• Title/Summary/Keyword: diffusion mechanism

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BONDING PHENOMENON IN TRANSIENT LIQUID PHASE BONDING OF NI BASE SUPERALLOY GTD-111

  • Kang, Chung-Yun;Kim, Dae-Up;Woo, In-Soo
    • Proceedings of the KWS Conference
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    • 2002.10a
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    • pp.798-802
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    • 2002
  • Metallurgical studies on the bonded interlayer of directionally solidified Ni-base superalloy GTD111 joints were carried out during transient liquid phase bonding. The formation mechanism of solid during solidification process was also investigated. Microstructures at the bonded interlayer of joints were characterized with bonding temperature. In the bonding process held at 1403K, liquid insert metal was eliminated by well known mechanism of isothermal solidification process and formation of the solid from the liquid at the bonded interlayer were achieved by epitaxial growth. In addition, grain boundary formed at bonded interlayer is consistent with those of base metal. However, in the bonding process held at 1453K, extensive formation of the liquid phase was found to have taken place along dendrite boundaries and grain boundaries adjacent to bonded interlayer. Liquid phases were also observed at grain boundaries far from the bonding interface. This phenomenon results in liquation of grain boundaries. With prolonged holding, liquid phases decreased gradually and changed to isolated granules, but did not disappeared after holding for 7.2ks at 1473K. This isothermal solidification occurs by diffusion of Ti to be result in liquation. In addition, grain boundaries formed at bonded interlayer were corresponded with those of base metal. In the GTD-ll1 alloy, bonding mechanism differs with bonding temperature.

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An Efficient Chaotic Image Encryption Algorithm Based on Self-adaptive Model and Feedback Mechanism

  • Zhang, Xiao;Wang, Chengqi;Zheng, Zhiming
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.11 no.3
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    • pp.1785-1801
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    • 2017
  • In recent years, image encryption algorithms have been developed rapidly in order to ensure the security of image transmission. With the assistance of our previous work, this paper proposes a novel chaotic image encryption algorithm based on self-adaptive model and feedback mechanism to enhance the security and improve the efficiency. Different from other existing methods where the permutation is performed by the self-adaptive model, the initial values of iteration are generated in a novel way to make the distribution of initial values more uniform. Unlike the other schemes which is on the strength of the feedback mechanism in the stage of diffusion, the piecewise linear chaotic map is first introduced to produce the intermediate values for the sake of resisting the differential attack. The security and efficiency analysis has been performed. We measure our scheme through comprehensive simulations, considering key sensitivity, key space, encryption speed, and resistance to common attacks, especially differential attack.

Thermal Degradation Kinetics of Antimicrobial Agent, Poly(hexamethylene guanidine) Phosphate

  • Lee, Sang-Mook;Jin, Byung-Suk;Lee, Jae-Wook
    • Macromolecular Research
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    • v.14 no.5
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    • pp.491-498
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    • 2006
  • The thermal degradation of poly(hexamethylene guanidine) phosphate (PHMG) was studied by dynamic thermogravimetric analysis (TGA) and pyrolysis-GC/MS (p-GC). Thermal degradation of PHMG occurs in three different processes, such as dephosphorylation, sublimation/vaporization of amine compounds and decomposition/ recombination of hydrocarbon residues. The kinetic parameters of each stage were calculated from the Kissinger, Friedman and Flynn-Wall-Ozawa methods. The Chang method was also used for comparison study. To investigate the degradation mechanisms of the three different stages, the Coats-Redfern and the Phadnis-Deshpande methods were employed. The probable degradation mechanism for the first stage was a nucleation and growth mechanism, $A_n$ type. However, a power law and a diffusion mechanism, $D_n$ type, were operated for the second degradation stage, whereas a nucleation and growth mechanism, $A_n$ type, were operated again for the third degradation stage of PHMG. The theoretical weight loss against temperature curves, calculated by the estimated kinetic parameters, well fit the experimental data, thereby confirming the validity of the analysis method used in this work. The life-time predicted from the kinetic equation is a valuable guide for the thermal processing of PHMG.

Radionuclide Diffusion in Compacted Domestic Bentonite (압축 국산 벤토나이트 내에서 방사성 핵종의 확산이동)

  • Choi, Jong-Won;Lee, Byung-Hun
    • Journal of Radiation Protection and Research
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    • v.16 no.2
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    • pp.27-39
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    • 1991
  • The diffusion of Sr-85, Cs-137, Co-60 and Am-241 in compacted domestic bentonite was studied, using a diffusion cell unit in which diffusion took place axially from the center of cylindrical bentonite sample body. The effects of compaction density and heat-treated bentonite on diffusion were analysed. And the diffusion mechanism of radionuclide was also analysed by evaluating the measured diffusivity of anion Cl-36. The apparent diffusivities obtained for Sr-85, Cs-137, Co-60 and Am-241 were $l.07{\times}10^{-11},\;6.705{\times}10^{-13},\;l.226{\times}10^{-13}\;and\; l.310{\times}10^{-14}m^2/sec$, respectively. When the as-pressed density of bentonite increased from $1.8\;to\;2.0g/cm^3$, the apparent diffusivity of Cs-137 decreased by quarter. In the case of bentonite heat-treated to $150^{\circ}C$, no significant change in diffusivity was observed, which showed the possibility that the domestic bentonite could be used as a chemical barrier to retard the radionuclide migration at below $150^{\circ}C$. From the calculated pore and surface diffusivity, the surface diffusion due to the concentration gradient of radionuclide sorbed on the solid phase was found to dominate greatly in total transport process.

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The Impact of Message Characteristics on Online Viral Diffusion in Online Social Media Services : The Case of Twitter (트위터 메세지 특성에 따른 온라인 구전효과에 대한 분석)

  • Nam, Young-Woo;Son, In-Soo;Lee, Dong-Won
    • Journal of Intelligence and Information Systems
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    • v.17 no.4
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    • pp.75-94
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    • 2011
  • In this paper, we explore the information diffusion mechanism under social network environments by investigating the effect of message characteristics on the volume and speed of retweeting in Twitter, a popular online social media service. To this end, we select eight main keywords (i.e., '무상급식', '반값등록금', '나가수', '평창', '김연아', '박태환', '아이폰', '갤럭시') that have been popular on online social media in recent days. Each keyword represents various social aspects of Korea that recently grab people's attention such as political issues, entertainment, sports celebrities, and the latest digital products, and eventually holds distinctive message characteristics. Analyzing the frequency and velocity of retweeting for each keyword, we find that more than half of the sample messages posted on Twitter contain personal opinions for the certain keyword, but we also find that the tweets which include objective messages with hyperlink are the fastest ones when being retweeted by other followers. In overall, when being retweeted, the group of messages related to the certain keyword present distinctive diffusion patterns and speed according to message characteristics. From academic perspective, the findings in the study broaden our theoretical knowledge of information diffusion mechanism over online social media. For practitioners, the results also provide managerial implications regarding how to strategically utilize online social media for marketing communications with customers.

Implantation of Protestant Methodist in Gangwha Islands and Cultural Change (개신교 감리교의 강화도 전래와 문화변동)

  • Oak, Han Suk
    • Journal of the Korean Geographical Society
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    • v.49 no.5
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    • pp.705-715
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    • 2014
  • Acculturation is caused with contact by two different cultures. This study investigates a cultural change of Gangwha society with Hagok confusianism influenced by implantation of methodism. At early periods methodism diffused rapidly and relocated toward marine routes. Lately hierarchical diffusion and contagious diffusion was typical, centering on the Gangwha Jungang Church. This successful acception was influenced with confusianism's acculturation. One of the reason why Gangwha people could accept the Christianity was reinterpretation and selective strategy by Hagok fraction that became one of confusinism, It seemed that several cultural elements of Hagok fraction was coincided with some elements of methodism. However, A methodist church transferred by clan's shrine, which family relationship was coerced, was split into it's members. This segregation other than social intergretation influenced establishment of a or more church per each village.

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Development of System for Measuring Evaporation Rate through Porous Medium in Fuel Cells (연료전지 다공성막을 통한 수분증발량의 정량적 측정에 관한 실험적 연구)

  • Kim, Jong-Rok;Kim, Moo-Hwan;Son, Sang-Young
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.6
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    • pp.579-582
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    • 2012
  • Removing residual water in a fuel cell is a critical operational process for managing its performance and controlling its lifetime. Understanding the mechanism of water transport in fuel cells is essential for the design of the water removal process. In this study, an experimental method for measuring the water evaporation rate through a gas diffusion layer, which is a porous medium, under steady-state conditions was developed. Experimental bench tests were conducted to apply the developed method. Then, the effects of various parameters of the drying gas and the gas diffusion layer were experimentally measured. The water evaporation rate increased as the humidity of the drying gas decreased and the flow rate of the drying gas increased. In addition, a thinner gas diffusion layer yielded a higher water evaporation rate.

A Study on the Evaluation Method of Subsidence Hazard by a Diffusion Equation and its Application (확산방정식을 이용한 침하 위험도 평가 기법 및 그 적용)

  • Ryu, Dong-Woo;Synn, Joong-Ho;Song, Won-Kyong;Kim, Taek-Kon;Park, Joon-Young
    • Tunnel and Underground Space
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    • v.17 no.5
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    • pp.372-380
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    • 2007
  • Surface damage due to subsidence is an inevitable consequence of underground mining, which may be immediate or delayed for many years. The surface damage due to abandoned underground mine is observed to be two subsidence types such as simple sinkhole or trough formation to a large scale sliding of the ground from with in the subsided area. An evaluation of the risk of a subsidence occurrence is vital in the areas affected by mining subsidence. For a subsidence prediction or a risk evaluation, there has been used various methods using empirical models, profile functions, influence functions and numerical models. In this study, a simple but efficient evaluation method of subsidence hazard is suggested, which is based on a diffusion theory and uses just information about geometry of caving and topography. The diffusion model has an analogous relationship with granular model which can explain a mechanism of subsidence. The diffusion model is applied for the evaluation of subsidence hazard in abandoned metal and coal mines. The model is found to be a simple but efficient tool because it needs information of geometry of caving and gangway and the topography.

A numerical study on soot formation in ethylene diffusion flames under 1g and 0g (1g와 0g에서의 에틸렌 확산화염 내 매연 생성 특성에 관한 수치적 연구)

  • Choi, Jae-Hyuk;Park, Sang-Kyun
    • Journal of Advanced Marine Engineering and Technology
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    • v.37 no.8
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    • pp.807-815
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    • 2013
  • A numerical study on soot formation in a laminar ethylene diffusion flame at atmospheric pressure was conducted to obtain a better understanding of the effects of buoyancy on sooting flames under 0g and 1g using a gas-phase reaction mechanism and thermal and transport properties. A simple model was employed to predict soot formation, growth and oxidation with interactions between the gas phase chemistry and the soot chemistry taken into account. Results showed that the flames in 0g are much wider than that of 1g because of the thicker diffusion layer and reduction in axial velocity. The reduction in the axial velocity in 0g results in longer residence times, and resulting in greatly enhanced soot volume fraction. And, under zero-gravity, due to the lack of a buoyancy-induced instability, flame instability disappears.

A study on the grain growth mechanism in dual-phase high Cr-steel (고크롬 (α+γ) 2상강의 결정립 성장기구)

  • Wey, Myeong-Yong
    • Journal of the Korean Society for Heat Treatment
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    • v.11 no.4
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    • pp.324-332
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    • 1998
  • The grain growth characteristics of dual-phase (${\alpha}+{\gamma}$) containing high Cr-steel have investigate using ${\alpha}$-, ${\gamma}$-single phases and (${\alpha}+{\gamma}$)dual-phase of 12%Cr Steel. The heat treatment has performed at $1000-1200^{\circ}C$ for 1-100hr. The results are as follows : 1) The grain growth rate in (${\alpha}+{\gamma}$) dual phase was substantially slower than that of single grain. 2) The relation between mean grain radius $\bar{{\gamma}}$ and annealing time t is, in general, described as following equation : $$(\bar{{\gamma}})^n-(\bar{{\gamma}_o})^n=K_n{\cdot}t{\cdots}{\cdots}(1)$$ i) In the case of single phase of high Cr steel, Eq.(1) is described as $(\bar{{\gamma}})^2-(\bar{{\gamma}_o})^2=K_2{\cdot}t$ and the grain growth is controlled by boundary migration. ii) In dual phase, the grain growth needs diffusion of alloying elements because the chemical composition of ${\alpha}$- and ${\gamma}$- phases differs from each other. When the volume fraction of ${\alpha}$-, ${\gamma}$-phase was almost equal and ${\gamma}$-phase in the case of 80 and $90%{\gamma}$. Eq.(1) is described as $(\bar{{\gamma}})^3-(\bar{{\gamma}_o})^3=K_3{\cdot}t$ because the grain growth is controlled by volume diffusion iii) In the case of ${\gamma}$-rich phase (80 and $90%{\gamma}$), the grain growth of minor phase (10 and $20%{\alpha}$) is described as $(\bar{{\gamma}})^4-(\bar{{\gamma}_o})^4=K_4{\cdot}t$ because the boundary diffusion is predominent rather than volume diffusion.

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