• 제목/요약/키워드: dielectric losses

검색결과 83건 처리시간 0.033초

졸-겔법에 의한 강유전 BST 박막의 제조 및 특성 (Fabrication and properties of ferroelectric BST thin films prepared by sol-gel method)

  • 이진홍;박병옥
    • 한국결정성장학회지
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    • 제11권2호
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    • pp.60-66
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    • 2001
  • ($Ba_x$$Sr_{1-x}$)$TiO_3$ (x=0.9, 0.7, 0.5)박막을 졸-겔법으로 ITO-coated glass기판 위에 제조하였다. BST의 perov-skite상 생성온도는 $600^{\circ}C$ 이상이며 Sr함량이 증가할수록, $Ba^{2+}$ 이온보다 작은 $Sr^{2+}$ 이온에 의해 perovskite상들의 피크가 높은 회절 각도로 이동하였다. 그리고 온도가 증가할수록 결정립은 조대화 되었고, Sr 함량이 증가할수록 결정립은 미세화 되었다. BST(50/50)의 유전상수 값은 다른 두 조성보다 큰 값을 나타내고 유전손실 값은 더 낮았다. 1 kHz때의 BST(50/50)박막의 유전상수 및 유전손실 값은 각각 652와 0.042였다.

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Relationship Between Enhancement of Electrostriction and Decrease of Activation Energy in Porcine Pancreatic Lipase Catalysis

  • PARK HYUN;LEE KI-SEOG;PARK SEON-MI;LEE KWANG-WON;KIM AUGUSTINE YONGHWI;CHI YOUNG-MIN
    • Journal of Microbiology and Biotechnology
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    • 제15권3호
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    • pp.587-594
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    • 2005
  • The contribution of electrostriction of water molecules to the stabilization of the negatively charged tetrahedral transition state of a lipase-catalyzed reaction was examined by means of kinetic studies involving high-pressure and solvent dielectric constant. A good correlation was observed between the increased catalytic efficiency of lipase and the decreased solvent dielectric constant. When the dielectric constant of solvents was lowered by 5.00 units, the losses of activation energy and free energy of activation were 7.92 kJ/mol and 11.24 kJ/mol, respectively. The activation volume for $k_{cat}$ decreased significantly as the dielectric constant of solvent decreased, indicating that the degree of electrostriction of water molecules around the charged tetrahedral transition state has been enhanced. These observations demonstrate that the increase in the catalytic efficiency of the lipase reaction with decreasing dielectric constant resulted from the stabilization of electrostatic energy for the formation of an oxyanion hole, and that this stabilization was caused by the increase of electrostricted water around the charged tetrahedral transition state. Therefore, we conclude that the control of solvent dielectric constant can stabilize the tetrahedral transition state, thus lowering the activation energy.

Scattering characteristics of metal and dielectric optical nano-antennas

  • Ee, Ho-Seok;Lee, Eun-Khwang;Song, Jung-Hwan;Kim, Jinhyung;Seo, Min-Kyo
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2015년도 제49회 하계 정기학술대회 초록집
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    • pp.76.1-76.1
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    • 2015
  • Optical resonances of metallic or dielectric nanoantennas enable to effectively convert free-propagating electromagnetic waves to localized electromagnetic fields and vice versa. Plasmonic resonances of metal nanoantennas extremely modify the local density of optical states beyond the optical diffraction limit and thus facilitate highly-efficient light-emitting, nonlinear signal conversion, photovoltaics, and optical trapping. The leaky-mode resonances, or termed Mie resonances, allow dielectric nanoantennas to have a compact size even less than the wavelength scale. The dielectric nanoantennas exhibiting low optical losses and supporting both electric and magnetic resonances provide an alternative to their metallic counterparts. To extend the utility of metal and dielectric nanoantennas in further applications, e.g. metasurfaces and metamaterials, it is required to understand and engineer their scattering characteristics. At first, we characterize resonant plasmonic antenna radiations of a single-crystalline Ag nanowire over a wide spectral range from visible to near infrared regions. Dark-field optical microscope and direct far-field scanning measurements successfully identify the FP resonances and mode matching conditions of the antenna radiation, and reveal the mutual relation between the SPP dispersion and the far-field antenna radiation. Secondly, we perform a systematical study on resonant scattering properties of high-refractive-index dielectric nanoantennas. In this research, we examined Si nanoblock and electron-beam induced deposition (EBID) carbonaceous nanorod structures. Scattering spectra of the transverse-electric (TE) and transverse-magnetic (TM) leaky-mode resonances are measured by dark-field microscope spectroscopy. The leaky-mode resonances result a large scattering cross section approaching the theoretical single-channel scattering limit, and their wide tuning ranges enable vivid structural color generation over the full visible spectrum range from blue to green, yellow, and red. In particular, the lowest-order TM01 mode overcomes the diffraction limit. The finite-difference time-domain method and modal dispersion model successfully reproduce the experimental results.

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Open-Short 방식의 임피던스 측정에 의한 분포정수의 보정 (A LOSSY LINE DISTRIBUTED PARAMETERS CALCULATION USING DATA OF OPEN-SHORT IMPEDANCE MEASURING METHOD)

  • ;조기연;변영복;서정일;김은수;김태진
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1999년도 하계학술대회 논문집 F
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    • pp.2553-2555
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    • 1999
  • The paper contains design formulas and an execution algorithm for calculation of distributed parameters as well as wave and impedance parameters of a uniform transmission line using data of the line input impedance measurements by the OPEN-SHORT method. In difference from published before works on the OPEN-SHORT method application for line parameters determination, in which the lines with small losses are considered /1-3/, the obtained formulas allow to calculate parameters of transmission lines with arbitrary losses. It opens new possibilities of the OPEN-SHORT method utilization for development and application of the probe - type lossy dielectric media parameters meters based on transmission lines, including probe-type moisture material meters.

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이종적층 LTCC 기술을 이용한 WLAN용 대역통과 필터 설계 (Design of BPF for WLAN with Heterogeneous LTCC Materials)

  • 고정호;육종관;박한규;김준철;이영신
    • 한국전자파학회:학술대회논문집
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    • 한국전자파학회 2003년도 종합학술발표회 논문집 Vol.13 No.1
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    • pp.188-192
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    • 2003
  • A multilayer two-stage LC bandpass filter using low-temperature cofired-ceramic (LTCC) is proposed in this paper. The proposed bandpass filter is composed of two ceramic substrates with different dielectric constant instead of single ceramic material from top to bottom layer. The bandpass filter size is $2.0 mm{\times}1.2 mm{\times}0.8 mm$. Positioning of attenuation polefrequency, importance parameter for a performance of filter, is discussed using even-odd mode analysis by tuned capacitance of coupling capacitor and those results is implemented to LTCC filter circuit. Measured filter performances show that the insertion losses are -4.5dB, -4.1dB at 2.45GHz, 2.75GHz and the return losses are -8.5dB, 8.7dB.

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교류손실 및 안정성을 고려한 22.9kV 초전도 케이블 설계 (Design of 22.9kV High Temperature Superconducting Cable Considering AC losses and Stability)

  • 장현만;이창영;김춘동;심기덕;조전욱
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2005년도 제36회 하계학술대회 논문집 B
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    • pp.1210-1212
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    • 2005
  • High temperature superconducting(HTS) power cable system consists of HTS cable, termination and cryogenic system. And the HTS cable consists of the former, HTS phase conductor, electric insulation, HTS shield and cryostat. Taking the advantage of HTS shield, the cold dielectric has been adopted. The phase conductor and the shield have been designed to minimize the AC loss below 1W/m/phase. The former has been designed to transport the fault current of 25kA, at fault condition. This paper describes the design process of 22.9kV HTS cable considering AC losses at normal state and the stability at fault condition.

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Investigations of Temperature Effect on the Conduction Mechanism of Electrical Conductivity of Copolymer/Carbon Black Composite

  • El Hasnaoui, M.;Kreit, L.;Costa, L.C.;Achour, M.E.
    • Applied Microscopy
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    • 제47권3호
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    • pp.121-125
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    • 2017
  • This study deals the prediction of temperature effect on low-frequency dispersion of alternating current (AC) conductivity spectra of composite materials based on copolymer reinforced with carbon black (CB) particles. A sample of ethylene butylacrylate loaded with 13% of CB particles were prepared and investigated using the impedance spectroscopy representation in the frequency range from 40 Hz to 0.1 MHz and temperature range from $20^{\circ}C$ to $125^{\circ}C$. The dielectric constant, ${\varepsilon}^{\prime}$, and dielectric losses, ${\varepsilon}^{{\prime}{\prime}}$, were found to decrease with increasing frequency. The frequency dependence of the AC conductivity follows the universal power law with a large deviation in the high frequency region, the positive temperature coefficient in resistivity effect has been observed below the melting temperature which makes this composite potentially remarkable for industrial applications.

마이크로파 대역에서 $PbTiO_3$ 박막의 Dipolar Relaxation에 대한 박막 두께의 효과 (The Effects of Film Thickness on the Dipolar Relaxation of $PbTiO_3$ Thin Films in the Microwave-Frequency Range)

  • 이도영;김용조
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2003년도 추계학술발표강연 및 논문개요집
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    • pp.142-142
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    • 2003
  • The effects of film thickness on the dipolar relaxation of ferroelectric PbTiO$_3$ films were investigated in the microwave-frequency range. The dielectric constants ($\varepsilon$) and the dielectric losses (tan $\delta$) were successfully measured up to 30 ㎓ using interdigital capacitors. The PbTiO$_3$ thin films were deposited on the quartz substrate at room temperature and postannealed in oxygen atmosphere. As the film thickness increased, its grain size and tetragonality were enhanced. And the dipolar relaxation behavior began to appear in the thin films with approximately 20 nm thickness, since ferroelectric domains could not be formed hi small grains. The observed relaxation frequency (above 10 ㎓) was higher than the previous values reported in bulk ceramics. It can be correlated with the extremely small domain size of the thinfilms as shown by TEM. And, the Rayleigh constant [1] from domain wall motions was alsoinvestigated by LCR meter at 100 KHz.

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Highly Miniaturized and Performed UWB Bandpass Filter Embedded into PCB with SrTiO3 Composite Layer

  • Cheon, Seong-Jong;Park, Jun-Hwan;Park, Jae-Yeong
    • Journal of Electrical Engineering and Technology
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    • 제7권4호
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    • pp.582-588
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    • 2012
  • In this paper, a highly miniaturized and performed UWB bandpass filter has been newly designed and implemented by embedding all the passive elements into a multi-layered PCB substrate with high dielectric $SrTiO_3$ composite film for 3.1 - 4.75 GHz compact UWB system applications. The high dielectric composite film was utilized to increase the capacitance densities and quality factors of capacitors embedded into the PCB. In order to reduce the size of the filter and avoid parasitic EM coupling between the embedded filter circuit elements, it was designed by using a $3^{rd}$ order Chebyshev circuit topology and a capacitive coupled transformation technology. Independent transmission zeros were also applied for improving the attenuation of the filter at the desired stopbands. The measured insertion and return losses in the passband were better than 1.68 and 12 dB, with a minimum value of 0.78 dB. The transmission zeros of the measured response were occurred at 2.2 and 5.15 GHz resulting in excellent suppressions of 31 and 20 dB at WLAN bands of 2.4 and 5.15 GHz, respectively. The size of the fabricated bandpass filter was $2.9{\times}2.8{\times}0.55(H)mm^3$.

희토류원소(Y, Nd, Sm, Gd)의 치환에 의한 $Bi_4Ti_3O_{12}$의 결정화학 및 유전물성 (Crystal Chemistry and Dielectric Properties of $Bi_4Ti_3O_{12}$ by the Substitution of Rare Earth Elements (Y, Nd, Sm, Gd))

  • 고태경;방규석
    • 한국세라믹학회지
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    • 제32권10호
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    • pp.1178-1188
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    • 1995
  • Bi4Ti3O12 (BIT) and its rare earth (Y, Nd, Sm, Gd)-substituted derivatives were synthesized using a sol-gel method to investigate their microstructures, cystal structures and electrical properties depending on the subsituted elemetns. Nd- or Sm-substitution into BIT appeared to be favorable, while Y- or Gd-substitution occurred with a pyrochlore phase. This suggests that a smaller trivalent rare earth ion may not be favorable in the structure of BIT. The rare earth derivatives showed that their particle sizes and shapes were considerably different depending on the kinds of substituted elements. Y-substitution resulted in developing a relatively even particle size and a dense microstructure. In structure, they may be similar to the pseudo-orthorhombic BIT but close to a paraelectric tetragonal phase. Their a (or b) axes were shortened, compared to the one of BIT. Such a distortion may result a decrease in the tilting of TiO6. BIT and the derivatives showed that their dielectric constants and losses were 40~120 and less than 0.03, respectively in the frequency range of 1~10 MHz. The dielectric loss of Y-substituted derivative was the lowest one and changed a little to frequency. Curie points were observed in all the derivatives like BIT to suggest that they would be ferroelectric. The temperature stability of the delectric properties of the derivatives below the Curie points were relatively better than the one of BIT.

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