• Title/Summary/Keyword: dipole moment

Search Result 178, Processing Time 0.034 seconds

Solvent Effects on the Solvatochromism of 7-Aminocoumarin Derivatives in Neat and Binary Solvent Mixtures: Correlation of the Electronic Transition Energies with the Solvent Polarity Parameters

  • Choi, Jin-Yeong;Park, Eun-Ju;Chang, Seung-Hyun;Kang, Tai-Jong
    • Bulletin of the Korean Chemical Society
    • /
    • v.30 no.7
    • /
    • pp.1452-1458
    • /
    • 2009
  • The change in the electronic absorption and emission energy of 7-aminocoumarin derivatives in binary solvent mixtures has been studied. The electronic transition energy along with the Stokes' shift is correlated with the orientation polarizability of the solvent as well as the empirical solvent polarity parameters $E_T$ (30). It is observed that the emission peak shift traces the change of $E_T$ (30) value very closely in binary solvent mixtures. The emission transition more strongly depends on the solvent polarity than the absorption, which indicates the dipole moment gets larger on excitation. From the dependence of the Stokes’ shift of 7-aminocoumarins with the solvent polarity parameters and the ground state dipole moment obtained by the semi-empirical calculations, the excited state dipole moment was estimated. The fluorescence lifetime change of 7-aminocoumarins in binary solvent mixtures was measured and the results are explained in terms of molecular conformation and solvent polarity. The study indicates the empirical solvent polarity $E_T$ (30) is a good measure of microscopic solvent polarity and it probes in general the non-specific solvent interactions.

Analysis of Corner Reflector Antennas feeding by Log-Periodic Dipole Antennas (대수주기 다이폴안테나로 급전되는 코너리플렉터안테나의 해석)

  • 최학윤
    • The Journal of Korean Institute of Communications and Information Sciences
    • /
    • v.28 no.7A
    • /
    • pp.511-519
    • /
    • 2003
  • In this paper, to achieve a broad-band and high-gain antenna, we thus designed and analyzed the CRLPDA(Corner Reflector Antenna feeding by Log-Periodic Dipole Antenna) made up of 90$^{\circ}$corner reflector, which is trough-reflector type installed a planar reflector at the folded line. CRLPDA for operating frequency band of 1,400 MHB ~ 2,400 MHz was designed and radiation characteristics of the designed antenna were analyzed by moment method. To verify the analysis results, CRLPDA was fabricated and the calculated results were compared with the measured results. The measured results showed good agreement with the calculated results. As the result of measurements, bandwidth(VSWR>2) for 1,000 MHz was achieved and gain was 13 dBi.

Analysis and Characteristics of Log-Periodic X Dipole Antennas (대수주기 X 다이폴 안테나의 해석 및 특성)

  • 최학근
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
    • /
    • v.10 no.3
    • /
    • pp.329-339
    • /
    • 1999
  • LPXDA(Log-Periodic X Dipole Antenna), consisting of X dipole elements, was proposed as a Log-periodic antenna with short boom length and good Performance relative to LPDA(Log-Periodic Dipole Antenna) . LPXDA for operating frequency band of 500 MHz~l,000 MHz was designed and radiation characteristics of the designed antenna was analyzed by moment method, and compared with LPDA characteristics. The proposed LPXDA, in this paper, was found to have shorter boom length by 20% and better radiation characteristics with variations of frequency relative to the LPDA. The calculated results show good agreement with measurements.

  • PDF

GA-Enhanced Dual-Band Aperiodic Linear Dipole Array with Low Sidelobe Level (낮은 부엽 준위를 갖는 이중 대역 다이폴 배열 안테나)

  • Son, Trinh-Van;Kwon, Gina;Hwang, Keum Cheol;Park, Joon-Young;Kim, Seon-Joo;Kim, Dong-Hwan
    • The Journal of Korean Institute of Communications and Information Sciences
    • /
    • v.37C no.12
    • /
    • pp.1296-1302
    • /
    • 2012
  • In this research, optimization of a dual-band dipole array was performed using genetic algorithm. A non-uniform, aperture-shared linear array was configured with dipoles which resonate at 4 GHz and 9.5 GHz. The excited current distributions on dipoles were computed considering mutual coupling between dipole elements. The current distributions were also computed using method of moment (MoM). The optimization using genetic algorithm was performed to obtain the low sidelobe levels in two operating frequency band. The PSLs of the optimized array for 4 GHz and 9.5 GHz are -15.7 dB and -17 dB, respectively. Comparison between computed and simulated results are also discussed.

Calculation of the Dipole Moments for Simple Molecules by the Expansion Method for Spherical Harmonics (Spherical Harmonics의 전개방법에 의한 간단한 분자의 쌍극자모멘트의 계산)

  • Ahn Sang Woon;Park, Byeong Bin
    • Journal of the Korean Chemical Society
    • /
    • v.22 no.6
    • /
    • pp.357-364
    • /
    • 1978
  • The dipole moments for $NH_3$, HF, CO, HCHO, HCN, PO, $PO^-\;and\;H_2O$ molecules are calculated, using the method for evaluation of the dipole moment matrix elements by the expansion method for spherical harmonics. The calculated dipole moments in this work are closer to the experimental values than those of the other work.

  • PDF

CONSTRAINTS ON PRE-INFLATION COSMOLOGY AND DARK FLOW

  • MATHEWS, GRANT J.;LAN, N.Q.;KAJINO, T.
    • Publications of The Korean Astronomical Society
    • /
    • v.30 no.2
    • /
    • pp.309-313
    • /
    • 2015
  • If the present universe is slightly open then pre-inflation curvature would appear as a cosmic dark-flow component of the CMB dipole moment. We summarize current cosmological constraints on this cosmic dark flow and analyze the possible constraints on parameters characterizing the pre-inflating universe in an inflation model with a present-day very slightly open ${\Lambda}CDM$ cosmology. We employ an analytic model to show that for a broad class of inflation-generating effective potentials, the simple requirement that the observed dipole moment represents the pre-inflation curvature as it enters the horizon allows one to set upper and lower limits on the magnitude and wavelength scale of pre-inflation fluctuations in the inflaton field and the curvature parameter of the pre-inflation universe, as a function of the fraction of the total initial energy density in the inflaton field. We estimate that if the current CMB dipole is a universal dark flow (or if it is near the upper limit set by the Planck Collaboration) then the present constraints on ${\Lambda}CDM$ cosmological parameters imply rather small curvature ${\Omega}_k{\sim}0.1$ for the pre-inflating universe for a broad range of the fraction of the total energy in the inflaton field at the onset of inflation. Such small pre-inflation curvature might be indicative of open-inflation models in which there are two epochs of inflation.

Detection of a Magnetic Dipole by Means of Magnetic Gradient Tensor (자력 변화율 텐서를 이용한 자기 쌍극자 위치 결정)

  • Rim, Hyoung-Rea
    • Journal of the Korean earth science society
    • /
    • v.32 no.6
    • /
    • pp.595-601
    • /
    • 2011
  • In this paper, I propose the algorithm that the location of a magnetic dipole can be detected from the magnetic gradient tensor. I induce the location vector of a vertically magnetizated dipole from the magnetic gradient tensor. Deficit of magnetic moment of magnetic dipole makes the induced location information incomplete. However, if the observation of magnetic gradient tensor would be collected on more points, the algorithm is able to catch the location of the magnetic dipole by clustering the solution of the proposed algorithm. For example, I show that the synthetic case of borehole observation of magnetic gradient tensor can find the source location successively by picking common solution area.