• 한국가스학회지
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• 제15권1호
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• pp.9-14
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• 2011

대형 디젤엔진은 주행거리가 길고 배기량이 크기 때문에 차량의 대수는 상대적으로 적지만 대기환경에 미치는 영향은 크다. 시내를 주행하는 시내버스의 경우 한일 월드컵을 계기로 CNG 버스로 전환되었다. 그러나 대형트럭과 장거리 시외버스의 경우 주행거리가 길고 CNG 충전소가 대도시의 시내버스 차고지 위주로 설치되어 있어 이용이 불가능하였다. 단열용기의 적용으로 천연가스를 압축상태가 아닌 액체 상태로 보관이 가능해져 주행거리가 긴 대형트럭이나 장거리 시외버스로의 적용이 가능해졌으며, 혼소엔진의 경우 LNG 충전이 어려운 지역에서는 디젤로 운행이 가능하다. 이와 같은 장점으로 인하여 석유 의존도를 크게 낮출 수 있어 에너지원의 다변화가 가능하며, 디젤차의 고질적인 단점으로 여겨왔던 매연 및 질소산화물뿐만 아니라 저탄소 연료를 사용함으로서 대표적인 온실가스중의 하나인 이산화탄소도 10%이상 저감할 수 있었다.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2012년도 춘계학술발표대회
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• pp.58.2-58.2
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• 2012

Heavy hydrocarbon reforming is a core technology for "Dirty energy smart". Heavy hydrocarbons are components of fossil fuels, biomass, coke oven gas and etc. Heavy hydrocarbon reforming converts the fuels into $H_2$-rich syngas. And then $H_2$-rich syngas is used for the production of electricity, synthetic fuels and petrochemicals. Energy can be used efficiently and obtained from various sources by using $H_2$-rich syngas from heavy hydrocarbon reforming. Especially, the key point of "Dirty energy smart" is using "dirty fuel" which is wasted in an inefficient way. New energy conversion laboratory of KAIST has been researched diesel reforming for solid oxide fuel cell (SOFC) as a part of "Dirty energy smart". Diesel is heavy hydrocarbon fuels which has higher carbon number than natural gas, kerosene and gasoline. Diesel reforming has difficulties due to the evaporation of fuels and coke formation. Nevertheless, diesel reforming technology is directly applied to "Dirty fuel" because diesel has the similar chemical properties with "Dirty fuel". On the other hand, SOFC has advantages on high efficiency and wasted heat recovery. Nippon oil Co. of Japan recently commercializes 700We class SOFC system using city gas. Considering the market situation, the development of diesel reformer has a great ripple effect. SOFC system can be applied to auxiliary power unit and distributed power generation. In addition, "Dirty energy smart" can be realized by applying diesel reforming technology to "Dirty fuel". As well as material developments, multidirectional approaches are required to reform heavy hydrocarbon fuels and use $H_2$-rich gas in SOFC. Gd doped ceria (CGO, $Ce_{1-x}Gd_xO_{2-y}$) has been researched for not only electrolyte materials but also catalysts supports. In addition, catalysts infiltrated electrode over porous $La_{0.8}Sr_{0.2}Ga_{0.8}Mg_{0.2}O_3-{\delta}$ and catalyst deposition at three phase boundary are being investigated to improve the performance of SOFC. On the other hand, nozzle for diesel atomization and post-reforming for light-hydrocarbons removal are examples of solving material problems in multidirectional approaches. Likewise, multidirectional approaches are necessary to realize "Dirty energy smart" like reforming "Dirty fuel" for SOFC.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2010년도 추계학술대회 초록집
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• pp.78.1-78.1
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• 2010

The metal-supported solid oxide fuel cell (SOFC) was studied. Hydrocarbon fueled operation is necessary to make SOFC system. Different operating characteristics for metal-supported SOFC are used than for conventional ones as hydrocarbon fueled operation. Metal-supported SOFC was successfully fabricated by a high temperature sinter-joining method and the cathode was in-situ sintered. Synthetic gas, which is compounded as the diesel reformate gas composition and low hydrocarbons was completely removed by the diesel reformer. Metal-supported SOFC with synthetic gas was operated and evaluated and its characteristics analyzed. Button cell and $5{\times}5cm^2$ single stack were mainly operated and analyzed. Long-term operation using diesel reformate shows degradation, and degradation analysis was completed in the view of metal oxidation. Solution to increase stability of long-term operation was tried in the way of materials and operating conditions. Finally, $5{\times}5cm^2$ metal-supported single stack using synthetic gas was operated for 1000 hours under the modified condition.

• 동력기계공학회지
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• 제19권2호
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• pp.64-69
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• 2015

Marine diesel engines with high thermal efficiency and fuel diversity used for propulsive power have been taking charge of important position on marine transport. However, marine environment has recently focused on emissions such as nitrogen oxide and sulfur oxide which is generated from combustion of low grade fuels. EGR(Exhaust gas recirculation) system is one of effective methods to reduce the nitrogen oxide emission from marine diesel engines. In general, it is considered that recirculating gas influences fuel combustion and emissions in diesel engines. However, along with positive effects of EGR, the EGR system using fuels of including high sulfur concentration should be considered about re-combustion and activation of sulfur dioxide in recirculating gas. Therefore, in experimental study, an author investigates effects of sulfur dioxide mixture concentration in intake air on combustion and exhaust emission characteristics in a direct injection diesel engine. In results, change of sulfur dioxide concentrations in intake air had negligible impact on combustion chamber pressure, rate of heat release and emissions compared with effects of oxygen decreasing and carbon dioxide increasing of EGR.

• Journal of Mechanical Science and Technology
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• 제15권11호
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• pp.1588-1598
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• 2001

The effects of recirculated exhaust gas on the characteristics of NOx and soot emissions under a wide range of engine loads were experimentally investigated by using a four-cycle, four-cylinder, sw irl chamber type, water-cooled diesel engine operating at three engine speeds. The purpose of this study was to develop the EGR-control system for reducing NOx and soot emissions simultaneously in diesel engines. The EGR system is used to reduce NOx emissions, and a novel diesel soot removal device with a cylinder-type scrubber for the experiment system was specially designed and manufactured to reduce soot contents in the recirculated exhaust gas to the intake system of the engine. The experiments were performed at the fixed fuel injection timing of 4$^{\circ}$ ATDC regardless of experimental conditions. It was found that soot emissions in exhaust gases were reduced by 20 to 70% when the scrubber was applied in the range of the experimental conditions, and that NOx emissions decreased markedly, especially at higher loads, while soot emissions increased owing to the decrease in intake and exhaust oxygen concentrations, and the increase in equivalence ratio as the EGR rate is elevated.

• 대한기계학회논문집B
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• 제32권8호
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• pp.597-603
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• 2008

The catalyzed diesel particulate filter (CDPF) is widely used for collecting soot from the exhaust gas of diesel engine. However, the CDPF need being regenerated after the soot accumulation. It is important to know characteristics of regeneration for CDPF with variation of exhaust gas temperature and composition. This study presents characteristics of regeneration according to variable exhaust gas composition. Furthermore, the experiment were performed variable gas temperature of CDPF inlet gas at each exhaust gas composition. Test-rig is used to control at each in let gas temperature and composition during regeneration of CDPF. Reaction intensity($I_c$) is used to compare with each result. Experimental results indicated that increased concentration of $NO_x$ and $O_2$ lead to regenerate more greatly. Also, higher temperature of exhaust gas leads to make CDPF cleaner.

• 한국자동차공학회논문집
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• 제13권5호
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• pp.188-194
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• 2005

The direct injection diesel engine is one of the most efficient thermal engines. For this reason DI diesel engines are widely used for heavy-duty applications. But the world is faced with very serious problems related to the air pollution due to the exhaust emissions of diesel engine. So, that is air pollution related to exhaust gas resulted from explosive combustion should be improved. Exhaust Gas Recirculation(EGR) is a proven method to reduce NOx emissions. In this study, the experiments were performed at various engine loads while the EGR rates were set from $0\%$ to $30\%.$ The emissions trade-off and combustion of diesel engine are investigated. The brake specific fuel consumption rate is very slightly fluctuated with EGR in the range of experimental conditions. The ignition delay increased with increasing EGR rate. The maximum value of premixed combustion for the rate of heat release is increased with increasing EGR rate. NOx emissions are decreased with increasing EGR rate at high load and high speed. It was found that the exhaust emissions with the EGR system resulted in a very large reduction in oxides of nitrogen at the expense of higher smoke emissions.

• 수산해양기술연구
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• 제56권3호
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• pp.230-237
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• 2020

In order to design a diesel engine system and predict its performance, it is necessary to analyze the gas flow of the intake and exhaust system. A gas flow analysis in three-dimensional (3D) format needs a high-resolution workstation and enormous time for analysis. Therefore, the method of characteristics (MOC) was used for a gas flow analysis with a fast calculation time and a low-resolution workstation. An experiment was conducted on a single cylinder diesel engine to measure pressure in cylinder, intake pipe and exhaust pipe. The one-dimensional (1D) gas flow was analyzed under the same conditions as the experiment. The engine speed, valve timing and compression ratio were the same conditions and the intake pressure was inputted as the experimental results. Bent pipe such as an exhaust port that cannot be realized in 1D was omitted. As results of validation, the cylinder pressure showed accuracy, but the exhaust pipe pressure exhibited inaccuracy. This is considered as an error caused by the failure to implement a bent pipe such as an exhaust port. When analyzed in 3D, calculation time required 61 hours more based on a model of this study. In the future, we intend to implement a bent pipe that cannot be realized in 1D using 3D and prepare a method to supplement reliability by using 1D-3D coupling.

• 해양환경안전학회지
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• 제15권3호
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• pp.269-274
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• 2009

LNGC(Liquefied Natural Gas Carrier)의 역사는 1959년 $5,000m^3$ 급 LNG선 "Methane Pioneer"호를 시작으로 1969년에는 $71,500m^3$ 급, 1973년에는 Moss Type의 최초 LNG운반선 "Norman Lady($87,600m^3$)호, 1980년대 $125,000m^3$ 급을 시작으로 1990년대를 거처 $135,000m^3$ 급, 2007년 $210,000m^3$급 그리고 2008년에는 $266,000m^3$ 급의 초대형 액화천연가스 운반선이 출현하였다. 또한 2006년 11월에는 기존 내 외연 기관이 아닌 발전기 기동으로 Propeller를 움직이는 DFDE(Duel Fuel Diesel Electric)엔진, 육상의 Storage Tank를 생략한 기화설비를 갖춘 LNG-RV(Re-gasification Vessel)와 주 기관은 Slow Diesel을 택하고, 운항 중 발생하는 BOG(Boil Off Gas)를 재액화시키는 설비를 갖춘 DRL(Diesel Re-Liquefaction)선박 및 해상 LNG 생산 저장시설인 LNG-FPSO(Floating Production and Storage Offshore), 그리 고 해상 LNG 인수기지 역할을 하는 LNG-FSRU(Floating Store and Re-gasification Unit) 등이 개발되었다. 이 논문에서는 LNG Project, 전 세계 에너지 시장과 LNGC의 발전 추세에 대하여 다루었다.

• 한국가스학회지
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• 제21권6호
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• pp.70-80
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• 2017

매년 OECD가 발표하는 대기환경 오염분야에서 우리나라가 최하위를 차지했다. 이에 따른 대책으로 수송분야에 관심이 집중되었고, 오염도 측정 결과 대형경유 및 노후차량에서 미세먼지 배출가스가 높게 발생하는 원인으로 정부는 발표하였다. 이를 해결하기 위해 정부가 관련부처 합동으로 "미세먼지 관리 특별대책과 종합대책"을 추진하였다. 환경오염 개선방안으로 시내버스와 전세버스를 대상으로 친환경자동차 전환을 위한 유가 보조금제도를 시행했다. 본 연구에서는 경유버스 대비 천연가스(CNG) 연료전환 시 경제성 평가와 오염물질 배출에 따른 환경비용을 비교분석하였다. 유형별 연료전환 시나리오를 통한 천연가스 차량으로 연료전환을 했을 때 사회적 편익과 환경적 비용을 고려한 정부지원금 정책의 타당성 및 지원금 확대 근거를 제시하였다.