• Title/Summary/Keyword: diffusion mechanism

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Study of Hydrogen Turbulent Non-premixed Flame Stabilization in Coaxial Air Flow (동축공기 수소 난류확산화염에서의 화염안정성에 대한 실험적 연구)

  • Oh, Jeong-Seog;Kim, Mun-Ki;Choi, Yeong-Il;Yoon, Young-Bin
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.32 no.3
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    • pp.190-197
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    • 2008
  • It was experimentally studied that the stabilization mechanism of turbulent, lifted jet flames in a non-premixed condition to reveal the newly found liftoff height behavior of hydrogen jet. The objectives are to report the phenomenon of a liftoff height decreasing as increasing fuel velocity, to analyse the flame structure and behavior of the lifted jet, and to explain the mechanisms of flame stability in hydrogen turbulent non-premixed jet flames. The hydrogen jet velocity was changed from 100 to 300m/s and a coaxial air velocity was fixed at 16m/s with a coflow air less than 0.1m/s. For the simultaneous measurement of velocity field and reaction zone, PIV and OH PLIF technique was used with two Nd:Yag lasers and CCD cameras. As a result, it was found that the stabilization of lifted hydrogen diffusion flames is correlated with a turbulent intensity and Karlovitz number.

Analysis of the Low Affinity System of the Uptake of Fructose in Suspension Culture Cells (조직 배양에서의 과당의 능동 수송에 대한 Low Affinity System의 분석)

  • 조봉희
    • Journal of Plant Biology
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    • v.30 no.4
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    • pp.277-285
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    • 1987
  • Undifferentiated suspension cells had the ability to transfer glucose and fructose actively, but the suspension culture cells were unable to transfer saccharide without previously splitting to monosccarides. The uptake of fructose showed the low- and high-affinity system compared to of glucose, which possessed only one saturable uptake system. In this paper, the low affinity system of the uptake of fructose has been studied intensively. Glucose did not inhibit the low affinity system of fructose competitively. The Km value was 47 mM for fructose, 7.4 mM for glucose and Vmax was 69 $\mu$mol/h.g fresh weight for fuctose, 9.8 $\mu$ mol/h.g fresh weight for glucose. Metabolizer inhibitors, both 50 $\mu$M of CCCP and DNP, inhibited 70% of the uptake of the low affinity system of fructose. The proton ions were accompanied by the uptake of fructose. The stoichiometry showed ratio of proton to fructose was 0.17. The mechanism ofthe uptake was fructose-proton-symport. The molecules of fructose accmululated inside 25 times more than outside. Therefore, the low affinity system of fructose was not mere diffusion, but depended on metabolic energy and thus transported actively. The importance of this system was discussed.

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A Study Towards the Determinants of the Intention to Use in the Auction Web Site (경매사이트 이용의도의 결정요인에 관한 연구)

  • Son Dal-Ho;SaKong Hye-Suk
    • The Journal of Information Systems
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    • v.15 no.1
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    • pp.49-71
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    • 2006
  • With a rapid diffusion of internet, more peoples are interested in electronic commerce and the various electronic commerce types are being appeared. In these respects, the internet auction being take the more attentions at the present. Since perceived usefulness and perceived ease of use are such a fundamental driver of usage intentions, it is important to understand the determinants of this construct and how their influences change. In these respects, the web site joyfulness, the web site trust and the institutional mechanism are included as the moderating variables in our research model. A better understanding of the interactions of these factors to the usage intention to the auction site would enable us to design the organizational interventions that would increase the user acceptance and the usage of auction systems. Therefore, the goal of the present research is to extend the organizational model of auction system with TAM's perceived usefulness and perceived ease of use and the additional motivating determinants. The result showed that the web site joyfulness and the trust were the significant determinants on the the usage of auction site. However, the direction of the effect was not consistant through the cases. The model suggested in this study need to be extended with including the more sociological factors and the empirical results founded in this study are required to be verified with the extended model.

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Design of silicon-on-nothing structure based on multi-physics analysis

  • Song, Jihwan;Zhang, Linan;Kim, Dongchoul
    • Multiscale and Multiphysics Mechanics
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    • v.1 no.3
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    • pp.225-231
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    • 2016
  • The formation of silicon-on-nothing (SON) structure during an annealing process from the silicon substrate including the trench structures has been considered as an effective technique to construct the structure that has an empty space under the closed flat surface. Previous studies have demonstrated the mechanism of the formation of SON structure, which is based on the surface diffusion driven by the minimization of their surface energy. Also, it has been fragmentarily shown that the morphology of SON structure can be affected by the initial design of trench (e.g., size, number) and the annealing conditions (e.g., temperature, pressure). Based on the previous studies, here, we report a comprehensive study for the design of the cavity-embedded structure (i.e., SON structure). To do this, a dynamic model has been developed with the phase field approach. The simulation results represent that the morphology of SON structures could be detailedly designed, for example the position and thickness of cavity, the thickness of top and bottom layer, according to the design parameters. This study will give us an advantage in the effective design of SON structures.

Strength deterioration of reinforced concrete column sections subject to pitting

  • Greco, Rita;Marano, Giuseppe Carlo
    • Computers and Concrete
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    • v.15 no.4
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    • pp.643-671
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    • 2015
  • Chloride induced reinforcement corrosion is widely accepted to be the most frequent mechanism causing premature degradation of reinforced concrete members, whose economic and social consequences are growing up continuously. Prevention of these phenomena has a great importance in structural design, and modern Codes and Standards impose prescriptions concerning design details and concrete mix proportion for structures exposed to different external aggressive conditions, grouped in environmental classes. This paper focuses on reinforced concrete column section load carrying capacity degradation over time due to chloride induced steel pitting corrosion. The structural element is considered to be exposed to marine environment and the effects of corrosion are described by the time degradation of the axial-bending interaction diagram. Because chlorides ingress and consequent pitting corrosion propagation are both time-dependent mechanisms, the study adopts a time-variant predictive approach to evaluate residual strength of corroded reinforced concrete columns at different lifetimes. Corrosion initiation and propagation process is modelled by taking into account all the parameters, such as external environmental conditions, concrete mix proportion, concrete cover and so on, which influence the time evolution of the corrosion phenomenon and its effects on the residual strength of reinforced concrete columns sections.

Pharmacokinetic Modeling and Simulation of the Carrier-Mediated Hepatic Transport of Organic Anions (음이온계 약물의 간수송과정에 있어서 담체매개 수송의 약물동력학적 모델링 및 시뮬레이션)

  • 이준섭;강민희;김묘경;이명구;정석재;심창구;정연복
    • YAKHAK HOEJI
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    • v.47 no.2
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    • pp.110-119
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    • 2003
  • The purpose of the present study was to kinetically investigate the carrier-mediated uptake in the hepatic transport of organic anions, and to simulate the ″in vivo counter-transport″ phenomena, using kinetic model which was developed in this study. The condition that the mobility of carrier-ligand complex is greater than that of free carrier is not essential for the occurrence of ″counter-transport″ phenomenon. To examine the inhibitory effects on the initial uptake of a ligand by the liver, it is necessary to judge whether the true counter-transport mechanism (trans-stimulation) is working or not. The initial plasma disappearance curves of a organic anion were then kinetically analyzed based on a flow model, in which the ligand is eliminated only from the peripheral compartment (liver compartment). Moreover, ″in vive counter-transport″ phenomena were simulated based on the perfusion model which incorporated the carrier-mediated transport and the saturable intracellular binding. The ″in vivo counter-transport″ phenomena in the hepatic transport of a organic anion were well demonstrated by incorporating the carrier-mediated process. However, the ″in vivo counter-transport″ phenomena may be also explained by the enhancement of back diffusion due to the displacement of intracellular binding. In conclusion, one should be more cautious in interpreting data obtained from so-called ″in vivo counter-transport″ experiments.

A Study of Static Fatigue of Domestic Soda-Lime Glass (국산 Soda-석탄유리의 피노현상에 관한 연구)

  • 이희수;현상훈;이형복
    • Journal of the Korean Ceramic Society
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    • v.12 no.1
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    • pp.16-22
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    • 1975
  • The network structure of a glass is known to be cracked by a chemical reaction, diffusion, and ion exchange of alkali ion, formed at the crack tip of the glass surface, when water is present on the glass surface. Since the durability of glass is reduced, due to the fatigue phenomenon mentioned above, pollution problem of glass goods, especially bottle glass, is becoming acute gradually. A static fatigue phenomenon was studied thermodynamically in this paper, and a mechanism of static fatigue, a quality control, and a method of preventing pollution for the main local glass goods were also investigated. The PH of reacted solution and the quantity of extracted alkali were measured at different conditions such as temperature, reacting time, particle size of a crushed glass sample, and the nature of reacting solution. The enthalpy change was calculated from the Arrhenius equation. The results are given below; 1) The absolute value of enthalpy change for the bottle glass was found to be higher than the for the flat glass. 2) The fatigue phenomenon of a glass was more sensitive to the temperature than to the reacting time. 3) The durability of glass in acid solution is stronger than in alkaline solution. 4) The substance which cracks the network structure of glas is considered the hydroxyl ion.

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Crystallization Mechanism of Slag-based Glass in $CaO-MgO-Al_2O_3-SiO_2(-Na_2O)$ System (Slag 위주의 $CaO-MgO-Al_2O_3-SiO_2(-Na_2O)$계 유리의 결정화 반응기구)

  • 장승현;정형진
    • Journal of the Korean Ceramic Society
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    • v.17 no.1
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    • pp.20-26
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    • 1980
  • The crystallization behaviors of slag-based glass in $CaO-MgO-Al_2O_3-SiO_2(-Na_2O)$ system have been studied. The mother glass containing 16.50 CaO, 7.50MgO, 19.70Al2O3, 50.80SiO3 and 2.09wt% $Na_2O$ was prepared by using Korean domestic raw materials such as granulated slag, serpentine, sea sand and etc. The glass-ceramics composed of major crystalline phase diopside was produced by the heat treatment in a temperature range from 850$^{\circ}$ to 9$25^{\circ}C$ for 0-6hr. The composition and morphology of diopside phase formed in the system were examined by X-ray diffraction analysis and electron microscopy. The kinetic measurements such as J.M. A plot and Arrhenius plot indicated that the process of nucleation of the initially formed diopside phase could be described from the view point of instantaneous nucleation. It was also demonstrated that the linear crystal growth of diopside phase was proceeded by short range diffusion of $Mg^{2+}$ and $Ca^{2+}$ ion. The microstructures of the resulting glass-ceramics were consisted of leafroidal shaped crystalline aggregations.

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Diurnal Changes in Stomatal Diffusion Resistance and Distribution of Stomata on Different Leaf Positions in Barley and Wheat (맥류의 기공확산저항의 일중변화와 입위별 기공의 분포)

  • 이호진;윤진일;이광회
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.26 no.1
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    • pp.45-50
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    • 1981
  • Diurnal changes in leaf stomatal resistances were measured on leaf positions and both surfaces to investigate the stomatal response to irradiance in wheat, var. Chokwang and barley, var. Dongbori 1. Stomatal frequency and size were also determined to explain the control mechanism of gas exchanges in two species. The leaf diffusive resistances of two species decreased, as the sun rose, to minimum at 10 to 11 o'clock a.m. and increased gradually in the afternoon, even faster at sunset. As the adaxial irradiance increased, stomatal resistances decreased sensitively in the range of 30uEm$^{-2}$ㆍsec$^{-1}$ to 150uEm$^{-2}$ㆍsec$^{-1}$ quantum flux density. The stomatal opening of the abaxial surface began at lower irradiance and was completed earlier than the adaxial surface. The adaxial irradiances decreased in order of leaf position, flag, the 2nd, the 3rd leaf, and the stomatal resistances increased in the same order. Even under the same irradiance, the stomatal resistance of lower leaves were higher than those of upper leaves. The stomatal frequencies of lower leaves were less, but the stomatal size was greater than those of upper leaves. Consequently, the relative leaf area occupied by stomatal pores were constant among leaf positions in two species.

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CHROMIUM LEACHABILITY FROM STABILIZED/SOLIDIFIED SOILS UNDER MODIFIED SEMI-DYNEMIC LEACHING CONDITIONS

  • Moon, Deok-Hyun
    • Environmental Engineering Research
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    • v.10 no.6
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    • pp.294-305
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    • 2005
  • The effectiveness of fly ash-, quicklime-, and quicklime-fly ash-based stabilization/solidification(S/S) in chromium(Cr) contaminated soils was investigated using modified semi-dynamic leaching tests. Artificial soil samples composed of kaolinite or montmorillonite contaminated with chromium nitrate(4000 mg $Cr^{3+}\;kg^{-1}$ of solid) were prepared and then subjected to S/S treatment using quicklime, fly ash, or quick lime-fly ash. The effectiveness of the treatment was evaluated by assessing the cumulative fraction of leached $Cr^{3+}$ as well as, by computing the effective diffusivity ($D_e$) and the leachability index (LX) of the treated samples. The reduction in $Cr^{3+}$ release for the untreated samples was more pronounced in the presence of montmorillonite, which was attributed to sorption. Treatment with quicklime, fly ash, or quick lime-fly ash was significantly effective in reducing $Cr^{3+}$ release most probably due to the formation of pozzolanic reaction products and $Cr(OH)_3$ precipitation. The most effective treatment was observed in montmorillonite-sand soil samples treated with quicklime-fly ash (99.8% removal). The mean $D_e$ decreased significantly and the mean LX was greater than 9 for all treated samples, indicating that the treated soils were acceptable for "controlled utilization". The mechanism controlling $Cr^{3+}$ leaching from all treated samples during the first 5 days appeared to be diffusion.