd as catalyst for methane decomposition with an DC magnetron sputtering method. Reaction temperature was $800^{\circ}C$ and high purity methane as reactant was employed to membrane side with 1.5 bar pressure. The $H_2$ produced by the reaction was transported through mixed conducting oxide membrane to the outer side. In addition, it was observed that the carbon, by-product, after methane direct cracking was deposited on the Pd/ZnO-$BaZr_{0.85}Y_{0.15}O_3$ membrane. The produced carbon has a shape of sphere and nanosheet, and a particle size of 80 to 100 nm.

• Journal of KIISE:Software and Applications
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• v.30 no.10
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• pp.894-903
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• 2003

Though XML is widely used, it is still hard for end users to write XML documents. A lot of XML documents are data-centric documents which have formal data format. Even novices can easily write the data-centric XML documents if they use form-based GUIs. In this paper, we introduce a new method for generating form-based XML editor for data-centric XML documents automatically and an XML editor generator called XED. The DTD consists of sequence, choice, and repetition, and this structure can be represented with Document Decomposition Graph(DDG). XED allows users to generate an XML editor by applying the presentation rules to DDG. It also permits users to modify generated editor through changing editor`s GUI properties with direct manipulation.

• Bulletin of the Korean Chemical Society
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• v.33 no.10
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• pp.3196-3202
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• 2012

Post-synthesis is used to synthesize organic hybrid inorganic mesoporous sieves. In this method, the activity and structure of the base sieve are crucial to obtain the definable hybrid materials. The chemical and physical properties of the base can be largely changed either by the final step of its synthesizing processes, by template removal which is accomplished with the oxidative thermal decomposition (burning) method or by solvent extraction method. In this paper we compared two methods for the post-synthesis of organic hybrid MCM-48. When the template was extracted with HCl/alcohol mixture, the final product showed larger pore size, larger pore volume and better crystallinity compared to the case of the thermal decomposition. The reactivity of the surface silanol group of template free MCM-48 was also checked with an alkylsilylation reagent $CH_2=CHSi(OC_2H_5)_3$. Raman and $^{29}Si$ NMR spectra of MCM-48 in the test reaction indicated that more of the organic group was grafted to the surface of the sample after the template was removed with the solvent extraction method. Direct synthesis of vinyl-MCM-48 was also investigated and its characteristics were compared with the case of post-synthesis. From the results, it was suggested that the structure and chemical reactivity can be maintained in the solvent extraction method and that organic grafting after the solvent extraction can be a good candidate to synthesize a definable hybrid porous material.

• Proceedings of the Korean Operations and Management Science Society Conference
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• 2000.04a
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• pp.724-727
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• 2000

Rapid Prototyping(RP)이란 3차원 솔리드 모델을 단면화한 뒤 하나씩 적층하는 가공방식을 총칭한다. 이때 단면화하는 방법에 따라서 uniform, adaptive slicing으로 나뉘며, 입력 모델에 따라서 direct slicing과 STL을 이용한 방식으로 나뉜다. 적층 방법에 따라서는 연속된 2D 윤곽을 기반으로 적층하는 vertical layer 방식과 인접한 두 개의 2D 윤곽들을 연결하며 만들어진 3D layer를 기반으로 가공하는 sloping layer방식으로 나뉠 수 있다. 현재 상용 RP 시스템들에서는 거의 모든 경우 vertical layer 방식이 채택되어 사용되고 있다. RP와 절삭 공정, 예를 들면 CNC 밀링의 장점을 효율적으로 결합하기 위해서는 임의의 복잡한 형상을 갖는 솔리드 모델을 정밀도에 제한이 없이 제조할 수 있어야 한다. 그러나 절삭 공정은 특별한 전문적 지식들을 필요로 한다 또한 상용 RP에서 사용하는 순차적인 적층 작업으로는 가공할 수 없는 형상들이 많다. 대표적인 것으로 지지대를 필요로 하는 형상들이 있다. 이러한 형상들을 지원하기 위해서는 복잡한 3D 형상을 절삭 가능한 형식으로 분할하는 것과 적층 가능한 순서대로 공정 계획하는 것이 필요하게 된다. 본 연구에서는 SDM에서 제시된 3D 분할 방법이 솔리드 모델을 기반으로 전개되어 STL file과 같은 삼각다면체 형식으로 근사화된 모델에 적용하기 어렵다는데 착안하여 STL file에서 읽어들인 삼각 다면체 모델을 가공 가능한 3D 형상으로 분할하는 알고리즘을 제시하고자 한다.

• Journal of the Korean Applied Science and Technology
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• v.23 no.2
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• pp.147-152
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• 2006

The accidents occurred by unstable material which is easily exploded or burnt up were caused by heat and collision under the condition of relatively low temperature without oxygen, have been reported frequently. However, the amount of the unstable material is getting higher by development of fine ceramic research area even though its dangerous characteristic is disregarded. This research studied a heat stability and measured boiling point of various carpet material. Carpet has been used in home as well as general indoor usage. Now a day, carpet material which is hardly burnt has been on commercial, but its detailed unstable conditions is not mentioned. This research reports the measurement of the initial temperature of generation heat and heat-radiation change on differential scanning calorimeter (DSC). The DSC data of nylon bulked continuous filament (N-BCF) yam 100%, nylon (NY), poly propylene (PP), and a new material named polytrimethylene terephthalate (PTT) are studied and researched about the effect of them using TGA, furnace, and direct-burning experiment.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.34 no.s02
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• pp.115-120
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• 1989

Universal characteristics of ginseng replanting problems appeared to be decrease in root yields due to root rot and inhibition of root growth. Incitants of ginseng replanting problems have not been clearly elucidated, however, it appeared to be a complex phenomenon with several pathogenic soil microorganisms and environmental changes in the soil due to decomposition of ginseng debris such as rootlets and shoots. Decomposition of ginseng debris may cause direct or indirect damage to the root. The effect of conventional fungicide on the control of the problems has not been recognized. However, it has been suggested that treatment with soil fumigants may solve the problems. Meanwhile paddy-rice and ginseng rotation system appeared to be the best way of solving the problems so far.

• Journal of Powder Materials
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• v.8 no.3
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• pp.201-206
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• 2001

$>LaMnO_3$$(La, Sr)MO_3$, and $(La, Sr)MO_3/YSZ$ gel films were deposited by spin-coating technique on scandium-doped zirconia (YSZ) substrate using the precursor solution prepared from $La(O-i-C_3H_7)_3$, $Co(CH_3COO)_2$or $Mn(O-i-C_3H_7)_2$,2-methoxyethanol, and polyethylene glycol. By heat-treating the gel films, the electrochemical cells, $(La, Sr)MnO_3{\mid}ScSZ{\mid}Pt$ were fabricated. The effect of polyethylene glycol on the microstructure evolution of $$LaCoO_3and $LaMnO_3$thin films was investigated, and NOx decomposition characteristics of the electrochemical cells were investigated at $500^{\circ}C$ to $600^{\circ}C$. By applying a direct current to the $(La, Sr)MnO_3{\mid}ScSZ{\mid}Pt$ electrochemical cell, good NOx conversion rate could be obtained relatively at low current value even if excess oxygen is included in the reaction gas mixture.

• Journal of Power Electronics
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• v.16 no.3
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• pp.936-945
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• 2016

Large magnitude common-mode voltage (CMV) and its variation dv/dt have an adverse effect on motor drives that leads to early winding failure and bearing deterioration. For matrix converters, the switch states that connect each output line to a different input phase result in the lowest CMV among all of the valid switch states. To reduce the output CMV for matrix converters, this paper presents a new space vector modulation (SVM) strategy by utilizing these switch states. By this mean, the peak value and the root mean square of the CMV are dramatically decreased. In comparison with the conventional SVM methods this strategy has a similar computation overhead. Experiment results are shown to validate the effectiveness of the proposed modulation method.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.3 no.1
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• pp.10-19
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• 2002

The purpose of this paper is to describe the design of a general multipurpose batch process or plant in terms of a series of mathematical programing models, and to develop approach solution methodologies. The proposed model for a single period is based on the formulation (MINLP; Mixed Integer Nonlinear Programming) of Papageorgaki and Reklaitis [1], but was linearized (MILP; Mixed Integer Linear Programming) so as to obtain an exact and practical solution, and to allow treatment of uncertainties to be considered in expanding the plant. As a solution strategy a modified Benders' Decomposition was introduced and was tested on three example problems. The optimizing solver, OSL code provided by the IBM Corporation, was used for solving the problems. The solution method was successful in that it showed remarkable reduction in the computing times as compared with the direct solution method.