• Korean Journal of Chemical Engineering
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• 제35권12호
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• pp.2355-2364
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• 2018

We evaluated the effect of particle size and associated dynamics on a hydrocyclone separation process in order to understand the movement of the particle trajectories inside the hydrocyclone via numerical analysis, with particles of acid hydrolysis residues discharged in $TiO_2$ production via the sulfate method as a case study. The values obtained from the numerical simulation were successfully compared with those from experimental tests in the literature, allowing a description of the dynamics of the particles, their acting forces, and their relevant properties together with separation efficiency. The results showed that particle motion is jointly controlled by the drag force, the pressure gradient force and the centrifugal force. With increasing particle size, the influence of the drag force is weakened, whereas that of the centrifugal force and pressure gradient is strengthened. Factors including particle density, slurry viscosity, and inlet slurry flow rate also contribute to a clear and useful understanding of particle motion behavior in the hydrocyclone as a method for improving the separation efficiency.

• Asian-Australasian Journal of Animal Sciences
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• 제26권11호
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• pp.1622-1629
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• 2013

The objective of this study was to develop a new method to separate phosvitin from egg yolk without using organic solvents. Phosvitin was extracted from yolk granules using 10% NaCl or 10% $(NH_4)_2SO_4$ (final concentration) and then treated with heat to precipitate the lipoproteins from the extracted solution. The optimal pH for the phosvitin extraction from yolk granules was determined, and the iron-binding ability of the extracted phosvitin (final product) was tested. Adding 10% $(NH_4)_2SO_4$ disrupted the granules, and the subsequent thermal treatment at $90^{\circ}C$ for 1 h precipitated low density and high density lipoproteins, which enabled separation of phosvitin by centrifugation. The phosvitin concentration in the extract was significantly higher when the pH of the solution was adjusted to pH ${\geq}9$. The purity and recovery rate of phosvitin at the end of the separation process were approximately 78% and 56%, respectively. The separated phosvitin was confirmed to have ferrous and ferric iron binding ability. The advantages of this new method compared with the traditional methods include no organic solvents and high-priced equipment are needed for the separation. Also, this method is more environment and consumer friendly than that of the traditional methods.

• 폴리머
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• 제24권3호
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• pp.342-349
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• 2000

아이소탁틱 폴리프로필렌과 대두유 시스템으로부터 열유도 상분리 및 연신공정에 의하여 중공사막을 제조하였다. 막의 구조와 성능에 관계되는 각종 조업변수들의 영향을 조사하였고 이들을 최적화하였다. 폴리프로필렌/대두유의 용융점도가 microfibril 형성에 영향을 미침을 확인하였고 기핵제를 첨가함에 따라 핵생성 밀도가 증가하여 연신에 의한 구정 간의 기공형성이 향상되었다. 막을 열처리함으로써 연신 시 유도되었던 stress를 이완시켜 막의 수축현상을 방지하여 다공도를 유지할 수 있었다. 기핵제를 첨가한 경우 고-액 상분리에 의하여 구조가 형성되며 응고조의 온도 변화에 따라 핵 생성 밀도가 변화하게 되고 이에 따라 연신에 의한 기공 형성이 영향을 받게 되었다. 기핵제를 첨가하지 않은 경우 핵 생성이 활발하지 않아서 주로 액-액 상분리 거동이 구조 형성에 영향을 미치게 되며 응고조 온도 변화에 따른 효과가 기핵제를 넣은 경우와는 반대의 경향을 나타내었다.

• Elastomers and Composites
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• 제54권1호
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• pp.54-60
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• 2019

The rapid development of the automobile industry is an important factor that led to the dramatic development of synthetic rubber. The tread part of tire that comes in direct contact with the road surface is related to the service life of the tire. Rubber compounds used in tire treads are often blended with SBR (styrene-butadiene rubber) and BR (butadiene rubber) to satisfy physical property requirements. However, when two or more kinds of rubber are blended, phase separation and silica dispersion problems may occur due to non-uniform mixing of the rubber. Therefore, in this study, we synthesized an SBR copolymer with the same composition as that of a typical SBR/BR blend compound by controlling butadiene content during ESBR (emulsion styrene-butadiene rubber) synthesis. Subsequently, silica filled compounds were manufactured using the synthesized ESBR, and their mechanical properties, dynamic viscoelasticity, and crosslinking density were compared with those of the SBR/BR blended compound. When the content of butadiene was increased in the silica filled compound, the cure rate accelerated due to an increased number of allylic positions, which typically exhibit higher reactivity. However, the T-2 compound with increased butadiene content by synthesis less likely to show an increase in crosslink density due to poor silica dispersion. In addition, the T-3 compound containing high cis BR content showed high crosslink density due to its monosulfide crosslinking structure. Because of the phase separation, SBR/BR blend compounds were easily broken and showed similar $M_{100%}$ and $M_{300%}$ values as those of other compounds despite their high crosslink density. However, the developed blend showed excellent abrasion resistance due to the high cis-1,4 butadiene content and low rolling resistance due to the high crosslink density.

• Korean Membrane Journal
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• 제2권1호
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• pp.36-47
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• 2000

This paper deals with the separation of MTBE-methanol mixtures using crosslinked Poly(vinyl alcohol)(PVA) membranes with sulfur-succinic acid(SSA) as a crosslinking agent by pervaporation and vapor permeation technique. The operating temperatures, methanol concentration in feed mixtures, and SSA concentrations in PVA membranes were varied to investigate the separation performance of PVA/SSA membranes and the optimum separation characteristics by pervaporation and vapor permeation. And also, for PVA/SSA membranes, the swelling measurements were carried out to study the transport phenomena. The swelling measurements were carried out for pure MTBE and methanol, and MTBE/methanol=90/10, 80/20 mixtures using PVA/SSA membranes with varying SSA compositions. There are two factors of the membrane network and the hydrogen bonding. In pervaporation separation was also carried out for MTBE/methanol=90/10, 80/20 mixtures at various temperatures. The sulfuric acid group in SSA took an important role in the membrane performance. The crosslinking effect might be over the hydrogen bonding effect due to the sulfuric acid group at 3 and 5% SSA membranes, and this two factors act vice versa on 7% SSA membrane. In this case, the 5% SSA membrane shows the highest separation factor of 2,095 with the flux of 12.79g/㎡$.$hr for MTBE/methanol=80/20 mixtures at 30$^{\circ}C$ which this mixtures show near the azeotopic composition. Compared to pervaporation, vapor permeation showed less flux and similar separation factor. In this case, the flux decreased significantly because of compact structure and the effect of hydrogen bonding. In vapor permeation, density or concentration of methanol in vaporous feed is lower than that of methanol in liquid feed, as a result, the hydrogen bonding portion between the solvent and the hydroxyl group in PVA is reduced in vapor permeation. In this case, the 7% SSA membranes shows the highest separation factor of 2,187 with the flux of 4.84g/㎡$.$hr for MTBE/methanol=80/20 mixtures at 30$^{\circ}C$.

• 멤브레인
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• 제2권1호
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• pp.36-36
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• 1992

This paper deals with the separation of MTBE-methanol mixtures using crosslinked Poly(vinyl alcohol)(PVA) membranes with sulfur-succinic acid(SSA) as a crosslinking agent by pervaporation and vapor permeation technique. The operating temperatures, methanol concentration in feed mixtures, and SSA concentrations in PVA membranes were varied to investigate the separation performance of PVA/SSA membranes and the optimum separation characteristics by pervaporation and vapor permeation. And also, for PVA/SSA membranes, the swelling measurements were carried out to study the transport phenomena. The swelling measurements were carried out for pure MTBE and methanol, and MTBE/methanol=90/10, 80/20 mixtures using PVA/SSA membranes with varying SSA compositions. There are two factors of the membrane network and the hydrogen bonding. In pervaporation separation was also carried out for MTBE/methanol=90/10, 80/20 mixtures at various temperatures. The sulfuric acid group in SSA took an important role in the membrane performance. The crosslinking effect might be over the hydrogen bonding effect due to the sulfuric acid group at 3 and 5% SSA membranes, and this two factors act vice versa on 7% SSA membrane. In this case, the 5% SSA membrane shows the highest separation factor of 2,095 with the flux of 12.79g/㎡·hr for MTBE/methanol=80/20 mixtures at 30℃ which this mixtures show near the azeotopic composition. Compared to pervaporation, vapor permeation showed less flux and similar separation factor. In this case, the flux decreased significantly because of compact structure and the effect of hydrogen bonding. In vapor permeation, density or concentration of methanol in vaporous feed is lower than that of methanol in liquid feed, as a result, the hydrogen bonding portion between the solvent and the hydroxyl group in PVA is reduced in vapor permeation. In this case, the 7% SSA membranes shows the highest separation factor of 2,187 with the flux of 4.84g/㎡·hr for MTBE/methanol=80/20 mixtures at 30℃.

• Korean Chemical Engineering Research
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• 제57권4호
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• pp.484-491
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• 2019

산업적으로 중요한 가치를 지니는 폴리프로필렌 합성의 원료인 프로필렌을 고순도로 얻기 위해서는 효율적인 프로필렌/프로판 분리 기술이 필요하다. 기존 증류 공정은 프로필렌과 프로판의 유사한 물리화학적 성질로 인해 매우 높은 에너지가 소모되기때문에, 흡착분리 기술이큰관심을받고있다. 본연구에서는 Grand Canonical Monte Carlo (GCMC) 분자 모사를 활용하여 기공의 형태가 다른 두 종류의 유무기복합다공체(Metal-Organic Frameworks)의 빈금속배위자리(open metal sites) 흡착 강도를 임의로 조절하며 프로필렌/프로판 흡착 분리 성능의 변화를 조사하였다. 흡착 분리 성능은 작업 용량, 선택도, Adsorption Figure of Merit (AFM) 등으로 평가하였고, 이를 통해 흡착제가 최적의 프로필렌/프로판 분리 성능을 가지기 위해 필요한 흡착 사이트의 밀도 및 강도 그리고 온도 조건 등을 제시하였다.

• 한국응용과학기술학회지
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• 제28권1호
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• pp.95-101
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• 2011

We estimated on the stability of W/O type emulsified fuel using by capacitance sensor, so it concluded the following conclusions. For the first 24 hours, prepared emulsified fuel reveals phase separation ratio of 5%, maintains stable status which verifies the stability of emulsified fuel. Adding more water increases the phase separation ratio rapidly, and adding more surfactant displays stable emulsification. Adding water causes larger size of water droplet diameter, and adding surfactant mixture causes smaller size of water droplet diameter. In conclusion, the size of W/O type emulsified fuel water droplet diameter is directly related to the volume of surfactant, and density of water droplet diameter changes thedistribution according to water contents.

• 대한설비공학회:학술대회논문집
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• 대한설비공학회 2008년도 하계학술발표대회 논문집
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• pp.271-276
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• 2008

The oil trap in oil separator is one of the most important characteristics for normal operation of compressor. In this study, oil separation characteristics has been investigated for $CO_2$/PAG mixture using a gravity type of oil separator. The experimental study has been carried out in the range of oil concentration 0 to 5 weight-percent and the mixture temperature range of $0^{\circ}C$ to $15^{\circ}C$. The results obtained indicate that oil separation ratio in oil separator is increased with an increase in the oil concentration and mixture temperature.

• 설비공학논문집
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• 제18권4호
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• pp.359-369
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• 2006

This study aims deriving analysis the flow characteristic of kitchen hood system with using 3-D numerical analysis method and improving the system to expel pollutes more efficiently. This system is applied with $k-{\varepsilon}$ turbulent model and using incompressibility viscosity flow range and boundary condition which are related to Bossinesq approximation following density variation in control volume. To understand the flow characteristics of four models, this study only focuses on velocity field, temperature field, and concentration field varying with followings whether separation plate is set or not and the shapes of separation plates. The quantity of air, speed of exhaust fan and temperature and concentration of heating source are concerned as constant values.