• Journal of the Korean Chemical Society
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• v.21 no.5
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• pp.339-352
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• 1977

The authors' theory developed in the preceding Paper 1 was applied to plastic deformation of ceramics, metals, alloys and single crystals. For polycrystalline substances, the flow mechanisms due to dislocation movement and grain boundary movement appear together or separately according to the experimental conditions whereas for single crystals, only the mechanism of dislocation movement appears. The parameters appearing in the flow equations $({\alpha}_{d1},\;1/{\beta}_{d1})and\;({\alpha}_{gj}/X_{gj},\;1/{\beta}_{gj})$ (j = 1 or 2), and the activation enthalpies ${\Delta}H_{k1}^{\neq}$ (k = d or g) were determined and tabulated. Here, the subscript d1 indicates the first kind of dislocation flow units and gj expresses the jth kind of grain boundary flow units. The predictions of the theory were compared with experiment with good agreement. Concerning the activation enthalpies, it was found that ${\Delta}H_{d1}^{\neq}$ 〉{\Delta}H_{g1}^{\neq}$ and that the former agrees with the activation enthalpy for bulk self-diffusion whereas the latter agrees with the activation enthalpy for grain boundary self-diffusion. These facts support the adequacy of the authors' theory which is considered as a generalized theory of plastic deformation.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.38 no.5
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• pp.331-341
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• 2005

Distribution of anchovy (Engraulis japonica) eggs and larvae was studied in the southwestern sea of Korea in July and November, 2001. Anchovy eggs were found mainly in the oceanic fronts of the northern sea area which were formed in the offshore area of Chuja Is. Bogil Is. and Chungsan Is. from west to east. Anchovy eggs were also found in the surrounding sea of Cheju Is. in the southern sea front area. The waters were highly heterogeneous and the water masses were bordered based on temperature $(10.8-26.4^{\circ}C)$ and salinity (28.9-33.7 psu). The anchovy eggs were mostly found outside of the China Coastal Water, where salinity was below 31 psu. The anchovy eggs were not found in November. Abundance of the anchovy larvae were higher in July than November. Temperature ranged from $10.8^{\circ}C\;to\;25.9^{\circ}C\;and\;15.9^{\circ}C\;to\;20.5^{\circ}C$, and salinity ranged from 28.9psu to 34.1psu and 33.2psu to 34.1psu in July and November, respectively. Non-swimmable larvae were found throughout the whole area of the southwestern sea of Korea. The area beyond the oceanic front had anchovy eggs dispersed from the spawning grounds to offshore. Dispersion pattern showed that the eggs were transported from the spawning grounds with a process of advection and diffusion based on the flow pattern which were caused by winds. Distribution pattern of the anchovy eggs and larvae may be used for the prediction of oceanic currents in each area.

• Journal of the Korea Society of Computer and Information
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• v.12 no.5
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• pp.131-137
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• 2007

Recently, Ant Colony Optimization (ACO) is emerged as a simple yet powerful optimization algorithm for routing and load-balancing of both wired and wireless networks. However, there are few researches trying to adopt ACO to enhance routing performance in WSN owing to difficulties in applying ACO to WSN because of stagnation effect. In this paper, we propose an energy-efficient path selection algorithm based on ACO for WSN. The algorithm is not by simply applying ACO to routing algorithm but by introducing a mechanism to alleviate the influence of stagnation. By the simulation result, the proposed algorithm shows better performance in data propagation delay and energy efficiency over Directed Diffusion which is one of the outstanding schemes in multi-hop flat routing protocols for WSN. Moreover, we checked that the proposed algorithm is able to mitigate stagnation effect than simple ACO adoption to WSN.

• Geomechanics and Engineering
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• v.21 no.4
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• pp.357-369
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• 2020

Different from the conventional planar fracture and simplified Newton model, for power-law slurries with a lower water-cement ratio commonly used in grouting engineering, flow model in geological rough fractures is built based on ten standard profiles from Barton (1977) in this study. The numerical algorithm is validated by experimental results. The flow mechanism, grout superiority, and water plugging of pseudo plastic slurry are revealed. The representations of hydraulic grouting properties for JRCs are obtained. The results show that effective plugging is based on the mechanical mechanisms of the fluctuant structural surface and higher viscosity at the middle of the fissure. The formulas of grouting parameters are always variable with the roughness and shear movement, which play a key role in grouting. The roughness can only be neglected after reaching a threshold. Grouting pressure increases with increasing roughness and has variable responses for different apertures within standard profiles. The whole process can be divided into three stationary zones and three transition zones, and there is a mutation region (10 < JRCs < 14) in smaller geological fractures. The fitting equations of different JRCs are obtained of power-law models satisfying the condition of -2 < coefficient < 0. The effects of small apertures and moderate to larger roughness (JRCs > 10.8) on the permeability of surfaces cannot be underestimated. The determination of grouting parameters depends on the slurry groutability in terms of its weakest link with discontinuous streamlines. For grouting water plugging, the water-cement ratio, grouting pressure and grouting additives should be determined by combining the flow conditions and the apparent widths of the main fracture and rough surface. This study provides a calculation method of grouting parameters for variable cement-based slurries. And the findings can help for better understanding of fluid flow and diffusion in geological fractures.

• Korean Journal of Metals and Materials
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• v.50 no.10
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• pp.775-783
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• 2012

The effect of thermal annealing on the in-situ growth characteristics of intermetallics (IMCs) and the mechanical strength of Cu pillar/Sn-3.5Ag microbumps are systematically investigated. The $Cu_6Sn_5$ phase formed at the Cu/solder interface right after bonding and grew with increased annealing time, while the $Cu_3Sn$ phase formed at the $Cu/Cu_6Sn_5$ interface and grew with increased annealing time. IMC growth followed a linear relationship with the square root of the annealing time due to a diffusion-controlled mechanism. The shear strength measured by the die shear test monotonically increased with annealing time. It then changed the slope with further annealing, which correlated with the change in fracture modes from ductile to brittle at a critical transition time. This is ascribed not only to the increasing thickness of brittle IMCs but also to the decreasing thickness of the solder, as there exists a critical annealing time for a fracture mode transition in our thin solder-capped Cu pillar microbump structures.

• Applied Chemistry for Engineering
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• v.30 no.2
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• pp.233-240
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• 2019

Molecular recognition technology has attracted considerable attention for improving the selectivity of a specific molecule by imprinting it on a polymer matrix. In this study, adsorption and release characteristics of chitosan based drug delivery films imprinted with sulindac (SLD) were investigated in terms of the plasticizer, temperature and pH and the results were also interpreted by the related mathematical models. The adsorption characteristics of target molecules on SLD-imprinted polymer films were better explained by the Freundlich and Sips equation than that of the Langmuir equation. The binding site energy distribution function was also useful for understanding the adsorption relationship between target molecules and polymer films. The drug release of SLD-imprinted polymer films followed the Fickian diffusion mechanism, whereas the drug release using artificial skin followed the non-Fickian diffusion behavior.

• Nuclear Engineering and Technology
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• v.51 no.1
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• pp.238-248
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• 2019

In the high-temperature and high-pressure irradiation environments, the multi-field coupling processes of hydrogen diffusion, hydride precipitation and mechanical deformation in Zircaloy cladding tubes occur. To simulate this hydrogen-induced complex behavior, a multi-field coupling method is developed, with the irradiation hardening effects and hydride-precipitation-induced expansion and hardening effects involved in the mechanical constitutive relation. The out-pile tests for a cracked cladding tube after irradiation are simulated, and the numerical results of the multi-fields at different temperatures are obtained and analyzed. The results indicate that: (1) the hydrostatic stress gradient is the fundamental factor to activate the hydrogen-induced multi-field coupling behavior excluding the temperature gradient; (2) in the local crack-tip region, hydrides will precipitate faster at the considered higher temperatures, which can be fundamentally attributed to the sensitivity of TSSP and hydrogen diffusion coefficient to temperature. The mechanism is partly explained for the enlarged velocity values of delayed hydride cracking (DHC) at high temperatures before crack arrest. This work lays a foundation for the future research on DHC.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.28 no.1B
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• pp.137-147
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• 2008

Soil Vapor Extraction (SVE) has been extensively used to remove volatile organic compounds (VOCs) from the vadoze zone. In order to investigate the removal mechanism during SVE operation, laboratory modeling experiments were carried out and tailing effect could be observed in later stage of the experiment. Tailing effect means that removal rate of contaminants gets significantly to decrease in later stage of SVE operation. Also, mathematical model simulating the tailing effect was used, which considers rate-limited diffusion in a water film during mass transfer among gas, liquid, and solid phases. Measurement data obtained through the experiment was used as input data of the numerical analyses. Sensitivity analysis was performed to examine the effect of each parameter on required time to reach final target concentration. Finally, it was found that the concentration in the soil phase decreased significantly with a liquid and gas diffusion coefficient larger, actual path length shorter, and water saturation smaller.

• Proceedings of the Korea Water Resources Association Conference
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• 2022.05a
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• pp.209-209
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• 2022

Reservoirs play a key role in the carbon cycle between terrestrial and marine systems and are pathways that release greenhouse gases(GHGs), CO₂, CH₄, and N₂O, into the atmosphere by decomposing organic matters. Developed countries have been actively conducting research on carbon emission assessment of dam reservoirs for over 10 years under the leadership of UNESCO/IHA, but associated research is very rare in Korea. In particular, the GHGs footprint evaluation, which calculates the change in net carbon emission considering the watershed environment between pre- and post- impoundment, is very important in evaluating the carbon emission of hydroelectric dams. The objective of this study was to estimate the GHG emissions and footprints in Daecheong Reservoir using the G-res Tool, an online platform developed by UNESCO/IHA. The G-res Tool estimates CO₂ and CH₄ emissions in consideration of diverse pathway fluxes of GHGs from the reservoir and characterizes changes in GHG fluxes over 100 years based on the expected lifetime of the dam. The input required to use the G-res Tool include data related to watersheds, reservoirs, and dams, and most were collected through the government's public portal. As a result of the study, the GHG footprint of Daecheong Reservoir was estimated to be 93 gCO₂eq/m²/yr, which is similar to that of other reservoirs around the world in the same climate zone. After impoundment, the CH₄ diffusion emission from the reservoir was 73 gCO₂eq/m²/yr, also similar to those of the overseas reservoirs, but the CH₄ bubbling emission, degassing emission, and CO₂ diffusion emissions were 44, 34, 252 gCO₂eq/m²/yr, respectively, showing a rather high tendency. Since the dam reservoir carbon footprint evaluation is essential for the Clean Development Mechanism evaluation of hydroelectric power generation, continuous research is needed in the future. In particular, experimental studies that can replace the emission factors obtained from the overseas dam reservoirs currently used in the G-res Tool should be promoted.

• Journal of the Korea Concrete Institute
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• v.22 no.6
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• pp.867-873
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• 2010

This study investigated the corrosion properties of reinforced concrete with the addition of steel fibers. The transport properties of steel fiber-reinforced concrete such as permeable void, absorption by capillary action, water permeability and chloride diffusion were first measured to evaluate the relationship with the corrosion of steel rebar. Test results showed a slight increase on the compressive strength with the addition of steel fibers as well as considerable improvement of penetration resistance to mass transport of harmful materials into concrete. The addition of steel fibers in reinforced concrete accelerated the initiation of steel corrosion contrary to the expected results based on the measured transport properties. The NaCl ponding surface showed the spalling failure due to the corrosion expansion of steel fibers and the cut-surface around the steel rebar showed the localized steel fiber's corrosion. The wet-dry cycling with high chloride ions as well as high temperature seems to induce the increase of salt crystallization on the pores continually and the increased pressure with the steel fiber's corrosion on the pores caused the spalling failure on the exposed surface. The microcracking on the surface therefore accelerated the movement of water, chloride ions and oxygen into the embedded steel rebar. The mechanism affecting corrosion of embedded steel reinforcement with steel fibers in this study are not yet fully understood and require further study comprising of accurate experimental design to isolate the effect of steel fiber's potential mechanism on the corrosion process.