• Title/Summary/Keyword: diffraction parameter

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Structural, Electrical, and Optical Properties of AZO Thin Films Subjected to Rapid Thermal Annealing Temperature (급속 열처리 온도 변화에 따른 AZO 박막의 구조, 전기 및 광학적 특성)

  • Jung, Jae-Yong;Cho, Shin-Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.4
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    • pp.280-286
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    • 2010
  • We have investigated the influence of rapid thermal annealing (RTA) temperature on properties of Al-doped zinc oxide (AZO) thin films deposited on glass substrate by using radio-frequency magnetron sputtering. The RTA is performed in a nitrogen ambient in the temperature range from 300 to $600^{\circ}C$ for 1 minute in a rapid thermal annealer after growing the AZO thin films. The crystallographic structure and the surface morphology of AZO thin film are measured by using X-ray diffraction, and atomic force microscopy and scanning electron microscopy, respectively. The optical transmittance of the deposited thin films is examined in the wavelength range of 300-1100 nm, where the average transmittance is above the 90% in the visible and near-infrared regions. The optical bandgap is calculated from the Tauc's model, and it shows a significant dependence on the RTA temperature. As for the electrical properties of the thin films, the AZO thin film annealed at $400^{\circ}C$ shows the lowest electrical resistivity of $8.6{\times}10^{-3}{\Omega}cm$ and the Hall mobility of $11.3cm^2$/V-sec. These results suggest that the RTA temperature is an important parameter to influence on the structural, electrical, and optical properties of AZO thin films.

Thermal Stability of Delithiated LiCoO2-organic Electrolyte for Lithium-Ion Rechargeable Batteries (리튬이온이차전지용 LiCoO2-유기전해액의 충전상태에 따른 열적 안정성)

  • Kim, Dong-Hun;Lee, Young-Ho;Shin, Hye-Min;Chung, Young-Dong;Doh, Chil-Hoon;Jin, Bong-Soo;Kim, Hyun-Soo;Moon, Seong-In;Oh, Dae-Hui;Kim, Ki-Won
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.5
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    • pp.421-424
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    • 2007
  • Thermal behavior of $Li_{1-x}CoO_2$ has been investigated employing DSC (Differential Scanning calorimetry) and TGA (Thermogravimetry Analyzer), and the crystal parameters were calculated from XRD (X-ray diffraction).for the commercial rectangular pouch cell(1000 mAh).The cathode materials coated over aluminium foil current collector is made up of a blend consisting of active material $LiCoO_2$(size $20\;{\mu}m$, 94 wt%), conducting material super p black (SPB, 3 wt%) and binder polyvinylidene fluoride (PVDF, 3 wt%). The anode is a mix consisting of carbon (92 wt%) and PVDF(8 wt%) coated over copper foil. The cells for the experiments were first preconditioned by cycling three times and stabilized at OCV=3.0, 3.5, 4.2, 4.35 and 4.5 V. The stabilized cathode material was used for thermal and crystal parameter investigations.

An Investigation of Design Parameter and Atomization Mechanism for Air Shrouded Injectors

  • Lee, Ki-Hyung;Lee, Chang-Sik;Kim, Bong-Gyu;Jeong, Hae-Young
    • Journal of Mechanical Science and Technology
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    • v.17 no.5
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    • pp.751-757
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    • 2003
  • With increasing requirements for the less harmful exhaust emissions and the better fuel economy, the conventional injectors in gasoline engines can be replaced by the air shrouded injector in order to provide improved combustion in engine operations. To find out the optimal shape of air shrouded atomizer attached to the conventional injector nozzle, the critical design parameters such as droplet size, fuel and air inlet angles, and injection angles were investigated based on experimental analyses. To explain the characteristics of fuel atomization, these experimental approaches were carried out using a Phase Doppler Particle Analyzer (PDPA) system. The droplet sizes of injected air fuel mixture were obtained by using the beam diffraction phenomenon. In order to improve the atomization effect, the various atomizers were investigated. The Saute. Mean Diameter (SMD) measured at the predetermined locations outside the atomizer represented the performance of fuel atomization. The experimental results show that the design factors and atomization mechanism needed for developing air shrouded injectors. The suggested design parameters in this paper can be a useful reference in the early design stage.

Performance Prediction of an OWC Wave Power Plant with 3-D Characteristics in Regular Waves

  • Hong, Do-Chun;Hong, Keyyong
    • Journal of Navigation and Port Research
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    • v.36 no.9
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    • pp.729-735
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    • 2012
  • The primary wave energy conversion by a three-dimensional bottom-mounted oscillating water column (OWC) wave power device in regular waves has been studied. The linear potential boundary value problem has been solved following the boundary matching method. The optimum shape parameters such as the chamber length and the depth of the front skirt of the OWC chamber obtained through two-dimensional numerical tests in the frequency domain have been applied in the design of the present OWC chamber. Time-mean wave power converted by the OWC device and the time-mean second-order wave forces on the OWC chamber structure have been presented for different wave incidence angles in the frequency-domain. It has been shown that the peak period of $P_m$ for the optimum damping parameter coincides with the peak period of the time.mean wave drift force when ${\gamma}=0$.

Marina Development Impact on the Tranquility of Small Coast Harbor

  • Lee, Dong-Hyun;Lee, Joong-Woo;An, Hyo-Jae;Kim, Kang-Min
    • Journal of Navigation and Port Research
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    • v.38 no.6
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    • pp.673-681
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    • 2014
  • Due to the increased demand for safety and security requirements on the port infrastructure, the harbor tranquility is one of the important parameter in the mooring basin of harbor. It relates keenly to berthing/unberthing and cargo handling works but also it is an important indicator to get the minimum water area as the safe refuge. Hupo harbor is a national coastal harbor located in east coast of Korea and a development plan for a new marina near the entrance is being carried out including berth layouts, breakwater extensions, 300m marina berths, dredging and land reclamation works. The new plan will impact on calmness of the existing port. Therefore, it is necessary to analyze in complex the variation of wave height and direction caused by wave refraction, diffraction, shoaling and reflection from the incident waves from outside the harbor. In order to check the calmness inside a harbor, the numerical models are being used currently need fundamental reviews according to the difference of results which depend on their respective features. In this study, hence, it was introduced the validity of numerical models by comparing the computational results with the hydraulic model experiment. The current investigations contribute to the existing development recommendations and provide further solutions for port planning.

Effect of Ar Flow Ratio on the Characteristics of Ga-Doped ZnO Grown by RF Magnetron Sputtering (마그네트론 스퍼터를 이용한 Ar 가스 유량 조절에 따른 GZO의 특성 변화)

  • Jeong, Youngjin;Lee, Seungjin;Son, Changsik
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.62.1-62.1
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    • 2011
  • The structural, optical, and electrical properties of Ga-doped ZnO (GZO) thin films on glass substrates grown by radio-frequency(RF) magnetron sputtering were investigated. The flow ratio of Ar was varied as a deposition parameter for growing high-quality GZO thin films. The structural properties and surface morphologies of GZO were characterized by the X-ray diffraction. To analyze the optical properties of GZO, the optical absorbance was measured in the wavelength range of 300-1100 nm by using UV-VIS spectrophotometer. The optical transmittance, absorption coefficient, and optical bandgap energy of GZO thin films were calculated from the measured data. The crystallinity of GZO thin films is improved and the bandgap energy increases from 3.08 to 3.23eV with the increasing Ar flow ratio from 10 to 100 sccm. The average transmittance of the films is over 88% in the visible range. The lowest resistivity of the GZO is $6.215{\times}10^{-4}{\Omega}{\cdot}cm$ and the hall mobility increases with the increasing Ar flow ratio. We can optimize the characteristics of GZO as a transparent electrode for thin film solar cells by controlling Ar flow ratio during deposition process.

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Crystal structures and Magnetic properties of Co-($Al_{1-X}Fe_X$) alloys (Co-($Al_{1-X}Fe_X$) 합금계의 결정구조 및 자기적 성질)

  • Koh, Kowan-Young;Yun, Seok-Gil
    • Korean Journal of Materials Research
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    • v.2 no.2
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    • pp.143-150
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    • 1992
  • Crystal structures and magnetic properties of annealed Co-(Al-Fe) alloys have been investigated. Annealed specimens showed superparamagnetism when x=0.05 and ferromagnetism when $x{\geq}0.10$. Magnetization increased as x increased. X-ray diffraction data revealed that specimens were single-phase in B2(CsCl) structure with constant lattice parameter $2.87{\AA}$. The experimental results were analized on the point of view of the local environmental effect of magnetic atoms.

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Growth and characterization of YBa2Cu3O7-$\delta$ thin films using pulsed laser (펄스레이저 증착에 의한 YBa2Cu3O7-$\delta$박막의 성장과 특성분석)

  • Chung, J.K.;Ko, R.K.;Choi, S.J.;Song, K.J.;Park, C.
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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    • 2003.02a
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    • pp.117-119
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    • 2003
  • YBa$_2$Cu$_3$O$_{7-{\delta}}$(YBCO) high temperature superconducting thin films were grown on SrTiO$_3$single crystal substrates by pulsed laser deposition(PLD). The texture and lattice parameter of the YBCO films were analysed using the GADDS (general area detector diffraction system) which enables XRD analyses to be done faster and with fewer sample movement than with the XRD system with point detector. The XRD results of the films grown in different deposition conditions are reported together with the SEM microstructure analysis results.ysis results.

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Effect of Process Parameter on Piezoelectric Properties of PZT Thin films (PZT 박막의 압전특성에 미치는 공정변수의 효과)

  • 김동국;지정범
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.12
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    • pp.1060-1064
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    • 2002
  • We have studied the effect of crystallization temperature, composition and film thickness, which are the fundamental processing parameters of lead zirconate titanate(PZT) thin film fabrication, in the respect of the piezoelectric properties by our pneumatic loading method(PLM). A great deal of research has been done in the field of characterization for piezoelectric thin films after the first report on the measurement for the piezoelectric coefficient of thin films in 1990. Even though the piezoelectric properties of thin films are very critical factors in the micro-electro mechanical system(MEMS) and thin film sensor devices, a few reports for the piezoelectric characterization are provided for the last decade unlikely the bulk piezoelectric devices. We have found that the piezoelectric properties of thin films are improved as the increase of crystallization temperature up to 750$\^{C}$ and this behavior can be also explained by the analysis of dielectric polarization hysteresis loop, X-ray diffraction and scanning electron microscopy. The effect of Zr/Ti composition has been also studied. This gives us the fact that the maximum piezoelectricity is found near Morphotropic Phase Boundary(MPB) as bulk PZT system does.

Effects of ion irradiation on microstructure and properties of zirconium alloys-A review

  • Yan, Chunguang;Wang, Rongshan;Wang, Yanli;Wang, Xitao;Bai, Guanghai
    • Nuclear Engineering and Technology
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    • v.47 no.3
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    • pp.323-331
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    • 2015
  • Zirconium alloys are widely used in nuclear reactors as structural materials. During the operation, they are exposed to fast neutrons. Ion irradiation is used to simulate the damage introduced by neutron irradiation. In this article, we briefly review the neutron irradiation damage of zirconium alloys, then summarize the effect of ion irradiation on microstructural evolution, mechanical and corrosion properties, and their relationships. The microstructure components consist of dislocation loops, second phase precipitates, and gas bubbles. The microstructure parameters are also included such as domain size and microstrain determined by X-ray diffraction and the S-parameter determined by positron annihilation. Understanding the relationships of microstructure and properties is necessary for developing new advanced materials with higher irradiation tolerance.