• Korean Journal of Materials Research
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• v.30 no.5
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• pp.252-261
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• 2020

We prepare ZnO nanoparticles by environmentally friendly synthesis using Cyathea nilgiriensis leaf extract. Various phytochemical constituents are identified through the assessment of ethanolic extract of plant Cyathea nilgiriensis holttum by GC-MS analysis. The formation of ZnO nanoparticles is confirmed by FT-IR, XRD, SEM-EDX, TEM, SAED and PSA analysis. TEM observation reveals that the biosynthesized ZnO nanopowder has a hexagonal structure. The calculated average crystallite size from the high intense plane of (1 0 1) is 29.11 nm. The particle size, determined by TEM analysis, is in good agreement with that obtained by XRD analysis. We confirm the formation of biomolecules in plant extract by FT-IR analysis and propose a possible formation mechanism of ZnO nanoparticles. Disc diffusion method is used for the analyses of antimicrobial activity of ZnO nanoparticles. The synthesized ZnO nanoparticles exhibit antimicrobial effect in disc diffusion experiments. The biosynthesized ZnO nanoparticles display good antibacterial performance against B. subtilis (Gram-positive bacteria) and K. pneumonia (Gram-negative bacteria). Bio-synthesized nanoparticles using green method are found to possess good antimicrobial performance.

• Structural Engineering and Mechanics
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• v.56 no.2
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• pp.257-273
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• 2015

Numerical value of correlation between effective parameters in the strength of a structure is as important as its stochastic properties in determining the safety of the structure. In this article investigation is made about the variation of coefficient of correlation between effective parameters in corrosion initiation time of reinforcement and the time of concrete cover cracking in reinforced concrete (RC) structures. Presence of many parameters and also error in measurement of these parameters results in uncertainty in determination of corrosion initiation and the time to crack initiation. In this paper, assuming diffusion process as chloride ingress mechanism in RC structures and considering random properties of effective parameters in this model, correlation between input parameters and predicted time to corrosion is calculated using the Monte Carlo (MC) random sampling. Results show the linear correlation between corrosion initiation time and effective input parameters increases with increasing uncertainty in the input parameters. Diffusion coefficient, concrete cover, surface chloride concentration and threshold chloride concentration have the highest correlation coefficient respectively. Also the uncertainty in the concrete cover has the greatest impact on the coefficient of correlation of corrosion initiation time and the time of crack initiation due to the corrosion phenomenon.

• BMB Reports
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• v.54 no.3
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• pp.157-163
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• 2021

The transient interactions between cellular components, particularly on membrane surfaces, are critical in the proper function of many biochemical reactions. For example, many signaling pathways involve dimerization, oligomerization, or other types of clustering of signaling proteins as a key step in the signaling cascade. However, it is often experimentally challenging to directly observe and characterize the molecular mechanisms such interactions-the greatest difficulty lies in the fact that living cells have an unknown number of background processes that may or may not participate in the molecular process of interest, and as a consequence, it is usually impossible to definitively correlate an observation to a well-defined cellular mechanism. One of the experimental methods that can quantitatively capture these interactions is through membrane reconstitution, whereby a lipid bilayer is fabricated to mimic the membrane environment, and the biological components of interest are systematically introduced, without unknown background processes. This configuration allows the extensive use of fluorescence techniques, particularly fluorescence fluctuation spectroscopy and single-molecule fluorescence microscopy. In this review, we describe how the equilibrium diffusion of two proteins, K-Ras4B and the PH domain of Bruton's tyrosine kinase (Btk), on fluid lipid membranes can be used to determine the kinetics of homodimerization reactions.

• Journal of Powder Materials
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• v.29 no.5
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• pp.357-362
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• 2022

The low-temperature sinterability of TiO₂-CuO systems was investigated using a solid solution of SnO₂. Sample powders were prepared through conventional ball milling of mixed raw powders. With the SnO₂ content, the compositions of the samples were Ti_1-xSn_xO₂-CuO(2 wt.%) in the range of x ≤ 0.08. Compared with the samples without SnO₂ addition, the densification was enhanced when the samples were sintered at 900℃. The dominant mass transport mechanism seemed to be grain-boundary diffusion during heat treatment at 900℃, where active grain-boundary diffusion was responsible for the improved densification. The rapid grain growth featured by activated sintering was also obstructed with the addition of SnO₂. This suggested that both CuO as an activator and SnO₂ dopant synergistically reduced the sintering temperature of TiO₂.

• Journal of ILASS-Korea
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• v.3 no.4
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• pp.43-49
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• 1998

In order to clarify the effect of equivalence ratio and kinds of fule in flame structure, a numerical simulation of triple flame developed in a co-flowing methane-air and air stream was carried out by the elementary chemical reaction mechanism. The following conclusions were obtained. Equivalence ratio at which the apparent burning velocity is maximum is a little larger than that of the one-dimensional premixed flame. Apparent burning velocities are two times higher than that of the one-dimensional premixed flame for the methane-air. The flame thrusts out forward in the downstream of the boundary between mixture and air stream, and a part of the flow is bent and forks out in this protruding flame so that a triple flame is originated; this triple flame is composed of fuel rich and lean premixed flame branches and a diffusion flame branch. Near the equivalence ratio at which the burning velocity of rule-dimensional premixed flame is the largest the effect of one-dimensional premixed flame becomes large and the fuel rich premixed flame advances and becomes vertical to the flow direction.

• Electrical & Electronic Materials
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• v.16 no.9
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• pp.63.2-64
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• 2003

Epitaxial yttrium-stabilized HfO$_2$ thin films were deposited on p-type (100) Si substrates by pulsed laser deposition at a relatively lower substrate temperature of 550. Transmission electron microscopy observation revealed a fixed orientation relationship between the epitaxial film and Si; that is, (100)Si.(100)HfO$_2$ and [001]Si/[001]HfO$_2$. The film/Si interface is not atomically flat, suggesting possible interfacial reaction and diffusion, X-ray photoelectron spectrum analysis also revealed the interfacial reaction and diffusion evidenced by Hf silicate and Hf-Si bond formation at the interface. The epitaxial growth of the yttrium stabilized HfO$_2$ thin film on bare Si is via a direct growth mechanism without involoving the reaction between Hf atoms and SiO$_2$ layer. High-frequency capacitance-voltage measurement on an as-grown 40-A yttrium-stabilized HfO$_2$ epitaxial film yielded an dielectric constant of about 14 and equivalent oxide thickness to SiO$_2$ of 12 A. The leakage current density is 7.0${\times}$ 10e-2 A/$\textrm{cm}^2$ at 1V gate bias voltage.

• Nuclear Engineering and Technology
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• v.56 no.9
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• pp.3750-3757
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• 2024

Rapidly obtaining the coverage characteristics of leaching solution in In-situ Leaching Area of Sandstone Uranium Mines is a necessary condition for optimizing well locations reasonably. In the presented study, the improved algorithm of the Fast Marching Method (FMM) was studied for rapidly solving coverage characteristics to replace the groundwater numerical simulator. First, the effectiveness of the FMM was verified by simulating diffusion characteristics of the leaching solution in In-situ Leaching Area. Second, based on the radial flow pressure equation and the interaction mechanism of the front diffusion of production and injection well flow field, an improved FMM which is suitable for In-situ Leaching Mining, was developed to achieve the co-simulation of production and injection well. Finally, the improved algorithm was applied to engineering practice to guide the design and production. The results show that the improved algorithm can efficiently solve the coverage characteristics of leaching solution, which is consistent with those obtained from traditional numerical simulators. In engineering practice, the improved FMM can be used to rapidly analyze the leaching process, delineate Leaching Blind Spots, and evaluate the rationality of well pattern layout. Furthermore, it can help to achieve iterative optimization and rapid decision-making of production and injection well locations under largescale mining area models.

• Tunnel and Underground Space
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• v.13 no.1
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• pp.20-32
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• 2003

To understand the behavior of migration of contaminants in a fractured porous medium is a key to assure the overall safety of a potential radwaste repository. The feasible retention mechanism of contaminant transport in a tinctured medium are sorption of contaminants on solid surface and matrix diffusion of contaminants from a fracture into an adjacent porous medium. The acceleration mechanisms are the migration of contaminants in the form of pseudo-colloids and the limit of a volume f3r matrix diffusion. In this paper, the effects of these two acceleration mechanisms are studied mathematically, then semi-analytically computed by the application of the Talbot theorem and verified. Results indicate that the acceleration processes cannot be neglected in the modeling of contaminant transport in a fractured porous medium.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1993.05a
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• pp.22-27
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• 1993

we prepared 70K new BiPbAgSrCaCuO superconductor used diffusion of dual layer which composed of SrCaCuO and BiPbAgCuO compound. This method is used permeation and diffusion on partial melting point of BiPbAgCuO compound. Samples were analyzed by means of X-ray diffraction analysis, Thermal analysis, critical temperature and scanning electron microscopy. It was found that the best results were obtained for spread volume (A:B=1:0.6) and sintring time 210hours.

• Applied Chemistry for Engineering
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• v.5 no.1
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• pp.127-138
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• 1994

In the process of pervaporation separation for aqueous ethanol solution through cellulose tai-acetate(CTA) membrane, the modelling on the solution-diffusion permeation mechanism was built up on the basis of sorption and permeation experimental results. Also its function type and parameter were examined. The composition of sorption equilibrium in three component system(Ethanol/Water/CTA) were compared with the calculated value by Flory-Huggins' equation using the pure component sorption data. In order to apply the thermodynamic equilibrium relationship between the membrane free composition in the membrane and the equilibrium composition in the liquid phase, the apparent activity this system, however, the results were not satisfied. Diffusion equations were expressed with the concentration gradient considering permeate alone, and a concentration-dependent diffusion coefficient which includes a parameter was used. And this model was fitted with the measured permeation rates. If the permeation rate and the amount of sorption of one component were much larger than those of the other, the bulk flow term could not be negligible. The flux and selectivity were increased with increasing temperature, and with decreasing downstream pressure.