• Title/Summary/Keyword: density separation

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Evaluation of the Effective Charge Density on Low Pressure Nanofiltration with the Separation Characteristics of Monovalent and Divalent Solutes in the Production of Drinking Water

  • Oh, Jeong-Ik;Taro, Urase
    • Environmental Engineering Research
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    • v.16 no.1
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    • pp.29-34
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    • 2011
  • The electric charge on a membrane was investigated by analyzing the experimental rejection of various monovalent and divalent ionic solutes. The characteristics of the separation of ionic solutes using various nanofiltration membranes were obtained from an experimental nanofiltration set-up, with a surface area of $40cm^2$ under the operational pressures between 0.25-0.3 MPa. The state of the membrane electric charge was observed using separation coefficients, i.e., the permeation ratio of monovalent to divalent ions. To confirm the state of the membrane charge observed via the separation coefficient, a calculation using the extended Nernst-Planck equation, coupled with the Donnan equilibrium, assuming different electric charge states of the membrane, was compared with the experimental rejection of ionic solutes. The examination of the characteristics of separation using three types of nanofiltration membranes showed that one of the membranes carried a negative/positive double charge density inside, while other two membranes carried either a positive or negative charge density.

Development of Curdlan Separation Process with Density Gradient Centrfugation (Density Gradient를 이용한 식품소재를 커들란의 분리공정개발)

  • 김봉영;이중헌
    • KSBB Journal
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    • v.16 no.5
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    • pp.523-525
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    • 2001
  • Curdlan is one biopolymer composed of ${\beta}$1,3-glucan and dissolved in a alkali solution but formed salt under neutral or acid condition. It was produced by Agrobactrium species and the separation process is necessary to make pure curdlan from the culture broth. The pH swing separation method was as feasible separation process using solubility changes with the pH difference. however, this method requires a lot of acid and alkali solution also produces a lot of waste. Therefore, an efficient process which could save energy and minimize toxic waste was developed. A density gradient separation process was developed in this research. High density sucrose solution was used as a separation agent. Curdlan was separated from the culture broth when the density of the sucrose solution was 1.15 g/L. Since the curdlan was produced on the surface of cell wall. the pre-treatment of culture broth was necessary. Curdlan recovery yield was increased up to 83% with the homogenization of the culture broth and further increased up to 87% with the treatment of alkai-acid solution.

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A Study on the Preparation of a Linear Low Density Polyethylene particles by Thermally Induced Phase Separation (열유도 상분리에 의한 선형 저밀도 폴리에틸렌 입자 제조에 관한 연구)

  • Park, Keun-Ho;Jang, Young-Min
    • Journal of the Korean Applied Science and Technology
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    • v.28 no.4
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    • pp.386-392
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    • 2011
  • We are crystallized to the linear low density polyethylene(LLDPE) particles by a thermally induced phase separation(TIPS). TIPS process based on the phase separation mechanism was performed for the LLDPE system which undergoes liquid-solid phase separation. The linear low density polyethylene particle formation occurred by the nucleation and growth mechanism in the metastable region. Although the growth rates depended on the experimental conditions such as the polymer concentration and temperature, the particles were larger when the polymer concentration was higher or temperature was higher. The particles were observed by SEM. The LLDPE particle size distribution became broader when the polymer concentration was higher.

A Study on the Crystallization of Low Density Polyethylene Microparticles in $n$-Dodecanol Solution ($n$-Dodecanol 용액에서 저밀도폴리에틸렌 마이크로 입자 결정화에 관한 연구)

  • Park, Keun-Ho;Jang, Young-Min
    • Journal of the Korean Applied Science and Technology
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    • v.28 no.3
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    • pp.306-312
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    • 2011
  • In this study, we are crystallized to the low density polyethylene (LDPE) micro-particles in $n$-dodecanol solution by thermally induced phase separation(TIPS) method. The Low density polyethylene micro-particles is used in a wide variety of polymer coatings and industrial application. The utility of that for a particular application depends on a number of factors such as the particle size and distribution, and chemical composition of the materials. However, there are still needs for new methods of preparation which will provide the structure with unique sizes. The widely used processes for micro-size particles are crystallization method and thermally induced phase separation. TIPS process based on the phase separation mechanism was performed for the LDPE system which undergoes liquid-solid phase separation. Effects of various operating parameters were examined on the structure variation of the particles. Professionality, take-up speed and crystallization rate depended on temperature and concentration of polymer in solution.

Adaptive Signal Separation with Maximum Likelihood

  • Zhao, Yongjian;Jiang, Bin
    • Journal of Information Processing Systems
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    • v.16 no.1
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    • pp.145-154
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    • 2020
  • Maximum likelihood (ML) is the best estimator asymptotically as the number of training samples approaches infinity. This paper deduces an adaptive algorithm for blind signal processing problem based on gradient optimization criterion. A parametric density model is introduced through a parameterized generalized distribution family in ML framework. After specifying a limited number of parameters, the density of specific original signal can be approximated automatically by the constructed density function. Consequently, signal separation can be conducted without any prior information about the probability density of the desired original signal. Simulations on classical biomedical signals confirm the performance of the deduced technique.

The Phase Separation of Low Alkali Borosilicate Glass by Substituting $Li_2O$ for $Na_2O$ (산화리튬의 치환에 따른 붕규산 유리의 분상에 관한 연구)

  • 양중식
    • Journal of the Korean Ceramic Society
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    • v.18 no.1
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    • pp.27-34
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    • 1981
  • The phase separation of low-alkali borosilicate glass with the composition of $6.25Na_2O$.$18.75B_2O_3$.$75.00SiO_2$(mole%) substituting $Li_2O$ for $Na_2O$ was studied. The phase separation in the temperature range of transformation was examined with various heating temperatures and soaking times. Durability to water, thermal expansion and specific density of the specimen were investigated and the microstructure of the separated phase was also observed by transmission electron micrograph techniques. The maximum alkali extraction result with the best phase separation effect was obtained when $Na_2O$ of the base glass was replaced with $1.88Li_2O$ (mole %) and electron micrograph of carbon film replica of $1.88Li_2O$$4.37Na_2O$.$18.75B_2O_3$.$75.00SiO_2$ (mole %) glass showed that the glass consisted of homogeneous two phases. The minimum specific density was shown with the specimen treated at 57$0^{\circ}C$ and it was also shown that the longer the treating time the lower the specific density. The apparent activation energies of approximately 45 kcal/mole by the alkali extraction and 43kcal/mole by the thermal expansion method were derived from the Arrhenius plots, respectively.

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Correlation between pit formation and phase separation in thick InGaN film on a Si substrate

  • Woo, Hyeonseok;Jo, Yongcheol;Kim, Jongmin;Cho, Sangeun;Roh, Cheong Hyun;Lee, Jun Ho;Kim, Hyungsang;Hahn, Cheol-Koo;Im, Hyunsik
    • Current Applied Physics
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    • v.18 no.12
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    • pp.1558-1563
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    • 2018
  • We demonstrate improved surface pit and phase separation in thick InGaN grown on a GaN/Si (111) substrate, using plasma-assisted molecular beam epitaxy with an indium modulation technique. The formation of surface pit and compositional inhomogeneity in the InGaN epilayer are investigated using atomic force microscopy, scanning electron microscopy and temperature-dependent photoluminescence. Indium elemental mapping directly reveals that poor compositional homogeneity occurs near the pits. The indium-modulation epitaxy of InGaN minimizes the surface indium segregation, leading to the reduction in pit density and size. The phase separation in InGaN with a higher pit density is significantly suppressed, suggesting that the pit formation and the phase separation are correlated. We propose an indium migration model for the correlation between surface pit and phase separation in InGaN.

Study on the Pervaporation Characteristic of Water-alcohol Mixtures through Aromatic Polyetherimide Membranes : II. the Pervaporation of Water-isopropanol Mixtures by the Density Change of Skin Layer (방향계 폴리에테르이미드막의 물-알콜 혼합액의 투과증발 특성에 관한 연구 : II.skin layer의 density변화에 의한 물-이소프로판올 혼합액의 투과증발)

  • Kim, S.G.;Jegal, J.G.;Lee, K.H.
    • Applied Chemistry for Engineering
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    • v.8 no.5
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    • pp.853-859
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    • 1997
  • For asymmetric polyetherimide membranes having a dense layer gradient structure on the skin layer, the morphology change and pervaporation behaviors of water/isopropanol mixture through chemical modification of dense skin layer were investigated. The extent of the density was controlled by the evaporation, time, and when the evaporation time was increased from 0 min to 4 min, the permeation flux was decreased, the separation factor was increased. Also, the pervaporation behaviors of the polyetherimide membranes modified with sodium hydroxide solution, as the modification time of dense skin layer increased, the selectivity increased, and the permeation flux decreased. The morphology change identified by SEM shows that the density of dense skin layer tends to increase with increasing modification time, this result is consistent with above observations.

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A Study on the Prediction Method of Belt Edge Separation due to the Belt Width Variation of a Tire (타이어의 Belt Width 변화에 따른 Belt Edge Separation 예측 방법에 관한 연구)

  • Kim Seong-Rae;Sung Ki-Deug;Kim Son-Joo;Cho Choon-Tack
    • Journal of the Korean Society for Precision Engineering
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    • v.23 no.8 s.185
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    • pp.137-144
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    • 2006
  • This study is concerned with the relation between steelbelt width and belt edge separation of a tire. Belt edge separation causes tire burst and threatens passenger's safety. For the reason, it is important to predict durability caused by belt edge separation in the early stage of the tire structure design. Usually, passenger car tires have two layers of steelbelts having opposite steel cord's angles, which makes a shear behaviour between each belt layer. Shear behaviour is one of reason to cause belt edge separation. In this study, to predict belt edge separation, we suggested the prediction method of belt edge separation and evaluated the effect of steelbelt width on the belt edge separation using FEM. We also studied on main parameters to affect shear behaviour at the belt edge area.

An Algorithm of Score Function Generation using Convolution-FFT in Independent Component Analysis (독립성분분석에서 Convolution-FFT을 이용한 효율적인 점수함수의 생성 알고리즘)

  • Kim Woong-Myung;Lee Hyon-Soo
    • The KIPS Transactions:PartB
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    • v.13B no.1 s.104
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    • pp.27-34
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    • 2006
  • In this study, we propose this new algorithm that generates score function in ICA(Independent Component Analysis) using entropy theory. To generate score function, estimation of probability density function about original signals are certainly necessary and density function should be differentiated. Therefore, we used kernel density estimation method in order to derive differential equation of score function by original signal. After changing formula to convolution form to increase speed of density estimation, we used FFT algorithm that can calculate convolution faster. Proposed score function generation method reduces the errors, it is density difference of recovered signals and originals signals. In the result of computer simulation, we estimate density function more similar to original signals compared with Extended Infomax and Fixed Point ICA in blind source separation problem and get improved performance at the SNR(Signal to Noise Ratio) between recovered signals and original signal.