• Title/Summary/Keyword: dendrites

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Influences on Distribution of Solute Atoms in Cu-8Fe Alloy Solidification Process Under Rotating Magnetic Field

  • Zou, Jin;Zhai, Qi-Jie;Liu, Fang-Yu;Liu, Ke-Ming;Lu, De-Ping
    • Metals and materials international
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    • v.24 no.6
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    • pp.1275-1284
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    • 2018
  • A rotating magnetic field (RMF) was applied in the solidification process of Cu-8Fe alloy. Focus on the mechanism of RMF on the solid solution Fe(Cu) atoms in Cu-8Fe alloy, the influences of RMF on solidification structure, solute distribution, and material properties were discussed. Results show that the solidification behavior of Cu-Fe alloy have influenced through the change of temperature and solute fields in the presence of an applied RMF. The Fe dendrites were refined and transformed to rosettes or spherical grains under forced convection. The solute distribution in Cu-rich phase and Fe-rich phase were changed because of the variation of the supercooling degree and the solidification rate. Further, the variation in solute distribution was impacted the strengthening mechanism and conductive mechanism of the material.

Microstructure and Mechanical Properties of Twin-Roll Strip-Cast Al-5.5Mg-0.02Ti Alloy Sheet (쌍롤 박판주조법으로 제조된 Al-5.5Mg-0.02Ti합금의 미세조직 및 기계적 특성)

  • Cheon, Boo-Hyeon;Han, Jun-Hyun;Kim, Hyoung-Wook;Lee, Jae-Chul
    • Korean Journal of Metals and Materials
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    • v.48 no.5
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    • pp.387-393
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    • 2010
  • High-strength aluminum alloy sheets with high magnesium contents were fabricated by a strip caster equipped with an asymmetric nozzle, which has been proven to be effective for reducing surface defects and internal segregation. 4 mm thick as-cast sheets consisting of fine dendrites and minor $Al_{8}Mg_{5}$ segregation were hot-rolled successfully to 1 mm sheets and subsequently annealed at various temperatures. The sheet revealed the tensile strength and elongation of 306 MPa and 34%, respectively, when it was rolled at 250${^{\circ}C}$ and subsequently annealed at 475${^{\circ}C}$, which exhibits the feasibility of the practical application for autobodies. The observed mechanical properties were explained on the basis of the microstructural characteristics of the alloy sheets.

Difference of Potential Range Formed at the Anode Between Water Drop Test and Temperature Humidity Bias Test to Evaluate Electrochemical Migration of Solders for Printed Circuit Board

  • Young Ran Yoo;Young Sik Kim
    • Corrosion Science and Technology
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    • v.22 no.3
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    • pp.153-163
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    • 2023
  • Two types of accelerated tests, Water Drop Test (WDT) and Temperature-Humidity-Bias Test (THBT), can be used to evaluate the susceptibility to electrochemical migration (ECM). In the WDT, liquid water is directly applied to a specimen, typically a patterned conductor like a printed circuit board. Time to failure in the WDT typically ranges from several seconds to several minutes. On the other hand, the THBT is conducted under elevated temperature and humidity conditions, allowing for assessment of design and life cycle factors on ECM. THBT is widely recognized as a more suitable method for reliability testing than WDT. In both test methods, localized corrosion can be observed on the anode. Composition of dendrites formed during the WDT is similar to that formed during THBT. However, there is a lack of correlation between the time to failure obtained from WDT and that obtained from THBT. In this study, we investigated the relationship between electrochemical parameters and time to failure obtained from both WDT and THBT. Differences in time to failure can be attributed to actual anode potential obtained in the two tests.

Recent Progress of Alloy-Based All-Solid-State Li-Ion Battery Anodes (전고체 리튬 이차전지용 합금계 음극 소재의 연구 동향)

  • Jeong-Myeong Yoon;Cheol-Min Park
    • Corrosion Science and Technology
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    • v.22 no.6
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    • pp.466-477
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    • 2023
  • The increasing demand for high-performance energy storage systems has highlighted the limitations of conventional Li-ion batteries (LIBs), particularly regarding safety and energy density. All-solid-state batteries (ASSBs) have emerged as a promising next-generation energy storage system, offering the potential to address these issues. By employing nonflammable solid electrolytes and utilizing high-capacity electrode materials, ASSBs have demonstrated improved safety and energy density. Automotive and energy storage industries, in particular, have recognized the significance of advancing ASSB technology. Although the use of Li metal as ASSB anode is promising due to its high theoretical capacity and the expectation that Li dendrites will not form in solid electrolytes, persistent problems with Li dendrite formation during cycling remain. Therefore, the exploration of novel high-performance anode materials for ASSBs is highly important. Recent research has focused extensively on alloy-based anodes for ASSBs, owing to their advantages of no dendrite formation and high-energy density. This study provides a comprehensive review of the latest advancements and challenges associated with alloy-based anodes for ASSBs.

Phase-Field Modelling of Zinc Dendrite Growth in ZnAlMg Coatings

  • Mikel Bengoetxea Aristondo;Kais Ammar;Samuel Forest;Vincent Maurel;Houssem Eddine Chaieb;Jean-Michel Mataigne
    • Corrosion Science and Technology
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    • v.23 no.2
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    • pp.93-103
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    • 2024
  • In the present work, a phase-field model for dendritic solidification is applied to hot-dip ZnAlMg coatings to elucidate the morphology of zinc dendrites and the solute segregation leading to the formation of eutectics. These aspects define the microstructure that conditions the corrosion resistance and the mechanical behaviour of the coating. Along with modelling phase transformation and solute diffusion, the implemented model is partially coupled with the tracking of crystal orientation in solid grains, thus allowing the effects of surface tension anisotropy to be considered in multi-dendrite simulations. For this purpose, the composition of a hot-dip ZnAlMg coating is assimilated to a dilute pseudo-binary system. 1D and 2D simulations of isothermal solidification are performed in a finite element solver by introducing nuclei as initial conditions. The results are qualitatively consistent with existing analytical solutions for growth velocity and concentration profiles, but the spatial domain of the simulations is limited by the required mesh refinement.

Ultrastructural Changes in the Neuropil of the Anterior Thalamic Nucleus following the Lesion in the Mamillary Body (유두체 손상이 시상전핵 조직상의 미세구조에 미치는 영향)

  • Lee, Byoung-Ho;Ko, Jeong-Sik;Ahn, E-Tay;Yang, Nam-Gil
    • Applied Microscopy
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    • v.18 no.2
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    • pp.177-186
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    • 1988
  • Degeneration of the axon terminals of mamillo-thalamic tract following the electrical coagulation of mamillary body is well known. In this study, the author investigated the ultrastructural alterations of neuropil components, initiated by terminal degenerations. Rats weighing approximately 250 gm were fixed on the stereotaxic instrument(David Kopf Inc., Heavy duty model), and NE 300 active electrode(Rhodes Med. Instr. Inc.) was introduced to the mamillary position of anterior 3.8 mm, lateral 0.5 mm, height 3.8 mm and lateral angle of $23^{\circ}$ according to De Groot's Atlas. Electric current of 20 mA was applied during 1 minute between active and inactive electrodes with Radio Frequency Lesion Generator(RFG 4, Radionics Inc.). Two hours, 2 days, 1 week and 2 weeks following the electrical coagulation of mamillary body, ipsilateral anterior thalamic nucleus was fixed in 1% glutaraldehyde-l% paraformaldehyde and 2% osmium tetroxide, embedded in Araldite mixture, cutted with LKB ultra tome V, stained with uranyl acetate-lead citrate and observed with JEOL 100 CX electron microscope. Observed results were as follows; 1. Degenerated mamillo-thalamic synapses were observed to form asymmetric axospinous or axo-dendritic types. 2. Terminal degeneration was not easily discernible at 2 hours interval after mamillary lesion, but following 2 days the terminal degeneration was apparent. 3. Postsynaptic spines, dendrites and even their cell bodies show edematic changes caused by the degeneration of postsynaptic counterpart. 4. Astrocytic territories, including perivascular processes forming glial limitans of blood-brain barrier, exhibit remarkable expansion. 5. Oligoglia and astroglia are actively engaged in the removal of degenerated elements. 6. Active forms of microglia were increased. 7. The observed results may represent typical ultrastructural alteration pattern within neuropil following the degeneration of certain input axon terminals.

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Fine Structure of the Neuroganglia in the Central Nervous System of the Harvestman Leiobunum japonicum (Arachnida: Opiliones)

  • Park, Yong-Ki;Gu, Hye-Yoon;Kwon, Hyun-Jung;Kim, Hoon;Moon, Myung-Jin
    • Applied Microscopy
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    • v.48 no.1
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    • pp.17-26
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    • 2018
  • The characteristic features of the arachnid central nervous system (CNS) are related to its body segmentation, and the body in the Opiliones appears to be a single oval structure because of its broad connection between two tagmata (prosoma and opisthosoma). Nevertheless, structural organization of the ganglionic neurons and nerves in the harvestman Leiobunum japonicum is quite similar to the CNS in most other arachnids. This paper describes the fine structural details of the main groups of neuropiles in the CNS ganglia revealed by the transmission electron microscopy. In particular, electron-microscopic features of neural clusters in the main neuroganglia of the CNS (supraesophageal ganglion, protocerebral ganglion, optic lobes, central body, and subesophageal ganglion) could provide indications for the nervous pathways associated with nerve terminations and plexuses. The CNS of this harvestman consists of a supraesophageal ganglion (brain) and a subesophageal mass, and there are no ganglia in the abdomen. Cell bodies of neuroganglia are found in the periphery, but central parts of the ganglia are mostly fibrous in all ganglia. Neuroglial cells occupy the spaces left by nerve cells. Since the nerve cells in the ganglia are typical composed of monopolar neurons, axons and dendrites of neurons are distributed along the same direction.

Microstructural evolution of primary solid particles and mechanical properties of AI-Si alloys by rheocasting (AI-Si계 리오캐스팅합금의 초정입자의 응고조직 및 기계적성질)

  • Lee, J.I.;Lee, H.I.;Ryoo, Y.H.;Kim, D.H.;Kim, M.I.
    • Journal of the Korean Society for Heat Treatment
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    • v.7 no.4
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    • pp.244-252
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    • 1994
  • The morphological changes of primary solid particles as a fuction of process time on Al-Si alloys during semi-solid state processing with a shear rate of 200s were studied. In hypereutectic Al-15.5wt%Si alloy, it was observed that primary Si crystals are fragmented in the early stage of stirring and morphologies of primary Si crystals change from faceted to spherical during isothermal shearing for 60 minutes. In quaternary Al-12.5wt%Si-2.9wt%Cu-0.7wt%Mg alloy system, it was observed both primary silicon and ${\alpha}$-alumunum particles. Microstructural evolution of primary Si crystals was similar to that of the hypereutectic Al-Si alloy but equiaxed ${\alpha}$-Al dendrites are broken into nearly spherical at the early stage of shearing and later stage of the isothermal shearing ${\alpha}$- Al particles are slightly coarsoned by Ostwald ripening. Mechanical properties of Al-Si-Cu-Mg alloy were compared to those from other processes (squeeze casting and gravity casting). After T6 heat treatment, comparable values of hardness were obtained while slightly lower compressive strength values were observed in rheocast alloy. The elongation, on the other hand, exhibited significant increasement of 15% over gravity cast alloy.

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Distribution of Substance P Immunoreactive Neurons and Their Synaptic Organization in the Cat Thoracic Cord (고양이 흉수에서 Substance P 면역반응 신경원의 분포와 연접연구)

  • Lee, Seung-Kyun;Park, Soo-Seog
    • The Korean Journal of Pain
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    • v.9 no.2
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    • pp.326-335
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    • 1996
  • Background: Though a number of studies have described the distribution of substance P(SP)-like immunoreactivity in the spinal cord, they have been focused on lamina I and II of the dorsal horn and there are little morphological studies on the topographic distribution and ultrastructure of the SP immunoreactive neurons especially in the ventral horn of the spinal cord. this study was conducted to identify distribution pattern of SP immunoreactive neurons and to difine the synaptic organization of their processes in ventral horn of the thoracic cord of the cat by preembbeding immunocytochemical method using SP antiserum. Methods: Five adults cats of either sex were used and deeply anesthetized by intramuscular injection of ketamine. After removal of the spinal cord, samples of thoracic cord were taken and placed in fresh fixative at $4^{\circ}C$ for 2 hours. Transverse sections $50{\mu}m$ thick were processed using the preembbeding immunocytochemical method and incubated consecutively in the specific primary antibody and the 10% normal goat serum, the rabbit anti-substance P antiserum, the biotin-labelled goat anti-rabbit IgG and finally the avidin-biotin-peroxidase complex. The processed tissue sections were throughly washed and stained in the black with 1% uranyl acetate. Section were examined on a electron microscope. Results: 1) SP immunoreactive neurons were observed in the gray matter around central canal. 2) In lamina I and II SP immunoreactivity was observed in both myelinated and unmyelinated nerve fibers, but in ventral horn only in the unmyelinated nerve fibers. 3) SP immunoreactive axon terminals with small round and large dense core vesicles made chemical synapses onto the dendrites of motor neurons in the ventral horn. Conclusion: SP immunoreactive neurons might play an important role in modulation of motor neurons in the ventral horn of the thoracic cord of the cat.

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The effects of Salviae Miltiorrhizae Radix(SR), Carthami Flos(CF) and Acori Graminei Rhizoma(AR) to cerebral contusion (뇌좌상(腦挫傷)에 단삼(丹蔘), 홍화(紅花), 석창포(石菖蒲)가 미치는 영향(影響))

  • Kim Haeng-Jin;Jeon Sang-Yun;Kim Jung-Sang;Kim Kyoung-Soo;Hong Seok
    • Herbal Formula Science
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    • v.11 no.2
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    • pp.159-171
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    • 2003
  • This study was done to investigate effects of SR, CF and AR to angiogenesis of cerebral tissues, protecting damage of cerebral neurons and activating them in cerebral contusion-induced rats. I observed these conclusions as follows ; 1. Observation of VEGF-immunoreactive cells : Groups of administered AR were not meaningful in increasing VEGF-immunoreactive cells for 3 days and 7 days, groups of administered SR meaningfully increased them to control groups in all groups, and groups of administered CF meaningfully increased them to control groups in all groups, too, interestingly, increased double to control group for 7 days. 2. Observation on cerebral neurons by Cresyl violet stain : Dendrites and axons of groups of administered SR, AR for 3 days were clearly observed to control group. Cerebral neurons of groups of administered CF for 3days and 7 days were increased a little, but were not meaningful. In conclusion, AR will be careful of being used in cerebral contusion. CF and SR were effective to activating cerebral hemokinesis by inducing angiogenesis in trauma of tissue, but weakly to protecting trauma of cerebral neurons and activating them. I think more studies will be done in these facts.

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