• Title/Summary/Keyword: degree of degradation

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Investigation of Degradation Mechanism of High Alumina Refractory in a Coal Gasifier (석탄 가스화기에서의 고알루미나 내화물의 손상 기구 규명)

  • Kim, Yuna;Lee, Jae Goo;Oh, Myongsook S.
    • Applied Chemistry for Engineering
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    • v.20 no.6
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    • pp.638-645
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    • 2009
  • High alumina refractory used in a coal gasifier was analyzed and the degradation mechanism by molten slag was investigated. The depth of refractory severely damaged by slag varied between 12~40 mm, including the adhered slag layer. The sample also showed the cracks formed in parallel to the slag/refractory interface. The degree of degradation varied with the micro-structures in the refractory. Fused alumina grains showed the uneven boundary and pore formation just along the edges, while the tablet alumina showed the slag penetrated between sintered alumina around which the formation of Al-Fe phase was observed. Calcium aluminate cements were not observed at the high temperature zone near the slag/refractory interface, probably due to dissolution into molten slag. Around large grains of alumina, rod shape alumina, which appeared to be recrystallized during cooling, were observed, and large pores were also formed around those grains. Therefore, in high alumina refractories, hot molten slag dissolves the bonding phase and rod-shape alumina phase is recrystallized upon cooling. During this process, cracks are developed due to structural change, and the degradation occurs by physical causes such as structural spalling.

Effects of Synchronicity of Carbohydrate and Protein Degradation on Rumen Fermentation Characteristics and Microbial Protein Synthesis

  • Seo, J.K.;Kim, M.H.;Yang, J.Y.;Kim, H.J.;Lee, C.H.;Kim, K.H.;Ha, Jong K.
    • Asian-Australasian Journal of Animal Sciences
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    • v.26 no.3
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    • pp.358-365
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    • 2013
  • A series of in vitro studies were carried out to determine i) the effects of enzyme and formaldehyde treatment on the degradation characteristics of carbohydrate and protein sources and on the synchronicity of these processes, and ii) the effects of synchronizing carbohydrate and protein supply on rumen fermentation and microbial protein synthesis (MPS) in in vitro experiments. Untreated corn (C) and enzyme-treated corn (EC) were combined with soy bean meal with (ES) and without (S) enzyme treatment or formaldehyde treatment (FS). Six experimental feeds (CS, CES, CFS, ECS, ECES and ECFS) with different synchrony indices were prepared. Highly synchronous diets had the greatest dry matter (DM) digestibility when untreated corn was used. However, the degree of synchronicity did not influence DM digestibility when EC was mixed with various soybean meals. At time points of 12 h and 24 h of incubation, EC-containing diets showed lower ammonia-N concentrations than those of C-containing diets, irrespective of the degree of synchronicity, indicating that more efficient utilization of ammonia-N for MPS was achieved by ruminal microorganisms when EC was offered as a carbohydrate source. Within C-containing treatments, the purine base concentration increased as the diets were more synchronized. This effect was not observed when EC was offered. There were significant effects on VFA concentration of both C and S treatments and their interactions. Similar to purine concentrations, total VFA production and individual VFA concentration in the groups containing EC as an energy source was higher than those of other groups (CS, CES and CFS). The results of the present study suggested that the availability of energy or the protein source are the most limiting factors for rumen fermentation and MPS, rather than the degree of synchronicity.

Characteristics of odorous VOCs removal by using electrolytic oxidant (전해 산화제에 의한 악취 원인 VOCs 제거 특성)

  • Lee, Tae Ho;Ryu, Hee Wook
    • Journal of odor and indoor environment
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    • v.17 no.4
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    • pp.381-388
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    • 2018
  • In this study, various conditions and phenomena that occur in the process of removing odorous VOCs by using electrolyzed oxidant were examined. The formation of hypochlorous acid, which is an oxidant produced by electrolysis, was investigated and the properties of the oxidizing agent used to decompose toluene, xylene, and cyclohexane were investigated. As a result, it was found that the production rate and the final concentration of the oxidizing agent increased with the current density. It was found that the degree of removal varies depending on the property of each pollutant. Interestingly, in the batch experiments in which the pH of the produced oxidant was controlled, it was found that the degree of elimination varied depending on the pH of the substance. These results suggest that the difference in the concentration and distribution of hypochlorous acid (HOCl) and hypochlorite ($OCl^-$) due to the pH change leads to the difference in oxidizing power on the oxidation characteristics of each substance. Styrene and terpineol showed better degradation characteristics than toluene and xylene in odorous VOC removal experiments by spraying electrolytic oxidant using a lab-scale continuous reactor. In conclusion, the removal of odorous VOCs by the electrolytic oxidant can have various applications in that it can oxidize pollutants of various spectra.

A study on the performance of various BIPV modules applied in a real building demonstration (BIPV시스템의 건물적용 실증에 대한 구성요소별 발전성능 분석)

  • Lee, Sang-Moon;Huh, Jung-Ho
    • Journal of the Korean Solar Energy Society
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    • v.36 no.2
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    • pp.53-63
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    • 2016
  • Building Integrated Photovoltaic (BIPV) is one of the best ways to generate electric power using the solar energy, which is clean and inexhaustible energy resources. The most of BIPV modules have the form of GtoG (Glass to Glass) photovoltaic in building applications. Degradation leading to failure in photovoltaic modules is very important factor in BIPV modules. This paper analyzed the performance of various BIPV modules through outdoor exposure tests. Performance of three BIPV modules(c-Si type, a-Si type and DSSC type) with three installation angles influenced by sun light, outdoor temperature, and wind velocity was monitored and analyzed. As a result, c-Si type BIPV module outperforms other BIPV modules(a-Si type). In terms of power efficiency of the module, the installed angle of $45^{\circ}$ is better than others(90 degree, 0 degree). In addition, more realistic data of various BIPV system performance could be available through the field test and integrated building test. In this study, relationship of the BIPV system is identified module's installation angle, power generation, architectural performance, etc.

An Efficient Feature Point Extraction Method for 360˚ Realistic Media Utilizing High Resolution Characteristics

  • Won, Yu-Hyeon;Kim, Jin-Sung;Park, Byuong-Chan;Kim, Young-Mo;Kim, Seok-Yoon
    • Journal of the Korea Society of Computer and Information
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    • v.24 no.1
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    • pp.85-92
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    • 2019
  • In this paper, we propose a efficient feature point extraction method that can solve the problem of performance degradation by introducing a preprocessing process when extracting feature points by utilizing the characteristics of 360-degree realistic media. 360-degree realistic media is composed of images produced by two or more cameras and this image combining process is accomplished by extracting feature points at the edges of each image and combining them into one image if they cover the same area. In this production process, however, the stitching process where images are combined into one piece can lead to the distortion of non-seamlessness. Since the realistic media of 4K-class image has higher resolution than that of a general image, the feature point extraction and matching process takes much more time than general media cases.

Electron Beam-induced Crosslinking and Characterization of Polycaprolactone Films in the Presence of Various Crosslinking Agents

  • Kang, Dong-Woo;Jung, Chan-Hee;Hwang, In-Tae;Choi, Jae-Hak;Nho, Young-Chang
    • Journal of Radiation Industry
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    • v.5 no.2
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    • pp.107-112
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    • 2011
  • Electron beam-induced crosslinking of polycaprolactone (PCL) films containing various crosslinking agents (CAs) was investigated in this study. PCL films containing various CAs prepared by a solution casting method were irradiated by electron beams at various absorption doses and the irradiated PCL films were investigated in terms of their crosslinking degree, thermal and mechanical properties, and biodegradability. Based on the results of the crosslinking degree measurement, triallyl isocyanurate was found to be most effective for the electron-beam induced crosslinking of PCL films. The results of the UTM, DMA, and TMA revealed that the thermal and mechanical properties of the crosslinked PCL films were greatly improved in comparison to those of the pure PCL. The results of the enzymatic degradation test revealed that the biodegradability of the crosslinked PCL films was reduced in comparison to that of the pure PCL.

Sensitivity to Intergranular Corrosion According to Heat Treatment of 304L Stainless Steel (304L 스테인리스강의 열처리에 따른 입계부식민감도 연구)

  • Jang, Hyung-Min;Kim, Dong-Jin;Kim, Hong-Pyo
    • Corrosion Science and Technology
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    • v.19 no.1
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    • pp.37-42
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    • 2020
  • Even though 304 low-carbon (304L) stainless steel was developed to enhance the resistance to intergranular corrosion and stress corrosion cracking, it is occasionally subject to degradation in harsh environments. The degree of sensitization (DOS) of 304L stainless steel was studied as a function of sensitization using a double-loop electrochemical potentiokinetic reactivation (DL-EPR) method. Sensitizing heat treatment was performed in an Ar atmosphere at 500℃, 600℃, and 700℃, with heat treatment times varying from 0 to 96 h. DOS was measured by the ratio of the peak current density value of the forward scan to that of the reverse scan. After the EPR experiment, the specimen surface was observed by scanning electron microscopy and energy dispersive spectroscopy. The DOS of the specimens heat-treated at 600℃ increased with heat treatment times up to 48 h and then decreased due to a self healing effect. The DOS was higher in specimens heat-treated at 600℃ than those at 500℃ or 700℃. Corrosion of the sensitized specimens occurred mainly at the δ-γ phase boundary. The corrosion morphology at the δ-γ phase boundary changed with sensitizing heat-treatment conditions due to differences in chromium activity in γ austenite and δ ferrite.

Comparative Performance Evaluation by Winter Apartment Temperature on the Outer Surface of the Insulation (동계 아파트 외표면 온도에 의한 단열성능 비교평가)

  • Park, Jung-Hun;Kim, Bong-Joo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.17 no.4
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    • pp.91-100
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    • 2013
  • This research is to measure and analyze the thermal performance of the apartment structure and to evaluate and establish standards of thermal insulation defect in order to make the basic data necessary for determining the degree of the thermal performance degradation and for repairing and reinforcing the exterior wall of the existing apartment. Furthermore, it is to predict the part of occurrence of the thermal bridge and condensation at the apartment building structure. On the other one hand, it is also to analyze the degree of thermal insulation performance according to the standards of thermal insulation and elapsed time, through the analysis by the workability of concrete.

Analysis of Phase Noise Effects in Transceiver Diversity Systems (송수신 다이버시티 시스템에서의 위상잡음 영향 분석)

  • Lee Seung-Ryong;Lee Jong-Gil
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2006.05a
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    • pp.643-646
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    • 2006
  • The popularity of OFDM systems is being increased because of high speed data transmission capability and the spectral efficiency characteristics. However, since OFDM systems are very sensitive to the phase noise, The interference among subcarriers and the total system noise can be increased seriously due to the degree of phase noise effects which can cause the orthogonality problems. Therefore, these phase noise effects were analyzed using the phase noise model by varying its parameters. Especially in this paper, The degree of system performance degradation was investigated for the OFDM systems applying the relatively simple transmit and receiver diversity.

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Static behavior of stud shear connectors with initial damage in steel-UHPC composite bridges

  • Qi, Jianan;Tang, Yiqun;Cheng, Zhao;Xu, Rui;Wang, Jingquan
    • Advances in concrete construction
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    • v.9 no.4
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    • pp.413-421
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    • 2020
  • For steel-concrete girders made composite using shear studs, initial damage on studs induced by weld defect, unexpected overloading, fatigue and others might degrade the service performance and even threaten the structural safety. This paper conducted a numerical study to investigate the static behavior of damaged stud shear connectors that were embedded in ultra high performance concrete (UHPC). Parameters included damage degree and damage location. The material nonlinear behavior was characterized by multi-linear stress-strain relationship and damage plasticity model. The results indicated that the shear strength was not sensitive to the damage degree when the damage occurred at 2/3d (d is the stud diameter) from the stud root. An increased stud area would be engaged in resisting shear force as the distance of damage location from stud root increased and the failure section becomes inclined, resulting in a less reduction in the shear strength and shear stiffness. The reduction factor was proposed to consider the degradation of the shear strength of the damaged stud. The reduction factor can be calculated using two approaches: a linear relationship and a square relationship with the damage degree corresponding to the shear strength dominated by the section area and the nominal diameter of the damaged stud. It was found that the proposed method is preferred to predict the shear strength of a stud with initial damage.