• 제목/요약/키워드: diffusion coefficients

검색결과 539건 처리시간 0.031초

Use of Monte Carlo code MCS for multigroup cross section generation for fast reactor analysis

  • Nguyen, Tung Dong Cao;Lee, Hyunsuk;Lee, Deokjung
    • Nuclear Engineering and Technology
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    • 제53권9호
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    • pp.2788-2802
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    • 2021
  • Multigroup cross section (MG XS) generation by the UNIST in-house Monte Carlo (MC) code MCS for fast reactor analysis using nodal diffusion codes is reported. The feasibility of the approach is quantified for two sodium fast reactors (SFRs) specified in the OECD/NEA SFR benchmark: a 1000 MWth metal-fueled SFR (MET-1000) and a 3600 MWth oxide-fueled SFR (MOX-3600). The accuracy of a few-group XSs generated by MCS is verified using another MC code, Serpent 2. The neutronic steady-state whole-core problem is analyzed using MCS/RAST-K with a 24-group XS set. Various core parameters of interest (core keff, power profiles, and reactivity feedback coefficients) are obtained using both MCS/RAST-K and MCS. A code-to-code comparison indicates excellent agreement between the nodal diffusion solution and stochastic solution; the error in the core keff is less than 110 pcm, the root-mean-square error of the power profiles is within 1.0%, and the error of the reactivity feedback coefficients is within three standard deviations. Furthermore, using the super-homogenization-corrected XSs improves the prediction accuracy of the control rod worth and power profiles with all rods in. Therefore, the results demonstrate that employing the MCS MG XSs for the nodal diffusion code is feasible for high-fidelity analyses of fast reactors.

Molecular Dynamics Study of the Self-Diffusion Coefficient and Velocity Autocorrelation Function of a Polymer Molecule in Solution

  • Kang, Hong-Seok;Lee, Young-Seek;Ree, Tai-kyue
    • Bulletin of the Korean Chemical Society
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    • 제4권5호
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    • pp.223-227
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    • 1983
  • A molecular dynamic computer experiment was performed on a system of 108 particles composed of a single polymer chain and solvent molecules. The state considered was in the immediate neighborhood of the triple point of the system. The polymer itself is an analog of a freely jointed chain. The Lennard-Jones potential was used to represent the interactions between all particles except for that between the chain elements forming a bond in the polymer chain, for which the interaction was expressed by a harmonic potential. The self-diffusion coefficient and velocity autocorrelation function (VACF) of a polymer were calculated at various chain lengths $N_p$, and various interaction strengths between solvent molecules and a polymer chain element. For self-diffusion coefficients D, the Einstein relation holds good; as chain length $N_p$ increases the D value decreases, and D also decreases as ${\varepsilon}_{cs}$ (the interaction parameter between the chain element and solvent molecules) increases. The relaxation time of velocity autocorrelation decreases as ${\varepsilon}_{cs}$ increases, and it is constant for various chain lengths. The diffusion coefficients in various conditions reveal that our systems are in a free draining limit as is well known from the behavior of low molecular weight polymers, this also agrees with the Kirkwood-Riesman theory.

겔 식품의 물질전달공정 중 확산량 예측모델 및 확산계수 (Diffused Quantity Prediction Model and Diffusion Coefficient of Gel Food in the Mass Transfer Process)

  • 이원영;최용희
    • 한국식품과학회지
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    • 제23권2호
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    • pp.217-223
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    • 1991
  • Gel식품의 구조적 특성을 밝히는 일은 특수한 장치나 분석방법이 요구되어 왔으나 본 연구에서는 조작이 간편하고 확산식에 잘 맞는 농도의 해를 구할 수 있는 capillary method를 통해 확산량과 확산계수를 예측하였다. 확산량은 거리, 시간, agar% 농도를 독립변수로 하여 도시하고 추정된 몇 가지 함수식으로부터 SPSS 통계 package 중 regression program을 이용해 단순회귀시켜 R-square가 가장 높은 식을 채택하고 다시 각 독립변수에 대한 함수식을 이용해 다중회귀분석을 실시함으로써 최종 model식을 수립하였다. 기존의 확산계수 예측방법은 Fick의 제 2법칙의 해식으로부터 예측되는 것이 일반적이었으나 그 식이 난해하고 시간이 많이 걸려 본 연구에서는 좀 더 간편한 방법으로 확산계수를 구하고자 수치해석적 방법에 따라 확산계수를 예측하였으며 그 산술평균을 확산계수 D값으로 나타내었다.

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나노크기 실리카를 사용한 반도체용 액상 에폭시 수지 성형재료의 흡습성질 (Moisture Absorption Properties of Liquid Type Epoxy Encapsulant with Nano-size Silica for Semiconductor Packaging Materials)

  • 김환건
    • 반도체디스플레이기술학회지
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    • 제9권2호
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    • pp.33-39
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    • 2010
  • The moisture absorption properties such as diffusion coefficient and moisture content ratio of liquid type epoxy resin systems with the filler were investigated. Bisphenol A type and Bisphenol F type epoxy resin, Kayahard MCD as hardener and 2-methylimidazole as catalyst were used in these epoxy resin systems. The nano-sized spherical type fused silica as filler were used in order to study the moisture absorption properties of these liquid type epoxy encapsulant according to the change of filler size. The temperature of glass transition (Tg) of these epoxy resin systems was measured using Dynamic Scanning Calorimeter (DSC), and the moisture absorption properties of these epoxy resin systems according to the change of time were observed at $85^{\circ}C$ and 85% relative humidity condition using a thermo-hygrostat. The diffusion coefficients in these systems were calculated in terms of modified Crank equation based on Ficks' law. An increase of Tg and diffusion coefficient with filler size in these systems can be observed, which are attributed to the increase of free volume with Tg. The change of maximum moisture absorption ratio according to the filler size and filler content cannot be observed; however, the diffusion coefficients of these systems decreased with filler content. The diffusion via free volume is dominant in the epoxy resin systems with low nano-sized filler content; however, the diffusion with the interaction of absorption according the increase of the filler surface area is dominant in the liquid type epoxy encapsulant with high nano-sized filler content.

촉진 염화물 시험결과를 이용한 비말대 콘크리트 구조물의 내구수명 평가 (Service life evaluation in RC structure near to sea shore through accelerated chloride diffusion test)

  • 김정수;권성준
    • 한국구조물진단유지관리공학회 논문집
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    • 제23권5호
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    • pp.30-36
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    • 2019
  • 염해에 노출된 콘크리트 구조물의 내구수명을 정량적으로 평가하기 위해서는 사용 배합을 통하여 확산계수를 평가하고 이를 이용한 염화물 침투 해석이 필요하다. 본 연구에서는 비말대에 노출된 콘크리트 구조물에 대하여 촉진 확산계수를 NT BUILD 492 및 ASTM 1202를 통하여 평가하였으며, 기존의 연구를 이용하여 겉보기 확산계수를 도출하였다. 사용배합의 특성과 가장 보수적인 조건인 임계 염화물량과 표면 염화물량을 고려하였으며, Life 365 ver.2 프로그램을 이용하여 외벽 및 기둥구조의 내구수명을 평가하였다. 10년 및 15년의 Built-up period의 변화에 대해서는 내구수명은 큰 차이를 보이지 않았으며. 슬래그를 사용한 두 개의 배합에서는 높은 시간의존성 지수와 낮은 초기 염화물 확산계수로 인해 75년 이상의 높은 내구수명이 확보되었다.

GLOBAL ASYMPTOTIC STABILITY FOR A DIFFUSION LOTKA-VOLTERRA COMPETITION SYSTEM WITH TIME DELAYS

  • Zhang, Jia-Fang;Zhang, Ping-An
    • 대한수학회보
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    • 제49권6호
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    • pp.1255-1262
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    • 2012
  • A type of delayed Lotka-Volterra competition reaction-diffusion system is considered. By constructing a new Lyapunov function, we prove that the unique positive steady-state solution is globally asymptotically stable when interspecies competition is weaker than intraspecies competition. Moreover, we show that the stability property does not depend on the diffusion coefficients and time delays.

소결에 의한 산화물촉매의 표면확산계수의 측정 (Determination of Surface Diffusivities of Oxides by the Combined Sintering)

  • 문세기;유경옥;김형진
    • 한국세라믹학회지
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    • 제14권2호
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    • pp.73-77
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    • 1977
  • The surface diffusion coefficients for nickel, nickel oxide, cuppric oxide, cobalt oxide, alumina and ferric oxide have been determined at various temperatures using the sintering technique. This investigation is based on the model accounting for the sum of the contribution of volume and surface diffusion to the overall shrinkage rate during the initial stage of sintering. Simultaneous measurements of shrinkages and shrinkage rates of the materials compacts were conducted for various annealing times, the results of which were then correlated to the diffusion coefficient.

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EULER-MARUYAMA METHOD FOR SOME NONLINEAR STOCHASTIC PARTIAL DIFFERENTIAL EQUATIONS WITH JUMP-DIFFUSION

  • Ahmed, Hamdy M.
    • Journal of the Korean Society for Industrial and Applied Mathematics
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    • 제18권1호
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    • pp.43-50
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    • 2014
  • In this paper we discussed Euler-Maruyama method for stochastic differential equations with jump diffusion. We give a convergence result for Euler-Maruyama where the coefficients of the stochastic differential equation are locally Lipschitz and the pth moments of the exact and numerical solution are bounded for some p > 2.

잡음주파수특성 성형에 의한 오차확산 영상이진화 기법 (An error- diffusion halftoning technique based on noise spectrum shaping)

  • 이광기;이재천;권용무;김형곤
    • 전자공학회논문지B
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    • 제32B권11호
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    • pp.1464-1472
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    • 1995
  • In this paper, we propose an error diffusion image halftoning technique based on the noise spectrum shaping. The new technique can arbitrarily control the shape of the display error spectrum whereas conventional halftoning algorithms have been known to minimize dc errors only in which case edge information cannot be properly rendered. As a method for estimating the error diffusion coefficients, a least mean square (LMS) approach is adopted.

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염분환경하 콘크리트 경화체의 내구성에 미치는 혼합재의 영향 (I) 시멘트 경화체중에서의 Cl-이온의 확산 (Effect of Blending Materials on the Durability of Concrete (I) Diffusion of Cl-ions through Hardened Cement Paste)

  • 김남중;최상흘;정재동;한기성
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1991년도 가을 학술발표회 논문집
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    • pp.11-14
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    • 1991
  • Apparent diffusion coefficients of Cl-ions through hardened cement paste(HCP), which were partly substituted blending materials, were determined. Also, pore solution was extracted from HCP which were immersed in NaCl solution, and Cl- concentration of the solution were analyzed. Partly substitution of pozzolanic materials considerably reduced the diffusion rate for Cl-ions and Cl- concentration of pore solution. Binding capacity of Cl- is related to the content of Al2O3 and pozzolanic reactivity.

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