• 한국환경과학회지
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• 제29권11호
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• pp.1025-1032
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• 2020

This work was performed to develop a dip injection wet scrubber (DIWS) system with chlorine dioxide as the oxidant. The exhaust pollutants from a lime kiln of paper-mill were introduced to the system. When NaClO₃ was used to oxidize NO into NO₂, the oxidation was unsatisfactory and the combination of HNO₃ or H₂SO₄ was required for 100% oxidation. ClO₂ is recommended to oxidize NO and SO₂ effectively. With the combination of 1^st stage of DIWS and ClO₂, 57.1% of NOx and 98% of SO₂ were effectively removed. In the case of 2^nd stage of DIWS and ClO₂, 93.5% of NOx and 99% of SO₂ were removed. The ClO₂+DIWS process was superior to the ClO₂+Scrubber process in terms of investment, running cost and NOx removal efficiency.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2006년도 추계학술대회 논문집 광주전남지부
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• pp.107-108
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• 2006

High $J_c$ $YBa_2Cu_3O_x$, superconducting films were fabricated by MOD method using fluorine-free dichloroacetic acid(DCA) as chelating solvent for preparing precursor solution. DCA-MOD precursor solution was coated on a single crystal (001) $LaAlO_3$(LAO) substrate by a dip coating method with a speed of 25 mm/min. Coated films were calcined at lower temperature up to $500^{\circ}C$ and Conversion heat treatment was performed at various temperatures of $780{\sim}810^{\circ}C$. SEM observations showed that films have very dense microstructures for the films prepared at the temperature higher than $800^{\circ}C$ regardless of diluting solvent; methanol or 2-methoxyethanol. A High critical current density ($J_c$) of 1.28 $MA/cm^2$ (@77 K and self-field) was obtained for the YBCO film prepared using 2-methoxyethanol as a solvent.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2005년도 제36회 하계학술대회 논문집 C
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• pp.2001-2003
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• 2005

Various organic acid were used in order to prepare new metalorganic deposition solution for high quality $REBa_2Cu_3O_{7-{\delta}}$ (RE=Y, Eu, Gd) films. Prepared fluorine free MO precursor solution was coated on single crystal (001) $LaAlO_3$ (LAO) by dip coating method. Processing parameters such as oxygen partial pressure, water vapor, ramping rate and pyrolysis temperature etc havebeen controlled in order to make high $J_c$ films with a good epitaxial relationship with substrate. 0.5 micron-thick film was obtained by single coating and no crack appeared after calcination. Oxygen partial pressure was varied in the range of $100{\sim}1,000 ppm$ and conversion heat treatment was carried out at the temperature of $725{\sim}765^{\circ}C$. A critical transition temperature $(T_{c0})$ of 90K and a critical transport current density $(J_c)$ of $>0.5MA/cm^2$ (77K and self-field) were demonstrated for the YBCO film on (001) oriented LAO substrates with a thickness of 0.5 micron. $I_c$ was determined by utilizing a transport measurement. SEM and XRD investigations confirmed that films were grown epitaxially onto the LAO single crystal substrate. It is thought that fluorine free new MOD solutionis promising for high quality REBCO films.

• 에너지공학
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• 제25권2호
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• pp.65-78
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• 2016

광촉매 연구의 초기는 태양에너지의 전환 및 저장에 관련된 분야들로부터 개발되어 왔다. 최근에는 광 또는 광촉매의 존재 하에서 자외선을 조사하여 물의 정제 및 폐수처리와 각종 유기화합물의 분해연구가 활발하게 진행되고 있다. 또한 산화물질-카본나노튜브, 그래핀 나노복합체 등이 광촉매물질로서 연구되고 있다. 이와 같은 복합체는 열적, 화학적으로 안정하기 때문에 플렉서블 소자를 포함한 광분해 태양전지 및 나노전자 소자를 구성하는 재료로서 적당하다.

• 한국습지학회지
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• 제17권2호
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• pp.118-123
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• 2015

제강산업의 냉연 산회수 설비공정을 검토하였고, 공정에서 발생되는 염화수소 가스를 처리하기 위하여 마이크로버블이 발생되는 DIWS 시스템을 운전하였다. 염화수소 가스의 대기배출허용기준을 만족하기 위해서는 추가공정의 도입이 필요한 것으로 나타났다. DIWS 장치로 유입되는 평균 염화수소 가스의 농도는 22.3 ppm, 배출가스의 농도는 0.59 ppm으로 평균 제거율은 97.3%였다. TMS 장치에 의한 10시간 5분 간격 측정에서도 평균 0.69 ppm으로 안정적이었으며, 수동으로 측정하여 TMS 장치의 신뢰도를 검증하였다.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2007년도 춘계학술발표회 초록집
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• pp.147-148
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• 2007

In this study, the technology to grow oriented nanotube thin film from dip-coated $TiO_2$ using hydrothermal method has been successfully developed. The effects of preparation parameters, such as reaction temperature, duration and post treatment conditions on the film morphologies and the adherence to the substrate, have been examined. A general formation mechanism of oriented titanate nanotube thin film is proposed in terms of the detailed observation of the products via two dimensional surface FESEM studies and HRTEM images. The overall formation of $TiO_2-based$ nanotube thin film can be summarized with three successive steps: (1) $TiO_2$ dissolving and amorphous $Na_2TiO_3$ deposition process; (2) layered $Na_2Ti_3O_7$ formation via spontaneous crystallization and rapid growth process; (3) formation of nanotube thin film via $Na_2Ti_3O_7$ splitting and multilayer scrolling process of (100) planes around the c axis of $Na_2Ti_3O_7$.

• Corrosion Science and Technology
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• 제20권1호
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• pp.7-14
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• 2021

PosMAC^® is a brand of Zn-Mg-Al hot-dip coated steel sheet developed by POSCO. PosMAC^® can form dense surface oxides in corrosive environments, providing advanced corrosion resistance compared to traditional Zn coatings such as GI and GA. PosMAC^® 3.0 is available for construction and solar energy systems in severe outdoor environments. PosMAC^®1.5 has better surface quality. It is suitable for automotive and home appliances. Compared to GI and GA, PosMAC^® shows significantly less weight reduction due to corrosion, even with a lower coating thickness. Thin coating of PosMAC^® provides advanced quality and productivity in arc welding applications due to its less generation of Zn fume and spatters. In repeated friction tests, PosMAC^® showed lower surface friction coefficient than conventional coatings such as GA, GI, and lubricant film coated GA. Industrial demand for PosMAC^® steel is expected to increase in the near future due to benefits of anti-corrosion and robust application performance of PosMAC^® steel.

• 대한금속재료학회지
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• 제48권5호
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• pp.401-409
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• 2010

This study was performed to develop an antibacterial film that can be dried at room temperature. A nanosized TiO$_2$ particle-dispersed solution was prepared by the hydrothermal treatment of peroxo-titanic acid at 160${^{\circ}C}$ for 4h. The binder was synthesized through the hydrolysis and condensation reactions of TEOS (10cc) and GPTS (3.5cc) in the mixture of H$_2$O (30cc) and EtOH (30cc). The synthesized binder was mixed with 0.1 M of TiO$_2$ solution in a volume ratio of binder/TiO$_2$ solution=0.25~0.5. The glass substrate was coated after using the dip coating method, which was then followed by drying for over 2h at room temperature. Although the TiO$_2$ particles did not chemically-bond to the binder, the coating layer strongly adhered to the substrate and displayed good antibacterial properties.

• 한국초전도ㆍ저온공학회논문지
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• 제10권1호
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• pp.1-5
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• 2008

The effect of $BaCeO_3$ doping on the critical current density of YBCO film by TFA-MOD method was studied. $BaCeO_3$ doping was made by two method; one is direct addition of $BaCeO_3$ nano-sized powder prepared by citrate process followed by grinding with planetary ball mill for 10 hours. Another is addition of Ba-Ce precursor solution prepared with Ba-acetate and Ce acetate dissolved in TFA to the YBCO-TFA precursor solution. The film was made by standard dip coating and heat treatment process with conversion temperature of $790^{\circ}C$ in 1000 ppm oxygen containing moisturized Ar gas atmosphere. The direct addition of $BaCeO_3$ powder resulted in YBCO film with good epitaxial growth and no evidence of second phase formation. The addition through precursor solution resulted in the increase of critical current density upto 30 at% doping and uniform dispersion of $BaCeO_3$ fine inclusion was confirmed by SEM-EDX.

• 한국해양공학회지
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• 제24권5호
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• pp.67-74
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• 2010

Chromate conversion coating is a coating technique used to passivate aluminum, zinc, cadmium, copper, silver, magnesium, tin, and their alloys to slow corrosion. The process uses various toxic chromium compounds, which may include hexavalent chromium. The industry is developing less toxic alternatives in order to comply with substance restriction legislation, such as RoHS. One alternative is to develop a Cr-free coating solution. In this study, eco-friendly, Cr-free solutions (urethane solution S-700, organic/inorganic solution with Si LRO-317) were used. Test specimens were dried in a drying oven at $190^{\circ}C$ for 3, 5, 7, and 9 minutes. Corrosion resistance was evaluated using a salt spray test for 72 hours. The results show that the optimum corrosion resistance was achieved at $190^{\circ}C$ for five minutes for EGI and three or five minutes for HDGI, respectively. The adhesive properties of the two types of coating solutions were superior regardless of drying time.