• Title/Summary/Keyword: differential mechanism

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Cure Konetics and Mechanism of DGEBA-MDA-Malononitrile System (Malononitrile로 개질된 DGEBA-MDA계의 경화반응 속도론 및 반응 메카니즘)

  • Im, Seong-Su;Jo, Seong-U;Yu, Hui-Yeol;Sim, Mi-Ja;Kim, Sang-Uk
    • Korean Journal of Materials Research
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    • v.3 no.3
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    • pp.215-222
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    • 1993
  • Malononitrile(MN) as a reactive additive was added to Diglycidyl ether of bisphenol A (DGEBA)/Methylene dianiline (MDA) system in order to modify a thermosetting epoxy resin. Cure ki. netics and cure mechanism of this modified system were investigated by using DSC(differential scanning calorimetry) and FT-IR(fourier transform infrared spectrometry). Cure kinetics gave an information that the DGEBA/MDA system modified with MN should cure at over $110^{\circ}C$ after curing at about $80^{\circ}C$ for the complete curing. The activation energy of the first cure was nearly constant and that of the second cure was increased as the MN content was increased. Cure mechanism for the system was investigated with the samples cured every $30^{\circ}C$, from $80^{\circ}C$ to $170^{\circ}C$, for Ihr. It was known that the cure reactions of the epoxy-diamine system were composed of PA -E, SA - E and E-OH reactions. Beside these three reactions, in the DGEBA/MDA/MN system PA-CN and CN-OH reaction was found.

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A parametric study of settlement and load transfer mechanism of piled raft due to adjacent excavation using 3D finite element analysis

  • Karira, Hemu;Kumar, Aneel;Hussain Ali, Tauha;Mangnejo, Dildar Ali;Mangi, Naeem
    • Geomechanics and Engineering
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    • v.30 no.2
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    • pp.169-185
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    • 2022
  • The urbanization and increasing rate of population demands effective means of transportation system (basement and tunnels) as well as high-rise building (resting on piled foundation) for accommodation. Therefore, it unavoidable to construct basements (i.e., excavation) nearby piled foundation. Since the basement excavation inevitably induces soil movement and stress changes in the ground, it may cause differential settlements to nearby piled raft foundation. To understand settlement and load transfer mechanism in the piled raft due to excavation-induced stress release, numerical parametric studies are carried out in this study. The effects of excavation depths (i.e., formation level) relative to piled raft were investigated by simulating the excavation near the pile shaft (i.e., He/Lp=0.67), next to (He/Lp=1.00) and below the pile toe (He/Lp=1.33). In addition, effects of sand density and raft fixity condition were investigated. The computed results have revealed that the induced settlement, tilting, pile lateral movement and load transfer mechanism in the piled raft depends upon the embedded depth of the diaphragm wall. Additional settlement of the piled raft due to excavation can be account for apparent loss of load carrying capacity of the piled raft (ALPC). The highest apparent loss of piled raft capacity ALPC (on the account of induced piled raft settlement) of 50% was calculated in in case of He/Lp = 1.33. Furthermore, the induced settlement decreased with increasing the relative density from 30% to 90%. On the contrary, the tilting of the raft increases in denser ground. The larger bending moment and lateral force was induced at the piled heads in fixed and pinned raft condition.

Fungal Metabolism of Environmentally Persistent Compounds: Substrate Recognition and Metabolic Response

  • Wariishi, Hiroyuki
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.5 no.6
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    • pp.422-430
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    • 2000
  • Mechanism of lignin biodegradation caused by basidiomycetes and the history of lignin biodegradation studies were briefly reviewed. The important roles of fungal extracellular ligninolytic enzymes such as lignin and manganese peroxidases (LiP and MnP) were also summarized. These enzymes were unique in their catalytic mechanisms and substrate specificities. Either LiP or MnP system is capable of oxidizing a variety of aromatic substrates via a one-electron oxidation. Extracellular fungal system for aromatic degradation is non-specific, which recently attracts many people working a bioremediation field. On the other hand, an intracellular degradation system for aromatic compounds is rather specific in the fungal cell. Structurally similar compounds were prepared and metabolized, indicating that an intracellular degradation strategy consisted of the cellular systems for substrate recognition and metabolic response. It was assumed that lignin-degrading fungi might be needed to develop multiple metabolic pathways for a variety of aromatic compounds caused by the action of non-specific ligninolytic enzymes on lignin. Our recent results on chemical stress responsible factors analyzed using mRNA differential display techniques were also mentioned.

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Review of the Usefulness of Inhibitors for Reducing the Corrosion of Iron in $H_2S$ Environments

  • Kim, Han-Sang;Yoon, Eun-Sub
    • Corrosion Science and Technology
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    • v.8 no.1
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    • pp.21-26
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    • 2009
  • The influence of $H_2S$ on the corrosion of iron and the corrosion prevention mechanism of an inhibitor was investigated with a differential capacitance measurement and a weight loss measurement method. The results show that $H_2S$ accelerates both the anodic iron dissolution and the cathodic hydrogen evolution in most cases. However, $H_2S$ acts as an inhibitor of the corrosion of iron under certain special conditions. An EIS method is proposed to explain the ability of inhibitors.

A Study on the Improvement of Numeric Integration Algorithm for the Dynamic Behavior Analysis of Flexible Machine Systems (탄성기계 시스템의 동적 거동 해석을 위한 수치 적분 알고리즘 개선에 관한 연구)

  • Kim, Oe-Jo;Kim, Hyun-chul
    • Journal of the Korean Society of Industry Convergence
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    • v.4 no.1
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    • pp.87-94
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    • 2001
  • In multibody dynamics, differential and algebraic equations which can satisfy both equation of motion and kinematic constraint equation should be solved. To solve this equation, coordinate partitioning method and constraint stabilization method are commonly used. The coordinate partitioning method divides the coordinate into independent and dependent coordinates. The most typical coordinate partitioning method arc LU decomposition, QR decomposition, projection method and SVD(sigular value decomposition).The objective of this research is to find a efficient coordinate partitioning method in flexible multibody systems and a hybrid decomposition algorithm which employs both LU and projection methods is proposed. The accuracy of the solution algorithm is checked with a slider-crank mechanism.

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DIFFERENTIAL EXPRESSION OF ORNITHINE DECARBOXYLASE AND HA-RAS CELLULAR ONCOGENE DURING DEVELOPMENT OF THE FEMALE RAT

  • Baik, M.G.;Park, C.S.
    • Asian-Australasian Journal of Animal Sciences
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    • v.7 no.1
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    • pp.119-124
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    • 1994
  • Experiments were performed to determine age-associated changes in ornithine decarboxylase (ODC) gene and Ha-ras cellular oncogene expression in tissues of female rats. In the kidney, ODC mRNA levels did not show age-associated changes, while ODC enzyme activities were decreased with advancing age from 3 to 10 months. These results suggest that post-transcriptional mechanism (s) are involved in the age-dependent decrease in renal ODC enzyme activity. In addition, we found no correlation between testosterone-induced renal ODC expression and DNA methylation pattern. Ha-ras mRNA levels in brain decreased as animals aged from 3 to 6 months, while renal Ha-ras mRNA levels were not influenced by age. Results demonstrate the age-dependent expression of Ha-ras in a tissue-specific manner.

The Anti-Inflammatory Effects of Phytochemicals by the Modulation of Innate Immunity

  • Youn, Hyung-Sun
    • Biomedical Science Letters
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    • v.18 no.3
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    • pp.181-192
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    • 2012
  • Toll-like receptors (TLRs) induce innate immune responses that are essential for host defense against invading microbial pathogens. In general, TLRs have two major downstream signaling pathways; myeloid differential factor 88 (MyD88) and Toll/IL-1R domain-containing adaptor inducing IFN-${\beta}$ (TRIF) leading to the activation of NF-${\kappa}B$ and IRF3. Numerous studies demonstrated that certain phytochemicals possessing anti-inflammatory effects inhibit NF-${\kappa}B$ activation induced by pro-inflammatory stimuli including lipopolysaccharide and tumor necrosis factor-${\alpha}$ ($TNF{\alpha}$). However, the direct molecular targets for such anti-inflammatory phytochemicals are not fully identified. In this paper, we will discuss about the molecular targets of phytochemicals in TLRs signaling pathways. These results present a novel anti-inflammatory mechanism of phytochemicals in TLRs signaling.

Vibration Control of an Axially Moving String: Inclusion of the Dynamics of Electro Hydraulic Servo System

  • Kim, Chang-Won;Hong, Keum-Shik;Kim, Yong-Shik
    • 제어로봇시스템학회:학술대회논문집
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    • 2003.10a
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    • pp.342-347
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    • 2003
  • In this paper, an active vibration control of a translating tensioned string with the use of an electro-hydraulic servo mechanism at the right boundary is investigated. The dynamics of the moving strip is modeled as a string with tension by using Hamilton’s principle for the systems with changing mass. The control objective is to suppress the transverse vibrations of the strip via boundary control. A right boundary control law in the form of current input to the servo valve based upon the Lyapunov’s second method is derived. It is revealed that a time-varying boundary force and a suitable passive damping at the right boundary can successfully suppress the transverse vibrations. The exponential stability of the closed loop system is proved. The effectiveness of the control laws proposed is demonstrated via simulations.

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Selection of Differentially Expressed Clones during Bombyx mori Embryogenesis

  • Hwang, Jae-Sam;Jeong, Go-hyun;Kim, Sung-Kuk;Seong, Su-Il;Kang, Seok-Woo;Goo, Tae-Won;Yun, Eun-Young;Park, Kwang-Ho
    • Proceedings of the Korean Society of Sericultural Science Conference
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    • 2003.10a
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    • pp.93-94
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    • 2003
  • To understand the molecular mechanism of diapause determination and termination during embyogenesis of the silkworm, Bombyx mori, mRNA from maintained or activated eggs of diapause was compared using differential expression. (omitted)

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A numerical method for dynamic analysis of cam-follower mechanism including impact, separation and elastic deformation (충격분리 및 탄성변형을 포함한 캠-종동절 기구의 동역학적 해석을 위한 수치해석적 방법)

  • Lee, Gi-Su
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.22 no.3
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    • pp.519-528
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    • 1998
  • A numerical method is presented for the dynamic analysis of cam and follower. Contact and separation between the cam and the follower are analyzed by imposing dynamic contact condition. The correct solution is obtained without spurious oscillation by imposing the velocity and acceleration constraints as well as the displacement constraint on the possible contact point. The constraints are satisfied by iteratively reducing the constraint errors toward zero, and a simple time integration of ordinary differential equation is employed for the solution of the equation of motion. The solution procedure associated with the iterative scheme is presented, and numerical simulations are conducted to demonstrate the accuracy of the solution.