• Title/Summary/Keyword: diffusion mechanism

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The Influence of External Stress on the Degradation Phenomena of PZT Ceramics (외부응력에 의한 PZT압전세라믹스의 열화현상)

  • Im, Jin-Ho;Lee, Jun-Hyeong;Kim, Jin-Ho;Jo, Sang-Hui
    • Korean Journal of Materials Research
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    • v.4 no.4
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    • pp.439-444
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    • 1994
  • The influence of the direction of applied compressive stress on degradation mechanism ofpoled PZT sample was studied. When compressive stress perpendicular to poling direction was appliedon poled PZT sample, the degradation phenomena was explained by the diffusion of space chargepolarization. On the contrary, compressive stress parallel to poling direction was applied, it wasexplained by the rearrangement of 90" domains. As the grain size increased, the degradation phenomenawas promoted. It is attributed to different internal stress due to difference of grain size. of grain size.

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A Study on Models of Graduate Courses in Governmental Research Institutes (출연(연) 단설대학원 운영모델 연구)

  • 김갑수;김전식;김정흠;이규호;이병민;조붕제;현병환
    • Journal of Korea Technology Innovation Society
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    • v.1 no.2
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    • pp.165-180
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    • 1998
  • This study suggests a new concept for the improvement of productivity and innovativeness of governmental research institutes(GRIs) : GRIs can also accomodate a special graduate course. Through the combination of educational function and research activities, the explict and tacit knowledge made by GRIs could be efficiently diffused to other sectors of national innovation system, especially industries. This study suggests three different models of graduate courses : independent course in each GRI, joint course by several GRIs, and joint course linking GRIs and university.

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Silicide Formation by Solid State Diffusion in Mo/Si Multilayer Thin Films (Mo/Si 다층박막에서의 고상확산에 의한 실리사이드 생성에 관한 연구)

  • 지응준;곽준섭;심재엽;백홍구
    • Journal of the Korean Vacuum Society
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    • v.2 no.4
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    • pp.507-514
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    • 1993
  • The solid state reaction of Mo/Si multilayer thin films produced by RF magnetron sputtering technique was examine dusing differential scanning calorimetry (DSC) and x-ray diffraction, and explained in view of two concepts, effective drivig force and effective heat of formation. In constant scanning rate DSC, there were two exothermic peks which corresponded to the formation of h-MoSi2 and t-MoSi2 , respectively. The activation energyfor theformation of h-MoSi2 was 1.5eV , and that of t-MoSi2 was 7.8eV. Nucleation wa stherate controlling mechanism for each of the silicide formation. Amorphous phase was not formed , which was consistent withtheprediction by the concept of effective driving force. h-MoSi2 the first crystalline phase, was considered to have lower interfacial free energy than t-MoSi2 and by increasing temperature it was transformed into more stable t-MoSi2.

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Development of a Mechanistic Model for Hydrogen Generation in Fuel-Coolant Interactions

  • Lee, Byung-Chul;Park, Goon-Cherl;Chung, Chang-Hyun
    • Nuclear Engineering and Technology
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    • v.29 no.2
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    • pp.99-109
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    • 1997
  • A dynamic model for hydrogen generation by Fuel-Coolant Interactions(FCI) is developed with separate models for each FCI stage, coarse mixing and stratification. The model includes the physical concept of FCI, semi-empirical heat and mass transfer correlation and the concentration diffusion equation with the general non-zero boundary condition. The calculated amount of hydrogen, which is mainly generated in stratification, is compared with the FITS experiments. The model developed in this study shows a good agreement within a range of 10 % fuel oxidation rate and predicts the controlled mechanism of the chemical reaction very well. And this model predicts more accurately than the previous works. It is shown from the sensitivity study that the higher initial temperature of fuel particle is, the larger the reaction rate is. Up to 2700 K of temperature of the particle, the reaction rate increases rapid, which can lead to metal ignition.

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Joining of 8 mol% YSZ Solid Electrolyte and Perovskite LaMnO3 (8 mol% YSZ 고체전해질과 페로프스카이트 $LaMnO_3$와의 접합)

  • 김명철;박순자
    • Journal of the Korean Ceramic Society
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    • v.29 no.5
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    • pp.377-382
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    • 1992
  • For the development of solid oxide fuel cell the joined interface formation between perovskite oxygen electrode and YSZ solid electrolyte is emphasized in the aspect of reducing the undisirable overpotential. The diffusion couple of LaMnO3 and YSZ was prepared by hot pressing at 130$0^{\circ}C$ in the flow of oxygen gas. The high temperature solid state reaction mechanism between LaMnO3 and YSZ is discussed on the basis of the cation composition profile through EDX analysis. The cation components in perovskite compound diffuse considerably into YSZ, while cations of YSZ diffuse little into perovskite.

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Synthesis of Carbon Nanotubes by Chemical Method at Warm Temperatures (탄소나노튜브의 중저온에서의 화학적 합성)

  • Ahn, Jung-Ho;Lee, Sang-Hyun;Kim, Yong-Jin;Chung, Byung-Sik
    • Journal of Powder Materials
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    • v.13 no.5 s.58
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    • pp.305-312
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    • 2006
  • Amorphous carbon nanotubes were synthesized by a reaction of benzene, ferrocene and Na mixture in a small autoclave at temperatures as low as $400^{\circ}C$. The resulting carbon nanotubes were short and straight, but their inner hole was filled with residual products. The addition of quartz to the reacting mixture considerably promoted the formation of carbon nanotubes. A careful examination of powder structure suggested that the nanotubes in this process were mainly formed by surface diffusion of carbon atoms at the surface of solid catalytic particles, not by VLS(vapor-liquid-solid) mechanism.

Analysis of Kinetic Data of Pectinases with Substrate Inhibition

  • Gummadi, Sathyanarayana-N.;Panda, T.
    • Journal of Microbiology and Biotechnology
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    • v.13 no.3
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    • pp.332-337
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    • 2003
  • Enzyme kinetics data play a vital role in the design of reactors and control of processes. In the present study, kinetic studies on pectinases were carried out. Partially purified polymethylgalacturonase (PMG) and polygalacturonase (PG) were the two pectinases studied. The plot of initial rate vs. initial substrate concentration did not follow the conventional Michaelis-Menten kinetics, but substrate inhibition was observed. For PMG, maximum rate was attained at an initial pectin concentration of 3 g/l, whereas maximum rate was attained when the initial substrate concentration of 2.5 g/l of polygalacturonic acid for PG I and PG II. The kinetic data were fitted to five different kinetic models to explain the substrate inhibition effect. Among the five models tested, the combined mechanism of protective diffusion limitation of both high and inhibitory substrate concentrations (semi-empirical model) explained the inhibition data with 96-99% confidence interval.

Application of Ultrasonic for agglomeration of fine soot particles (미세 매연입자의 응집을 위한 초음파장의 적용)

  • Jeong, Sang-Hyun;Hong, Won-Seok;Shim, Sung-Hun;Kim, Yong-Jin;Lee, Sung-Bum
    • Journal of the Korean Society of Combustion
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    • v.8 no.2
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    • pp.41-49
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    • 2003
  • Ultrasonic field of 28kHz with sound pressure level 162dB has been employed to agglomerate the fine soot particle produces in a diffusion flame in a chamber. The agglomeration process has been investigated with digital camcorder and analysed in terms of the decrease of number density with exposure time. From the observation of agglomeration process, the initial agglomeration has been carried out during the short time, and it has been dominated by the orthokinetic collision. Thereafter, a slower agglomeration mechanism, driven by acoustic streaming in the chamber takes over and agglomeraters grew to diameters of several millimeters were levitated at the pressure node of the acoustic wave. And, the circular disk shape of large agglomeraters with the rotational and translational motion is observed.

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Numerical Analysis for a Swirling Confined Non-Premixed Flame with Modified Lagrangian model (수정 Lagrangian model을 이용한 선회 비 예혼합 화염에 대한 수치적 연구)

  • Min, Byoung-Hyouk;Kim, Ho-Young;Chung, Jin-Taek
    • 한국연소학회:학술대회논문집
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    • 2002.06a
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    • pp.113-122
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    • 2002
  • The purpose of this study is to verify that the modified Lagrangian model can predict temperature, flow and scalar fields in the high temperature recirculation region of swirling confined diffusion flame. In the meantime numerical results from EBU and Equilibrium PDF models as well as experimental results are compared with those from the modified Lagrangian model. Adaption of three different turbulent models were accompanied with this procedure. Look-up table of the ignition characteristic time scale which is one of important factors of the Lagrangian model was referred to the 11-step reduced mechanism. Eventually, results with the Lagrangian model show a good accordance with experimental results, which shows the validity of this model. Results from Chen's model differ from those of the others. Numerical results of ${\widetilde{k}$ show significant deviation from experimental results for three models.

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Preparation of Furosemide Retard Tablets Using Hydroxyethylcellulose as Matrix Forming Material (히드록시에칠셀룰로오스를 겔상 메트릭스로 사용한 서방성 푸로세미드정제의 제조)

  • Kim, Choong-Ho;Shim, Chang-Koo;Lee, Min-Hwa;Kim, Shin-Keun
    • Journal of Pharmaceutical Investigation
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    • v.17 no.2
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    • pp.47-53
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    • 1987
  • Furosemide retard tablets were prepared using hydroxyethylcellulose(HEC) as a matrix material. Dissolution of furosemide from this tablet was retarded significantly comparing with conventional tablets and greatly dependent on HEC concentration and pH of the dissolution medium. The mechanism of retarded release was supposed to be due to HEC gel formation and drug diffusion through the gel matrix.

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