• Title/Summary/Keyword: degradation experiment

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In Sacco Ruminal Degradation Characteristics of Chemical Components in Fresh Zoysia japonica and Miscanthus sinensis Growing in Japanese Native Pasture

  • Ogura, S.;Kosako, T.;Hayashi, Y.;Dohi, H.
    • Asian-Australasian Journal of Animal Sciences
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    • v.14 no.1
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    • pp.41-47
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    • 2001
  • Ruminal degradation characteristics of dry matter (DM), neutral detergent fiber (NDF) and crude protein (CP) in fresh leaves of two Japanese native grasses (Zoysia japonica and Miscanthus sinensis) and one sown temperate grass (Dactylis glomerata) were investigated by an in sacco method in spring (mid-May), summer (mid-July) and autumn (mid-September). Japanese native grasses had higher NDF and lower CP concentrations than D. glomerata, and the CP concentration in native grasses decreased in autumn. Ruminal degradability of DM, NDF and CP was lower in native grasses than in D. glomerata (p<0.05) in all seasons. DM and NDF degradability decreased in summer for Z. japonica and D. glomerata, while it decreased in autumn for M. sinensis. CP degradability in Z. japonica was constant throughout the seasons, whereas that in M. sinensis greatly decreased in summer and autumn (p<0.05). It was concluded that Z. japonica could stably supply ruminally digestible nutrients for grazing animals in Japanese native pasture. However, the degradation characteristics of freshly chopped native grasses did not fit the exponential model of $D=a+b(1-e^{-ct})$ proposed by Ørskov and McDonald.

Effect of Unsaturated Fatty Acids on Cellulose Degradation and Fermentation Characteristics by Mixed Ruminal Microbes

  • Hwang, I.H.;Kim, H.D.;Shim, S.S.;Lee, Sang S.;Ha, J.K.
    • Asian-Australasian Journal of Animal Sciences
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    • v.14 no.4
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    • pp.501-506
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    • 2001
  • This experiment was conducted to evaluate the effects of supplemental unsaturated fatty acids (UFA) on fermentation characteristics, especially on gas production, cellulose degradation and volatile fatty acid (VFA) concentration by mixed ruminal microorganisms. In order to attain this objective, unsaturated fatty acids including oleic acid (C 18:1), linoleic acid (C18:2) and arachidonic acid (C22:4) were added at varying level. Mixed ruminal microbes used in this experiment were obtained from the rumen of a cannulated Holstein cow. Medium pH values after 7 d incubation were significantly affected by type and level of unsaturated fatty acids (p<0.01). All of UFA inhibited total gas production, and especially treatment of arachidonic acid at the levels of 0.01% gave the lowest gas. production after 7 d incubation (p<0.01). Comparison of the population of protozoa revealed that UFA did not have any significant effect on the total protozoa number. The addition of UFA did not effect dry matter degradation. Volatile fatty acid (VFA) composition of the culture was influenced little by UFA, although the considerable amount of iso-type VFA were detected in UFA supplemented incubations. The ratio of acetic acids to propionic acids, however, was lower than control in all the treatments after 7 d incubation (p<0.01).

Degradation of methyl orange by pulsed corona discharges in aqueous solution (수중 펄스코로나 방전에 의한 메틸오렌지 제거 특성)

  • Lee, Hyeon-Don;Kim, Jong-Oh;Kim, Hyoung-Kab;Chung, Jae-Woo
    • Journal of Korean Society of Water and Wastewater
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    • v.26 no.1
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    • pp.69-76
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    • 2012
  • A laboratory experiment on methyl orange degradation in pulsed corona discharges was carried out. Effects of operating parameters such as applied voltage, pH, conductivity and initial concentration on methyl orange degradation were investigated. The pulsed corona discharges decreased the pH of solution and increased conductivity, probably due to products generated from methyl orange degradation by corona discharges. The decrease of initial pH enhanced the methyl orange degradation. The methyl orange degradation was fastest in $100{\mu}S/cm$ conductivity solution, followed by 50 and $200{\mu}S/cm$, indicating that $100{\mu}S/cm$ is the most favorable in the aspect of radical generation among the experimented conditions. The methyl orange of initial concentration from 20 to 60mg/L was effectively degraded in pulsed corona discharges. The lower initial concentration of methyl orange, the faster degradation was observed.

The Improvement and Diagnosis of DC Degradation Properties with The Equivalent-Circuit Analysis of ZnO Varistors (ZnO 바리스터의 등가회로 분석을 통한 DC 열화특성의 향상과 진단)

  • So, Soon-Jin;Kim, Deok-Kyu;Kim, Young-Jin;So, Byung-Moon;Park, Choon-Bae
    • Proceedings of the KIEE Conference
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    • 1999.11d
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    • pp.978-980
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    • 1999
  • In this paper, DC degradation of ZnO varistor sintered in the atmospheres of nitrogen and oxygen was investigated. The content of $SiO_2$ containing 0.0, 0.2, 0.5 mol% respectively was addicted for the improvement of degradation property. ZnO varistor was fabricated in the special electrical furnace which had the vacuum system. The temperature and the voltage for the DC degradation test were $115{\pm}2^{\circ}C$, $0.85V_{1mA/cm^2}$. The time conditions for this test were 0, 2, 4, 8 hours and Current-voltage analysis is used to determine nonlinear coefficients($\alpha$). Frequency analysis are accomplished for the understanding of electrical properties as DC degradation test. In this experiment, We concluded that nonlinear coefficient decreased as the amount of $SiO_2$ addition increased, but degradation rate coefficient increased as the amount of $SiO_2$ addition increased. Also, degradation test with the analysis of equivalent circuit showed that the degradation phenomenon of ZnO varistor wasn't linearity.

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Electrochemical Degradation of Benzoquinone in a Flow through Cell with Carbon Fibers

  • Yoon, Jang-Hee;Yang, Jee-Eun;Shim, Yoon-Bo;Won, Mi-Sook
    • Bulletin of the Korean Chemical Society
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    • v.28 no.3
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    • pp.403-407
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    • 2007
  • The anodic degradation of benzoquinone(BQ), a model compound for wastewater treatment was carried out using a home-made flow-through electrochemical cell with carbon fibers. To optimize the controlled current electrolysis condition of an aqueous BQ solution, the experimental variables affecting the degradation of BQ, such as the applying current, pH, reaction time, and flow rate of the BQ solution were examined. The degradation products of the oxidation reaction were identified by High Performance Liquid Chromatography and Inductively Coupled Plasma Atomic Emission Spectrometer. Low molecular weight aliphatic acids, and CO2 were the major products in this experiment. The removal efficiency of BQ from the solution increased with the applying current and time. 99.23% of 1.0 × 10-2 M BQ was degraded to aliphatic acids and CO2 when the applying current is 175 mA in a 12 hr electrolysis.

A Novel Oxidation Model with Photolysis for Degradation of Trichlorobenzenes (TCBs)

  • Kim, Jae-Hyoun
    • Environmental Analysis Health and Toxicology
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    • v.12 no.3_4
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    • pp.1-13
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    • 1997
  • First- and second-order kinetic oxidation rates of trichlorobenzenes (TCBs) were obtained and compared by a chemical activation system (CAS) which mimics mixed functional oxidase activity. The system consists of EDTA, ferrous sulfate, ascorbic acid, and $H_2O_2$ in potassium phosphdte buffer (monobasic at pH 7.4). The rate of transformation in CAS was enhanced in the presence and absence of catalase in the sequence 1, 2, 3-TCB < 1, 2, 4-TCB < 1, 3, 5-TCB. In general, the rates of degradation were greater in the test media with catalase. The effect of photolysis on the degradation of the TCBs with the CAS were examined. Sensitized photolysis with nitrite, Fenton's reagent, TiO$_2$ and triethylamine (TEA) studied in concert with the CAS demonstrated significant enhancement of the degradation rate of TCBs. Disappearance rates of TCBs in CAS with prior photolysis or prior photosensitization were at least 10-fold higher than the sum of the rate for each single experiment. This study proves that the combination of the CAS and photolysis can be used as a suitable technique for enhancing degradation of TCBs in aqueous systems.

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An Experimental Study on the Degradation of Polymer in Closed Flow System (밀폐계 유동시스템내에서 고분자물질의 퇴화에 관한 실험적 연구)

  • 김재근
    • Journal of Advanced Marine Engineering and Technology
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    • v.23 no.5
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    • pp.679-686
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    • 1999
  • This study is to investigate the effect of a substantial drag reduction caused by the polymer(A611P) when the working fluids flow to the vertical direction in the vertical cylindrical equipment of closed flow system. The drag reduction is associated with the mechanical degrada-tion thermal degradation and heat transfer. By ignore the heat fluxs within the closed system the pressure drop due to the polymer concentration the flow velocity and flow time have been mea-sured. By taking into account the mechanical and thermal degradation in the closed system an experiment has been focused on the determination of the condition which could improve the pump capacity in the heat union electric power plant. Under the condition of non-boiling it has been found out that the change of heat flux has little influence on the drag reduction.

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Yield survey and nutritional evaluation of garlic stalk for ruminant feed

  • Lee, Y.H.;Kim, Y.I.;Oh, Y.K.;Ahmadi, F.;Kwak, W.S.
    • Journal of Animal Science and Technology
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    • v.59 no.10
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    • pp.22.1-22.7
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    • 2017
  • Background: Very limited information exists on the ruminal degradation kinetics of nutrients in garlic stalk. The present study aimed to survey the annual yield of garlic stalk in Korea and determine its feed-nutritive value for ruminants. Methods: In Experiment 1, garlic stalk was incubated in situ in the rumen of two Hanwoo steers ($360{\pm}15kg$ body weight) and removed after 12, 24, or 48 h to determine the ruminal degradation kinetics of DM and NDF. Rice straw was also included for comparison. In Experiment 2, In Experiment 2, six male Corriedale sheep were randomized to two dietary treatments to determine the apparent digestibility of nutrients in garlic stalk. Diets included a control ration without garlic stalk (60% concentrate mix +40% ryegrass) or a treatment ration (70% control diet +30% garlic stalk). Results: The Korean national yield of garlic stalk (sun-dried basis) in 2016 was estimated to be 31,910 tons, with the southern coastal regions producing the highest quantity. Compared with rice straw, garlic stalk had lower NDF, higher ADF, and greater effective degradabilities of DM and NDF, resulting in a greater TDN value (56.3%), which was higher than that obtained for rice straw (43.7%). Conclusion: These results provide basic information on the ruminal DM and NDF degradation kinetics of garlic stalk, which would be helpful for the efficient utilization of this by-product in ruminant diets

Effect of Evaluation Conditions on Electrochemical Accelerated Degradation of PEMFC Polymer Membrane (PEMFC 고분자 막의 전기화학적 가속 열화에 미치는 평가조건들의 영향)

  • Sohyeong Oh;Donggeun Yoo;Suk Joo Bae;Sun Geu Chae;Kwonpil Park
    • Korean Chemical Engineering Research
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    • v.61 no.3
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    • pp.356-361
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    • 2023
  • In order to improve the durability of the proton exchange membrane fuel cell (PEMFC), it is important to accurately evaluate the durability of the polymer membrane in a short time. The test conditions for chemically accelerated durability evaluation of membranes are high voltage, high temperature, low humidity, and high gas pressure. It can be said that the protocol is developed by changing these conditions. However, the relative influence of each test condition on the degradation of the membrane has not been studied. In chemical accelerated degradation experiment of the membrane, the influence of 4 factors (conditions) was examined through the factor experiment method. The degree of degradation of the membrane after accelerated degradation was determined by measuring the hydrogen permeability and effluent fluoride ion concentration, and it was possible to determine the degradation order of the polymer membrane under 8 conditions by the difference in fluoride ion concentration. It was shown that the influence of the membrane degradation factor was in the order of voltage > temperature > oxygen pressure > humidity. It was confirmed that the degradation of the electrode catalyst had an effect on the chemical degradation of the membrane.

Study on the Tracking Characteristics Depending on Accelerated Degradation of PVC Insulation Material (PVC 절연재료의 가속열화에 따른 트래킹 특성에 관한 연구)

  • Choi, Su-Gil;Kim, Si-Kuk
    • Fire Science and Engineering
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    • v.31 no.6
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    • pp.91-98
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    • 2017
  • The present paper is a study on the tracking characteristics depending on accelerated degradation of PVC insulation material. In order to insulation degradation of PVC insulation material, the Arrhenius equation, a type of accelerated degradation test formula, was used to conduct accelerated degradation experiments with experiment samples prepared at the following age equivalents: 0, 10, 20, 30 and 40 years. Afterwards, a tracking experiment was conducted on the accelerated experiment samples as part of the KS C IEC 60112 criteria. When measuring the PVC tracking features according to the accelerated aging, the results showed that when 0.1% of ammonium chloride was added to the PVC insulating material, but no tracking occurred. However, depending on the age equivalent, The results of analyzing the current waveform and voltage waveform of the tracking propagation process showed the age equivalent from 0 years to 40 years displayed a break down in insulation resistance and even the BDB(before dielectric breakdown) sections did not maintain the same functionality of the original material. Based on a criterion of an age equivalent of 0 years, material with an age equivalent of 10 years posed a 1.4 times greater risk, material with an age equivalent of 20 years posed a 2 times greater risk, material with an age equivalent of 30 years posed a 4.6 times greater risk, and material with an age equivalent of 40 years posed a 7 times greater risk.