• Title/Summary/Keyword: deposition condition

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Effects of Membrane Size and Organic Matter on Membrane Fouling (천연유기물질의 특성과 막의 종류에 따른 막오염 메카니즘 분석)

  • Jung, Chul-Woo;Son, Hee-Jong
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.10
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    • pp.1046-1054
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    • 2006
  • The raw water DOC contained 39.3% of hydrophilics, 42.9% of hydriophobic, and 17.8% of transphilic. The hydrophobic fraction in this raw water was mostly fulvic acid. Fulvic acid comprised of 62% and the rest was humic acid(38%). There was more carboxylic acid functional group(64%) than phenolic group(36%). HPI-N and HPI-C comprised of 17% and 22% in the hydrophilic portion, respectively. The fouling mechanisms on the membrane surface and into its porous structure were analyzed in terms of several kinetic models. In order to analyze the fouling kinetics, the various kinetic models described in this paper were used to fit the experimental results. The kinetic models and kinetic constants obtained for each operation condition. The permeate flux was rapidly declined by simultaneous pore blocking and cake formation. Also, the permeate flux declined with decreasing internal pore size resulted from organic deposition into the membrane pore. The results of the membrane fouling test using UF membrane according to NOM fractions. HPI-N caused more fouling than HPI-C. Humic acid caused more fouling than fulvic acid probably due to higher adsorption capacity. Since humic acid has higher adsorption capacity than fulvic acid, it would be more adsorbed onto the membrane pores.

Effects of Annealing Condition on Properties of ITO Thin Films Deposited on Soda Lime Glass having Barrier Layers (Barrier층을 갖는 Soda lime glass 기판위에 증착된 ITO박막의 Annealing 조건에 따른 영향)

  • Lee, Jung-Min;Choi, Byung-Hyun;Ji, Mi-Jung;Park, Jung-Ho;Ju, Byeong-Kwon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.66-66
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    • 2008
  • Most of the properties of ITO films depend on their substrate nature, deposition techniques and ITO film composition. For the display panel application, it is normally deposited on the glass substrate which has high strain point (>575 degree) and must be deposited at a temperature higher than $250^{\circ}C$ and then annealed at a temperature higher than $300^{\circ}C$ in order to high optical transmittance in the visible region, low reactivity and chemical duration. But the high strain point glass (HSPG) used as FPDs is blocking popularization of large sizes FPDs because it is more expensive than a soda lime glass (SLG). If the SLG could be used as substrate for FPDs, then diffusion of Na ion from the substrate occurs into the ITO films during annealing or heat treatment on manufacturing process and it affects the properties. Therefore proper care should be followed to minimize Na ion diffusion. In this study, we investigate the electrical, optical and structural properties of ITO films deposited on the SLG and the Asahi glass(PD200) substrate by rf magnetron sputtering using a ceramic target ($In_2O_3:SnO_2$, 90:10wt.%). These films were annealed in $N_2$ and air atmosphere at $400^{\circ}C$ for 20min, 1hr, and 2hrs. ITO films deposited on the SLG show a high electrical resistivity and structural defect as compared with those deposited on the PD200 due to the Na ion from the SLG on diffuse to the ITO film by annealing. However these properties can be improved by introducing a barrier layer of $SiO_2$ or $Al_2O_3$ between ITO film and the SLG substrate. The characteristics of films were examined by the 4-point probe, FE-SEM, UV-VIS spectrometer, and X-ray diffraction. SIMS analysis confirmed that barrier layer inhibited Na ion diffusion from the SLG.

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Study of Catalytic Performance of $La_{0.7}Sr_{0.3}Cr_{1-x}Ni_{x}O_{3}$ Perovskite for Steam Reforming of Propane ($La_{0.7}Sr_{0.3}Cr_{1-x}Ni_{x}O_{3-{\delta}$ Perovskite 촉매의 프로판 수증기 개질 반응에서의 특성 연구)

  • Kim, Jae-Ro;Kim, Nak-Hyeon;Sohn, Jung-Min
    • Korean Chemical Engineering Research
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    • v.49 no.6
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    • pp.715-719
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    • 2011
  • The $La_{0.7}Sr_{0.3}Cr_{1-x}Ni_{x}O_{3}$(LSCN-x) perovskites were prepared by citric acid and EDTA using a sol-gel method. The LSCN-x was characterized by BET, XRD, SEM, $H_2$-TPR, EA and TEM. The catalytic performance of LSCN-x catalysts in steam reforming of propane in the temperature range 600~$800^{\circ}C$ was investigated. Propane conversion and hydrogen yield increased with an increase in the amount of added Ni up to x=0.5 in the B-site, denoted as LSCN-0.5, under S/C=1 and S/C=1.7 reaction conditions. The LSCN-0.5 catalyst exhibited the best performance under Ni-substitution of which propane conversion and hydrogen yield was 100%, 95.9% at $800^{\circ}C$ in the S/C=1.7 condition, respectively. The morphology of carbon deposited on the catalysts after reaction exhibited filamentous carbon and amount of carbon deposited on the catalysts after reaction increased with an increase in the amount of added Ni.

Radiological Characterization of the High-sensitivity MOSFET Dosimeter (고감도 MOSFET 선량계 방사선학적 특성 연구)

  • Cho Sung Koo;Kim Chan-Hyeong
    • Progress in Medical Physics
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    • v.15 no.4
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    • pp.215-219
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    • 2004
  • Due to their excellence for the high-energy therapy range of photon beams, researchers show increasing interest in applying MOSFET dosimeters to low- and medium-energy applications. In this energy range, however, MOSFET dosimeter is complicated by the fact that the interaction probability of photons shows significant dependence on the atomic number, Z, due to photoelectric effect. The objective of this study is to develop a very detailed 3-dimensional Monte Carlo simulation model of a MOSFET dosimeter for radiological characterizations and calibrations. The sensitive volume of the High-Sensitivity MOSFET dosimeter is very thin (1 ${\mu}{\textrm}{m}$) and the standard MCNP tallies do not accurately determine absorbed dose to the sensitive volume. Therefore, we need to score the energy deposition directly from electrons. The developed model was then used to study various radiological characteristics of the MOSFET dosimeter. the energy dependence was quantified for the energy range 15 keV to 6 MeV; finding maximum dependence of 6.6 at about 40 keV. A commercial computer code, Sabrina, was used to read the particle track information from an MCNP simulation and count the tracks of simulated electrons. The MOSFET dosimeter estimated the calibration factor by 1.16 when the dosimeter was at 15 cm depth in tissue phantom for 662 keV incident photons. Our results showed that the MOSFET dosimeter estimated by 1.11 for 1.25 MeV photons for the same condition.

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Post-annealing Effect of Giant Magnetoresistance-Spin Valve Device for Sensor (센서용 거대자기저항 스핀밸브소자의 열처리 효과)

  • Lee, Sang-Suk;Park, Sang-Hyun;Soh, Kwang-Sup;Joo, Ho-Wan;Kim, Gi-Wang;Hwang, D.G.
    • Journal of the Korean Magnetics Society
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    • v.17 no.4
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    • pp.172-177
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    • 2007
  • In order to detect of the magnetic property in the cell unit, we studied the GMR-SV (giant magnetoresistance-spin valves) biosensor, which was depended on the micro patterned features according to two easy directions of longitudinal and transversal axes. Here, the multi layer structure was glass/NiO/NiFe/CoFe/Cu/CoFe/NiFe. The uniaxial anisotropy direction was applied to the patterned biosensor during the deposition and vacuum post-annealing at $200^{\circ}C$ under the magnitude of 300 Oe, respectively. Considering the magnetic shape anisotropy effect, the size of micro patterned biosensor was a $2{\times}5{\mu}m^2$ after the photo lithography process. By our experimental results, we confirmed that the best condition of GMR-SV biosensor should be the same direction of the axis sensing current and the easy axis of pinned NiO/NiFe/CoFe triple layer oriented to the width direction of device, and the direction of the easy axis of free CoFe/NiFe bilayer was according to the longitudinal direction of device.

Structural and Electrical Properties of Amorphous 2Ti4O12 Thin Films Grown on TiN Substrate (TiN 기판 위에 성장시킨 비정질 BaSm2Ti4O12 박막의 구조 및 전기적 특성 연구)

  • Park, Yong-Jun;Paik, Jong-Hoo;Lee, Young-Jin;Jeong, Young-Hun;Nahm, Sahn
    • Korean Journal of Materials Research
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    • v.18 no.4
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    • pp.169-174
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    • 2008
  • The structural and electrical properties of amorphous $BaSm_2Ti_4O_{12}$ (BSmT) films on a $TiN/SiO_2/Si$ substrate deposited using a RF magnetron sputtering method were investigated. The deposition of BSmT films was carried out at $300^{\circ}C$ in a mixed oxygen and argon ($O_2$ : Ar = 1 : 4) atmosphere with a total pressure of 8.0 mTorr. In particular, a 45 nm-thick amorphous BSmT film exhibited a high capacitance density and low dissipation factor of $7.60\;fF/{\mu}m2$ and 1.3%, respectively, with a dielectric constant of 38 at 100 kHz. Its capacitance showed very little change, even in GHz ranges from 1.0 GHz to 6.0 GHz. The quality factor of the BSmT film was as high as 67 at 6 GHz. The leakage current density of the BSmT film was also very low, at approximately $5.11\;nA/cm^2$ at 2 V; its conduction mechanism was explained by the the Poole-Frenkel emission. The quadratic voltage coefficient of capacitance of the BSmT film was approximately $698\;ppm/V^2$, which is higher than the required value (<$100\;ppm/V^2$) for RF application. This could be reduced by improving the process condition. The temperature coefficient of capacitance of the film was low at nearly $296\;ppm/^{\circ}C$ at 100 kHz. Therefore, amorphous BSmT grown on a TiN substrate is a viable candidate material for a metal-insulator-metal capacitor.

Seismic reflection survey in a tidal flat: A case study for the Mineopo area (갯벌 지역에서의 탄성파 탐사: 민어포 조간대 지역의 사례)

  • Jou Hyeong-Tae;Kim Han-Joon;Lee Gwang-Hoon;Choi Dong-Lim;Kim Min-Ji;Cho Hyun-Moo
    • 한국지구물리탐사학회:학술대회논문집
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    • 2002.09a
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    • pp.67-84
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    • 2002
  • A shallow high-resolution seismic reflection survey was carried out at the Mineopo tidal flat on the western coast of Korea. The purpose of the survey was to investigate shallow sedimentary structure of the tidal (fat associated with the recent sea level change. A total of 795 shots were generated at 1 m interval from a 5-kg hammer source and recorded on 48 channels of 100 Hz geophones along two mutually perpendicular profiles. The water-saturated ground condition resulted in suppressed ground rolls by significantly decreasing rigidity. In addition, seismic velocities over 1500 m/s provided easy segregation of reflected arrivals from lower velocity noise. As a consequence, seismic sections were created that are high in resolution and signal to noise ratio as well. The stack sections show that the tidal flat consists of 5 sedimentary sequences above acoustic basement. Although deposition is largely characterized by the transgressive sedimentary facies resulting from sea level rise, erosional surfaces are well-resolved within the sequences.

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Effects of Additives on the Characteristics of Sodium Borosilicate Thin Film Fabricated by AFD Method (첨가제가 AFD법에 의해 제조된 광소자용 Sodium Borosilicate 박막의 물성에 미치는 영향)

  • Chung, Hyung-Gon;Chun, Young-Yun;Mun, Jong-Ha;Chung, Suck-Jong;Lee, Hyung-Jong
    • Korean Journal of Materials Research
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    • v.8 no.8
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    • pp.693-698
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    • 1998
  • The effects of $AI_{2}$$O_{3}$ and the ratio of $Na_2O/B_2O_3$ on the phase separation and optical properties of sodium borosilicate glass film fabricated by AFD(Aerosol Flame Deposition) were investigated. When AI,O, of 6wt% was added to $66SiO_2-27B_2O_3-7Na_2O$ the clear glass film without any crystallization was produced under air-quenching condition after consolidation. As the amount of $AI_{2}$$O_{3}$ increased from 1.5 to 6.0 wt% the refractive index linearly increased from 1.4610 to 1.4701, and the difference of TE and TM mode causing by residual stress in film increased gradually. However, the difference of TE and TM mode to reveal birefringence could be minimized by annealing below the glass transition temperature after consolidation and air quenching. On the other hand. as the ratio of $Na_2O/B_2O_3$ increased the refractive index and birefringence of glass film tended to increase, but the measurement of their values were not available at over the critical ratio of $Na_2O/B_2O_3$, because of the cloudiness due to crystallization. The phase separation was greatly accelerated with increasing the ratio of $Na_2O/B_2O_3$.

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Weathering Characteristics according to Seawater Immersion of the Magai Wareiishi Jizo (Buddhist Statue Carved on Rock Surface) in Hiroshima, Japan (일본 히로시마현 마애화령석지장(磨崖和靈石地藏)의 해수 침수에 의한 풍화특성)

  • Lee, Sun Myung;Lee, Myeong Seong;Chun, Yu Gun;Lee, Jae Man;Morii, Masayuki
    • Journal of Conservation Science
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    • v.28 no.4
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    • pp.329-341
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    • 2012
  • Magai Wareiishi Jizo (Buddhist statue carved on rock surface) is close to shoreline and a part of rock block is periodically immersed by seawater. Rock material of the Wareiishi-jizo statue is composed mainly of medium or coarse-grained biotite granite and very durable. However, physical properties of the rock have been changed according to the complex interactions of the salt solution and surrounding environment. Exfoliation of the rock surface is a serious condition by salt crystallization. Exfoliation (14.6%) is concentrated on the upper part of the rock block with mainly boundary of seawater as the center. On the other hand, lower part of the rock block show black layers by contaminants deposition. In addition, brown discoloration and biological contaminants is overlapped. Rock surface show high discoloration rate of 50.5% (black discoloration, 29.2% > yellow discoloration, 14.1% > brown discoloration, 4.4% > green discoloration, 2.9%). Upper part of the rock block had a lot of change in the physical properties than lower part that is immersed by seawater. In particular, surface properties of the rock block was very weak state at the boundary surface of seawater permeation.

Performance Evaluation of Stirrers for Preventing Dendrite Growth on Liquid Cathode (액체음극에서의 금속 수지상 성장 억제를 위한 교반기 성능평가)

  • Kim, Si-Hyung;Yoon, Dal-Seong;You, Young-Jae;Paek, Seung-Woo;Shim, Joon-Bo;Ahn, Do-Hee
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.7 no.2
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    • pp.125-131
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    • 2009
  • An electrolytic system (zinc anode-gallium cathode) was setup to evaluate the performance of several stirrers prepared for this study, where stirrers have been used to prevent uranium from forming dendrite on the cathode in pyrochemical process. In the case of no-stirring condition, zinc dendrites began to grow on the gallium surface in 1 hour and some dendrite grew out of the cathode crucible around 6 hours. When a rectangular stirrer or a tilt stirrer was rotated, at 40${\sim}$150 rpm, to mix the liquid gallium cathode, dendritic growth of zinc metal was prevented irrespective of revolution speed, but some of the deposits overflowed out of the cathode crucible owing to the large centrifugal forces at 150 rpm. The harrow stirrer did not nearly retard the dendrite growth at 40 rpm, but the dendrite growth was retarded at higher than 100 rpm and the zinc deposits also did not overflow at 150 rpm. Pounder could also prevent the dendrite growth to some extent but it had some difficulties in operation compared with other types of stirrers.

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