• Journal of the Korean Chemical Society
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• v.21 no.3
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• pp.219-224
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• 1977

The free radical initiated copolymerization of vinyl acetate (VAc) and bis(${\beta}$-chloroethyl)vinylphosphonate (BCVP) was studied. The monomer reactivity ratios for the monomer pair determined at $50^{\circ{C$ using benzoyl peroxide as an initiator are: $r_1 (VAc) = 0.33,\;r_2 (BCVP) = 0.47$ The values of Alfrey-Price's Q and e for the bis(${\beta}$-chloroethyl)vinylphosphonate were calculated to be 0.06 and 1.1, respectively. The statistical analyses for the monomer sequence distribution and the mean sequence length show that the copolymer formed from these two monomers are of fairly alternating tendency. Differential thermal analysis showed that thermal stability of the copolymers decreases as the content of BCVP in the copolymer increases.

• Smart Structures and Systems
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• v.18 no.2
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• pp.355-374
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• 2016

This paper presents and compares a one-dimensional (1D) bending theory for piezoelectric thin beam-type structures with resistive-inductive electrodes to ANSYS$^{(R)}$ three-dimensional (3D) finite element (FE) analysis. In particular, the lateral deflections and vibrations of slender piezoelectric beams are considered. The peculiarity of the piezoelectric beam model is the modeling of electrodes in such a manner that is does not fulfill the equipotential area condition. The case of ideal, perfectly conductive electrodes is a special case of our 1D model. Two-coupled partial differential equations are obtained for the lateral deflection and for the voltage distribution along the electrodes: the first one is an extended Bernoulli-Euler beam equation (second-order in time, forth order in space) and the second one the so-called Telegrapher's equation (second-order in time and space). Analytical results of our theory are validated by 3D electromechanically coupled FE simulations with ANSYS$^{(R)}$. A clamped-hinged beam is considered with various types of electrodes for the piezoelectric layers, which can be either resistive and/or inductive. A natural frequency analysis as well as quasi-static and dynamic simulations are performed. A good agreement between the extended beam theory and the FE results is found. Finally, the practical relevance of this type of electrodes is shown. It is found that the damping capability of properly tuned resistive or resistive-inductive electrodes exceeds the damping performance of beams, where the electrodes are simply linked to an optimized impedance.

• Journal of Adhesion and Interface
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• v.3 no.4
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• pp.27-36
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• 2002

The organic/organic core-shell composite polymer for nonwomen binder were synthesized by stage polymerization of methyl methacrylate and styrene with ammonium persulfate after preparing monomer pre-emulsion in the presence of anionic surfactant. We study the effect of initiator concentration, $0.79{\times}10^{-3}{\sim}3.16{\times}10^{-3}mol/L$ for core polymer, $2.0{\times}10^{-4}{\sim}8.0{\times}10^{-4}mol/L$ for shell polymer, sulfactant concentration, $1.45{\times}10^{-5}{\sim}4.15{\times}10^{-5}mol/L$ for core polymer, $0.73{\times}10^{-5}{\sim}2.91{\times}10^{-5}mol/L$ for shell polymer on core-shell structure of polymethyl methacrylate/polystyrene and polystyrene/polymethyl methacrylate. Emulsion stability was major test method, particle size and particle size distribution were measured using particle size analyzer and the morphology of the core-shell composite polymer was determined using transmission electron microscope, glass temperature was also measured using differential scanning calorimeter.

• Geomechanics and Engineering
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• v.5 no.1
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• pp.17-36
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• 2013

Settlement of the piled raft can be estimated even after years of completing the construction of any structure over the foundation. This study is devoted to carry out numerical analysis by the finite element method of the consolidation settlement of piled rafts over clayey soils and detecting the dissipation of excess pore water pressure and its effect on bearing capacity of piled raft foundations. The ABAQUS computer program is used as a finite element tool and the soil is represented by the modified Drucker-Prager/cap model. Five different configurations of pile groups are simulated in the finite element analysis. It was found that the settlement beneath the piled raft foundation resulted from the dissipation of excess pore water pressure considerably affects the final settlement of the foundation, and enough attention should be paid to settlement variation with time. The settlement behavior of unpiled raft shows bowl shaped settlement profile with maximum at the center. The degree of curvature of the raft under vertical load increases with the decrease of the raft thickness. For the same vertical load, the differential settlement of raft of ($10{\times}10m$) size decreases by more than 90% when the raft thickness increased from 0.75 m to 1.5 m. The average load carried by piles depends on the number of piles in the group. The groups of ($2{\times}1$, $3{\times}1$, $2{\times}2$, $3{\times}2$, and $3{\times}3$) piles were found to carry about 24%, 32%, 42%, 58%, and 79% of the total vertical load. The distribution of load between piles becomes more uniform with the increase of raft thickness.

• The Journal of Korean Academy of Prosthodontics
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• v.31 no.3
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• pp.411-422
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• 1993

Osseointegrated dental implants are now an accepted part of the prosthetic treatment of fully and partially edentulous patients. Clinical studies have shown that osseointegrated dental implants may successfully be used as abutments for prosthetic rehabilitations, and that the supporting tissue can be kept in a stable and healthy clinical state for prolonged periods of time. The purpose of this study was to look for differences in the distribution in the bacterial morphotypes around natural teeth and osseointegrated dental implants. The subgingival plaque around natural teeth and implants was analysed by means of differential phase-contrast microscopy. In addition, clinical indices used to analyse natural teeth condition were used to compare the condition of natural teeth and implants. The results were as follows : 1. In implants of partially edentulous patients, the plaque index, sulcus bleeding index(P<0.05), pocket depth(P<0.01) were greater than natural teeth. 2. Gingival crevicular fluid volume was not significantly different between natural teeth and implants. 3. In implants of fully edentulous patients, the plaque index was greater than natural teeth(P<0.01) and implants of partially edentulous patients(P<0.05), but sulcus bleeding index was not significantly different. 4. In partially edentulous patient, coccoid cell proportion was greater in implants than natural teeth (P<0.05). 5. In implants of fully edentulous patients, coccid cell proportion was even greater than implants of partially edentulous patients(P<0.05) and natural teeth(P<0.01). 6. Among three groups, the proportions of non-motile rods, motile rods, spirochetes and others were not significantly different. 7. The proportion of motile bacteria was not significantly different among three group.

• Development and Reproduction
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• v.24 no.3
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• pp.177-185
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• 2020

Although many aquaporin (AQP) transcripts have been demonstrated to express in the female reproductive tract, the defined localizations and functions of AQP subtype proteins remain unclear. In this study, we investigated the expression of AQP1, AQP3, AQP5, AQP6, and AQP9 proteins in female reproductive tract of mouse and characterized their precise localizations at the cellular and subcellular levels. Immunofluorescence analyses for AQP1, AQP3, AQP6, and AQP9 showed that these proteins were abundantly expressed in female reproductive tract and that intense immunoreactivities were observed in mucosa epithelial cells with a subtype-specific pattern. The most abundant aquaporin in both vagina and uterine cervix was AQP3. Each of AQP1, AQP3, AQP6, and AQP9 exhibited its distinct distribution in stratified squamous or columnar epithelial cells. AQP9 expression was predominant in oviduct and ovary. AQP1, AQP3, AQP6, and AQP9 proteins were mostly seen in apical membrane of ciliated epithelial cells of the oviduct as well as in both granulosa and theca cells of ovarian follicles. Most of AQP subtypes were also expressed in surface epithelial cells and glandular cells of endometrium in the uterus, but their expression levels were relatively lower than those observed in the vagina, uterine cervix, oviduct and ovary. This is the first study to investigate the expression and localization of 5 AQP subtype proteins simultaneously in female reproductive tract of mouse. Our results suggest that AQP subtypes work together to transport water and glycerol efficiently across the mucosa epithelia for lubrication, proliferation, energy metabolism and pH regulation in female reproductive tract.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.6
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• pp.1063-1072
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• 2000

Kinetic tests on pyrolysis of the mixture of waste automobile lubricating oil and polystyrene were carried out with thermogravimetric technique at the heating rates of 0.5, 1.0, $2.0^{\circ}C/min$ in a stirred batch reactor. The activation energy and the reaction order were determined at conversions of 1 to 100% using differential method. The mixture of waste automobile lubricating oil and polystyrene was pyrolyzed at lower temperature rather than waste automobile lubricating oil and polystyrene. respectively. Also, the thermal decomposition took place in two broad reaction steps. The pyrolyzed oil of mixture represented high selectivity of styrene monomer and dimer like that of polystyrene pyrolyzed products.

• Tunnel and Underground Space
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• v.26 no.6
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• pp.493-507
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• 2016

Scaled model tests were performed to investigate the stability of a foundation located above limestone cavities. Cavity shape was assumed to be an ellipse having 1/3 for the ratio of minor to major axis lengths. 12 different test models which have various depths, locations, inclinations, sizes and numbers of cavity were experimented and they were classified into 5 different groups. Crack initiation pressure, maximum pressure, deformation behaviors, failure modes and subsidence profiles of test models were obtained, and then the influences of those parameters on the foundation stability were investigated. No cavity model showed a general shear failure, whereas the models including various cavities showed the complicated three different failure modes which were only punching failure, both punching and shear failures, and double shear failure. The stability of foundation was found to be decreased as the cavity was located at shallower depth, the size and number of cavity were increased. Differential settlements appeared when the cavity was located under the biased part of foundation. Furthermore, subsidence profiles were found to depend on the distribution of underground cavities.

• Polymer(Korea)
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• v.29 no.1
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• pp.8-13
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• 2005

Polystyrene (PS) particles containing the phase change material (PCM) were synthesized by miniemulsion polymerization. The polymer particles prepared with different parameters were investigated in terms of average particle size, particle distribution, and latent heat storage of encapsulated paraffin wax (PW) as PCM. The morphology and particle features of PS particles were analyzed by scanning electron microscope and particle size analyzer, respectively. As a result, the diameters of PS particles were adjusted with manufacturing conditions. The stable and spherical PS particles of nanosize were obtained by miniemulsion polymerization, which could be attributed to the prevention of Ostwald ripening by cosurfactant. Thermal properties of PS particle containing PCM were studied by differential scanning calorimetry. From DSC freeze-thaw cycle, PCM coated with PS exhibited the thermal energy storage and release behaviors, and the latent heat was found to be a maximum 145 J/g. It was noted that PS particles containing PCM showed a good potential as a thermal energy storage medium.

• Korean journal of food and cookery science
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• v.30 no.6
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• pp.716-725
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• 2014

Gelatinization properties and the molecular structure of Korean waxy rice starchesisolated from two japonica types, Sinseonchal, and Dongjinchal, as well as an indica type, Hangangchal 1 were investigated. Sinseonchal is preferred cultivar for making Korean traditional rice cakes and cookies. Sinseonchal starch was the highest in crude protein, amylopectin, damaged starch contents, and water binding capacity among the cultivars tested. The initial pasting temperature ($72.75^{\circ}C$), peak (360.54 RVU), breakdown (162.21 RVU) and setback (30.83 RVU) viscosities of Sinseonchal had the highest values (p<0.05). Onset and peak temperatures by differential scanning calorimeter were also the highest in Sinseonchal. The molecular weight of Sinseonchal amylopectin was 5.46 107higher than those of the other cultivars, but its peak height and area were the lowest among them. The amylopectin peak by HPSEC showed a shoulder in the lower molecular weight portion and its relative area decreased in the following order; Sinseonchal > Dongjinchal > Hangangchal 1. On the branch chain length distribution of amylopectin, the proportion of DP13-24 and DP25-36 showed reverse trends, with higher japonica type amylopectin in DP13-24.