• 한국세라믹학회지
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• 제46권3호
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• pp.242-248
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• 2009

Forsterite is a crystalline magnesium silicate with chemical formula $Mg_2SiO_4$, which has extremely low electrical conductivity that makes it an ideal substrate material for electronics. In this study, forsterite precursors were synthesized with magnesium silicate gels from the mixture of magnesium nitrate solution and various sodium silicate solution by the geopolymer technique. Precursors and heattreated powders were characterized by thermogravimetrical differential thermal analyzer(TG-DTA), X-ray diffractometer(XRD), scanning electron microscopy(SEM), Si magic angle spinning nuclear magnetic resonance(MAS-NMR), transmission electron microscopy(TEM). As the result of analysis about the crystallization behavior by DTA, the synthesized precursors were crystallized in the temperature range of $700^{\circ}C$ to $900^{\circ}C$. The XRD results showed that the gel composition began to crystallize at various temperature. Also, it was found that the sodium orthosilicate based precursors(named as 'FO') began to crystallize at above $550^{\circ}C$. The FO peaks were much stronger than sodium silicate solution based precursors(named as 'FW'), sodium metasilicate based precursors(named as 'FM') at $800^{\circ}C$. TEM investigation revealed that the 100nm particle sized sample was obtained from FO by heating up to $800^{\circ}C$.

• Carbon letters
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• 제12권4호
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• pp.229-235
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• 2011

Isotactic polyacrylonitrile (PAN) with triad isotacticity of 0.53, which was determined by $^{13}C$ NMR, using dialkylmagnesium as an initiator, was successfully synthesized. Isothermal treatment of iso-PAN was conducted in air at 200, 220, 250 and $280^{\circ}C$. Structural evolutions and chemical changes were studied with Fourier transformation infrared and wide-angle X-ray diffraction during stabilization. A new parameter $CNF={I_{2240cm}}^{-1}/ ({I_{1595cm}}^{-1}+f^*{I_{1595cm}}^{-1})$ was defined to evaluate residual nitrile groups. Crystallinity and crystal size were calculated with X-ray diffraction dates. The results indicated that the nitrile groups had partly converted into a ladder structure as stabilization proceeded. The rate of reaction increased with treatment temperature; crystallinity and crystal size decreased proportionally to pyrolysis temperature. The iso-conversional method coupled with the Kissinger and Flynn-Wall-Ozawa methods were used to determine kinetic parameters via differential scanning calorimetry analysis with different heating rates. The active energy of the reaction was 171.1 and 169.1 kJ/mol, calculated with the two methods respectively and implied the sensitivity of the reaction with temperature.

• 한국산업융합학회 논문집
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• 제3권1호
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• pp.69-75
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• 2000

Multichip packages are comprised of dissimilar materials which expand at different rates on heating. The differential expansion must be accommodated by the various structural elements of the package. A types of heat exposures occur operation cycles. This study presents a finite element analysis simulation of flip-chip among multichip. The effects of geometries and material properties on the reliability were estimated during the analysis of temperature and thermal stress of flip-chip. From the results, it could be obtained that the more significant parameters to the reliability of flip-chip arc chip power cycle, heat convection and height of solder bump.

• Journal of Astronomy and Space Sciences
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• 제11권1호
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• pp.21-30
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• 1994

VV Cep-type long period spectroscopic-eclipsing binary AZ Cas has been observed for five years, 1985 Oct~1990 Feb, UBV at the Ilsan Station of Yonsei University Observatory. A total of 431 observations (U=129, B=142 and V=160) are made for 86 nights. Instrumental differential UBV and B-V light curves made with these observations cover phases nearly a half of one period. There is no appreciable light variation in V but in other two passbands a gradual decrease of the brightness is clearly noticed. The loss of light in B resulted in a reddening in $\Delta(B-V)$ by + 0.06 at phases between 0.4~0.5 as compared with that of at phase ~0.1. This intrinsic reddening arouses a question why at the orbital phase of the transit of a hot star in front of a cool M supergiant the heating of the facing hemisphere of M supergiant by the strong radiation from the B stat is absent. With regard to this unusual situation we propose a hypothesis that a large amount of gas stream of low temperature ejected from the surface of M supergiant component towards the B star dominates the brightness of B star and the reflection effect.

• 한국세라믹학회지
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• 제28권2호
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• pp.160-166
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• 1991

Microstructure and phase changes during the sintering of ZnO varistors were studied in ZnO-Bi2O3-CoO-Sb2O3 and ZnO-Bi2O3-CoO-Sb2O3-Cr2O3 systems using acanning electron microscopy (SEM) with an energy dispersive X-ray analysis (EDAX), X-ray diffraction (XRD) and differential thermal analysis (DTA). The spinel phase and the Bi2O3 phase were formed by the decomposition of the pyrochlore phase during heating. The spinel particles (2-4$\mu\textrm{m}$), which were formed both along ther grain boundaries and within the ZnO grain, were always found near the pyrochlore phase. Intergranular phases (Bi2O3 and pyrochlore) were precipitated from the liquid phase during cooling. The Bi2O3 phases were located at the triple (or multiple) point of the ZnO grains. Cr2O3 played a role in decreasing the formation temperature of the spinel phase and Bi2O3 phase during sintering, and inhibited the grain growth.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2010년도 하계학술대회 논문집
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• pp.58-58
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• 2010

We designed and synthesized DFPCE blue emitting materials by Mc Murry coupling reaction in order to improve the device efficiency and stability. The structure was confirmed by $^1H$-NMR. The physical properties were characterized by differential scanning calorimetry, thermogravimetric analysis, UV-vis, photoluminescence spectrum and cyclic voltammetry. The decomposition temperature of the material, which correspond to a 5% weight loss upon heating, is $513.58^{\circ}C$. The photoluminescence (PL) spectrum of DFPCE exhibited blue emission at 425 nm in chloroform solution and 462 nm in film.

• 한국생산제조학회지
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• 제22권3_1spc호
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• pp.615-621
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• 2013

A blind system for window glass has been designed and manufactured as a CapStone Design project at Seoul National University of Science and Technology. This system automatically controls the interior illuminance to maintain a uniform temperature. The aim of this project was to support an air conditioning system and heating equipment to maintain a good indoor environment. Proportional integral differential (PID) control using cadmium sulfide (CdS) sensors was applied to control it. Polaroid film was attached to the new blind system to reflect sunlight. It was found that the system had the potential to reduce energy consumption and may be used with a building energy management system (BEMS).

• 한국태양에너지학회 논문집
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• 제31권2호
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• pp.143-147
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• 2011

On-off differential controller is one of the very important component which has influence on the system performance of the solar hot water system. In this study, it was analysed the influence of "on-off" setting temperature on the system efficiency and the electrical consumption by circulation pump. This study was performed by computer simulation using TRNSYS program. The simulation system was developed in this study was verified the its reliability by the experimental results.

• Advances in nano research
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• 제16권6호
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• pp.579-591
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• 2024

This study explained the effects of radiation, magnetic field, and nanoparticle shape on the peristaltic flow of an Upper-Convected Maxwell nanofluid through a porous medium in an asymmetric channel for a better understanding of cooling and heating mechanisms in the presence of magnetic fields. These phenomena are modeled mathematically as a system of non-linear differential equations, that are solved under long-wavelength approximation and low Reynolds number conditions using the perturbation method. The results for nanofluid and temperature described the behavior of the pumping characteristics during their interaction with (the vertical position, thermal radiation, the shape of the nanoparticle, and the magnetic field) analytically and explained graphically. Also, the combined effects of thermal radiation parameters and some physical parameters on pressure rise, pressure gradient, velocity, and heat distribution are pointed out. Qualitatively, a reverse velocity appears with combined high radiation and Grashof number or combined high radiation and low volume flow rate. At high radiation, the spherical nanoparticle shape has the greatest effect on heat distribution.

• 에너지공학
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• 제26권2호
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• pp.64-72
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• 2017

중동지역 환경에 적합한 70 W급 LED 조명등의 성능분석을 집중변수모델을 이용하여 수행하였다. LED 조명등은 발열기판, 히프파이프, 방열판으로 구성된다. LED 조명등을 4개의 물체로 구분하고, 각각에 대해 에너지평형을 적용하여, 4개의 연립 비선형미분방정식 형태의 집중변수모델을 수립하였다. 연립 방정식의 해는 Runge-Kutta법을 이용하여 구하였다. 집중변수모델의 대류열전달계수는 다차원해석을 통하여 구하였으며, 실험결과와 비교한 결과, 발열기판은 $1.5^{\circ}C$, 상부방열판에서 $1.8^{\circ}C$의 오차를 가지며, 상대오차는 약 0.6 %임을 확인하였다. 이 모델을 이용하여 대기온도가 $55^{\circ}C$인 정상 운전조건, 태양광만 주어질 때의 조건, 태양광이 주어진 상태에서의 비정상 운전조건, 상부방열판이 없는 경우 등에 대한 온도분포분석을 수행하였다.