• Title/Summary/Keyword: degree of degradation

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Corrosion Behavior of Ti-6Al-4V Alloy after Plasma Electrolytic Oxidation in Solutions Containing Ca, P and Zn

  • Hwang, In-Jo;Choe, Han-Cheol
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2016.11a
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    • pp.120-120
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    • 2016
  • Ti-6Al-4V alloy have been used for dental implant because of its excellent biocompatibility, corrosion resistance, and mechanical properties. However, the integration of such implant in bone was not in good condition to achieve improved osseointergraiton. For solving this problem, calcium phosphate (CaP) has been applied as coating materials on Ti alloy implants for hard tissue applications because its chemical similarity to the inorganic component of human bone, capability of conducting bone formation and strong affinity to the surrounding bone tissue. Various metallic elements, such as strontium (Sr), magnesium (Mg), zinc (Zn), sodium (Na), silicon (Si), silver (Ag), and yttrium (Y) are known to play an important role in the bone formation and also affect bone mineral characteristics, such as crystallinity, degradation behavior, and mechanical properties. Especially, Zn is essential for the growth of the human and Zn coating has a major impact on the improvement of corrosion resistance. Plasma electrolytic oxidation (PEO) is a promising technology to produce porous and firmly adherent inorganic Zn containing $TiO_2(Zn-TiO_2)$coatings on Ti surface, and the a mount of Zn introduced in to the coatings can be optimized by altering the electrolyte composition. In this study, corrosion behavior of Ti-6Al-4V alloy after plasma electrolytic oxidation in solutions containing Ca, P and Zn were studied by scanning electron microscopy (SEM), AC impedance, and potentiodynamic polarization test. A series of $Zn-TiO_2$ coatings are produced on Ti dental implant using PEO, with the substitution degree, respectively, at 0, 5, 10 and 20%. The potentiodynamic polarization and AC impedance tests for corrosion behaviors were carried out in 0.9% NaCl solution at similar body temperature using a potentiostat with a scan rate of 1.67mV/s and potential range from -1500mV to +2000mV. Also, AC impedance was performed at frequencies ranging from 10MHz to 100kHz for corrosion resistance.

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Preparation and Biocompatibility of 6-amino-6-deoxychitosan for Immobilization of Epidermal Growth Factor (세포성장인자 고정화를 위한 6-amino-6-deoxychitosan의 제조와 생체적합성)

  • Son, Tae Il;Park, Se Hoon;Kang, Hahk Soo;Jang, Eui Chan
    • Applied Chemistry for Engineering
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    • v.16 no.2
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    • pp.226-230
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    • 2005
  • Chitosan derivatives, 6-amino-6-deoxychitosan (6A6DC) was successively prepared as a reactive carbohydrate for the stabilization of epidermal growth factor (EGF) by the reactions of chitosan with tosyl chloride, sodium azide, and lithium aluminum tetrahydride. The structure of 6A6DC was confirmed by EA, FT-IR, $^1H-NMR$ and $^{13}C\{^1H\}-NMR$. The degree of substitution (ds) of amino groups in 6A6DC was determined to be 0.7. 6A6DC did not show any cytotoxicity on the normal human dermal fibroblast (NHDF) proliferation at least in the range tested (0.3 g/mL 600 g/mL) and was considered as a suitable material for the stabilization of EGF against proteolytic degradation due to its non-cytotoxicity and high reactivity.

Ammonium Adsorption Property of Acrylic Acid and Styren Grafting Polypropylene Non-Woven Fabric Synthesized by Photo-induced Polymerization (광조사 중합법에 의해 합성된 PP-g-AA와 PP-g-St 부직포의 암모니아성 질소 흡착특성 비교)

  • Park, Hyun-Ju;Na, Choon-Ki
    • Journal of Environmental Science International
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    • v.17 no.11
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    • pp.1255-1263
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    • 2008
  • The efficiency of PP-g-AA and PP-g-St nonwoven fabric synthesized by photoinduced polymerization as an adsorbent for removal $NH_3-N$ from waste water was evaluated. The results evidently indicate that the adsorption capacities of $NH_3-N$ onto PP-g-AA nonwoven fabric were extremely superior to those onto sulfonated PP-g-St nonwoven fabric, PK and zeolite. PP-g-AA nonwoven fabric showed the maximum adsorption capacity of $NH_3-N$ at the degree of grafting of 80 wt.%. The adsorption behaviour of $NH_3-N$ onto PP-g-AA and sulfonated PP-g-St nonwoven fabric was controlled by an ion exchange reaction, and tended to be similar to both trends of Langmiur and Freundlish isotherm. Futhermore, PP-g-AA non-woven fabric could be regenerated more than 5 times by a simple washing with 0.1N HCl with no decrease of adsorption capacity and no degradation of physical properties. Also sulfonated PP-g-St nonwoven fabric could be regenerated by washing with 0.1N ${H_2}{O_4}$. However, their regeneration efficiency was significantly low because grafting layer acted as functional radical for adsorption was continuously desquamated in the adsorption or regeneration processes, which resulted in decrease of adsorption capacity and weight of adsorbent. All results obtained from this study indicate that the $NH_3-N$ removal capacity of PP-g-AA non-woven fabric was extremely superior to those of PP-g-St non-woven fabric, PK and zeolite.

Landscape changes in suburban villages resulting from plant locations (공장입지에 따른 대도시 근교지역 농촌마을의 경관변화 특징)

  • Son, Yong-Hoon;Lee, Cha-Hee;Saito, Yukihiko
    • Journal of Korean Society of Rural Planning
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    • v.20 no.1
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    • pp.13-26
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    • 2014
  • The purpose of this study is to identify characteristics of the landscape changes in Gwangjyu city and Icheon city, the suburban areas on the outskirts of the Seoul metropolitan area, by focusing on the causes of the urban sprawl and the resultant morphological characteristics of landscape degradation. Particular attention has been given to the 'advantages for developing suburb including geographical proximity and land price', 'institutional regulation such as land-use regulation' and 'community solidarity' as drivers for possible introduction of external factors. The types of landscape change were divided into three, after having on-the-ground research on eleven chosen towns and interviews with head of a village: Overwhelming Change, Separated and Small-Scale Change. It was found that, in general, the quality of landscape was best for the small-scale change type, followed by separated and overwhelming change types. While the types of landscape change are correlated with the geographical proximity, its relevance with land regulation is relatively weak. The study found that imposing a land-use regulation as a means to prevent changes in suburban village landscape may not be fully effective. Also it analyzed that villages could better manage with keen interest the surrounding landscape if there is a high degree of solidarity within the village community. Therefore, the sense of community could play an important complementary role to land-use regulation which does not suffice in itself to manage suburban landscape.

Physical Properties and Morphology of Carbon Nanotubes Prepared by Thermal and Plasma CVD of Acetylene (아세틸렌의 열 및 플라즈마 CVD법으로 제조한 탄소나노튜브의 물성과 구조적 특성)

  • Kim, Myung-Chan;Moon, Seung-Hwan;Lim, Jae-Seok;Hahm, Hyun-Sik;Kim, Myung-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.21 no.2
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    • pp.174-181
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    • 2004
  • Multi-walled carbon nanotubes (CNTs) were prepared by thermal chemical vapor deposition (CVD) and microwave plasma chemical vapor deposition (MPCVD) using various combination of binary catalysts with four transition metals such as Fe, Co, Cu, and Ni. In the preparation of CNTs from acetylene precursor by thermal CVD, the CNTs with very high yield of 43.6 % was produced over $Fe-Co/Al_2O_3$. The highest yield of CNTs was obtained with the catalyst reduced for 3 hr and the yield was decreased with increasing reduction time to 5 hr, due to the formation of $FeAl_2O_4$ metal-aluminate. On the other hand, the CNTs prepared by acethylene plasma CVD had more straight, smaller diameter, and larger aspect ratio(L/D) than those prepared by thermal CVD, although their yield had lower value of 27.7%. The degree of graphitization of CNTs measured by $I_d/I_g$ value and thermal degradation temperature were 1.04 and $602^{\circ}C$, respectively.

Stabilization of Solid Waste in Lysimeter by Air Injection Mode (공기주입 방식을 이용한 매립모형조내 폐기물 안정화)

  • Kim, Kyung;Park, Joon-Seok;Lee, Hwan;Lee, Cheol-Hyo;Kim, Joung-Dae
    • Journal of Environmental Health Sciences
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    • v.31 no.1
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    • pp.15-22
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    • 2005
  • This study was conducted to evaluate air injection mode on stabilization of solid waste in lysimeter. For three lysimeters, one was maintained under anaerobic condition as control, and air was injected into two lysimeters in continuous mode (atmospheric pressure) and intermittent mode (high pressure of 2 bar). Distilled water was sprayed over solid waste in 1.4 l/$m^3$(solid waste)/day, supposing rainfall intensity of 1,200 mm/yr and 30% infiltration. Oxygen in landfill gas was not detected in control lysimeter during operational days. After 30 day-aeration, oxygen concentrations of continuous and intermittent modes were maintained in 14% and 6%, respectively. $COD_{Cr}$ removal efficiencies of continuous and intermittent modes were about 70% and 50%, and BOD5 removal efficiencies were about 80% and 20%, respectively. In view of oxygen supply, and $COD_{Cr}$ and $BOD_5$ removal, continuous air injection mode of atmospheric pressure was more effective than intermittent mode of 2 bar. Settling degree of solid waste in case of two air injection modes was 3 times higher than that of anaerobic condition as control. Considering the above results, it was thought that air injection (especially continuous atmospheric pressure) could improve degradation of solid waste and induce preliminary stabilization in landfill site.

Relationship between Molecular Structure of Acid-Hydrolyzed Rich Starch and Retrogradation (산처리 쌀전분의 분자구조와 노화속도)

  • Kang, Kil-Jin;Kim, Kwan;Lee, Sang-Kyu;Kim, Sung-Kon
    • Korean Journal of Food Science and Technology
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    • v.29 no.5
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    • pp.876-881
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    • 1997
  • The relationship between the molecular structure of acid-hydrolyzed rice starch and the retrogradation rate of starch gel was investigated. The molecular structure of starch was modified by acid hydrolysis with 1 N HCl at $35^{\circ}C$. The molecular weight of starch decreased as acid hydrolysis time was increased. At the early stage of hydrolysis up to 3 hr, the branching point of amylopectin was degraded and thereafter both ${\alpha}-1,4\;and\;{\alpha}-1,6$ linkages were hydrolyzed. The starch gel (50%) stored at $20^{\circ}C$ revealed that the rapid retrogradation occurred during 4 hr of storage which was more pronounced as the hydrolysis time increased. The degree of retrogradation of starch gels after 4 hr storage showed a linear relationship with the yield of hydrolyzate. These results suggested that the retrogradation of starch gel was accelerated by degradation of ${\alpha}-1,6$ linkages with acid.

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Ultrastructural Changes of Hair Treated with Bleaching Agent (탈색된 머리카락의 미세구조적 변화)

  • Chang, Byung-Soo;Lee, Gwi-Yeong
    • Applied Microscopy
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    • v.36 no.1
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    • pp.25-33
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    • 2006
  • This study applied a bleaching agent. which is commonly used in the beauty salons, to the hair of normal adult women, collected the hair immediately and 10 days and 20 days from the bleaching, were investigated the degree of degradation of the hair by using scanning and transmission electron microscopes. The surface of hair just after bleaching was observed to be similar to that of normal hair, showing no split or damage of scale. In the hair of 10 days after bleaching, however, the scale came off. From this time, scale on the cuticular layer of hair began to be separated. In 10 days from bleaching, the scale on the cuticular layer was separated from hair and some cytoplasm of cuticular cells was broken into pieces or fell off. The cell remains made the surface coarse and uneven. At this period, damaged scales had a sharp end. In the hair of 20 days after bleaching, scale fell off from the whole surface of the hair and the surface looked rough. On the bleached hair, many vacuoles were formed in the endocuticle of cuticular cells. As a result, deformation caused by the formation of vacuoles in cuticles broke up the cuticular cells.

Dynamic punching shear tests of flat slab-column joints with 5D steel fibers

  • Alvarado, Yezid A.;Torres, Benjamin;Buitrago, Manuel;Ruiz, Daniel M.;Torres, Sergio Y.;Alvarez, Ramon A.
    • Structural Engineering and Mechanics
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    • v.81 no.3
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    • pp.281-292
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    • 2022
  • This study aimed to analyze the dynamic punching shear performance of slab-column joints under cyclic loads with the use of double-hooked end (5D) steel fibers. Structural systems such as slab-column joints are widely found in infrastructures. The susceptibility to collapse of such structures when submitted to seismic loads is highly dependent on the structural performance of the slab-column connections. For this reason, the punching capacity of reinforced concrete (RC) structures has been the subject of a great number of studies. Steel fibers are used to achieve a certain degree of ductility under seismic loads. In this context, 5D steel hooked fibers provide high levels of fiber anchoring, tensile strength and ductility. However, only limited research has been carried out on the performance under cyclic loads of concrete structural members containing steel fibers. This study covers this gap with experimental testing of five different full-scale subassemblies of RC slab-column joints: one without punching reinforcement, one with conventional punching reinforcement and three with 5D steel fibers. The subassemblies were tested under cyclic loading, which consisted of applying increasing lateral displacement cycles, such as in seismic situations, with a constant axial load on the column. This set of cycles was repeated for increasing axial loads on the column until failure. The results showed that 5D steel fiber subassemblies: i) had a greater capacity to dissipate energy, ii) improved punching shear strength and stiffness degradation under cyclic loads; and iii) increased cyclic loading capacity.

Performance Evaluation of Efficient Vision Transformers on Embedded Edge Platforms (임베디드 엣지 플랫폼에서의 경량 비전 트랜스포머 성능 평가)

  • Minha Lee;Seongjae Lee;Taehyoun Kim
    • IEMEK Journal of Embedded Systems and Applications
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    • v.18 no.3
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    • pp.89-100
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    • 2023
  • Recently, on-device artificial intelligence (AI) solutions using mobile devices and embedded edge devices have emerged in various fields, such as computer vision, to address network traffic burdens, low-energy operations, and security problems. Although vision transformer deep learning models have outperformed conventional convolutional neural network (CNN) models in computer vision, they require more computations and parameters than CNN models. Thus, they are not directly applicable to embedded edge devices with limited hardware resources. Many researchers have proposed various model compression methods or lightweight architectures for vision transformers; however, there are only a few studies evaluating the effects of model compression techniques of vision transformers on performance. Regarding this problem, this paper presents a performance evaluation of vision transformers on embedded platforms. We investigated the behaviors of three vision transformers: DeiT, LeViT, and MobileViT. Each model performance was evaluated by accuracy and inference time on edge devices using the ImageNet dataset. We assessed the effects of the quantization method applied to the models on latency enhancement and accuracy degradation by profiling the proportion of response time occupied by major operations. In addition, we evaluated the performance of each model on GPU and EdgeTPU-based edge devices. In our experimental results, LeViT showed the best performance in CPU-based edge devices, and DeiT-small showed the highest performance improvement in GPU-based edge devices. In addition, only MobileViT models showed performance improvement on EdgeTPU. Summarizing the analysis results through profiling, the degree of performance improvement of each vision transformer model was highly dependent on the proportion of parts that could be optimized in the target edge device. In summary, to apply vision transformers to on-device AI solutions, either proper operation composition and optimizations specific to target edge devices must be considered.