• 대한화학회지
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• 제22권4호
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• pp.229-238
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• 1978

Spherical harmonic의 전개방법과 쌍극자모멘트의 행렬요소를 Mulliken의 overlap integral로 전환시키는 방법을 사용하여 쌍극자모멘트의 행렬요소를 계산하는 두가지 방법을 발전시켰다. 이 두 방법에 의하여 계산한 쌍극자모멘트행렬요소의 값은 서로 일치하였다.

• Bulletin of the Korean Chemical Society
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• 제6권3호
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• pp.158-162
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• 1985

The dipole moment derivatives of $NH_3$ are reexamined based on our recent intensity data. We have resolved the previous contradiction in the proper signs for the dipole moment derivatives of this molecule.

• Journal of Photoscience
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• 제12권2호
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• pp.57-61
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• 2005

The ground and excited state dipole moments of Coumarin 450 (C 450) laser dye were measured at room temperature in several solvents of varying dipole moments. The ground state dipole moment (${\mu}_g$) is estimated by using the modified Onsagar model and the excited state dipole moments (${\mu}_e$) were estimated by the method of solvatochromism as well as by utilizing the microscopic solvent polarity parameter ($E^N_T$). Further, the deviation of some of the points from the linearity of the $E^N_T$ versus Stokes shift indicates the existence of specific type of solute-solvent interaction. The excited state dipole moment of C 450 were found to be higher than those of the ground state and is interpreted in terms of the resonance structure of the molecule. A reasonable agreement has been observed between the values obtained by the method of solvatochromism and modified Onsagar model. It is observed that, corresponding to cyclohexane solution, the fluorescence maxima shift towards the red region with increasing the polarity of the solvents, hence the transition involved are of ${\pi}-{\pi}^*$ type.

• Bulletin of the Korean Chemical Society
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• 제5권1호
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• pp.3-16
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• 1984

The effect of solvent on the dipole moments for (chloromethyl) stannanes has been investigated by applying EHT calculation for the isomers of trigonal bipyramidal Sn(Ⅳ)$Cl_4X$ and $Cl_n$Sn(Ⅳ) $(CH_2Cl)_{4-n}$, octahedral Sn(Ⅳ)$Cl_42X$ and $Cl_nSn$(Ⅳ)$(CH_2Cl)_{4-n}$ 2X type complexes in dioxane and ethylacetate solutions (X: dioxane or ethylacetate). For Sn(Ⅳ)$Cl_4$ in dioxane solution, the calculated dipole moment for the trigonal bipyramidal Sn(Ⅳ)$Cl_4X$ type complex [isomer (b)] is closer to the experimental dipole moment than octahedral Sn(Ⅳ)$Cl_4X$2X type complexes. This calculated dipole moment suggests that Sn(Ⅳ)$Cl_4X$ may have the trigonal bipyramidal structure in dioxane solution. However, the calculated dipole moment for octahedral $Cl_3$Sn(Ⅳ) ($CH_2$Cl)2X type complex [Isomer (d)], ClSn(Ⅳ)(CH2Cl)32X type complex [Isomer(k)] and Cl2Sn(Ⅳ)(CH2Cl)22X type complex [Isomer(h)] are closer to the experimental dipole moments than other isomers for octahedral complexes and trigonal bipyramidal complexes. Such theoretical results indicate that $Cl_3Sn$(Ⅳ )($CH_2Cl$), ClSn(Ⅳ)$(CH_2Cl)_3$ and $Cl2Sn$(Ⅳ)$(CH_2Cl)_2$ complexes may have octahedral structures, Isomer(d), (k) and (h) in ethylacetate solution, respectively.

• Bulletin of the Korean Chemical Society
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• 제7권5호
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• pp.380-384
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• 1986

The infrared intensities of $CH_{4}$ and $CD_{4}$ are analyzed. The experimental dipole moment derivatives thus obtained are compared with corresponding values from the molecular orbital calculations. The theoretical results are analyzed for the charge-charge flux-overlap(CCFO) electronic contributions to the dipole derivatives.

• Journal of Astronomy and Space Sciences
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• 제36권3호
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• pp.181-186
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• 2019

The attitude information of spacecraft can be obtained by the sensors attached to it using a star tracker, three-axis magnetometer, three-axis gyroscope, and a global positioning signal receiver. By using these sensors, the spacecraft can be maneuvered by actuators that generate torques. In particular, electromagnetic-torque bars can be used for attitude control and as a momentum-canceling instrument. The spacecraft momentum can be created by the current through the electrical circuits and coils. Thus, the current around the electromagnetic-torque bars is a critical factor for precisely controlling the spacecraft. In connection with these concerns, a solar-cell array can be considered to prevent generation of a magnetic dipole moment because the solar-cell array can introduce a large amount of current through the electrical wires. The maximum value of a magnetic dipole moment that cannot affect precise control is $0.25A{\cdot}m^2$, which takes into account the current that flows through the reaction-wheel assembly and the magnetic-torque current. In this study, we designed a 300-W solar cell array and presented an optimal wire-routing method to minimize the magnetic dipole moment for space applications. We verified our proposed method by simulation.

• 대한전기학회논문지:전기기기및에너지변환시스템부문B
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• 제51권11호
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• pp.616-621
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• 2002

With biological effects by ELF (Extremely Low Frequency) magnetic field generated from power system, the transient magnetic field from electric appliances is a major issue presently. Because the transient magnetic field induces higher current than the power frequency field inside living bodies, transient magnetic field exposure has been much focused. In this paper, it is shown that transient magnetic field from electric home appliances can be characterized as magnetic dipole moment. In this method, the dipole moment vector is assumed by allowing an uncertainty of 6dB in the estimated field. A parameter M that represents biological interaction was applied also. The proposed method was applied to 7 types of appliances (hair drier, heater, VDT, etc.) and their equivalent magnetic dipole moment and harmonic components were estimated. As the results, the useful data for quantifying magnetic field distribution around electric appliances were obtained.

• 한국전자파학회지:전자파기술
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• 제1권1호
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• pp.28-34
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• 1990

본 논문에서는 다이폴 안테나의안테나 인자를 이론적으로 검토하였다, 안테나에 흐르는 전류분포를 모멘트 법으로 구하여 자유공간 속에 놓여진 반파장 다이폴 안테나의 유효길이와 안테나 인자를 계산하였다.

• Bulletin of the Korean Chemical Society
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• 제8권1호
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• pp.10-15
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• 1987

The results of an ab initio (6-31G) molecular orbital calculation of the dipole moment derivatives and gas phase IR intensities of difluoromethane are reported. The results are compared with corresponding values obtained from a CNDO calculation. The directions of the dipole derivatives calculated by the two methods agree very well, whereas the intensities differ significantly. The results are also analyzed for the charge-charge flux-overlap electronic contributions to the dipole derivatives.

• 대한전자공학회논문지
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• 제15권2호
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• pp.15-18
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• 1978

입력임피던스를 크게 하기 위하여 널리 사용되는 접힌 안테나의 임피이던스 변환비와 견환비에 따른 입력어드미턴스의 변화모양을 Moment법에 의하여 계산했다. 계산결과는 Guertler의 공식에 의한 것과 비교하여 이론적타당성을 확인한다. 절힌 안테나의 입력콘덕턴스는 공진주파수보다 다소 낮은 고파수에서 최대로 되고 써셉턴스는 주기적 성질을 가져서 안테나 두 소자의 굵기가 매우 다르지 않을 때는 몇 경의 주파수에서 0으로 된다. 또한 안테나 두 소자의 굴기차가 심할 수록 입력어드미턴스의 주파수에 대한 변화가 완만하여 좋은 주파수특성을 갖는다.