• Title/Summary/Keyword: diffusion mechanism

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Analysis of Creep Crack Growth at High-Temperature Components by Diffusive Growth Model of Grain Boundary Cavities (I)-Effect of Grain Boundary Cavitation on Stress Field and Crack Growth Rate- (입계기공의 확산성장 모델을 이용한 고온기기의 크립균열전파해석(1)-응력장 및 균열전파속도에 미치는 입계기공의 영향-)

  • Jeon, Jae-Young
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.20 no.4
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    • pp.1177-1185
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    • 1996
  • The crack growth under creep condition is one of the major damage mechanisms which determines remaining life of the component operating at high temperatures. In this paper, the creep crack growth by grain boundary cavitation is studied, which is frequently observed failure mechanism for creep brittle materials. As a result of diffusive growth of creep cavities, it is shown that the crack-tip stress field is modified from the original stress distribution by the amount of singularity attenuation parameter which is function of crack growth rate and material properties. Also, the stress relaxation at crack-tip results in the extension of cavitating area by the load dump effect to meet the macroscopic force equilibrium conditdion.

Electrochemical Study of Nickel(II) Complexes with Diaza-Macrocyclic Ligands in Acetonitrile

  • Moo-Lyong Seo;Zun-Ung Bae;Tae-Myoung Park
    • Bulletin of the Korean Chemical Society
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    • v.12 no.4
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    • pp.368-370
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    • 1991
  • The electrochemical behavior and the complex formation between N$i^{2+}$ and 1,7-diazs-15-crown-5 and 1,10-diaza-18-crown-6 in acetonitrile solution have been studied by DC polarography, differential puke polarography and cyclic voltammetry. Nickel(Ⅱ) complexes gave a single well-defined wave. The formation constants of their complexes were 1$0^{4.89} and 10^{3.86}$, respectively. Nickel(Ⅱ) ion was found to form complexes of 1-to-1 composition with 1,7-diaza-15-crown-5 and 1,10-diaza-18-crown-6. In addition, reduction steps were irreversible and the reduction current were diffusion controlled. The electrochemical reduction mechanism of Ni(Ⅱ)-macrocyclic diaza-crown complexes in acetonitrile solution is estimated.

Memristive Devices Based on RGO Nano-sheet Nanocomposites with an Embedded GQD Layer (저결함 그래핀 양자점 구조를 갖는 RGO 나노 복합체 기반의 저항성 메모리 특성)

  • Kim, Yongwoo;Hwang, Sung Won
    • Journal of the Semiconductor & Display Technology
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    • v.20 no.1
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    • pp.54-58
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    • 2021
  • The RGO with controllable oxygen functional groups is a novel material as the active layer of resistive switching memory through a reduction process. We designed a nanoscale conductive channel induced by local oxygen ion diffusion in an Au / RGO+GQD / Al resistive switching memory structure. A strong electric field was locally generated around the Al metal channel generated in BIL, and the local formation of a direct conductive low-dimensional channel in the complex RGO graphene quantum dot region was confirmed. The resistive memory design of the complex RGO graphene quantum dot structure can be applied as an effective structure for charge transport, and it has been shown that the resistive switching mechanism based on the movement of oxygen and metal ions is a fundamental alternative to understanding and application of next-generation intelligent semiconductor systems.

Individual approach in the recanalization treatment of the acute ischemic brain stroke according to the various MR findings in hyperacute stage

  • Y. Jang;Lee, D.;Kim, H.;Lee, J.;Park, C.G.;Lee, H.K.;Kim, S.;D. Suh
    • Proceedings of the KSMRM Conference
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    • 2003.10a
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    • pp.98-98
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    • 2003
  • We will present various MR findings of hyperacute ischemic stroke with our own experiences in the management of the patients according to the findings. 대상 및 방법: A total of 441 patients were underwent 'acute stroke MR' imaging protocol between Mar. 2001 and Jun. 2003. The protocol included initial T2-weighted image (WI), diffusion WI (DWI, b=2000), time-of-flight (TOF) MR angiography (MRA), and pefusion WI(PWI), and follow-up T2WI, DWI, TOF MRA, and neck vessel contrast-enhanced MRA obtained three to five days after the insult. Among them, we retrospectively reviewed the MR findings and clinical courses of 193 patients with anterior circulation territorial infarction. Those ICA and MCA lesions were divided into six and five groups respectively according to the level and mechanism of the occlusion. PWI findings can be another factor in the management planning.

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Ritualism versus Universalism: The Challenge of Establishing an Effective Rights-Based Labor Migration Regime in ASEAN

  • Tigno, Jorge V.
    • SUVANNABHUMI
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    • v.11 no.2
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    • pp.159-186
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    • 2019
  • Southeast Asia accounts for nearly a tenth of total worldwide cross-border movements of migrant workers. Cambodia, Indonesia, Laos, Myanmar, and Philippines make up the sending countries while Malaysia, Singapore, and Thailand are the major destinations. Migrant worker movements are predominantly in production process and low- to medium-skilled sectors. It is not unusual for irregular or undocumented movements to take place. In not a few instances, migrants work under harsh and exploitative conditions. In recent years, however, ASEAN has taken steps to manage labor migration at the regional level. The paper argues that ASEAN has not managed these cross-border labor flows as well as it should particularly in terms of protecting and promoting the human rights of migrants. It will be difficult to establish the genuine building blocks for a regional human rights mechanism unless there is a diffusion of alternative universal norms and standards to what ASEAN already embodies. As long as states resist any attempt to weaken or question or deligitimize their capacity to determine who gets to enter, stay, and leave their jurisdictions, it will be difficult to establish an effective migrant rights framework for the region.

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Development of hybrid resin to reduce silica in borated water

  • Ramzan Akhtar ;Shahid Latif ;Syed Aizaz Ali Shah ;Shaukat Saeed ;Abdul Aziz
    • Nuclear Engineering and Technology
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    • v.55 no.7
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    • pp.2547-2555
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    • 2023
  • Amberlite IRN-78 resin was incorporated with iron to make a hybrid resin for the removal of silica from the borated water of nuclear power plants. The hybrid resin contained 0.84 wt % iron compounds upon pyrolysis. In batch experiments carried out at room temperature, 1 g of the hybrid resin removed ~60 ㎍ silica from 1 ppm borated water in ~120 min. The efficiency of the hybrid material increased with the resin quantity, decreased with silica concentration, and remained unchanged at different pH values. Freundlich and Temkin isothermal adsorption dominated the silica removal process and followed the pseudo-first-order and intra-particle diffusion mechanism simultaneously. The concentration of the leached iron remained appreciably under the safe limits of 200 ㎍/l during the experiments. This detailed study suggests the use of hybrid resin for the removal of silica from borated water streams and other similar systems.

Ultrasonic cavitation bubble- and gas bubble-assisted fractional precipitation for the purification of (+)-dihydromyricetin

  • Jieun Hong;Jin-Hyun Kim
    • Korean Journal of Chemical Engineering
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    • v.39
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    • pp.3067-3073
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    • 2022
  • This study presents the ultrasonic cavitation bubble- and gas bubble-assisted fractional precipitation that dramatically improves the precipitation efficiency in existing precipitation method for purifying (+)-dihydromyricetin. Compared to the conventional method, the time required for precipitation was reduced by 40 times. The particle size was reduced by 4.0-7.4 times and 3.7-4.4 times for cavitation bubbles and gas bubbles, respectively, and the diffusion coefficient was increased by 5.1-9.2 times (cavitation bubble) and 3.7-4.4 times (gas bubble). Meanwhile, the precipitation rate constant was increased by 11.0-65.0 times and 17.0-24.6 times and the activation energy was decreased by -5,543~-9,655 J/mol and -6,546~-7,404 J/mol, which resulted in an improved precipitation rate. The results of the thermodynamic analysis showed that the precipitation was exothermic and non-spontaneous.

Inhibitory Mechanism of Daidzein on Helicobacter pylori Growth (Helicobacter pylori 의 생육에 대한 Daidzein의 저해 특성)

  • Bae, Kyung-Mi;Lee, Ju-Youn;Lee, Hee-Seob
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.39 no.7
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    • pp.1083-1086
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    • 2010
  • This study was conducted to investigate the inhibitory effects of daidzein against H. pylori and its cholesterol $\alpha$-glucosyltransferase ($CHL{\alpha}GcT$). $CHL{\alpha}GcT$ is responsible for the production of $\alpha$-glucosyl cholesterol which constitutes more than 25% of cell wall lipids in H. pylori, and it has been suggested that it is essential for H. pylori viability. $CHL{\alpha}GcT$ was inhibited by daidzein, in a dose-dependant manner, of which $IC_{50}$ value was $128.5\;{\mu}M$. Daidzein also showed the inhibitory effect toward H. pylori growth by paper disc diffusion assay. Therefore, it is thought that the inhibition of daidzein on $CHL{\alpha}GcT$ was related to its anti-Helicobacter activity.

Characteristics of Autoignited Laminar Lifted Flames in Heated Coflow Jets of Carbon Monoxide/Hydrogen Mixtures (일산화탄소/수소 혼합기의 가열된 동축류 제트에서 자발화된 층류 부상화염의 특성)

  • Choi, Byung-Chul;Chung, Suk-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.6
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    • pp.639-646
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    • 2012
  • The characteristics of autoignited lifted flames in laminar jets of carbon monoxide/hydrogen fuels have been investigated experimentally in heated coflow air. In result, as the jet velocity increased, the blowoff was directly occurred from the nozzle-attached flame without experiencing a stabilized lifted flame, in the non-autoignited regime. In the autoignited regime, the autoignited lifted flame of carbon monoxide diluted by nitrogen was affected by the water vapor content in the compressed air oxidizer, as evidenced by the variation of the ignition delay time estimated by numerical calculation. In particular, in the autoignition regime at low temperatures with added hydrogen, the liftoff height of the autoignited lifted flames decreased and then increased as the jet velocity increased. Based on the mechanism in which the autoignited laminar lifted flame is stabilized by ignition delay time, the liftoff height can be influenced not only by the heat loss, but also by the preferential diffusion between momentum and mass diffusion in fuel jets during the autoignition process.

Fabrication of Poly Seed Layer for Silicon Based Photovoltaics by Inversed Aluminum-Induced Crystallization (역 알루미늄 유도 결정화 공정을 이용한 실리콘 태양전지 다결정 시드층 생성)

  • Choi, Seung-Ho;Park, Chan-Su;Kim, Shin-Ho;Kim, Yang-Do
    • Korean Journal of Materials Research
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    • v.22 no.4
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    • pp.190-194
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    • 2012
  • The formation of high-quality polycrystalline silicon (poly-Si) on relatively low cost substrate has been an important issue in the development of thin film solar cells. Poly-Si seed layers were fabricated by an inverse aluminum-induced crystallization (I-AIC) process and the properties of the resulting layer were characterized. The I-AIC process has an advantage of being able to continue the epitaxial growth without an Al layer removing process. An amorphous Si precursor layer was deposited on Corning glass substrates by RF magnetron sputtering system with Ar plasma. Then, Al thin film was deposited by thermal evaporation. An $SiO_2$ diffusion barrier layer was formed between Si and Al layers to control the surface orientation of seed layer. The crystallinity of the poly-Si seed layer was analyzed by Raman spectroscopy and x-ray diffraction (XRD). The grain size and orientation of the poly-Si seed layer were determined by electron back scattering diffraction (EBSD) method. The prepared poly-Si seed layer showed high volume fraction of crystalline Si and <100> orientation. The diffusion barrier layer and processing temperature significantly affected the grain size and orientation of the poly Si seed layer. The shorter oxidation time and lower processing temperature led to a better orientation of the poly-Si seed layer. This study presents the formation mechanism of a poly seed layer by inverse aluminum-induced crystallization.