• Title/Summary/Keyword: deposition condition

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A Study on the Deposition Condition and Molecular Orientation of the Ultrathin Organic Films using the Langmuir-Blodgett Technique (Langmuir-Blodgett 법을 이용한 유기초박막의 제작조건 및 분자배향에 관한 연구)

  • 김태완;신동명;최강훈;권영수;강도열
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.43 no.2
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    • pp.303-311
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    • 1994
  • Optimum conditions for the deposition of N-docosylquinolium-TCNQ ultrathin organic films using the Langmuir-Blodgett etchnique and the molecular orientation and alignment of the LB films were studied. The $\pi$-A isotherm of the N-docosylquinolium-TCNQ was measured at the air-water interface varying with the subphase temperature, subphase pH, compressing speed and amounts of solutions for spreading. The LB film was deposited under the surface pressure of 30mN.m and 45mN/m and other deposition conditions. The molecular orientation and alignment of the LB films were studied by the polarization absorption technique. The $\pi$-A isotherm showed that the stable N-docosylquinolium -TCNQ monolayer was formed on the water surface at the condition of 25$^{\circ}C$,pH 5.6, molecular density of 2.1${\times}$10S014T~2.6${\times}$10S014T/cmS02T. The LB film was deposited under the surface pressure of 45mN/m had better packing density, orientation and alignment than the film of 30mN/m.

The fabrication of textured ZnO:Al films using HCI wet chemical etching (후 식각법을 이용한 Textured ZnO:Al 투명전도막 제조)

  • Yoo, Jin-Su;Lee, Jeong-Chul;Kang, Ki-Hwan;Kim, Seok-Ki;Yoon, Kyung-Hoon;Song, Jin-Soo;Park, I-Jun
    • Proceedings of the KIEE Conference
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    • 2002.07c
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    • pp.1482-1484
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    • 2002
  • Transparent conductive oxides (TCO) are necessary as front electrode for most thin film solar cell. In our paper, transparent conducting aluminum-doped Zinc oxide films (ZnO:Al) were prepared by rf magnetron sputtering on glass (Corning 1737) substrate as a variation of the deposition condition. After deposition, the smooth ZnO:Al films were etched in diluted HCI (0.5%) to examine the electrical and surface morphology properties as a variation of the time. The most important deposition condition of surface-textured ZnO films by chemical etching is the processing pressure and the substrate temperature. In low pressures (0.9mTorr) and high substrate temperatures $({\leq}300^{\circ}C)$, the surface morphology of films exhibits a more dense and compact film structure with effective light-trapping to apply the silicon thin film solar cells.

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Characterization of Single-walled Carbon Nanotubes Synthesized by Water-assisted Catalytic Chemical Vapor Deposition

  • Lee, Yeon-Ja;Kim, Bawl;Yu, Zhao;Lee, Cheol-Jin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.381-381
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    • 2011
  • The influence of the water vapor on the growth of single-walled carbon nanotubes (SWCNTs) was investigated. SWCNTs were synthesized by catalytic chemical vapor deposition of acetylene over Fe-Mo/MgO catalyst with injection of water vapor. The morphologies and structures of the water-assisted SWCNTs were investigated according to the growth conditions such as water vapor concentrations, flow rate of the gas, furnace temperature, and growth time. Water-assisted SWCNTs exhibited large bundle morphological features with well-alignment of each CNT, while SWCNTs synthesized in the absence of water vapor showed entangled CNT with the random orientation. We also found that the diameter of the SWCNT bundle could be controlled by the growth condition. In our optimal growth condition, the product yield and the purity were 300 wt. % and 75%, which were 7.5 and 2.5 times higher than those of SWCNTs synthesized without water vapor, respectively. More detail discussion will be offered at the poster presentation.

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Seasonal Deposition Characteristics of Water-soluble Ion Species in Ambient Aerosol in Iksan City (익산지역 대기에어로졸 중 수용성 이온성분의 계절별 침적 특성)

  • Kang, Gong-Unn
    • Journal of Environmental Health Sciences
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    • v.39 no.1
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    • pp.56-70
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    • 2013
  • Objectives: This paper aims to investigate the seasonal deposition characteristics of water-soluble ion species by comparing the deposition amount of two samples taken according to different sampling methods of deposition for ambient aerosol such as gases and particulate matters. Methods: Deposition samples were collected using two deposition gauges in the downtown area of Iksan City over approximately two weeks of each season in 2004. The type of deposition gauges consisted of two different sampling methods known as dry gauge and a wet gauge. The dry gauge was empty and used a dry PE bottle with an inlet diameter of 9.6 cm. Before the beginning of each deposition sampling, a volume of 30-50 ml distilled ionized water was added to the wet gauge to wet the bottom during the sampling period. Deposition samples were measured twice per day and analyzed for inorganic water-soluble ion species using ion chromatography. Results: The daily deposition amounts of all measured ions in the dry gauge and the wet gauge showed a significant increase when precipitation occurred, having no difference of deposition amount between in the wet gauge and in the dry gauge. By excluding two samples from rainy days during the sampling period, the mean daily deposition of all ions in dry gauge and wet gauge were $6.58mg/m^2/day$ and $18.16mg/m^2/day$, respectively. The mean deposition amounts of each ion species were higher in the wet gauge than in the dry gauge because of the surface difference of the sampling gauge, especially for $NH_4{^+}$ and ${SO_4}^{2-}$. The mean deposition amounts of $NH_4{^+}$ and ${SO_4}^{2-}$ in the wet gauge were found to be about 15.4 times and 5.2 times higher than that in dry gauge, with a pronounced difference between spring and summer, while the remaining ion species were 1.1-2.0 times higher in the wet gauge than in the dry gauge. Dominant species in the dry gauge were $Ca^{2+}$ and $NO_3{^-}$, accounting for 36.4% and 18.1% of the total ion deposition, whereas those in the wet gauge were $NH_4{^+}$ and ${SO_4}^{2-}$, accounting for 32.5% and 25.0% of the total ion deposition, respectively. Conclusion: The seasonal differences in deposition amounts of water-soluble ion species in ambient aerosol depending on the two types of different sampling methods were identified. This suggests that the removal of ambient aerosol is strongly influenced by the weather conditions of each season as well as the condition of earth's surface, such as dry ground and water.

Diamond thin film deposition on Ni in microwave plasma CVD (Microwave plasma CVD에서 Ni 기판에 다이아몬드 박막 증착)

  • Kim, Jin-Kon;Ryu, Su-Chak;Cho, Hyun
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.12 no.6
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    • pp.311-316
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    • 2002
  • Two different approaches, namely two-step deposition process and Bias-Enhanced Nucleation (BEN) technique have been examined for deposition of high quality diamond thin film on polycrystalline Ni which has low chemical activity with the carbon neutrals provided from the $CH_4/H_2$mixtures. A two-step deposition process, consisted of pre-deposition of soot layer at lower temperatures and subsequent deposition at higher temperature condition, has been developed to deposit diamond layer directly on Ni substrate. Diamond particles were observed after deposition step at $925^{\circ}C$ for 5 hours and those particles seem to be nucleated from the soot layer pre-deposited at lower temperatures ($810^{\circ}C$). Diamond particles of a substantial size were found on Ni substrate after biasing -220 V for 10 minutes and subsequent deposition for 2 hours while no diamond particles were observed under the conditions without applied bias.

Friction Properties of Carbon Coated Ultra-thin Film using Taguchi Experimental Design (다구찌 실험계획법을 이용한 탄소코팅 초박막의 마찰특성)

  • 안준양;김대은;최진용;신경호
    • Journal of the Korean Society for Precision Engineering
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    • v.20 no.4
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    • pp.143-150
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    • 2003
  • Frictional properties of ultra-thin carbon coatings on silicon wafer were investigated based on Taguchi experimental design method. Sensitivity analysis was performed with normal load, relative humidity, deposition process, and coating thickness as the variables. It was found that despite low thickness, the carbon coating resulted in relatively low friction coefficient. Also, the frictional behavior was affected significantly by humidity and normal load.

The Study of erosion characteristics for MgO layer in plasma display panel (플라즈마 디스플레이 패널의 MgO막 부식 특성에 관한 연구)

  • Shin, Jae-Hwa;Jeong, Dong-Hyo
    • Proceedings of the KIEE Conference
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    • 2002.06a
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    • pp.72-74
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    • 2002
  • In this paper, we showed the erosion characteristics of MgO protector layer releated to lifetime of plasma display panel(PDP). We observed MgO erosion characteristic as a functions of deposition conditions. In RIE condition of Xe gas, the lowest erosion rate appears in the conditions of no heating, bias voltage -30V and pressure 5mtorr. In general. as deposition rate increases, erosion rate decreases.

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ELECTROLESS PLATING OF NICKEL FOR MICRO-STRUCTURE FABRICATION

  • Jin, Huh;Lee, Jae-Ho
    • Journal of the Korean institute of surface engineering
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    • v.32 no.3
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    • pp.331-335
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    • 1999
  • Electroless plating nickel has superior mechanical property to electroplated nickel. Furthermore nickel can be coated on nonconducting substrate. In this research, electroless plating of nickel were conducted in different bath condition to find optimum conditions of electroless nickel plating for MEMS applications. The selectivity of activation method on several substrates was investigated. The effects of nickel concentration, reducing agent concentration and inhibitor on deposition rate were investigated. The effect of pH on deposition rate and content of phosphorous in deposited nickel was also investigated.

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A study on Oral condition of Pregnant Woman (임부의 구강상태에 관한 연구)

  • Choi, Sang-Ryul;Sung, Baik-Kyoon
    • The Journal of the Korean dental association
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    • v.11 no.10
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    • pp.643-647
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    • 1973
  • The auther has made the oral examination of 523 pregnant women-such as calculus, gingival disease, periodontal disease, and dental caries-who visit the dental department and obstetric department in National Medical Center in Seoul. After the above studies, results of the changes of the pregnant women's oral condition are following. 1. In creasing of calculus deposition due to the changes of saliva components. 2. Increasing of incidence of gingival and periodontal and pathological changes followed by calculus deposition. 3. Incidence of new cavities are not related to the pregnancy, but old cavities have become more progressive in dental caries.

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