• Journal of Environmental Health Sciences
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• v.26 no.4
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• pp.110-114
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• 2000

Determination of mercury(II) using Nafion-EDTA-modified glassy carbon electrodes is proposed. it is based on the chemical reactivity of an immobilized modifier, Nafion-EDTA. Differential pulse voltammetry is employed, and the oxidation of complexes, at +0.43V vs. Ag/AgCl, is observed. For a 5-min preconcentration period, a linear calibration curve is obtained for mercury(II) concentrations ranging from 1.0$\times$ 10$^{-8}$ to 1.0$\times$10$^{-6}$ M. Further, when an approximate amount of copper(II) is added to the test solution, We demonstrate that at a preconcentration time of 5 min the Nafion-EDTA-modified glassy carbon electrode has a dynamic range of 2 orders of magnitude(from 10$^{-10}$ to 10$^{-8}$ M) and the detection limit is as low as 0.5$\times$ 10$^{-10}$ M(0.01 ppb). This method is applied to the determination of mercury(II) in sea water(4.0$\times$10$^{-10}$ M, 0.08ppb). The result agrees satisfactorily with the value(below 0.1 ppb) measured by using ICP/MS.

• Journal of Korea Water Resources Association
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• v.33 no.2
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• pp.237-245
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• 2000

Sihwa seadike is originally designed to control the water level In lake Sihwa. However the sluice gate is being operated everyday to preserve the water quality of lake. Due to the frequent operation of gates the bottom of drainage canal which is composed of weathered rock and soft rock is being scoured. Recently the bottom in the front area of apron was protected by putting underwater concrete. This study is carried out to understand the hydraulic situation for protection, and to estimate the trend of scouring by comparing between energy dissipation and registance of bottom rock. Annandale(1995) introduced the erodibility index theory, and suggested a criteria to judge the erodibility of rock through the relation between the erodibility index and energy dissipation. Determenation of erodibility index of rock is based on the results of sample core analysis, and the energy dissipation of flow is calculated from the estimation of total head on the scale model. These two values are plotted on the criteria, and the erodibility of rock is determined.