• Journal of Surface Science and Engineering
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• v.27 no.2
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• pp.83-90
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• 1994

We have investigated the mechanism for the abnormal oxide growth occuring during oxidation of the crystalline tungsten silicide. TEM and XPS analysis reveal the abnormaly grown oxide layer consisting of crystalline $Wo_3$ and amorphous $SiO_2$. The presence of crystalline $Wo_3$ provides a rapid diffusion of oxygen through the oxide layer. The abnormal oxide growth is mainly due to the poor quality of initial oxide layer growth on tungsten silicide. Two species such as tungsten and silicon from decomposition fo tungsten silicide as well as silicon supplied from the underlying polysilicon are the main contributors sto abnormal oxide forma-tion. Consequently, the abnormal oxidation results in the disintegration of tungsten silicide and thinning of polysilicon as well.

• Journal of Pharmaceutical Investigation
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• v.19 no.1
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• pp.39-46
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• 1989

The clonidine transport mechanism through the skin was investigated with assumptions that epidermis is heterogeneous and two-layer membrane. Immobilization of clonidine was not found in stratum corneum but in viable epidermis. The sorption in the viable epidermis agreed with the dual sorption theory. Diffusion coefficient in stratum corneum was five order magnitude less than that in viable epidermis. In viable epidermis, the ratio of true diffusivity to apparent diffusivity increased initially then decreased as a function of clonidine concentration, and the true diffusivity was always larger than the apparent diffusivity.

• Proceeding of EDISON Challenge
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• 2014.03a
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• pp.183-195
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• 2014

Kinetically constrained models (KCM) have attracted interest as models that assign dynamic origins to the interesting dynamic properties of supercooled liquid. Signs of dynamic heterogeneity in the crossover model that linearly interpolates between the FA-like symmetric constraint and the East model constraint by asymmetric parameter b were investigated using Monte Carlo technique. When the asymmetry parameter was decreased sufficiently, smooth fragile-to-strong dynamic transition was observed in terms of the relaxation time, diffusion constant, Stokes-Einstein violation, and dynamic length scale. Competition between energetically favored symmetric relaxation mechanism and entropically favored asymmetric relaxation mechanism is behind such transition.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.5 no.3
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• pp.240-249
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• 1993

The suspended sediment mechanism was systematically investigated by analyzing existing data together with new data obtained under several wave folds. A simple empirical formula has been developed to predict the time-averaged suspended sediment concentration above movable bed by the effect of wave and current interaction. The present study shows linear dependency of the diffusion coefficient of suspended sediment on the eddy viscosity coefficient obtained by considering the ripple geometry. Furthermore, it is proved that reference sediment concentration is reduced by the effect of ripple asymmetry.

• Bulletin of the Korean Chemical Society
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• v.30 no.7
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• pp.1563-1566
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• 2009

One-dimensional aluminum nitride (AlN) nanostructures were synthesized by calcining an Al(OH)(succinate) complex, which contained a very small amount of iron as a catalyst, under a mixed gas flow of nitrogen and CO (1 vol%). The complex decomposed into a homogeneous mixture of alumina and carbon at the molecular level, resulting in the lowering of the formation temperature of the AlN nanostructures. The morphology of the nanostructures such as nanocone, nanoneedle, nanowire, and nanobamboo was controlled by varying the reaction conditions, including the reaction atmosphere, reaction temperature, duration time, and ramping rate. Iron droplets were observed on the tips of the AlN nanostructures, strongly supporting that the nanostructures grow through the vapor-liquid-solid mechanism. The variation in the morphology of the nanostructures was well explained in terms of the relationship between the diffusion rate of AlN vapor into the iron droplets and the growth rate of the nanostructures.

• Transactions of the Korean Society of Machine Tool Engineers
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• v.16 no.6
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• pp.181-186
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• 2007

UBM (Under Bump Metallurgy) of flip chip assemblies consists of several layers such as the solder wetting, the diffusion barrier, and the adhesion layers. In addition, IMC layers are formed between the solder wetting layers (e.g. Cu, Ni) and the solder. The primary failure mechanism of the solder joints in flip chips is widely known as the fatigue failure caused by thermal fatigues or electromigration damages. Sometimes, the premature brittle failure occurs in the IMC layers. However, these phenomena have thus far been viewed from only experimental investigations. In this sense, this paper presents a method for solid modeling of IMC layers in flip chip assemblies, thus providing a pre-processing tool for finite element analysis to simulate the IMC failure mechanism. The proposed modeling method is CSG-based and can also be applied to the modeling of UBM structure in flip chip assemblies. This is done by performing Boolean operations according to the actual sequences of fabrication processes

• Proceedings of the Membrane Society of Korea Conference
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• 1998.10a
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• pp.75-78
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• 1998

1. Introduction : The clean technology using ion exchange membranes have drawn attention increasingly with advancement of the membrane synthesis. Ion exchange membranes have been used for diffusion dialysis, electrodialysis, electrodialytic water splitting and electrodeionization. Bipolar membranes(BPM), consisting of a cation exchange layer and an an_ion exchange layer, can convert a salt to an acid and a base without chemical addition. Using the bipolar membrane, a large quantity of industrial wastes containing salts can be reprocessed to generate acids and bases. Recent development of high performance bipolar membranes enables to further expand the potential use of electrodialysis in the chemical industry. The water-splitting mechanism in the bipolar membrane, however, is a controversial subject yet. In this study bipolar membranes were prepared using commercial ion exchange membranes and hydrophilic polymer as a binder to investigate the effects of the interface hydrophilicity on water-splitting efficiency. In addition, the water splitting mechanism by a metal catalyst was discussed.

• Bulletin of the Korean Chemical Society
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• v.18 no.11
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• pp.1199-1203
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• 1997

The investigation of cure kinetics of biphenyl epoxy (4,4-diglycidyloxy-3,3,5,5-tetramethyl biphenyl)-xylok resin system with four different catalysts was performed by differential scanning calorimeter using an isothermal approach. All kinetic parameters of the curing reaction including the reaction order, activation energy and rate constant were calculated and reported. The results indicate that the curing reaction of the formulations using triphenylphosphine (TPP) and 1-benzyl-2-methylimidazole (1B2MI) as a catalyst proceeds through a first order kinetic mechanism, whereas that of the formulations using diazabicyloundecene (DBU) and tetraphenyl phosphonium tetraphenyl borate (TPP-TPB) proceeds by an autocatalytic kinetic mechanism. To describe the cure reaction in the latter stage, we have used the semiempirical relationship proposed by Chern and Poehlein. By combining an nth order kinetic model or an autocatalytic model with a diffusion factor, it is possible to predict the cure kinetics of each catalytic system over the whole range of conversion.

• Journal of Advanced Marine Engineering and Technology
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• v.33 no.2
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• pp.259-266
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• 2009

An experimental study was conducted to investigate the effects of forcing amplitude on the flow structure near the nozzle exit of forced jet diffusion flames. The jet was excited up to the blowout occurrence by a considerable large amplitude with a periodic velocity fluctuation at the tube resonating frequency. In the attached flame regime, we disclosed the very interesting result newly that adding of a moderate forcing amplitude caused the jet flame to become longer in spite of being forced. Particular attention is focused on the turnabout mechanism of vortex roll-up around the elongated flame, which has not been reported previously, and on the inner coherent structure of the forced jet in the attached flame regime. From the velocity and flow visualization results, it was ascertained that the surrounding air due to the occurrence of negative velocity parts was suck into the fuel nozzle. To aid in understanding the rotating phenomenon of coherent structure, we present a schematic diagram of the turnabout mechanism of vortex roll-up. The mechanism of vortex turnabout phenomenon can be easily understood by considering the positive and negative velocity amplitudes about the instantaneous velocity of the forcing flow, as shown in this diagram.

• English Language & Literature Teaching
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• v.11 no.3
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• pp.25-38
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• 2005

Postmodern American science fiction authors often dramatize the human fear and hope for the newly emerging artificial life forms. For example, Helen as an advanced artificial intelligence Richard Power's Galatea 2.2 shows that the student's memorizing efforts for exams can be useless someday. In Neal Stephenson's Snow Crash machines are liable to be infected with viruses like human bodies. In He, She and It, Piercy's parallel of an artificial human (Yod) and a mythic personification (Golem) allegorically reveals the pandora-like unpredictable effect of advanced technology. More than the mechanical entities (the diffusion and linear models for Latour), these biologically artificial entities reveal the limitations of even the fantastically idealized technology simply because the human being as the creators or impersonators of these machines are not perfect. Compared to illustrative mechanism, biologically artificial entities (Latour's transition or whirlwind models) are inherently rebellious because of their closeness to the creators. The Butler's organic environmental interaction of the Earthseed convincingly demonstrates how the wrong use of science ruins the holy earth and also how human beings survive through the right use of effective science with the aid of anthroposophy.